Polymeric Materials Research Articles

Morphological Study before and after Thermal Treatment of Polymer-Polymer Mixed-Matrix Membranes for Gas Separations.

A good integration of the polymer materials that form a mixed-matrix membrane (MMM) for gas separation is essential to reaching interesting permselective properties. In this work, a porous polymer network (PPN), obtained by combining triptycene and trifluoroacetophenone, has been used as a filler, which was blended with two o-hydroxypolyamides (HPAs) that act as polymer matrices. These polymer matrices have been thermally treated to induce a thermal rearrangement (TR) of the HPAs to polybenzoxazoles (β-TR-PBOs) through a solid-state reaction. For its structural study, various techniques have been proposed that allow us to undertake a morphological investigation into the integration of these materials. To access the internal structure of the MMMs, three different methods were used: a polishing process for the material surface, the partial dissolution of the polymer matrix, or argon plasma etching. The argon plasma technique has not only revealed its potential to visualize the internal structure of these materials; it has also been proven to allow for the transformation of their permselective properties. Force modulation and phase contrast in lift-mode techniques, along with the topographic images obtained via the tapping mode using a scanning probe microscope (SPM), have allowed us to study the distribution of the filler particles and the interaction of the polymer and the filler. The morphological information obtained via SPM, along with that of other more commonly used techniques (SEM, TGA, DSC, FTIR, WASX, gas adsorption, and permeability measurements), has allowed us to postulate the most probable structural configuration in this type of system.

Green conversion of carbon disulfide to degradable polydithiourethanes through catalyst-free multicomponent polymerizations of diamines, carbon disulfide and diacrylates

In the pursuit of advanced functional polymer materials, sulfur-containing polymers have received tremendous attention owing to their superior chemical stability, high refractive indices, various supramolecular interactions, and robust dynamic covalent chemistry. However, their synthesis usually involves either expensive monomers or toxic byproducts and requires catalysts, thus hindering their widespread application. In this work, we present a catalyst-free multicomponent polymerization in organic solvents for the synthesis of various polydithiourethanes with excellent yields (up to 98 %) and high molecular weights (up to 112 kg/mol). This reaction involves the direct polymerization of carbon disulfide, an abundant one-carbon feedstock, with commercially available diamines and diacrylates. This polyaddition process demonstrates high atom economy and no byproduct, occurring at room temperature without the need for a catalyst, thus exhibiting excellent green chemistry metrics. By utilizing the dynamic covalent chemistry of dithiourethane groups, these polymers can be efficiently degraded via aminolysis and used to fabricate reprocessable vitrimers. This multicomponent polymerization opens up a new avenue for the efficient utilization of carbon disulfide resources and accelerates the exploration of diversified sulfur-containing functional polymer materials.

A comparative and experimental study to evaluate the use of nanocontainer solutions for removing polymeric coatingsfrom glass artifacts

Purpose The purpose of this study is to evaluate the effectiveness of nanocontainer solutions in removing deteriorated and aged polymers commonly used in coating and consolidating archaeological glass. Design/methodology/approach This study focused on characterizing glass surfaces coated with two commonly used polymeric materials in archaeological glass preservation. Furthermore, the study evaluates the elimination of these coatings from the surfaces by using innovative aqueous systems composed of micellar solutions (MS) and oil-in-water (O/W) Texapon-P microemulsions (TEX). Glass samples coated with selected polymers were subjected to thermal and photochemical aging to simulate natural degradation conditions. This study aimed to evaluate the effectiveness of nanocontainer aqueous systems compared to acetone (Ac), a conventional solvent commonly used for removal procedures. The characterization procedures involved transmission electron microscopy, USB digital microscopy, scanning electron microscopy, color alteration and gravimetric measurement. Findings The findings indicate that the effectiveness of novel techniques using aqueous nanocontainer systems is quite promising when considering a “green approach” to preserving cultural heritage. Microscopic examination demonstrated the efficacy of MS in effectively removing acrylic and vinyl polymers from the glass surface. Furthermore, TEX proved effective in removing polyvinyl acetate (PVA) over Paraloid B72 (B-72). In addition, the measurement of color alteration values revealed a decrease after using MS compared to the standard sample before applying the polymers, with values of ΔE = 1.48 and 1.82 for B-72 polymer and PVA, respectively. Originality/value This research provides nanocontainer solutions for removing aged polymers from the glass surface. This makes the current study a promising step for treating archaeological glass.

A review on retrofitting concrete members with near‐surface mounted‐fiber reinforced polymer composites

AbstractIn an era flooded with a multitude of studies investigating the performance of concrete structures retrofitted using fiber‐reinforced polymer (FRP) materials, this review addresses the critical need for a comprehensive overview of the retrofitting of concrete members using near‐surface mounted (NSM)‐FRP composites, aiming to save time and effort while providing engineers and research community with valuable resources relevant to the field. This review focuses on the key factors influencing both the flexural and shear retrofitting processes of reinforced concrete (RC) beams, such as the percentage, type, size and geometry of NSM‐FRP reinforcement, as well as groove design, groove‐filling materials and beam depth. Moreover, the paper explores the failure modes associated with each retrofitting type, for example, debonding failures, shear/flexural failure and rupture of steel or NSM‐FRP reinforcement, to name a few. The review also delves into the bond behavior of NSM‐FRP‐bonded joints, examining factors, such as the bonded length, surface texture of NSM‐FRP reinforcement and type of bonding agent, which would affect the bond behavior and strength of the joints. The failure mechanisms associated with the bonded joints, such as interfacial bond failure, FRP rupture and splitting of the adhesive cover, are also highlighted. Finally, this compilation aims to guide engineers and researchers by offering a critical and comprehensive database for optimal designs, further development and suggesting future research directions.

Fluorophilic Sigma(σ)‐Lock Self‐Healable Copolymers

Although F‐containing molecules and macromolecules are often used in molecular biology to increase the binding with Lewis acidic groups by introducing favorable C‐F dipoles, there is virtually no experimental evidence and limited understanding of the nature of these interactions, especially their role in synthetic polymeric materials. These studies elucidate the molecular origin of inter‐ and intra‐chain interactions responsible for self‐healing of F‐containing copolymers composed of pentafluorostyrene and n‐butyl acrylate units (p(PFS/nBA). Guided by dynamic surface oscillating force (SOF) and spectroscopic measurements supported by molecular dynamics (MD) simulations, these studies show that the reformation of σ‐σ orbitals in ‐C‐F of PFS and CH3CH2‐ of nBA units enables the recovery of entropic energy via flouorophilic‐σ‐lock van der Waals forces when PFS/nBA molar ratios are ~50/50. The strength of these interactions determined experimentally for self‐healable PFS/nBA compositions is in the order ~0.3 kcal/mol which primarily comes from flouorophilic‐σ‐lock (~70%) contributions. These interactions are significantly diminished for non‐self‐healable counterparts. Strongly polarized ‐C‐F σ orbitals create lateral dipolar forces enhancing the affinity towards ‐C‐H orbitals, facilitating energetically favorable interactions. Entropic recovery driven by non‐covalent bonding offers a valuable tool in designing materials with unique functionalities, particularly self‐healable batteries or other energy storage devices.

Fluorophilic Sigma(σ)-Lock Self-Healable Copolymers.

Although F-Containing molecules and macromolecules are often used in molecular biology to increase the binding with Lewis acidic groups by introducing favorable C-F dipoles, there is virtually no experimental evidence and limited understanding of the nature of these interactions, especially their role in synthetic polymeric materials. These studies elucidate the molecular origin of inter- and intra-Chain interactions responsible for self-healing of F-Containing copolymers composed of pentafluorostyrene and n-butyl acrylate units (p(PFS/nBA). Guided by dynamic surface oscillating force (SOF) and spectroscopic measurements supported by molecular dynamics (MD) simulations, these studies show that the reformation of σ-σ orbitals in -C-F of PFS and CH3CH2- of nBA units enables the recovery of entropic energy via fluorophilic-σ-lock van der Waals forces when PFS/nBA molar ratios are ~50/50. The strength of these interactions determined experimentally for self-healable PFS/nBA compositions is in the order ~0.3 kcal/mol which primarily comes from fluorophilic-σ-lock (~70 %) contributions. These interactions are significantly diminished for non-self-healable counterparts. Strongly polarized -C-F σ orbitals create lateral dipolar forces enhancing the affinity towards -C-H orbitals, facilitating energetically favorable interactions. Entropic recovery driven by non-Covalent bonding offers a valuable tool in designing materials with unique functionalities, particularly self-healable batteries and energy storage devices.

Synergistic enhancement mediated sensitive SERS-based immunoassay of PSA using versatile PDMS@AgNPs@ZIF-67 biomimetic substrates

Among various biomimetic polymer materials, polydimethylsiloxane (PDMS) stands out as an ideal matrix for surface-enhanced Raman scattering (SERS) due to its unique intrinsic Raman signal and tenacity. In order to realize the precise detection of prostate-specific antigen (PSA), we proposed a sandwich-type SERS-active immunostructure composed of PDMS@silver nanoparticles (Ag NPs)@ZIF-67 biomimetic film as the immunosubstrate and gold nanorods (Au NRs) as immunoprobes. Due to the synergistic effect of electromagnetic enhancement facilitated by biomimetic surfaces and chemical enhancement achieved by ZIF-67, this structure enabled an ultrasensitive and selective detection of PSA across a broad range from 10−3 to 10−9 mg/mL. The achieved limit of detection was as low as 3.0 × 10−10 mg/mL. Particularly, the intrinsic Raman signal of PDMS matrix at 2905 cm−1 was employed as a potential internal standard (IS) in the detection, achieving a high coefficient of determination (R2) value of 0.996. This multifunctional SERS substrate-mediated immunoassay holds vast potential for early diagnosis of prostate cancer, offering promising prospects for clinical applications.

4D printed shape memory bismaleimide resin with high storage modulus and low shrinkage rate via second-stage curing

In recent years, the field of shape memory materials with active deformation capabilities has experienced rapid development. However, bismaleimide, as a widely used structural material in the aerospace industry, has been neglected in the field of shape memory. This work designed a UV-crosslinked network with 1-vinyl-2-pyrrolidone monomer, and prepared 4D printed smart structures based on shape memory bismaleimide resin through UV-assisted DIW printing. 4D printed semi-interpenetrating network polymer materials were obtained through a two-stage UV-thermal curing process, resulted in an increase in the material's glass transition temperature to a maximum of 187.4 °C. The storage modulus was improved to 5229 MPa. More important, we achieved a lowest shrinkage rate (0.21 %) of 4D printed polymer. The composite sandwich structure with electrical-driven shape memory performance was printed by double-sided printing of bismaleimide resin on conductive carbon fabric. 4D printed composite structure realizes in-situ self-blocking secondary curing, deformation process after curing. This significant progress provides a promising prospect for remote controllable and precise driving in the aerospace field.

Exploiting Waste towards More Sustainable Flame-Retardant Solutions for Polymers: A Review.

The development of sustainable flame retardants is gaining momentum due to their enhanced safety attributes and environmental compatibility. One effective strategy is to use waste materials as a primary source of chemical components, which can help mitigate environmental issues associated with traditional flame retardants. This paper reviews recent research in flame retardancy for waste flame retardants, categorizing them based on waste types like industrial, food, and plant waste. The paper focuses on recent advancements in this area, focusing on their impact on the thermal stability, flame retardancy, smoke suppression, and mechanical properties of polymeric materials. The study also provides a summary of functionalization methodologies used and key factors involved in modifying polymer systems. Finally, their major challenges and prospects for the future are identified.

IMAC application of extracellular polymeric substances doped composite membranes for α-amylase immobilization and kinetic studies

Immobilized metal affinity chromatography (IMAC), extensively utilized technique in affinity chromatography, has proven to be highly effective in purifying α-amylase, a crucial enzyme in industrial applications. Here, Poly (2-hydroxyethyl methacrylate) (PHEMA) based composite membranes were fabricated using the radical copolymerization technique in a petri dish. Extracellular polymeric materials (EPS) as the metal binding agent. The attachment of Cu2+ ions to the membranes occurred through the utilization of EPSs (Cu2+-EPS). The membranes having Cu2+-EPS (Cu2+-EPS-PM) were subjected to various characterization techniques, including scanning electron microscopy (SEM), attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR), swelling tests, and surface area measurements. The investigation also encompassed the examination of various factors, including pH, initial α-amylase concentration, temperature, and ionic strength, that exert an influence on the adsorption of α-amylase from an aqueous medium. The Cu2+-EPS-PMs demonstrated maximum adsorption capacity with a value of 54.2 mg/g polymer (pH 5.0 sodium acetate buffer, temperature: 25°C, initial α-amylase concentration of 2 mg/mL). Additionally, it has been observed that the enzyme is able to be used in adsorption and desorption cycles on Cu2+-EPS-PM many times. The investigation also focused on examining the impact of pH, temperature, storage, and operational stability over the activities of both free and immobilized α-amylase. The outcomes showed that immobilization had positive effects on activity.

Intrinsically Stretchable Organic Thermoelectric Polymers Enabled by Incorporating Fused-Ring Conjugated Breakers.

While research on organic thermoelectric polymers is making significant progress in recent years, realization of a single polymer material possessing both thermoelectric properties and stretchability for the next generation of self-powered wearable electronics is a challenging task and remains an area yet to be explored. A new molecular engineering concept of "conjugated breaker" is employed to impart stretchability to a highly crystalline diketopyrrolepyrrole (DPP)-based polymer. A hexacyclic diindenothieno[2,3-b]thiophene (DITT) unit, with two 4-octyloxyphenyl groups substituted at the tetrahedral sp3-carbon bridges, is selected to function as the conjugated breaker that can sterically hinder intermolecular packing to reduce polymers' crystallinity. A series of donor-acceptor random copolymers is thus developed via polymerizing the crystalline DPP units with the DITT conjugated breakers. By controlling the monomeric DPP/DITT ratios, DITT30 reaches the optimal balance of crystalline/amorphous regions, exhibiting an exceptional power factor (PF) value up to 12.5 µW m-1 K-2 after FeCl3-doping; while, simultaneously displaying the capability to withstand strains exceeding 100%. More significantly, the doped DITT30 film possesses excellent mechanical endurance, retaining 80% of its initial PF value after 200 cycles of stretching/releasing at a strain of 50%. This research marks a pioneering achievement in creating intrinsically stretchable polymers with exceptional thermoelectric properties.

Evaluation of the Degree of Degradation of Brake Pad Friction Surfaces Using Image Processing

The improvement of drilling rig systems to ensure a reduction in unproductive time spent on lowering and lifting operations for replacing drilling tools and restoring the performance of drilling equipment units is an important task. At the same time, considerable attention is paid to the reliable and efficient operation of the braking systems of drilling rig winches. In the process of operation, the polymer pads periodically come into contact with the outer cylindrical surface of the metal pulley during braking, work in extreme conditions and wear out intensively, so they need periodic replacement. Tests were carried out on a modernized stand and in industrial conditions for the brakes of drilling winches. A methodology for evaluating the degradation of the brake pad friction surface during its operation is proposed. The assessment of the degradation degree is carried out based on the image of the brake pad surface using image processing techniques. Geometric transformations of the input image were performed to avoid perspective distortions caused by the concave shape of the brake pads and the spatial angle at which the image is acquired to avoid glares. The crack detection step was implemented based on the scale-space theory, followed by contour detection and skeletonization. The ratios of the area and perimeter of segmented and skeletonized cracks to the total area were chosen as integral characteristics of the degradation degree. With the help of scanning electron microscopy, the character of the destruction of the friction surface and the degradation of the polymer material was investigated. Experimental studies were performed, and the application of the proposed method is illustrated.

Recovery of Ag(I) from Wastewater by Adsorption: Status and Challenges.

Untreated or inadequately treated silver-containing wastewater may pose adverse effects on hu-man health and the ecological environment. Currently, significant progress has been made in the treatment of Ag(I) in wastewater using adsorption methods, with adsorbents playing a pivotal role in this process. This paper provides a systematic review of various adsorbents for the recovery and treatment of Ag(I) in wastewater, including MOFs, COFs, transition metal sulfides, metal oxides, biomass materials, and other polymeric materials. The adsorption mechanisms of these materials for Ag(I) are elaborated upon, along with the challenges currently faced. Furthermore, insights into optimizing adsorbents and developing novel adsorbents are proposed in this study.

Materials and Methods for All-Cellulose 3D Printing in Sustainable Additive Manufacturing

Additive manufacturing, commonly referred to as 3D printing, is an exciting and versatile manufacturing technology that has gained traction and interest in both academic and industrial settings. Polymeric materials are essential components in a majority of the feedstocks used across the various 3D printing technologies. As the environmental ramifications of sole or primary reliance on petrochemicals as a resource for industrial polymers continue to manifest themselves on a global scale, a transition to more sustainable bioderived alternatives could offer solutions. In particular, cellulose is promising due to its global abundance, biodegradability, excellent thermal and mechanical properties, and ability to be chemically modified to suit various applications. Traditionally, native cellulose was incorporated in additive manufacturing applications only as a substrate, filler, or reinforcement for other materials because it does not melt or easily dissolve. Now, the exploration of all-cellulose 3D printed materials is invigorated by new liquid processing strategies involving liquid-like slurries, nanocolloids, and advances in direct cellulose solvents that highlight the versatility and desirable properties of this abundant biorenewable photosynthetic feedstock. This review discusses the progress of all-cellulose 3D printing approaches and the associated challenges, with the purpose of promoting future research and development of this important technology for a more sustainable industrial future.

A Comparative Study of "Grafting to" and "Grafting from" Conjugation Methods for the Preparation of Antibody-Temperature-Responsive Polymer Conjugates.

Early diagnosis of infectious diseases is still challenging particularly in a nonlaboratory environment or limited resources areas. Thus, sensitive, inexpensive, and easily handled diagnostic approaches are required. The lateral flow immunoassay (LFIA) is commonly used in the screening of infectious diseases despite its poor sensitivity, especially with low pathogenic loads (early stages of infection). This article introduces a novel polymeric material that might help in the enrichment and concentration of pathogens to overcome the LFIA misdiagnosis. To achieve this, we evaluated the efficiency of introducing poly(N-isopropylacrylamide) (PNIPAAm) into immunoglobulin G (IgG) as a model antibody using two different conjugation methods: grafting to (GT) and grafting from (GF). The IgG-PNIPAAm conjugates were characterized using SDS-PAGE, DLS, and temperature-responsive phase transition behavior. SDS-PAGE analysis revealed that the GF method was more efficient in introducing the polymer than the GT method, with calculated polymer introduction ratios of 61% and 34%, respectively. The GF method proved to be less susceptible to steric hindrance and more efficient in introducing high-molecular-weight polymers into proteins. These results are consistent with previous studies comparing the GT and GF methods in similar systems. This study represents an important step toward understanding how the choice of polymer incorporation method affects the properties of IgG-PNIPAAm conjugates. The synthesized polymer allowed binding and enrichment of mouse IgG that was used as a model antigen with a clear LFIA band. On the basis of our findings, this system might help in improving the sensitivity of simple diagnostics.

Review and Assessment of Material, Method, and Predictive Modeling for Fiber-Reinforced Polymer (FRP) Partially Confined Concrete Columns.

The repairing and strengthening of concrete structures using external and internal partial confinements are inevitable in the construction industry due to the new standards and rapid developments. The conventional materials and methods of confinement are unable to meet modern safety and functional standards. The fiber-reinforced polymer (FRP) enhances the strength and ductility of deteriorating and new concrete columns by reducing lateral confinement pressure and resistance against seismic shocks. The precise methods of partial confinement are inevitable for effective FRP-concrete bonding, durability, and cost-effectiveness under different loading conditions and to cope with external environmental factors. Predictive modeling and simulation techniques are pivotal for the optimization of confinement materials and methods by investigating the FRP-concrete novel confinement configurations, stress-strain responses, and failure modes. The novel materials and methods for concrete columns' partial confinement lack high compressive strength, ductility, chemical attack resistivity, and different fiber orientation impacts. This review provides an overview of recent confinement materials, novel methods, and advanced modeling and simulation techniques with a critical analysis of the research gaps for partial FRP confinement of concrete columns. The current challenges and future prospects are also presented.

Binder-free all-carbon composite supercapacitors

Carbon-based electrode materials have widely been used in supercapacitors. Unfortunately, the fabrication of the supercapacitors includes a polymeric binding material that leads to an undesirable addition of weight along with an increased charge transfer resistance. Herein, binder-free and lightweight electrodes were fabricated using powder processing of carbon nanofibers (CNFs) and graphene nanoplatelets (GNPs) resulting in a hybrid all-carbon composite material. The structural, morphological, and electrochemical properties of the composite electrodes were studied at different concentrations of GNPs. The specific capacitance (Cs) of the CNFs/GNPs composite was improved by increasing the concentration of GNPs. A maximum Cs of around 120 F g−1 was achieved at 90 wt% GNPs which is around 5-fold higher in value than the pristine CNFs in 1 M potassium hydroxides (KOH), which then further increased to 189 F g−1 in 6 M KOH electrolyte. The energy density of around 20 Wh kg−1 with the corresponding power density of 340 W kg−1 was achieved in the supercapacitor containing 90 wt% GNPs. The enhanced electrochemical performance of the composite is related to the presence of a synergistic effect and the CNFs establishing conductive/percolating networks. Such binder-free all-carbon electrodes can be a potential candidate for next-generation energy applications.

The influence of face mask color on perceptions of African American and white men.

Despite their widespread use during the COVID-19 pandemic, face masks hinder abilities to interpret facial expressions. Yet, they can also reduce the appearance of characteristics that are used to categorize individuals into racial groups, such as Afrocentric features. The color of a face mask might also promote associations with certain types of behavior and professional occupations (e.g., blue surgical mask connoting physician stereotypes; black masks potentially being associated with criminality). This study assessed whether the presence and color of a face mask impacted perceptions of a target male of varying race. White participants (N = 250) were presented with an African American or White male adult face from the Chicago Face Database (of equal age and attractiveness) wearing a blue or black surgical mask, or no mask (Photoshopped onto the face) and rated the man on emotions (happy, sad, angry) as well as how trustworthy, threatening, and attractive the target appeared. Targets wearing a blue surgical mask were judged as more trustworthy and attractive than those wearing no mask (perhaps due to association with medical professions), but these judgements were not qualified by race, despite the African American target's selection based on Afrocentric features. The color black on a face mask did not exacerbate negative perceptions of targets, perhaps suggesting a decline effect in previously demonstrated associations between this color and criminal actions. Unlike previous research performed at the beginning of the Covid-19 Pandemic on cloth masks shown to potentially exacerbate racial biases, surgical masks (pleated and made of polymeric materials), appear to lessen potential stereotyping of Black relative to White men.

Computational Insights into Cyclodextrin Inclusion Complexes with the Organophosphorus Flame Retardant DOPO.

Cyclodextrins (CDs) were used as green char promoters in the formulation of organophosphorus flame retardants (OPFRs) for polymeric materials, and they could reduce the amount of usage of OPFRs and their release into the environment by forming [host:guest] inclusion complexes with them. Here, we report a systematic study on the inclusion complexes of natural CDs (α-, β-, and γ-CD) with a representative OPFR of DOPO using computational methods of molecular docking, molecular dynamics (MD) simulations, and quantum mechanical (QM) calculations. The binding modes and energetics of [host:guest] inclusion complexes were analyzed in details. α-CD was not able to form a complete inclusion complex with DOPO, and the center of mass distance [host:guest] distance amounted to 4-5 Å. β-CD and γ-CD allowed for a deep insertion of DOPO into their hydrophobic cavities, and DOPO was able to frequently change its orientation within the γ-CD cavity. The energy decomposition analysis based on the dispersion-corrected density functional theory (sobEDAw) indicated that electrostatic, orbital, and dispersion contributions favored [host:guest] complexation, while the exchange-repulsion term showed the opposite. This work provides an in-depth understanding of using CD inclusion complexes in OPFRs formulations.

Solar-powered porous polymer materials-enabled rapid atmospheric water harvesting and storage of liquid water

Atmospheric water harvesting (AWH) is emerging as a promising strategy to produce fresh water from abundant airborne moisture to reduce the global clean water shortage. Hydrogels are considered attractive adsorbents due to their higher water retention and tunable polymer-water interactions. Here, we report the super hygroscopic polymer material (SHPMs) using modified NH2-MIL-101(Cr) as a functional crosslinker by copolymerization with acrylic acid and 2-Acrylamide-2-methylpropanesulfonic acid, achieving a water uptake of about 28.8–49.7 mg/g at 28–38 % RH. The material can desorption quickly under sunlight, and the desorbed water can be stored in a polymer skeleton for use by vegetation or crops during periods of water demand. Besides, the Water retention and storage performance and its outdoor experiment also proved that the application of this material in agriculture, forestry and desertification control laid the foundation to improve the effective availability of soil moisture and water harvesting and conservation. With its excellent water retention and atmospheric water harvesting performance, the material offers a sustainable method for rapid water extraction in arid climates.