Mining leads to serious degradation of the ecological values of the landscape. After mining is completed, degraded areas should be reclamated in order to mitigate the destructive effects of mining activities. Effective reclamation aims to initiate soil-forming processes. The paper evaluates the effects of land reclamation in post-mining areas 12 to 14 years after the reclamation process. The assessment was based on a determination of the activity of selected enzymes. Municipal sewage sludge compost (SSC) and compost with a composition of 70% municipal sewage sludge + 30% fly ash (SSFAC) were used as an external source of organic matter in the reclamation. The activity of dehydrogenases, phosphatases, and urease was determined. The fertilization of reclaimed soil with compost caused a significant increase in the activity of the assessed enzymes. Significantly higher dehydrogenase activity was found in the soil treated with SSC. The soil treated with SSFAC was characterized by higher activity of phosphatase and urease. The one-time application of composts from sewage sludge and sludge with fly ash, and the introduction of a mixture of grasses, allow for a permanent reclamation effect. An additional ecological advantage of this reclamation model is waste management, which is part of the circular economy strategy.