This paper presents a novel control method that integrates super-twisting sliding mode (STSM) voltage control with proportional-integral (PI) current control for a four-phase interleaved boost converter (IBC) in fuel cell applications. The STSM control, employed in the outer voltage loop, provides robust voltage regulation by generating precise reference currents for each phase. The conventional PI control in the inner current loop utilizes these reference currents to generate pulse width modulation (PWM) signals for each phase. The effectiveness of the proposed control strategy is evaluated through comprehensive simulation studies in MATLAB/Simulink, demonstrating an improvement in dynamic performance and enhanced robustness compared to conventional methods. Quantitative analysis shows that the output voltage quickly rises to the reference voltage within approximately 0.25 seconds in the proposed STSM-PI control method and improves transient response by 16 times compared to the conventional PI-PI method. This integrated STSM-PI control strategy offers significant advancements in reliability and efficiency making it a promising solution for high-performance fuel cell power systems.