Quantum Thermal Machines Research Articles

Advances in Photovoltaic Technologies from Atomic to Device Scale

The question of how energy resources can be efficiently used is likewise of fundamental and technological interest. In this opinion, we give a brief overview on developments of harvesting solar energy across different length scales and address some strategies to tackle economic and ecological challenges, in particular with a view to sustainability and toward a circular economy. On the mesoscopic scale, the emergence of thermodynamic laws in open quantum systems is of central importance and how they can be employed for efficient quantum thermal machines and batteries. The broad tunability of band gaps in quantum dot systems makes them attractive for hybrid photovoltaic devices. Complementary, machine learning-aided band gap engineering and the high-throughput screening of novel materials assist with improving absorption characteristics. On the device scale, hybrid concepts of optical control via metasurfaces enable a multitude of functionalities such as a directed re-emission of embedded photoluminescent materials or field enhancement effects from nanostructures. Advanced techniques in computational nanophotonics concern a topology optimization of nanostructured layers together with multiobjective optimization toward specific light management tasks. On the industrial level, modern manufacturers explore 3D printing and flexible solar cell platforms obtained from roll-to-roll technologies. The remote control of solar parks through applications via the Internet of Things opens up new strategies to expand to difficult terrain where human interaction is only required to a limited extent.

Quantum speed limits for observables

In the Schr{\"o}dinger picture, the state of a quantum system evolves in time and the quantum speed limit describes how fast the state of a quantum system evolves from an initial state to a final state. However, in the Heisenberg picture the observable evolves in time instead of the state vector. Therefore, it is natural to ask how fast an observable evolves in time. This can impose a fundamental bound on the evolution time of the expectation value of quantum mechanical observables. We obtain the quantum speed limit time-bound for observable for closed systems, open quantum systems and arbitrary dynamics. Furthermore, we discuss various applications of these bounds. Our results can have several applications ranging from setting the speed limit for operator growth, correlation growth, quantum thermal machines, quantum control and many body physics.

Dynamical control of quantum heat engines using exceptional points

A quantum thermal machine is an open quantum system coupled to hot and cold thermal baths. Thus, its dynamics can be well understood using the concepts and tools from non-Hermitian quantum systems. A hallmark of non-Hermiticity is the existence of exceptional points where the eigenvalues of a non-Hermitian Hamiltonian or a Liouvillian superoperator and their associated eigenvectors coalesce. Here, we report the experimental realization of a single-ion heat engine and demonstrate the effect of Liouvillian exceptional points on the dynamics and the performance of a quantum heat engine. Our experiments have revealed that operating the engine in the exact- and broken-phases, separated by a Liouvillian exceptional point, respectively during the isochoric heating and cooling strokes of an Otto cycle produces more work and output power and achieves higher efficiency than executing the Otto cycle completely in the exact phase where the system has an oscillatory dynamics and higher coherence. This result opens interesting possibilities for the control of quantum heat engines and will be of interest to other research areas that are concerned with the role of coherence and exceptional points in quantum processes and in work extraction by thermal machines.

Quantum heat engine based on a spin-orbit- and Zeeman-coupled Bose-Einstein condensate

We explore the potential of a spin-orbit coupled Bose-Einstein condensate for thermodynamic cycles. For this purpose we propose a quantum heat engine based on a condensate with spin-orbit and Zeeman coupling as a working medium. The cooling and heating are simulated by contacts of the condensate with an external magnetized media and demagnetized media. We examine the condensate ground state energy and its dependence on the strength of the synthetic spin-orbit and Zeeman couplings and interatomic interaction. Then we study the efficiency of the proposed engine. The cycle has a critical value of spin-orbit coupling related to the engine maximum efficiency.

Dynamical heat engines with non-Markovian reservoirs

We discuss whether, and under which conditions, it is possible to realize a heat engine simply by dynamically modulating the couplings between the quantum working medium and thermal reservoirs. For that purpose, we consider the paradigmatic model of a quantum harmonic oscillator, exposed to a minimal modulation, that is, a monochromatic driving of the coupling to only one of the thermal baths. We demonstrate, at any order in the system/bath coupling strength, that in this setup non--Markovianity of the bath is a necessary condition to obtain a heat engine. In addition, we identify suitable structured environments for the engine to approach the ideal Carnot efficiency. Our results open up new possibilities for the use of non--Markovian open quantum systems for the construction and optimization of quantum thermal machines.

Nonlocal quantum heat engines made of hybrid superconducting devices

We discuss a quantum thermal machine that generates power from a thermally driven double quantum dot coupled to normal and superconducting reservoirs. Energy exchange between the dots is mediated by electron-electron interactions. We can distinguish three main mechanisms within the device operation modes. In the Andreev tunneling regime, energy flows in the presence of coherent superposition of zero- and two-particle states. Despite the intrinsic electron-hole symmetry of Andreev processes, we find that the heat engine efficiency increases with increasing coupling to the superconducting reservoir. The second mechanism occurs in the regime of quasiparticle transport. Here we obtain large efficiencies due to the presence of the superconducting gap and the strong energy dependence of the electronic density of states around the gap edges. Finally, in the third regime there exists a competition between Andreev processes and quasiparticle tunneling. Altogether, our results emphasize the importance of both pair tunneling and structured band spectrum for an accurate characterization of the heat engine properties in normal-superconducting coupled dot systems.

Periodically refreshed quantum thermal machines

We introduce unique class of cyclic quantum thermal machines (QTMs) which can maximize their performance at the finite value of cycle duration τ where they are most irreversible. These QTMs are based on single-stroke thermodynamic cycles realized by the non-equilibrium steady state (NESS) of the so-called Periodically Refreshed Baths (PReB) process. We find that such QTMs can interpolate between standard collisional QTMs, which consider repeated interactions with single-site environments, and autonomous QTMs operated by simultaneous coupling to multiple macroscopic baths. We discuss the physical realization of such processes and show that their implementation requires a finite number of copies of the baths. Interestingly, maximizing performance by operating in the most irreversible point as a function of τ comes at the cost of increasing the complexity of realizing such a regime, the latter quantified by the increase in the number of copies of baths required. We demonstrate this physics considering a simple example. We also introduce an elegant description of the PReB process for Gaussian systems in terms of a discrete-time Lyapunov equation. Further, our analysis also reveals interesting connections with Zeno and anti-Zeno effects.

Continuous measurement boosted adiabatic quantum thermal machines

We present a unified approach to study continuous measurement-based quantum thermal machines in static as well as adiabatically driven systems. We investigate both steady-state and transient dynamics for the time-independent case. In the adiabatically driven case, we show how measurement-based thermodynamic quantities can be attributed geometric characteristics. We also provide the appropriate definition for heat transfer and dissipation owing to continuous measurement in the presence and absence of adiabatic driving. We illustrate the aforementioned ideas and study the phenomenon of refrigeration in two different paradigmatic examples: a coupled quantum dot and a coupled qubit system, both undergoing continuous measurement and slow driving. In the time-independent case, we show that quantum coherence can improve the cooling power of measurement-based quantum refrigerators. Exclusively for the case of coupled qubits, we consider linear as well as nonlinear system-bath couplings. We observe that nonlinear coupling produces cooling effects in certain regimes where otherwise heating is expected. In the adiabatically driven case, we observe that quantum measurement can provide significant boost to the power of adiabatic quantum refrigerators. We also observe that the obtained boost can be larger than the sum of power due to individual effects. The measurement-based refrigerators can have similar or better coefficient of performance in the driven case compared to the static one in the regime where heat extraction is maximum. Our results have potential significance for future application in devices ranging from measurement-based quantum thermal machines to refrigeration in quantum processing networks.

Engineering entanglement between resonators by hot environment

Autonomous quantum thermal machines do not require an external coherent drive or work input to perform the desired tasks, making them a promising candidate for thermal management in quantum systems. Here, we propose an autonomous quantum thermal machine in which two uncoupled macroscopic mechanical resonators or microwave resonators achieve considerable entanglement via a hot thermal bath. This becomes possible by coupling the resonators to a common two-level system or third harmonic oscillator and driving it by the hot incoherent thermal bath. The critical step to make the entanglement involves suitable engineering of the hot bath, realized by bath spectrum filtering. Our results suggest that the bath spectrum filtering can be an alternative to typical non-autonomous reservoir engineering schemes to create exotic quantum states.

Theoretical Demonstration of Hot-Carrier Operation in an Ultrathin Solar Cell

Based on a quantum modeling of the electronic transport, this work shows that ultra-thin solar cells can exhibit an improved open-circuit voltage ${V}_{\mathrm{OC}}$, without current reduction. This improvement is obtained when an energy-selective contact is considered between the absorber and the reservoir, and is attributed to a hot-carrier effect. While extraction with a nonselective contact does not generate hot carriers, the use of energy-selective contact induces an increase of carrier temperature up to 130 K and a corresponding ${V}_{\mathrm{OC}}$ enhancement of 41 meV, considering an ($\mathrm{In},\mathrm{Ga})\mathrm{As}$ absorber. This enhancement agrees with a simple and general expression formulated in the quantum thermal machine field. Concerning the current, we show that current through an energy-selective contact is of the same order of magnitude as the one obtained without selectivity. This remarkable behavior, which is explained by the hybridization of states in the absorber with the state of the contact, requires a quantum confinement and thus an ultrathin absorber. Finally, we propose a simple rate model enabling an intuitive interpretation of the numerical results.

Work costs and operating regimes for different manners of system-reservoir interactions via collision model

In this work, we study effects of different types of system-reservoir interactions on work costs and operating regimes of thermal machines by considering a quantum system consisting of two subsystems embedded in both independent and common reservoirs. The model allows us to make a contrast between three configurations of system-reservoir interactions, namely, the three-body one, the two-body one with and without intrasystem interaction between two subsystems. After establishing general formulations of thermodynamics quantities, we derive specific forms of heat and work with respect to these three configurations based on a model with two coupled qubits. It is shown that both the amount and sign of work are closely related to ways of system-reservoir interactions, by which six types of operating regimes of machines are constructed for a given setting. We find that different modes of system-reservoir interactions lead to different numbers of operating regimes of machines on the one hand, and on the other hand machines of the same kinds can appear in different scenarios of system-reservoir interactions, but which one is superior over others relies on intervals of parameters. A possible implementation of the setup based on the platform of circuit quantum electrodynamics is discussed briefly. We then generalize the bipartite model to multipartite case and derive the corresponding formulations of thermodynamics quantities. Our results indicate that interacting manners of system-reservoir play an important role in modifying thermodynamics process and can thus be utilized in designing quantum thermal machines with requisite functions.

Dephasing-enhanced performance in quasiperiodic thermal machines

Understanding and controlling quantum transport in low-dimensional systems is pivotal for heat management at the nanoscale. One promising strategy to obtain the desired transport properties is to engineer particular spectral structures. In this work we are interested in quasiperiodic disorder - incommensurate with the underlying periodicity of the lattice - which induces fractality in the energy spectrum. A well known example is the Fibonacci model which, despite being non-interacting, yields anomalous diffusion with a continuously varying dynamical exponent smoothly crossing over from superdiffusive to subdiffusive regime as a function of potential strength. We study the finite-temperature electric and heat transport of this model in linear response in the absence and in the presence of dephasing noise due to inelastic scattering. The dephasing causes both thermal and electric transport to become diffusive, thereby making thermal and electrical conductivities finite in the thermodynamic limit. Thus, in the subdiffusive regime it leads to enhancement of transport. We find that the thermal and electric conductivities have multiple peaks as a function of dephasing strength. Remarkably, we observe that the thermal and electrical conductivities are not proportional to each other, a clear violation of Wiedemann-Franz law, and the position of their maxima can differ. We argue that this feature can be utilized to enhance performance of quantum thermal machines. In particular, we show that by tuning the strength of the dephasing noise we can enhance the performance of the device in regimes where it acts as an autonomous refrigerator.

Operational nonclassicality in minimal autonomous thermal machines

Thermal machines exploit interactions with multiple heat baths to perform useful tasks, such as work production and refrigeration. In the quantum regime, tasks with no classical counterpart become possible. Here, we consider the minimal setting for quantum thermal machines, namely two-qubit autonomous thermal machines that use only incoherent interactions with their environment, and investigate the fundamental resources needed to generate entanglement. Our investigation is systematic, covering different types of interactions, bosonic and fermionic environments, and different resources that can be supplied to the machine. We adopt an operational perspective in which we assess the nonclassicality of the generated entanglement through its ability to perform useful tasks such as Einstein-Podolsky-Rosen steering, quantum teleportation and Bell nonlocality. We provide both constructive examples of nonclassical effects and general no-go results that demarcate the fundamental limits in autonomous entanglement generation. Our results open up a path toward understanding nonclassical phenomena in thermal processes.

Steady state entanglement behavior between two quantum refrigerators

An entangled steady-state behavior between two quantum thermal refrigeration machines is evaluated. Each machine is made up of three qubits of two-level, where each qubit interacts with its proper reservoir. The coupling between the qubits and the reservoirs is investigated with weak interaction. In addition, thermodynamic quantities such as heat flux are examined as a function of entanglement. The effect of temperature on entanglement is also studied in the cases of resonance and non-resonance. The obtained results show that the steady-state entanglement is more robust in the case of resonance than in the case of non-resonance. However, the maintenance in this case corresponds to the higher cooling power of the machine.

Optimal control of quantum thermal machines using machine learning

Identifying optimal thermodynamical processes has been the essence of thermodynamics since its inception. Here, we show that differentiable programming (DP), a machine learning (ML) tool, can be employed to optimize finite-time thermodynamical processes in a quantum thermal machine. We consider the paradigmatic quantum Otto engine with a time-dependent harmonic oscillator as its working fluid, and build upon shortcut-to-adiabaticity (STA) protocols. We formulate the STA driving protocol as a constrained optimization task and apply DP to find optimal driving profiles for an appropriate figure of merit. Our ML scheme discovers profiles for the compression and expansion strokes that are superior to previously-suggested protocols. Moreover, using our ML algorithm we show that a previously-employed, intuitive energetic cost of the STA driving suffers from a fundamental flaw, which we resolve with an alternative construction for the cost function. Our method and results demonstrate that ML is beneficial both for solving hard-constrained quantum control problems and for devising and assessing their theoretical groundwork.

Strong system-bath coupling effects in quantum absorption refrigerators.

We study the performance of three-level quantum absorption refrigerators, paradigmatic autonomous quantum thermal machines, and reveal central impacts of strong couplings between the working system and the thermal baths. Using the reaction coordinate quantum master equationmethod, which treats system-bath interactions beyond weak coupling, we demonstrate that in a broad range of parameters the cooling window at strong coupling can be captured by a weak-coupling theory, albeit with parameters renormalized by the system-bath coupling energy. As a result, at strong system-bath couplings the window of cooling is significantly reshaped compared to predictions of weak-coupling treatments. We further show that strong coupling admits direct transport pathways between the thermal reservoirs. Such beyond-second-order transport mechanisms are typically detrimental to the performance of quantum thermal machines. Our study reveals that it is inadequate to claim for either a suppression or an enhancement of the cooling performance as one increases system-bath coupling-when analyzed against a single parameter and in a limited domain. Rather, a comprehensive approach should be adopted so as to uncover the reshaping of the operational window.

Minimal quantum thermal machine in a bandgap environment: non-Markovian features and anti-Zeno advantage

A minimal model of a quantum thermal machine is analyzed, where a driven two level working medium (WM) is embedded in an environment (reservoir) whose spectrum possesses bandgaps. The transition frequency of the WM is periodically modulated so as to be in alternating spectral overlap with hot or cold reservoirs whose spectra are separated by a bandgap. Approximate and exact treatments supported by analytical considerations yield a complete characterization of this thermal machine in the deep quantum domain. For slow to moderate modulation, the spectral response of the reservoirs is close to equilibrium, exhibiting sideband (Floquet) resonances in the heat currents and power output. In contrast, for faster modulation, strong-coupling and non-Markovian features give rise to correlations between the WM and the reservoirs and between the two reservoirs. Power boost of strictly quantum origin (‘quantum advantage’) is then found for both continuous and segmental fast modulation that leads to the anti-Zeno effect of enhanced spectral reservoir response. Such features cannot be captured by standard Markovian treatments.

Bounds on fluctuations for ensembles of quantum thermal machines

We study universal aspects of fluctuations in an ensemble of noninteracting continuous quantum thermal machines in the steady-state limit, beyond linear response. Considering an individual machine, such as a refrigerator, in which relative fluctuations (and high order cumulants) of the cooling heat current to the absorbed heat current, η (n), are upper-bounded, with n ⩾ 2 and η C the Carnot efficiency, we prove that an ensemble of N distinct machines similarly satisfies this upper bound on the relative fluctuations of the ensemble, . For an ensemble of distinct quantum refrigerators with components operating in the tight-coupling limit we further prove the existence of a lower bound on in specific cases, exemplified on three-level quantum absorption refrigerators and resonant-energy thermoelectric junctions. Beyond special cases, the existence of a lower bound on for an ensemble of quantum refrigerators is demonstrated by numerical simulations. We further show that the lower bound on may, however, be violated for an ensemble of quantum engines.

Engineering Dynamical Couplings for Quantum Thermodynamic Tasks

An open quantum system, where system-environment couplings are periodically modulated, is studied, and formalism is developed to apply optimal control and machine learning techniques to quantum thermal machines.

Laser Cooling beyond Rate Equations: Approaches from Quantum Thermodynamics

Solids can be cooled by driving impurity ions with lasers, allowing them to transfer heat from the lattice phonons to the electromagnetic surroundings. This exemplifies a quantum thermal machine, which uses a quantum system as a working medium to transfer heat between reservoirs. We review the derivation of the Bloch-Redfield equation for a quantum system coupled to a reservoir, and its extension, using counting fields, to calculate heat currents. We use the full form of this equation, which makes only the weak-coupling and Markovian approximations, to calculate the cooling power for a simple model of laser cooling. We compare its predictions with two other time-local master equations: the secular approximation to the full Bloch-Redfield equation, and the Lindblad form expected for phonon transitions in the absence of driving. We conclude that the full Bloch-Redfield equation provides accurate results for the heat current in both the weak- and strong- driving regimes, whereas the other forms have more limited applicability. Our results support the use of Bloch-Redfield equations in quantum thermal machines, despite their potential to give unphysical results.