Polymeric Materials Research Articles

Exploring the influence of polymers on soil ecosystems: prospective from agricultural contexts

The utilization of advanced polymeric materials has indeed emerged as a significant trend in sustainable agriculture, offering a range of innovative applications aimed at enhancing productivity, minimizing environmental impact, and promoting resource efficiency. Smart polymeric materials enable the controlled release of pesticides, herbicides, and fertilizers, thereby enhancing their efficacy while reducing the quantities needed. Superabsorbent polymeric materials act as soil conditioners, assisting in alleviating the negative impacts of drought by retaining moisture and enhancing soil structure. This fosters improved plant growth and resilience in water-scarce environments. Polycationic polymers play a role in plant bioengineering, facilitating genetic transformation processes aimed at enhancing crop productivity and disease resistance. Advanced polymeric systems contribute to the arsenal of precision agriculture tools by enabling precise delivery and targeted application of agricultural inputs. This approach enhances resource efficiency, reduces waste, and minimizes environmental impact while optimizing crop yields. In reviewing recent developments in the design and application of advanced polymeric systems for precision agriculture, several key considerations emerge.

Comparative study between UVB 313 nm, UVC 254 nm, and far UVC 222 nm light on the aging of polyamide 66

Polyamide-66 underwent substantial growth worldwide in the late 1930´s. It can be found in several public spaces. After 2019, due to the coronavirus disease (COVID-19), the sanitization of the interior of aircraft and public spaces by using UV light became important. Most of all, the effect of the far UVC 222 nm became a research hot spot and is still a research blank. In the present work, a comparative study on the post-exposure damage of polyamide- 66 occurred when controlled ultraviolet irradiation (UVC 254 nm, far UVC 222 nm, UVB 310 nm) and moisture-condensation were carried out. Chemical (FTIR), thermal (DMA), and nano-mechanical properties were evaluated. FTIR analysis showed the formation of O-H and/or N-H bonds since there appeared absorptions at 3400 cm-1 along with the vanishing of other signals related to C-N bonding. These changes are more evident in samples exposed to UVC 254 nm followed by samples that were irradiated with UVC 222 nm. Samples that were aged with UVA 313 nm didn´t show a change in FTIR spectra. FTIR on spectra and nanoindentation showed that UVB 313 nm produced a lower aging effect on this material. In contrast, UVC 254 nm light caused the highest degree of surface chemical-mechanical change attributed to cleavage/crosslinking reactions initiated by free radicals produced by UV light and moisture. On the contrary, far UVC 222 nm light presented moderate effects on Polyamide-66. Glass-transition temperature (Tg) diminished as the time to exposure increased attributed to water absorption and surface damage, being the highest change at -16.05 °C for samples irradiated with 245 UVC nm. However, the potential of far UVC 222 nm light for COVID-19 sanitization, with no significant degradation effects on polymeric materials, is a promising finding that should be further explored and could provide a hopeful solution in the fight against the pandemic.

Effect of ionic bonding on luminescence properties of histidine maleic anhydride derivatives

Polymeric materials exhibiting room-temperature phosphorescent (RTP) have attracted wide attention for their easy synthesis, low toxicity, and applications in various fields such as data encryption, cell imaging, information security and other fields. Nevertheless, the conventional ways of preparing such materials are mainly focused on doping, which may suffer from phase separation, poor compatibility, and lack of effective methods to promote intersystem crossing and suppress the nonradiative deactivation rates. Herein, a series of polymers with fluorescence and phosphorescence dual emission were prepared by simple radical solution copolymerization. Through rigid ion-bonded cross-linked networks and cross-linked hydrogen-bonded networks between the polymer chains, the non-radiative jumps and achieve ultra-long phosphorescence lifetimes were able to suppress. By suppressing non-radiative transitions through rigid ion-bonded cross-linked networks and intermolecular hydrogen-bonding networks between polymer chains, ultra-long phosphorescence is achieved. Impressively, a LRTP lifetime of up to 815.38 ms in polymers under ambientconditions is set up. Moreover, in this study, phosphorescence emission can be easily tuned by balancing ion radius and charge states. These results outline the construction of polymeric materials, endowing traditional polymers with new characteristics and promising potential applications.

Polymeric Advancements in Transdermal Drug Delivery: A Comprehensive Review on Stability, Safety, and Biocompatibility

AbstractTransdermal drug delivery systems have received a lot of attention due to their noninvasive nature and possible advantages over standard drug administration methods. Because transdermal administration systems skip the gastrointestinal tract and hence avoid hepatic first pass metabolism, also the chance of adverse effects such as liver malfunction and gastrointestinal tract discomfort is low. This comprehensive review explores the various aspects of polymeric advancements in transdermal drug delivery, encompassing their roles as matrix and microreservoir formers, microneedles, pressure sensitive adhesives, rate controlling membranes, and many other components. The article emphasizes the importance of biocompatibility, chemical compatibility, and stability of polymers within the transdermal delivery system. Furthermore, it delves into the recent advancements in synthetic and natural polymer‐based transdermal drug delivery systems. Thus, a comprehensive search strategy is conducted in electronic databases such as PubMed, Scopus, and Web of Science to write this review paper. The scope of this investigation involves an in‐depth study of the various polymeric materials used, their formulations, and the mechanisms that support their efficacy in delivering medications over the skin barrier. Additionally, it explores the challenges associated with stability and safety concerns, while highlighting novel approaches to overcome these problems. Furthermore, the review discusses the biocompatibility of polymeric materials, crucial for ensuring minimal adverse effects and maximum therapeutic efficacy.

Enhancing 3D printed PET physicochemical properties to prevent bacterial adhesion: Phenolic compound-based approach

Polyethylene terephthalate (PET) has emerged as a versatile and widely used polymeric material in the healthcare sector, particularly for medical device manufacturing, owing to its exceptional properties such as biocompatibility, high uniformity, and mechanical strength. However, the susceptibility of PET to bacterial adhesion remains a critical challenge in medical applications, potentially leading to serious complications for patients. In this study, we assessed, using the contact angle and scanning electron microscopy (SEM) techniques, the effectiveness of various phenolic compounds, including gallic acid (GA), tannic acid (TA), caffeic acid (CA) and epigallocatechin gallate (EGCG), in preventing the adhesion of Staphylococcus aureus and Pseudomonas aeruginosa to 3D printed PET surfaces. The results revealed that PET, initially hydrophobic (θw = 75.7 ± 0.56° and ΔGiwi = −52.17 mJ/m2), became hydrophilic after treatment with TA, GA and CA, enhancing its physicochemical properties. Additionally, GA demonstrated remarkable anti-adhesive efficacy against S.aureus with inhibition percentage of 97.4 %, whereas TA exhibited a high inhibition rate against P.aeruginosa (98.5 %). In contrast, PET remained qualitatively hydrophobic after treatment with EGCG, which showed limited anti-adhesive efficacy with a percentage of coverage by S.aureus and P.aeruginosa of 70.15 and 92.7 %, respectively. These findings contribute to the development of sustainable anti-adhesive surfaces for medical devices.

Crystallization ripening and erosion of calcium oxalate under the effect of bacteria and a polymer materials surface.

As typical examples of pathological biomineralization, urinary stones and stent encrustation have been associated with bacteria, yet the underlying mechanisms remain unclear. In this study, the effect of Gram-negative Escherichia coli and Gram-positive Staphylococcus aureus on the nucleation and growth of calcium oxalate crystals both in solution and on material surfaces in vitro was investigated. Both bacteria can promote calcium oxalate crystallization, and E. coli shows a prominent ability to boost the nucleation and growth rate. Interestingly, we discovered an Ostwald ripening phenomenon after the initial nucleation on the material surfaces, where larger particles emerge upon the disappearance of small nuclei particles, evident in the case of S. aureas. Over an extended period of time, erosion and disintegration of the crystals was observed when bacteria were involved. Based on these understandings, we developed a new functional surface by synthesizing an antibacterial polypeptoid in-house and utilizing polyurethane as the substrate material. This surface exhibits a synergistic effect that inhibits the formation of calcium oxalate crystals. This study helps to elucidate the role of bacteria in calcium oxalate biomineralization and supports further development of treatment approaches such as anti-encrustation polymer materials.

Combined use of Bacteria and Enzymes in the Degradation of Polymer Materials

The development of the plastics industry, pro-ecological directives and environmental problems related to the decomposition of biodegradable plastics create necessity to develop a way to properly manage waste from materials that should not be deposited in the environment. A bioproduct has been developed to be used for accelerating the biodegradation of polymer materials. The bioproduct includes carefully selected microorganisms and enzymes. It has been observed that metabolic activity of selected bacteria increases significantly in the presence of plastic material, causing degradative changes. In addition, enzymes were used that also stimulate the decomposition of polymer materials. Impact of bacteria and enzymes on polymer biodegradation was analyzed using different methods: BOD, mass loss, SEM-EDX and FTIR-ATR. Also the effect on plant growth was examined. Five bacterial strains were selected as the active ingredients of the bioproduct, including two bacterial strains from the designated collection and three isolated from environment. Four hydrolytic enzymes have been selected that have the potential to accelerate the decomposition of polymer materials. Keywords: bacteria, enzymes, biodegradation, polymer materials

Photochemical Oxidation of Polyethylene Terephthalate Microplastics Adsorbed on Sand and Silica Surfaces.

The environmental contamination by plastics, microplastics, and related compounds is a major concern. While the detection and release of micro- and nanoparticles from these materials have been widely studied, the formation and release of molecules resulting from their degradation in the environment have been overlooked. This work presents a study of the products released from poly(ethylene terephthalate) (PET) irradiated as pure particles and adsorbed on silica and sand surfaces under different irradiation conditions. The role of oxygen was also evaluated. The products were identified by gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-high resolution mass spectrometry (LC-HRMS). The main released molecules can be accounted for by considering the cleavage of α- and β-bonds next to the ester moiety of the polymer chain. Volatile products such as benzene as well as monomer units of the polymer and related products were identified. In the presence of oxygen, acetic acid and products resulting from hydroxylation at the benzenic ring or at the ethyl moiety were detected. Adsorption on silica and sand has little effect on the photoproduct distributions. The irradiation at 360 nm leads to distributions similar to the ones observed at 257 nm, but the reaction rate is lower. The identified product ethylene terephthalate is a marker of PET plastics and particles and can therefore be used to evaluate the environmental contamination by this polymer material.

N18 ring: A building block for constructing 1D and 2D polymeric nitrogen frameworks

Exploring the fundamental building block is essential for constructing functional materials with extended topological configurations. In the polymeric nitrogen system, no fundamental building blocks have been reported so far. Here, we successfully synthesize the buckled 1-dimensional (1D) band-shaped and 2-dimensional (2D) layered polymeric nitrogen frameworks with N18 ring as a fundamental building block for the first time. Furthermore, the dimensions of the polymeric nitrogen frameworks can be regulated by pressure conditions. Bader charge analyses indicate that the charge transfer from the La atom to the low-order bonded nitrogen atom plays a crucial role in stabilizing these two low-dimensional polymeric frameworks. Both LaN16 and LaN8 are promising high-energy-density materials (HEDMs). This study reveals that the N18 ring can serve as a fundamental building block, analogous to thesix-membered ring in carbon-based materials, enabling the construction of novel polymeric nitrogen materials with extended frameworks.

Hydrogen as power storage technology, polymeric and interconnect material innovations for future AI datacenter applications: a review

Hydrogen as power storage technology, polymeric and interconnect material innovations for future AI datacenter applications: a review

An experimental analysis of mechanical properties for a dissimilar pattern structure in the 3-D printing of a PLA5F filament using the Taguchi method

Abstract Many automobile components and machine parts can be fabricated using the Fused Deposition Modeling (FDM) process with materials such as Polylactic Acid (PLA), Acrylonitrile Butadiene Styrene (ABS), Polyethylene Terephthalate Glycol (PET-G), and polymeric composite materials (e.g., PLA with carbon fiber, PLA with glass fiber). In this study, a new polymeric composite material was fabricated using Polylactic Acid and natural flax fiber was analysed for tensile stress, elongation, and impact load resistance using Taguchi Analysis. This analysis optimized the printing parameters, including layer thickness (0.15, 0.25, 0.35 mm), nozzle movement speed (80, 100, 120 mm s−1), filling structure (Lines - a, Triangular - b, and Octet - c), and occupancy rate (20%, 40%, 60%). The American Society for Testing and Materials (ASTM) standards for tensile strength (ASTM D638) and impact strength (ASTM D256) were used for evaluation. As a result, layer thickness was found to be the most effective variable for improving tensile characteristics, compared to extruder temperature, occupancy rate, or filling structure pattern. Mechanical properties including a layer thickness of 0.25 mm, an occupancy ratio of 20% for the bottom of the 2nd layer and 40% for the top of the 4th layer, triangular and octet filling structures, a nozzle speed of 100 mm s−1, and an extruder temperature of 200 °C are considered the most appropriate parameters for producing automotive parts in Three Dimensional (3D) Printing. Due to its tensile properties and impact strength resistance, these settings can be utilized in potential application in a wide variety of machine parts and vehicle components.

Synthesis and Characterization of Chitosan/Sericin Composite Blend Membranes Containing Silver Nanoparticles for Effective Antibacterial Applications

AbstractDue to drug‐resistant bacteria, antimicrobial composite materials that will replace antibiotics are among the current research topics. In this study, environmentally‐friendly, low‐cost, easy‐to‐synthesize chitosan/silk sericin/silver nanoparticles (Cht/SS/AgNPs) membranes were obtained for use in antibacterial applications. For material synthesis, firstly, AgNPs were obtained by mixing solution of 2 % sericin (at pH 11)‐10 mM AgNO3 at 100 °C with hydrothermal method and AgNPs formation was confirmed by UV‐Vis measurements. Then, sericin/AgNPs solution was added to chitosan solutions at different ratios and Cht/SS/AgNPs composites were obtained by solvent casting method. The final forms of the membranes were characterized by fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM)‐energy dispersive X‐ray spectroscopy (EDS), and thermogravimetric analysis (TGA). Water retention capacities and mechanical properties of the membranes were also determined. Finally, antibacterial and biocompatibility properties were evaluated by disc diffusion test method on Escherichia coli and Staphylococcus aureus and MTT on L929 fibroblast cell line, respectively. The obtained membranes had homogeneous appearance, high swelling ratios, good mechanical properties. The composites also showed excellent antibacterial activity, especially on S. aureus and good biocompatibility. In summary, Cht/SS/AgNPs composites can be used as an alternative polymeric antibacterial materials especially as the wound‐dressing materials or functional packaging materials.

Dynamic Covalent Bonds Enabled Carbon Fiber Reinforced Polymers Recyclability and Material Circularity.

Due to their remarkable features of lightweight, high strength, stiffness, high-temperature resistance, and corrosion resistance, carbon fiber reinforced polymers (CFRPs) are extensively used in sports equipment, vehicles, aircraft, windmill blades, and other sectors. The urging need to develop a resource-saving and environmentally responsible society requires the recycling of CFRPs. Traditional CFRPs, on the other hand, are difficult to recycle due to the permanent covalent crosslinking of polymer matrices. The combination of covalent adaptable networks (CANs) with carbon fibers (CFs) marks a new development path for closed-loop recyclable CFRPs and polymer resins. In this review, we summarize the most recent developments of closed-loop recyclable CFRPs from the unique paradigm of dynamic crosslinking polymers, CANs. These sophisticated materials with diverse functions, oriented towards CFs recycling and resin sustainability, are further categorized into several active domains of dynamic covalent bonds, including ester bonds, imine bonds, disulfide bonds, boronic ester bonds, and acetal linkages, etc. Finally, the possible strategies for the future design of recyclable CFPRs by combining dynamic covalent chemistry innovation with materials interface science are proposed.

Quaternized poly(aryl imidazolium) containing bulky binaphthyl group as proton exchange membrane for high-temperature fuel cells

The low power output and high phosphoric acid (PA) leakage are the main constraints restricting the commercialization of PA-doped high-temperature proton exchange membranes (HT-PEMs). Ionized imidazoles have been shown to be an effective strategy to improve PA retention, however, less research has been conducted on the fractional free volume (FFV) of the backbone of the main chain on PA loss. Herein, novel imidazolium ions polymer (PQBN-4-IM) material with bulky binaphthyl (BN) group was prepared as PA-doped HT-PEM using a one-step superoxid acid catalyzed polycondensation and subsequent methylation process. The rigidity and hydrophobicity of the BN group promote PQBN-4-IM PEM to produce more obvious microphase separation morphology and large FFV, which is beneficial for forming better ion transport channels and excellent PA interaction. Notably, the PA-doped PQBN-4-IM (PQBN-4-IM/PA) membrane has the highest proton conductivity (90.26 mS cm−1, 180 ℃) and peak power density (PPD) (802.5 mW cm−2, 180 ℃) than PQTP-4-IM/PA and m-PBI/PA HT-PEMs. Moreover, the PQBN-4-IM/PA membrane has higher PA retention at 80 ℃/40 % relative humidity (RH), 40 ℃/60 % RH, or immersed in water due to enhancement on ion-pair interactions by microstructure. Under the accelerated stress test (AST) of the fuel cell (FC), the PQBN-4-IM/PA membrane loses only 12.22 % of PPD after 200 cycles at 80 ℃, which exhibits higher PPD retention than that of the PQBP-4-IM/PA (70.23 %), PQTP-4-IM/PA (74.36 %) and m-PBI/PA (65.25 %) membranes, and shows excellent durability of cell performance for more than 1000 h without significant voltage decay at 160 °C. Thus, the outstanding performance suggests that the microstructure and morphology of imidazolium ions polymer membranes significantly influence proton conductivity, performance, and the durability of a cell.

Device for Performing Spirometry in Total Laryngectomized Patients.

Patients who have undergone total laryngectomy (TL) are, in most cases, affected by lung disease due to smoking habits. Therefore, as part of the follow-up protocol for these patients, a spirometry test should be performed to adequately assess lung function. Current spirometers do not allow for spirometry tests in patients who breathe through a tracheostomy, as the patient cannot perform respiratory acts from the spirometer mouthpiece, which is designed to be used by mouth. We have, therefore, designed a device that allows the test to be performed through the tracheostoma. The device is made of biocompatible polymeric material, modeled using a 3-dimensional printer, reusable, and hermetically connected to the spirometer distally and to the tracheostoma proximally. The device was used on 5 patients who underwent TL and was found to be comfortable, safe, and valid for diagnostic purposes.

Pressure-induced formability and degradability of block copolymers composed of poly(1,5-dioxepan-2-one) and poly(L-lactide)

An aliphatic polyether/carbonate block copolymer, comprising poly(1,5-dioxepan-2-one) (PDXO, glass transition temperature Tg: -38°C) and poly(L-lactide) (PLLA, Tg: 55°C), evinces remarkable formability under pressure at temperatures significantly below the melting point of PLLA. A quantitative and detailed evaluation of the low-temperature molding of the block copolymer was conducted using a capillary rheometer. The findings reveal that block copolymers with PDXO composition >55 wt% demonstrate a propensity to flow at room temperature under 50 MPa pressure. Consequently, the practice of low-temperature molding serves to mitigate the degradation of polymer chains during the molding process, thereby augmenting recyclability. Furthermore, the enzymatic degradability of the block copolymer was extensively investigated using lipase PS and proteinase K. An interplay between the structure of the block copolymer and the degradation kinetics was explored. The polymeric materials developed, possessing both pressure formability and degradability, hold promising potential as environmentally benign polymers with reduced environmental impact.

Synthesis and characteristics properties of lignified PVA copolymer with enhanced UV-blocking performance and water solubility

The increasing environmental concerns have heightened the pursuit of sustainable materials, with a particular emphasis on biodegradable polymers. Polyvinyl alcohol (PVA), a recognized biodegradable synthetic polymer, faces challenges such as cost, slow biodegradation, and limited UV resistance. This study explores lignin, an abundant and eco-friendly biopolymer, as a cost-effective additive to enhance PVA properties via the copolymerization technique. The Mannich reaction was utilized to effectively alkylate lignin with allylthiourea, leading to the synthesis of a lignin-based macromonomer (LATU). Subsequently, the LATU macromonomer was copolymerized with vinyl acetate, producing Poly(VAc-Co-LATU) copolymer in a reaction conducted at 70 °C for 6 h. Finally, the copolymers were hydrolyzed (saponification) with potassium hydroxide to obtain Poly(VA-Co-LATU) copolymers. Extensive investigations, including FTIR, XPS, XRD, and 1H NMR, effectively validated the synthesis of the copolymers. The high monomer conversion rate above 89 % emphasizes the effectiveness of the synthesis method. The addition of LATU has a direct impact on the crystalline structure of the copolymer. X-ray diffraction patterns indicate a reduction in crystallinity, which in turn affects the other properties of the synthesized copolymers. Consequently, the lignified copolymer, Poly(VA-co-LATU), exhibited slight decrease in molecular weight (Mw), improved UV-blocking effectiveness, and greater solubility in water as comparison to PVA. This study demonstrates the feasibility of using lignin as a monomer to create novel bio-based polymeric materials that exhibit the necessary properties for certain applications.

Hydrogen Separation Membranes: A Material Perspective

The global energy market is shifting toward renewable, sustainable, and low-carbon hydrogen energy due to global environmental issues, such as rising carbon dioxide emissions, climate change, and global warming. Currently, a majority of hydrogen demands are achieved by steam methane reforming and other conventional processes, which, again, are very carbon-intensive methods, and the hydrogen produced by them needs to be purified prior to their application. Hence, researchers are continuously endeavoring to develop sustainable and efficient methods for hydrogen generation and purification. Membrane-based gas-separation technologies were proven to be more efficient than conventional technologies. This review explores the transition from conventional separation techniques, such as pressure swing adsorption and cryogenic distillation, to advanced membrane-based technologies with high selectivity and efficiency for hydrogen purification. Major emphasis is placed on various membrane materials and their corresponding membrane performance. First, we discuss various metal membranes, including dense, alloyed, and amorphous metal membranes, which exhibit high hydrogen solubility and selectivity. Further, various inorganic membranes, such as zeolites, silica, and CMSMs, are also discussed. Major emphasis is placed on the development of polymeric materials and membranes for the selective separation of hydrogen from CH4, CO2, and N2. In addition, cutting-edge mixed-matrix membranes are also delineated, which involve the incorporation of inorganic fillers to improve performance. This review provides a comprehensive overview of advancements in gas-separation membranes and membrane materials in terms of hydrogen selectivity, permeability, and durability in practical applications. By analyzing various conventional and advanced technologies, this review provides a comprehensive material perspective on hydrogen separation membranes, thereby endorsing hydrogen energy for a sustainable future.

A foundational framework for the mesoscale modeling of dynamic elastomers and gels

Discrete mesoscale network models, in which explicitly modeled polymer chains are replaced by implicit pairwise potentials, are capable of predicting the macroscale mechanical response of polymeric materials such as elastomers and gels, while offering greater insight into microstructural phenomena than constitutive theory or macroscale experiments alone. However, whether such mesoscale models accurately represent the molecular structures of polymer networks requires investigation during their development, particularly in the case of dynamic polymers that restructure in time. We here introduce and compare the topological and mechanical predictions of an idealized, reduced-order mesoscale approach in which only tethered dynamic bonding sites and crosslinks in a polymer’s backbone are explicitly modeled, to those of molecular theory and a Kremer-Grest, coarse-grained molecular dynamics approach. We find that for short chain networks (∼12 Kuhn lengths per chain segment) at intermediate polymer packing fractions, undergoing relatively slow loading rates (compared to the monomer diffusion rate), the mesoscale approach reasonably reproduces the chain conformations, bond kinetic rates, and ensemble stress responses predicted by molecular theory and the bead–spring model. Further, it does so with a 90% reduction in computational cost. These savings grant the mesoscale model access to larger spatiotemporal domains than conventional molecular dynamics, enabling simulation of large deformations as well as durations approaching experimental timescales (e.g., those utilized in dynamic mechanical analysis). While the model investigated is for monodisperse polymer networks in theta-solvent, without entanglement, charge interactions, long-range dynamic bond interactions, or other confounding physical effects, this work highlights the utility of these models and lays a foundational groundwork for the incorporation of such phenomena moving forward.

Measuring linear birefringence via rotating-sample transmission Stokes spectropolarimetry

Linear birefringence is a fundamental property of optically anisotropic media, defined by the difference in refractive index experienced by light polarized along orthogonal directions. It is usually manifested in microscopically aligned molecular systems, where a preferential direction of light–matter interaction is created. For instance, the anisotropic structure of calcite crystal causes the famous double-refraction phenomenon. Another common example is commercial adhesive tapes, which are polymeric materials possessing birefringent properties due to their manufacturing processes. The intrinsic relation between birefringence and molecular alignment forges a new analytical route to study materials such as polymeric thin films. Therefore, the capacity of measuring linear birefringence and its fast axis is of paramount importance for the science of anisotropic molecular systems. In this contribution, a comprehensive approach to acquire linear birefringence using rotating-sample transmission Stokes spectropolarimetry is presented and applied to transparent adhesive tapes as a case study. The experimental setup comprises a thermal light source and a spectropolarimeter capable of determining wavelength distributions of Stokes parameters. The samples are carefully aligned in a rotating mount and subjected to a fixed broadband vertically polarized light beam. Then, the transmitted light is analyzed using a rotating retarder type of spectropolarimeter. Through systematic variation of the sample’s angular position, the Stokes parameters of transmitted light are measured for each transmitted wavelength as a function of the sample’s angular position. The linear retardance and fast axis direction relative to the tape’s long axis are then determined from the modulation of Stokes parameters over sample rotation. The model derivation, experimental procedure, and signal processing protocol are described in detail, and the approach is verified with a simple correlation between linear retardance and the number of stacked layers of tape.