Supercritical carbon dioxide (sCO2) and ammonia (NH3) can be used as coolants in high power-density microelectronics. sCO2 at the micro scale provides enhanced heat transfer solutions for a range of microelectronics cooling applications·NH3 can also potentially provide appropriate cooling solutions as it has favorable thermophysical properties at high pressure, and it can be used as an energy carrier as it contains Hydrogen atoms. Near its critical and pseudocritical condition sCO2 exhibits abrupt changes in its thermophysical properties and at similar pressures liquid NH3 too has adequate properties that make it a good coolant. While sCO2 is non-toxic, NH3 is a toxic substance and should only be used in closed loop micro heat exchangers.The current study compares the convective heat transfer performance of supercritical carbon dioxide (sCO2) and ammonia for microchannel cooling. A total of 144 numerical cases inside a square microchannel of hydraulic diameter of 200 µm with a total length of 52 mm and a heated length of 50 mm at constant surface temperatures in laminar flow conditions were examined. Two scenarios were investigated, in one the inlet mass flux was kept constant at 100, 150, and 200 kg/m2s, and in the second the pressure drop across the microchannel was maintained at 200, 400, and 600 Pa. Both scenarios were investigated at pressures of 8 and 10 MPa and at surface temperatures of 32, 40, 50, 60, 70, and 80 °C. In all cases the inlet temperature of both fluids was kept at 21 °C. At the same mass flux, NH3 yielded a higher average heat transfer coefficient (havg) but at the same pressure drop, sCO2 resulted in higher havg at certain surface temperatures. The havg for NH3 didn’t show significant variation but for sCO2 it showed significant change with surface temperature, and this was due to the significant change in the thermophysical properties of sCO2. The havg showed a mixed behavior with respect to the pumping power. The coefficient of performance (COP) was as high as 600,000 for sCO2 and it was significantly higher than that for NH3. Near the pseudocritical region, the COP for sCO2 witnessed a significant improvement, more than double, for 8 MPa compared to 10 MPa.
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