Porous Carbon Skeleton Research Articles

MoS2@porous biochar derived from rape pollen as anode material for lithium‐ion batteries

AbstractPreparation of porous carbon from natural biomass offers attractive features to facilitate the specific capacity and promote the rate capability of lithium‐ion battery (LIB). Herein, the hollow mesh porous rape pollen carbon (RPC) microsphere derived from treated RP (TRP) was utilized as a skeleton to load MoS2 nanoparticles. The MoS2@porous biochar‐derived RP (MoS2@RPC) anode materials were obtained by the hydrothermal–pyrolysis route. Attributing to the synergistic effect of spherical, hollow, and mesh porous carbon skeletons, larger specific surface areas, evenly distributed MoS2 nanoparticles, and an appropriate amount of TRP, the MoS2@RPC‐1.0 (TRP amount of 1.0 g) anode material reveals exceptional rate capability and cycling stability. A high specific capacity of ∼800 mAh g−1 at 100 mA g−1 is observed after 100 cycles, and that of ∼600 mAh g−1 at 500 mA g−1 is also obtained after 500 cycles. In conclusion, the MoS2@porous biochar composite is expected to become one of the most promising anode materials for LIBs.

Developing bio-carbon matrices for the encapsulation of silicon nanoparticles for high-performance lithium-ion battery anode materials.

Silicon (Si) is considered to be one of the most promising anode materials for next-generation lithium-ion batteries because of its abundant reserves, low discharge potential, and most importantly, its high theoretical specific capacity. However, the practical application of Si-based anodes is mainly hindered by the low intrinsic conductivity of Si and the large volume change upon lithiation/de-lithiation. In order to improve the electrochemical performance of Si-based anodes, we prepared a composite material consisting of Si nanoparticles (NPs) and coconut silk bio-carbon (CSC) skeleton. The porous carbon skeleton derived from coconut silk with natural through-holes and ample micropores on the wall, which was used as the carrier of Si NPs. The continuous through-holes and well-distributed oxygen-containing functional groups of the CSC provided sufficient space and abundant adsorption active sites for Si NPs, what's more, the good dispersion of Si NPs in the through-holes increased their contact with the surrounding carbon materials, which was conducive to electron transport. Meanwhile, the pore structure also provided buffer space for the volume expansion of Si. The rich oxygen-containing functional groups can form a certain chemical force with silicon particles, and further stabilize the nano silicon particles. Hence, the CSC/Si electrode revealed an excellent capacity retention of 82.8 % at 1 A g-1 after 100 cycles. This study provides a simple universal high-throughput method to obtain anode materials with outstanding electrochemical properties and promotes the further development of Si/C composites.

Nitrogen-doped porous carbon skeleton derived from glycine boosting superior rate capability and long lifespan for Na3V2(PO4)3 with high thermal safety

Currently, the both low electronic and ionic conductivity have seriously hindered the further application of Na3V2(PO4)3 (NVP). Nevertheless, traditional carbon materials modification only improves the electronic conductive property, rather than modifying the ionic conductivity. Herein, N-rich carbon resources of glycine (GLY) is introduced to synthesize NVP, which can act as reducing agent and morphology inducer to optimize NVP sample. Notably, GLY supplies favorable N-doped carbon skeleton, and this defective carbon structure benefits for the accelerated electronic conductivity. Besides, porous construction is established after introducing GLY. This unique morphology significantly improves the infiltration effects of electrolyte, thus providing more electrochemical active sites for Na+ de-intercalation to improve the ionic conductivity. Meanwhile, porous framework supplies enough space for the shrinkage of crystal cells, so the stress-strain effect is highly restrained, which is demonstrated by Ex-situ XRD. The stabilized crystal and morphological structure of NVP@GLY-2 has been verified by after-cycled XRD/SEM/XPS. Highly improved kinetic characteristics are also investigated by In-situ EIS. Moreover, Accelerating Rate Calorimeter (ARC) measurements indicate that NVP@GLY-2-based half and full cells also have excellent thermal safety properties. Comprehensively, NVP@GLY-2 reveals a high capacity of 119 mAh g−1 at 0.1 C. It reveals 84.5 and 71.2 mAh g−1 at 10 and 50 C, with capacity retention rates of 88.9 % and 85.8 % after 1000 cycles.

MXene quantum dots modified pitaya peel-based composite phase change material with excellent thermal properties for building energy efficiency applications

Bio-based materials have attracted much attention because their application in the construction field is conducive to energy saving and emission reduction. In this paper, a bio-based composite phase change material (CPCM) was prepared by utilizing pitaya peel as a bio-based material, MXene quantum dots (MQDs) as a modified material, and polyethylene glycol (PEG) as a phase change medium. MXene quantum dots dispersed in the pitaya peel-based porous carbon skeleton enhanced the three-dimensional thermal conductivity network of the porous carbon skeleton somewhat improved the thermal conductivity (0.676 W/mK) of the polyethylene glycol/MXene quantum dots-modified pitaya peel-based porous carbon foam (PPF) composite phase change material (PEG/PPF@M). It is worth noting that PEG/PPF@M has excellent thermal stability and its enthalpy is basically unchanged after 100 cycles, which proves the recyclable stability of PEG/PPF@M in practical applications. PEG/PPF@M has great potential for thermal management of buildings and electronic components. Overall, a novel multifunctional CPCM was prepared in this study using a simple process method, which can not only be applied in electronic products to improve the service life of electronic components, but also in the field of construction to realize energy saving and emission reduction, as well as the recycling and reuse of waste.

Study on preparation and performance of CoS2/NiS2-CNT@C anode material for high-performance lithium‑sulfur batteries

Functional carbon materials with high porosity have been widely used in energy storage materials. In this work, a porous carbon skeleton was constructed by a rigid template method, and carbon nanotubes grown in situ in the skeleton to realize the organic combination of the honeycomb structure and carbon nanotubes, thereby forming a carrier material with a specific structure. At the same time, bimetallic sulfide (CoS2/NiS2) was introduced as a modification material on the specific structure. The two transition metal sulfides have a matching energy band structure, which can form a high-quality interface in the composite. The electron transfer can be accelerated through the interface between different substances, and the electron regulation and redistribution can be realized, thereby further improving the reaction kinetics. Electrochemical tests also confirmed the superiority of its performance. At a current density of 0.5 A/g, the first discharge-specific capacity reached 1378.9 mAh/g, and there was still a capacity of 993.5 mAh/g after 100 cycles. Even at a high current (5 A/g), the capacity remained at 503 mAh/g.

Construction of dielectric and magnetic coupling cobalt salt/chitosan derived Co/C hybrid aerogels for high-performance infrared/radar compatible applications

In virtue of mutually exclusive stealth mechanisms, effectively protecting from infrared detection and attenuating microwaves through composition and structure design remains a formidable challenge. To achieve high-efficiency infrared/radar compatible stealth, in this work, 0D magnetic Co nanoparticles were successfully in situ grown onto the renewable biomass chitosan-based 3D porous carbon skeletons via facile liquid reaction, freeze-drying, and calcination method. Herein, the as-prepared Co/C hybrid aerogels exhibit dielectric and magnetic coupling network, and the relevant infrared/radar compatible stealth property can be regulated by adjusting the addition amount of Co salt. The minimum thermal conductivity value reached 0.095 W m−1 K−1 at 60 °C, and the lowest infrared emissivity of 0.717 in the 8–14 μm band was also achieved. Furthermore, the minimum reflection loss (RLmin) value of −44.70 dB at a relatively thin thickness of 1.35 mm and the maximum effective absorption bandwidth (EAB) of 5.45 GHz at only 1.5 mm appeared in the optimal Co/C hybrid aerogel with the most appropriate Co content. Compared with perfect conductive layer (PEC), the simulated radar cross section (RCS) signals of Co/C composites covered PEC have been significantly reduced by 18.44 dB m2 at the scanning angle of 80°. This study inspires the exploration of the elaborate design strategy and facile construction method for environment-friendly infrared/radar compatible hybrid aerogels in the future.

Designing a Microstructure of NiCo-LDH@CNTs@Carbon Foam for Efficient Electromagnetic Wave Absorption and Excellent Environmental Tolerance.

The constantly evolving environment imposes increasingly stringent demands on the mechanical qualities of materials employed for absorbing electromagnetic waves (EMWs). Therefore, there is an urgent need for advanced materials capable of efficiently absorbing EMWs and withstanding harsh electromagnetic conditions. In this study, the electrodeposition method was effectively used to synthesize nickel-cobalt layered double hydroxides (NiCo-LDHs) in a controlled manner on a composite structure of carbon nanotubes and carbon foam, creating an exquisite construction. The manipulation of the electrodeposition time facilitated the regulation of the density of the layered structure within the composite material, thereby significantly enhancing its polarization relaxation performance. Increased defect sites and interface polarization enhance impedance matching and the attenuation constant, resulting in greatly improved absorption performance. The optimized sample demonstrated exceptional wave-absorbing performance in comparative experimental analysis, attaining a maximum reflection loss of -58.18 dB. It also has an effective absorption bandwidth of 5.36 GHz at a wavelength of 2.28 mm. The exceptional isolation effect of LDH, coupled with the outstanding insulation ability of the porous carbon skeleton, confers remarkable corrosion resistance and thermal insulation performance on the composite material. Hence, this discovery offers novel insights into designing environmentally tolerant absorbent materials.

Preparation of Magnetic Spongy Porous Carbon Skeleton Materials for Efficient Removal of BTEX.

Magnetic polymer microspheres have been extensively utilized as separable and highly efficient adsorbents in wastewater treatment. In this study, a series of novel magnetic spongy porous carbon skeleton materials (Mag-SPCS) have been designed and synthesized by acetonitrile suspension precipitation polymerization, which combines the advantages of the acetonitrile precipitation method and the suspension polymerization method. It was demonstrated that the transformation of the material morphology from microspheres to a porous sponge was achieved by a gradual decrease in the usage amount of ethylene glycol. After N,N-dimethyloctadecylamine (C18) was grafted onto the Mag-SPCS materials, the C18-Mag-SPCS materials with a superhigh saturation adsorption capacity and superfast adsorption efficiency were used for the removal of BTEX (toluene, benzene, and para-xylene) in wastewater. Subsequently, the adsorption properties of the composites with different morphologies were evaluated, and the effect of the usage amount of C18 on the adsorption properties of the C18-Mag-SPCS was further investigated. The maximum adsorption capacities of C18-Mag-SPCS for benzene, toluene, and para-xylene were 714.84, 564.32, and 394.48 mg/g, respectively. The adsorption process was conducted in accordance with the proposed secondary and Langmuir models. Finally, the FTIR, XPS, and XRD characterization results before and after adsorption demonstrated that the adsorption mechanism of toluene onto C18-Mag-SPCS was primarily hydrogen bonding, π-π stacking, and van der Waals forces. These findings of the study indicate that the composite material exhibits an ultrahigh saturation adsorption capacity and ultrafast adsorption efficiency, thereby confirming its considerable potential for application in wastewater treatment.

Silica Hard Template Extracted from Semicoke Residue Toward the Hierarchical Porous Carbon Skeleton for Lithium–Sulfur Batteries

Silica Hard Template Extracted from Semicoke Residue Toward the Hierarchical Porous Carbon Skeleton for Lithium–Sulfur Batteries

Stable Hierarchical Porous Heterostructure Ni2P/NC@CoNi2S4 Fabricated via the NiCo-LDH Template Strategy for High-Performance Supercapacitors.

Transition metal phosphide/sulfide (TMP/TMS) heterostructures are attractive supercapacitor electrode materials due to their rapid redox reaction kinetics. However, the limited active sites and weak interfacial interactions result in undesirable electrochemical performance. Herein, based on constructing the NiCo-LDH template on Ni-MOF-derived Ni2P/NC, Ni2P/NC@CoNi2S4 with a porous heterostructure is fabricated by sulfurizing the intermediate and is used for supercapacitors. The exposed Ni sites in the phosphating-obtained Ni2P/NC coordinate with OH- to in situ form an intimate-connected Ni2P/NC@NiCo-LDH, and the CoNi2S4 nanosheets retaining the original cross-linked structure of NiCo-LDH integrate the porous carbon skeleton of Ni2P/NC to yield a hierarchical pore structure with rich electroactive sites. The conducting carbon backbone and the intense electronic interactions at the interface accelerate electron transfer, and the hierarchical pores offer sufficient ion diffusion paths to accelerate redox reactions. These confer Ni2P/NC@CoNi2S4 with a high specific capacitance of 2499 F·g-1 at 1 A·g-1. The NiCo-LDH template producing a tight interfacial connection, significantly enhances the stability of the heterostructure, leading to a 91.89% capacitance retention after 10,000 cycles. Moreover, the fabricated Ni2P/NC@CoNi2S4//NC asymmetric supercapacitor exhibits an excellent energy density of 73.68 Wh kg-1 at a power density of 700 W kg-1, superior to most reported composites of TMPs or TMSs.

Interconnected Pd Nanowire Networks Stereoassembled on Biomass-Derived Porous Carbon Skeletons as Bifunctional Electrocatalysts for Efficient Methanol and Formic Acid Oxidation

Interconnected Pd Nanowire Networks Stereoassembled on Biomass-Derived Porous Carbon Skeletons as Bifunctional Electrocatalysts for Efficient Methanol and Formic Acid Oxidation

Construction of Bi/Bi2O3 particles embedded in carbon sheets for boosting the storage capacity of potassium-ion batteries

Bismuth-based materials have attracted interest in potassium-ion batteries (PIBs). However, the large volume expansion prevents further use of bismuth-based materials for potassium storage. This work employs a two-step synthesis method to innovatively synthesize of Bi/Bi2O3 nanoparticles assembled on N-doped porous carbon sheets (Bi/Bi2O3@CN). The layered structures with uniformly shaped and N-doped porous carbon skeleton buffer the expansion of Bi and the Bi/Bi2O3 particles increase the capacity of potassium storage. In brief, the Bi/Bi2O3@CN served as anode in half-cell of PIBs have a good rate capacity of more than 234.7 mAh/g at 20 A/g. The specific capacity retention was 73 % compared with 322.16 mAh/g at 1 A/g, demonstrating good holding capacity for diverse current densities. The cycle also displays 163 mAh/g after 1500 cycles at 2 A/g in the KPF6 metal salt solution, showing its potential as one of the anode materials in PIBs.

Encapsulating Antimony metal nanoparticles in hierarchical porous carbon skeleton as high-performance potassium- and lithium-ion batteries anodes

Metallic antimony (Sb) as alkaline metal battery anode material, being thoroughly researched for its high theoretical specific capacity, but there is still a huge expansion problem with repeated insertion/de-insertion., We reported a unique composite material that encapsulates Sb nanoparticles in hierarchical porous carbon skeletons (Sb@HPCs) in this work, to explore the effect of the hierarchical porous carbon structure on the electrochemical performance of the Sb@HPCs as potassium-ion batteries (KIBs) and lithium-ion batteries (LIBs) anode materials. The macropores could promote the penetration of electrolyte, thus reducing the internal impedance of the battery. The mesopores provide a short ion diffusion path and a large diffusion region, which plays a crucial role in facilitating rapid ionic migration in both KIBs and LIBs. The micropores in the electrode material contribute to a larger specific surface area, which provides more surface area for charge storage, thus enhancing the energy density of the material. Importantly, when the Sb@HPCs composite material is applied as anode material of KIBs, it exhibits an outstanding specific capacity of 360 mAh g−1 after 100 cycles at 100 mA g−1. In the LIBs, the specific capacity of the composite material is 595.2mAh g−1 after 100 cycles at a current density of 0.1 A g−1; even at a high current density of 1.0 A g−1, the specific capacity still maintains at 320.4 mAh g−1 after 800 cycles, indicating an excellent cycling stability. The development of hierarchical porous three-dimensional structure offers a practical solution to the capacity degradation issues of metal anode in KIBs/LIBs.

Handy preparation of a carbon-Ni/NiO/Ni(OH)2 composite and its application in high-performance supercapacitors

The growing demand for energy storage is required with the development of the intermittent renewable energy. Supercapacitors are a promising energy storage equipment, but their capacitive performance mainly depend on the electrode material. To obtain a high-performance electrode material for supercapacitors, in this work, a carbon-Ni/NiO/Ni(OH)2 composite was prepared from pine sawdust as the carbon precursor by integrating CO2 gasification and electrochemical deposition. It is found that the carbon-ternary nickel composite shows good electrochemical performance due to synergistic effect of the unique hierarchical structure and components involving porous carbon skeleton, Ni0 and NiO nanoparticles, and Ni(OH)2 microspheres. The composite displays the specific capacitance of 1875.6 F/g (or 937.8 C/g) at a current density of 1 A/g in a traditional three-electrode system. The assembled asymmetric supercapacitor device presents a potential window of 1.6 V, along with the energy density of 38.24 Wh/kg at the power density of 400 W/kg (or 22.60 Wh/kg at 2000 W/kg). After 6000 charge-discharge cycles, the capacitance retention ratio of the assembled supercapacitor reaches up to 105 %, exhibiting a good application potential. This work provides a novel and handy strategy for preparation of ternary nickel-based composite for advanced supercapacitors.

Strategy for the Preparation of ZnS/ZnO Composites Derived from Metal-Organic Frameworks toward Lithium Storage.

The synergistic effect between multicomponent electrode materials often makes them have better lithium storage performance than single-component electrode materials. Therefore, to enhance surface reaction kinetics and encourage electron transfer, using multicomponent anode materials is a useful tactic for achieving high lithium-ion battery performance. In this article, ZnS/ZnO composites were synthesized by solvothermal sulfidation and calcination, with the utilization of metal-organic frameworks acting as sacrificial templates. From the point of material design, both ZnS and ZnO have high theoretical specific capacities, and the synergistic effect of ZnS and ZnO can promote charge transport. From the perspective of electrode engineering, the loose porous carbon skeleton that results from the calcination of metal-organic frameworks can enhance composite material conductivity as well as full electrolyte penetration and the area of contact between the electrolyte and active material, all of which are beneficial to enhancing lithium storage performance. As expected, ZnS/ZnO anode materials displayed remarkably high specific capacities and outstanding performance at different rates. Combining material design and electrode engineering, this paper provides another idea for preparing anode materials with excellent lithium storage properties.

Enhanced potassium-ion battery performance with Bi Nanoparticle-Infused 3D porous carbon composites

Bismuth (Bi) based materials are widely utilized in potassium-ion batteries (PIBs) due to their high theoretical capacity; however, they undergo severe volume changes during electrochemical processes. To develop Bi-based anode with extended lifespan, Bi nanoparticles and porous carbon materials were composited by a template method in this study. N-doped three-dimensional porous carbon coated Bi nanoparticles (Bi@3DNC) composites were successfully synthesized by using sodium chloride as a template and anchoring Bi nanoparticles on a porous carbon skeleton. Bi@3DNC exhibits excellent electrochemical performance as an anode material for PIBs, retaining a capacity of 273 mAh/g after 700 cycles at 1 A/g. We elucidate that the 3D porous carbon mesh serves to confine the alloying particles and buffer the volume expansion of the metal during continuous K+ de-intercalation, while also enhancing the availability of active sites. This strategy offers promising prospects for the development of advanced metal based anodes for PIBs.

1T-rich MoS2 nanosheets anchored on conductive porous carbon as effective polysulfide promoters for lithium–sulfur batteries

The practical applications of lithium-sulfur (Li-S) batteries have severely been hindered by notorious shuttle effect and sluggish redox kinetics of lithium polysulfide intermediates (LiPSs), which bring about rapid capacity degradation, low coulombic efficiency and poor cycling stability. In this work, 1T-rich MoS2 nanosheets are in-situ developed onto the conductive porous carbon matrix (1T-rich MoS2@PC) as efficient polysulfide promotors for high-performance Li-S batteries. The porous carbon skeleton tightly anchors MoS2 nanosheets to prevent their reaggregation and ensures accessible electrical channels, and at the same time provides a favorable confined space that promotes the generation of 1T-rich MoS2 structure. More importantly, the uniformly distributed metallic 1T-rich MoS2 nanosheets not only affords rich sulfphilic sites and high binding energy for immobilizing LiPSs, but also favors rapid electron transfer and LiPSs conversation kinetics, substantially regulating sulfur chemistry in working cells. Consequently, the Li-S cell assembled with 1T-rich MoS2@PC modified separator delivers a remarkable cycling stability with ultralow capacity decay rate of 0.067% over 500 cycles at 1C. Encouragingly, under harsh conditions (high sulfur loading of 4.78 mg cm−2 and low E/S ratio of 8 μL mg−1), a favorable electrochemical performance can still be demonstrated. This study highlights the profitable design of 1T-rich MoS2/carbon based electrocatalyst for suppressing shuttle effect and promoting catalytic conversation of LiPSs, and has the potential to be applied to in other energy storage systems.

Co nanoparticle-loaded porous carbon for high-performance supercapacitors

Porous carbon materials doped with transition metals have emerged as promising electrode materials in the field of energy storage due to their higher theoretical capacitance and cost-effectiveness. In this study, metallic cobalt nanoparticles (Co NPs) were successfully loaded into porous carbon via one-step carbonization method for electrochemical research applications as electrode materials (Co/CM). A comparative investigation was conducted by varying the content of polystyrene microspheres (PS) to optimize the porous morphology. Scanning electron microscopy (SEM) analysis revealed that the Co/CM-3 composite displayed a plate-like porous structure, while transmission electron microscopy (TEM) confirmed the uniform loading of Co NPs within the porous carbon skeleton. The composite with the optimal PS content (Co/CM-3) exhibited a specific capacitance of up to 810 F g−1 (at 1 A g−1) in the three-electrode system. Furthermore, asymmetric supercapacitors assembled with the prepared electrode as the positive electrode and activated carbon as the negative electrode demonstrated an impressive energy density of up to 40 Wh kg−1 (at a power density of 746 W kg−1). Remarkably, the capacitance retention rate remained at 88.24 % even after 5000 consecutive charge and discharge cycles, highlighting the promising potential of this electrode material for practical applications in energy storage.

MXene-modified lemon peel-based composite phase change material with excellent photo-thermal conversion efficiency, thermal storage capacity and thermal conductivity for thermal management of electronic components

The preparation of multifunctional composite phase change materials using green technology to achieve an efficient energy storage and conversion remains an issue of concern. In this paper, a lemon peel-based porous carbon (LPC) composite phase change material (CPCM) was prepared by using polyethylene glycol (PEG) 6000 as a phase change medium and MXene nanosheet-modified carbonized lemon peel as a support carrier. MXene nanosheets were bonded to a lemon peel-based porous carbon skeleton to construct an excellent continuous three-dimensional thermally conductive grid system. What makes it noteworthy is that the presence of MXene nanosheets substantially improves the thermal conductivity (0.66 W/mK) and photo-thermal conversion efficiency (θ = 96.4 %) of MXene-modified lemon peel-based porous carbon/polyethylene glycol composite phase change materials (PEG/LPC@M). It is noteworthy that PEG/LPC@M has remarkable thermal stability and still has high enthalpy after 100 cycles, which further proves the recyclability of PEG/LPC@M and PEG/LPC@M embodies great potential in the field of thermal management of electronic components. In conclusion, a novel multifunctional CPCM was prepared by a simple and green process method in this study, which provides a new idea for waste recycling and reuse, and also has a wide range of applications in thermal management of electronic devices.

MOF-on-MOF-derived Fe[sbnd]Zr bimetal oxides supported on hierarchically porous carbonized wood to promote photo-Fenton degradation of ciprofloxacin

MOF-on-MOF derivatives have served as promising heterogeneous Photo-Fenton (hetero-PF) catalysts, but its self-aggregation instability and limited photocatalytic activity inhibit the effective ciprofloxacin (CIP) removal. In this study, a novel hetero-PF catalyst, dual MOF-derived FeZr bimetal oxide embedded in a wood-converted porous carbon skeleton (ZrO2@Fe3O4/WPC), was successfully synthesized via a straightforward in-situ growth strategy combined with co-pyrolysis. The as-prepared hybrid photocatalysts, featuring a large surface area, effective porous structures, efficient light absorption and a narrow band gap demonstrated superior photo-Fenton activity, accomplishing approximately 99.1 % degradation of CIP within 120 min under neutral conditions. Furthermore, the ZrO2@Fe3O4/WPC hetero-PF system showed satisfactory performance in treating real water matrices. It can be inferred that the abundant heterojunctions, resulting from the synergistic effect of FeZr mixed oxide and the porous carbonized wood substrate, contributed to the rapid separation and migration of photogenerated electron-hole pairs. Meanwhile, the FeZr site in the graphitized carbon framework activates H2O2 to accelerate the generation of the OH and O2− radicals, leading to a heightened degradation efficiency of CIP. Besides, the photodegradation pathway of CIP is obtained by liquid chromatography-mass spectrometry (LC-MS). This study indicates that combining porous carbonized wood and heterometallic MOF derived materials provides a promising method for realizing high-efficiency photo-Fenton degradation of antibiotic water pollutions.