Photoacoustic Gas Sensor Research Articles

Miniature optical fiber photoacoustic spectroscopy gas sensor based on a 3D micro-printed planar-spiral spring optomechanical resonator

Photoacoustic spectroscopy (PAS) gas sensors based on optomechanical resonators (OMRs) have garnered significant attention for ultrasensitive trace-gas detection. However, a major challenge lies in balancing small size with high performance when developing ultrasensitive miniaturized optomechanical resonant PAS (OMR-PAS) gas sensors for space-constrained applications. Here, we present a miniature optical fiber PAS gas sensor based on a planar-spiral spring OMR (PSS-OMR) that is in situ 3D micro-printed on the end-face of a fiber-optic ferrule. Experimental results demonstrate that mechanical vibrational resonance can enhance the sensor's acoustic sensitivity by over two orders of magnitude. Together with a 1.4 μL non-resonant photoacoustic cell, it can detect C2H2 gas concentration at the 45-ppb level, and its response is very fast approximating 0.2 seconds. This optical fiber OMR-PAS gas sensor holds great promise for the detection or monitoring of rapidly varying trace gas in many applications ranging from production process control to industrial environmental surveillance.

A Review on Photoacoustic Spectroscopy Techniques for Gas Sensing.

The rapid growth of industry and the global drive for modernization have led to an increase in gas emissions, which present significant environmental and health risks. As a result, there is a growing need for precise and sensitive gas-monitoring technologies. This review delves into the progress made regarding photoacoustic gas sensors, with a specific focus on the vital components of acoustic cells and acoustic detectors. This review highlights photoacoustic spectroscopy (PAS) as an optical detection technique, lauding its high sensitivity, selectivity, and capability to detect a wide range of gaseous species. The principles of photoacoustic gas sensors are outlined, emphasizing the use of modulated light absorption to generate heat and subsequently detect gas pressure as acoustic pressure. Additionally, this review provides an overview of recent advancements in photoacoustic gas sensor components while also discussing the applications, challenges, and limitations of these sensors. It also includes a comparative analysis of photoacoustic gas sensors and other types of gas sensors, along with potential future research directions and opportunities. The main aim of this review is to advance the understanding and development of photoacoustic gas detection technology.

Highly sensitive photoacoustic gas sensor based on near-concentric cavity.

The precise detection of trace gases in the atmosphere is vital for both environmental preservation and human health. Addressing the inherent challenges in enhancing the sensitivity of photoacoustic spectroscopy, a highly sensitive photoacoustic gas detection method utilizing a near-concentric cavity was proposed. By constructing a near-concentric optical cavity, laser reflections within the photoacoustic cell were substantially amplified, resulting in enhanced sensitivity of photoacoustic signal detection. Additionally, to align with the optical path characteristics of the near-concentric cavity, a miniaturized dumbbell-like photoacoustic cell was designed. Characterized by its high-frequency resonance, this design effectively mitigated background noise while maintaining a high sound pressure level. Experimental results demonstrated a remarkable enhancement in both signal intensity and signal-to-noise ratio by factors of 22.06 and 21.26, respectively, compared to traditional excitation methods. According to the 1σ standard, with a laser power of 21 mW, the setup achieved a detection limit of 10.15 ppb for NO2. The corresponding normalized noise equivalent absorption was calculated to be 2.84 × 10-9 cm-1WHz-1/2, with a gas consumption rate of merely 15.19 mL.

Wavelength-modulated photoacoustic spectroscopic instrumentation system for multiple greenhouse gas detection and in-field application in the Qinling mountainous region of China

We present a sensitive and compact quantum cascade laser-based photoacoustic greenhouse gas sensor for the detection of CO2, CH4 and CO and discuss its applicability toward on-line real-time trace greenhouse gas analysis. Differential photoacoustic resonators with different dimensions were used and optimized to balance sensitivity with signal saturation. The effects of ambient parameters, gas flow rate, pressure and humidity on the photoacoustic signal and the spectral cross-interference were investigated. Thanks to the combined operation of in-house designed laser control and lock-in amplifier, the gas detection sensitivities achieved were 5.6 ppb for CH4, 0.8 ppb for CO and 17.2 ppb for CO2, signal averaging time 1 s and an excellent dynamic range beyond 6 orders of magnitude. A continuous outdoor five-day test was performed in an observation station in China’s Qinling National Botanical Garden (E longitude 108°29’, N latitude 33°43’) which demonstrated the stability and reliability of the greenhouse gas sensor.

A dual‐resonance enhanced photoacoustic spectroscopy gas sensor based on a fiber optic cantilever beam microphone and a spherical photoacoustic cell

AbstractWe propose a novel high‐performance dual‐resonance enhanced photoacoustic spectroscopy (DRE‐PAS) gas sensor based on a highly sensitive fiber optic cantilever beam microphone and a high‐Q spherical photoacoustic cell (PAC). The first‐order resonant frequency (FORF) of the spherical PAC is analyzed by finite element analysis to match the FORF of the cantilever microphone for the double resonance enhancement of the photoacoustic signal. The photoacoustic spectroscopy (PAS) system, including the DRE‐PAS sensor, a 1532.8 nm distributed feedback laser, and a high‐speed spectrometer, has been successfully exploited for trace acetylene (C2H2) detection. The experimental results show that the limit of detection (LOD) is 106.8 parts‐per‐billion (ppb) with an integral time of 1 s, and the LOD can be further reduced to 11.03 ppb by Allan‐Werle deviation for 100 s integral time. The normalized noise equivalent absorption coefficient can be obtained as 2.44 × 10−8 cm−1 WHz−1/2. The reported DRE‐PAS gas sensor has the superior characteristics of photoacoustic signal enhancement, high sensitivity, and strong antielectromagnetic interference capability, which can provide a new solution for PAS development.

Photoacoustic trace gas detection of OCS using a 2.45 mL Helmholtz resonator and a 4823.3 nm ICL light source

A miniaturized photoacoustic spectroscopy-based gas sensor is proposed for the purpose of detecting sub-ppm-level carbonyl sulfide (OCS) using a tunable mid-infrared interband cascade laser (ICL) and a Helmholtz photoacoustic cell. The tuning characteristics of the tunable ICL with a center wavelength of 4823.3 nm were investigated to achieve the optimal driving parameters. A Helmholtz photoacoustic cell with a volume of ∼2.45 mL was designed and optimized to miniaturize the measurement system. By optimizing the modulation parameters and signal processing, the system was verified to have a good linear response to OCS concentration. With a lock-in amplifier integration time of 10 s, the 1σ noise standard deviation in differential mode was 0.84 mV and a minimum detection limit (MDL) of 409.2 ppbV was achieved at atmospheric pressure and room temperature.

Fiber optic photoacoustic gas sensor enhanced by multi-pass cell with overlapping phantom spots

A neotype fiber optic photoacoustic gas sensor with overlapping phantom spots based multi-pass is proposed, which greatly improves the reflection times and the length of gas absorption path. Moreover, the detection accuracy of photoacoustic spectroscopy (PAS) system is independent of the optical interference effect caused by overlapping spots, which is different from tunable diode laser absorption spectroscopy (TDLAS) technology. A mathematical model including light beam motion space, spot size and overlap discrimination of multi-pass structure based on overlapping phantom spots is established. The incident light is reflected up to dozens of times in the resonator with a diameter of only 8 mm. The emergent light does not need to converge on a photodetector, which reduces the difficulty of adjusting the optical path and promotes the realization of overlapping phantom spots. The experimental results show that the amplitude of photoacoustic signal is improved by about 40 times compared with the single spot structure. Appling high-sensitivity optical fiber cantilever to detect the sound pressure signal. The detection limit of C2H2 gas reaches 8.2 ppt. The normalized noise equivalent absorption (NNEA) coefficient of the gas sensor is achieved to be 9.3×10−11 cm−1WHz−1/2.

Wavelet-Based Machine Learning Algorithms for Photoacoustic Gas Sensing

The significance of intelligent sensor systems has grown across diverse sectors, including healthcare, environmental surveillance, industrial automation, and security. Photoacoustic gas sensors are a promising type of optical gas sensor due to their high sensitivity, enhanced frequency selectivity, and fast response time. However, they have limitations such as dependence on a high-power light source, a requirement for a high-quality acoustic signal detector, and sensitivity to environmental factors, affecting their accuracy and reliability. Machine learning has great potential in the analysis and interpretation of sensor data as it can identify complex patterns and make accurate predictions based on the available data. We propose a novel approach that utilizes wavelet analysis and neural networks with enhanced architectures to improve the accuracy and sensitivity of photoacoustic gas sensors. Our proposed approach was experimentally tested for methane concentration measurements, showcasing its potential to significantly advance the field of gas detection and analysis, providing more accurate and reliable results.

Dense Multibutterfly Spots-Enhanced Miniaturized Optical Fiber Photoacoustic Gas Sensor.

A miniaturized optical fiber photoacoustic gas sensor enhanced by dense multibutterfly spots is reported for the first time. The principle of space light transmission of neglecting paraxial approximation is theoretically analyzed for designing a dense multibutterfly spots-based miniature multipass cell. In a multipass photoacoustic tube with a diameter of 16 mm, the light beam is reflected about a hundred times. The light spots on the mirror surfaces at both ends of the photoacoustic tube form a dense multibutterfly distribution. The volume of the micro multipass gas chamber is only 5.3 mL. An optical fiber cantilever based on F-P interference is utilized as a photoacoustic pressure detector. Compared with that of the single-pass structure, the gas detection ability of the photoacoustic system with dense multibutterfly spots is improved by about 50 times. The proposed miniaturized sensor realizes a detection limit of 3.4 ppb for C2H2 gas with an averaging time of 100 s. The recognized coefficients of minimum detectable absorption (αmin) and normalized noise equivalent absorption are 1.9 × 10-8 cm-1 and 8.4 × 10-10 W cm-1 Hz-1/2, respectively.

A high-performance infrared photoacoustic sensor with improved low-frequency response microphone

Infrared photoacoustic gas sensors with the advantages of good selectivity, low interference, fast response speed, good stability, high accuracy, good explosion-proof performance, high signal-to-noise ratio, and long service life, have developed rapidly in recent years. In order to solve the problem of poor low-frequency response performance of the MEMS piezoelectric thin film microphone sensor prepared with AlN and Mo thin films in infrared photoacoustic gas sensors, this article analyzes its principle and tests an improved solution. The internal stress distribution was changed through hot tempering experiments, significantly improving its structure. The article qualitatively and quantitatively analyzes the inherent mechanism of this phenomenon. The experimental results confirm that the improved scheme improves its response performance under low-frequency signals, with good stability and repeatability.

Miniature diffusive mid-infrared photoacoustic gas sensor for carbon dioxide detection

A low-cost miniature diffusive infrared photoacoustic (PA) sensor (MDIPS) was proposed and designed for the detection of carbon dioxide. To reduce the volume and the power consumption, the air pumps and air valves in the traditional PA sensing system were replaced by a breathable hole and filter membrane. Through finite element analysis, the radius of the optimized membrane was selected between 0.2 μm and 0.5 μm. Rapid gas exchange is achieved while effectively suppressing the loss of PA pressure. In addition, a micro-electro-mechanical (MEMS) mid-infrared thermal light source and a MEMS microphone were integrated into the PA sensor. Through theoretical analysis and experimental verification, the volume of the cooper tube in the PA sensor was designed as only 126 μL. A signal processing algorithm combining lock-in amplification and Kalman filtering was implemented in a microcontroller to extract the weak PA signal from a background of substantial interference. The designed sensor achieved a minimum detection limit (MDL) of 2.6 ppm for CO2. The response time measured by 10 %–90 % step was 136 s.

Miniature mid-infrared photoacoustic gas sensor for detecting dissolved carbon dioxide in seawater

A miniature mid-infrared photoacoustic (PA) gas sensor with a chamber volume of approximately 73 μL for detection of dissolved gases in seawater was presented. This sensor offers several advantages: small size, high sensitivity, low cost, and low power consumption. The strong absorption band of carbon dioxide (CO2) near 4.26 µm was targeted by utilizing a mid-infrared microelectromechanical system (MEMS) thermal light source and a narrow bandwidth optical filter. The thermal light source was electrically modulated, which simplified the sensor structure. Double-pass absorption was implemented to enhance the PA signal, which was detected by a small and low-cost MEMS electric microphone. The gas entered the sensor through a small hole in a diffusion manner without the need for valves or an air pump. This design feature contributes to a compact structure with dimensions of only 2.43 cm × 1.25 cm × 1.8 cm. The analysis results showed that the minimum detection limit (MDL) of CO2 reached 0.72 ppm with an averaging time of 100 s. A polydimethylsiloxane (PDMS) membrane was used as the water-gas separation unit. The performance of the designed PA sensor for detecting dissolved gases in seawater has been verified. When the flow rate of the water pump was 600 mL/min, the time for water-gas equilibrium was only 3.5 min. This can be attributed to the small size of the gas chamber and the rapid water exchange.

Development of a non-resonant photoacoustic gas sensor for CO2 detection

Photoacoustic spectroscopy (PAS) is an attractive technique for gas detections and analysis. This study focuses on optimizing a photoacoustic gas sensor by analyzing key structural parameters. Through the establishment of a 3D model, simulations, and subsequent experimental validation, the impact of these parameters on the sensor's performance was explored. This comprehensive approach successfully determined the optimal structural parameters. The photoacoustic gas sensor consists of a micro-electro-mechanical systems (MEMS) emitter, a miniature photoacoustic-cell, a MEMS microphone and a circuit. The footprint of the sensor is approximately 12 mm × 12 mm × 6 mm (length × width × height) which is 10 % of conventional non-dispersive infrared gas sensors. The accuracy of the sensor is ±0.05 % in 0 % to 10 % CO2 concentrations. And the response time (T100) is 80 s. The limit of detection (LOD) in CO2 concentrations is 0.12 %. The power consumption of the sensor is only 44 mW.

High sensitivity miniaturized multi-pass absorption enhanced differential Helmholtz photoacoustic gas sensor

A high sensitivity photoacoustic (PA) gas sensor based on multi-pass absorption differential Helmholtz cell with a chamber volume of only 37 mL was proposed. The reported cell has an absorption path length of 2.5 m, which can effectively enhance the optical excitation. The differential Helmholtz structure can heighten the photoacoustic signal and effectively suppress ambient noise. To optimize the differential Helmholtz resonant PA cell, the PA field distribution of the cell was calculated by thermoviscous acoustic theory using the finite element method. The detection performance of the sensor was evaluated using a distributed feedback laser operating at a center wavelength of 1650.44 nm and targeting CH4 gas. Compared with a single pass, the PA signals were enhanced by 11 times in multiple pass mode. The differential mode suppressed 30 % of background noise. The calculated normalized noise equivalent absorption (NNEA) coefficient was 3.45 × 10-10 cm-1WHz1/2. The experimental results showed that the minimum detection limit (MDL) of CH4 was 6.6 ppb with an averaging time of 100 s.

High-sensitivity photoacoustic spectroscopy gas sensor enhanced by a microphone-array-coupled differential resonator

High-sensitivity photoacoustic spectroscopy gas sensor enhanced by a microphone-array-coupled differential resonator

Performance Comparison of 3-D Printed Photoacoustic Gas Sensors and a Commercial Quartz Enhanced Photoacoustic Spectrometer

Performance Comparison of 3-D Printed Photoacoustic Gas Sensors and a Commercial Quartz Enhanced Photoacoustic Spectrometer

Fiber-Optic Photoacoustic Gas Sensor with Multiplexed Fabry-Pérot Interferometric Cantilevers.

A fiber-optic photoacoustic (PA) gas sensor with multiplexed Fabry-Pérot (F-P) interferometric cantilevers is demonstrated. A compact cylindrical nonresonant PA tube with a volume of only 0.45 mL is designed. The PA signal is measured by two symmetrically installed fiber-optic interferometric cantilever microphones (FOICMs) to improve the signal-to-noise ratio (SNR). For multiplexing the two cantilevers by a single demodulation system, a dual cavity length synchronous measurement method based on total-phase demodulation algorithm with ultrahigh resolution is developed. The PA signal detection is realized by the second-harmonic wavelength modulation spectroscopy (2f-WMS) technique. The sensor performance is verified by conducting the detection of trace acetylene (C2H2). The normalized noise equivalent absorption (NNEA) coefficient is 2.5 × 10-9 cm-1·W·Hz-1/2, and the minimum detection limit (MDL) downs to about 0.2 ppm with an averaging time of 1 s. The fiber-optic PA gas sensor has characteristics of high resolution and immunity to electromagnetic and vibration interference. Furthermore, the technical scheme of the multiplexed cantilever demodulation shows great potential for remote multipoint monitoring of gases in harsh environments.

Miniaturized and highly-sensitive fiber-optic photoacoustic gas sensor based on an integrated tuning fork by mechanical processing with dual-prong differential measurement

A proof-of-concept gas sensor based on a miniaturized and integrated fiber-optic photoacoustic detection module was introduced and demonstrated for the purpose of developing a custom tuning-fork (TF)-enhanced photoacoustic gas sensor. Instead of piezoelectric quartz tuning fork (QTF) in conventional quartz-enhanced photoacoustic spectroscopy (QEPAS), a low-cost custom aluminum alloy TF fabricated by mechanical processing was employed as a photoacoustic transducer and the vibration of TF was measured by fiber-optic Fabry-Pérot (FP) interferometer (FPI). The mechanical processing-based TF design scheme greatly increases the flexibility of the TF design with respect to the complex and expensive manufacture process of custom QTFs, and thus it can be better exploited to detect gases with slow vibrational-translational (V-T) relaxation rates and combine with light sources with poor beam quality. The resonance frequency and the quality factor of the designed custom TF at atmospheric pressure were experimentally determined to be 7.3 kHz and 4733, respectively. Dual-prong differential measurement method was proposed to double the photoacoustic signal and suppress the external same-direction noise. After detailed optimizing and investigating for the operating parameters by measuring H2O, the feasibility of the developed sensor for gas detection was demonstrated with a H2O minimum detection limit (MDL) of 1.2 ppm, corresponding to a normalized noise equivalent absorption (NNEA) coefficient of 3.8 × 10−8 cm−1 W/Hz1/2, which are better than the QTF-based photoacoustic sensors. The proposed gas sensing approach combined the advantages of QEPAS and fiber-optic sensing, which can greatly expand the application domains of PAS-based gas sensors.

Multiplexed fiber-optic photoacoustic sensors for simultaneous detection of multi-point gases

A multiplexing scheme of fiber-optic photoacoustic (PA) gas sensors is demonstrated for simultaneous detection of multi-point gases. By sharing the PA demodulation device, the average cost of single point measurement can be significantly reduced. The passive fiber-optic PA gas sensing probe is integrated by a PA tube and a Fabry-Perot (F-P) interferometric (FPI) cantilever. The laser excited the PA signals is simultaneously incident into two sensing probes. The superimposed F-P interference spectrum containing multi-point gas concentration information is received by a high-speed spectrometer. For synchronous measurement of multi-point gases, a white-light interferometry (WLI) based frequency division multiplexing (FDM) spectral demodulation method is exploited. A multi-point acetylene gas remote monitoring system is established by two PA gas sensing probes with 3 km fiber cable. The experimental results show that the sensing probes have achieved the detection limit of sub-ppm. The crosstalk between the two sensors is characterized by the gas concentrations at the two points, indicating a crosstalk of about − 35 dB. This multiplexing scheme of fiber-optic PA sensing probes has the merits of remote monitoring, low crosstalk, high sensitivity, intrinsic safety and low cost. It can be applied for coal spontaneous combustion monitoring, dissolved gas analysis and gas micro-leakage monitoring.

Design of flexible hollow core fiber based photoacoustic gas sensor with high cell constant and compact size.

Here we designed, optimized, and proposed a flexible low frequency resonant photoacoustic (PA) gas sensor by using a large core leaky hollow core fiber (L-HCF). The influences from the dimensions, the transmission loss and the bending loss on the performance of the flexible PA gas sensor were systematically investigated. In this work, the optimized inner diameter and length of the L-HCF were 1.7 mm and 300 mm, respectively. The L-HCF based PA cell constant was calculated to be 12115 Pa/(W·cm-1). The minimum detectable limit (MDL) for trace C2H2 detection achieved 23.0 ppb when the lock-in integration time was 200 s by using a near-infrared distributed feedback (DFB) laser source and a low-cost electrical micro-electro-mechanical system (MEMS) microphone. Besides, the amplitude decay ratio of the of the PA signal was only 11.3% when the bending radius of the L-HCF was 100 mm. The normalized noise equivalent absorption (NNEA) coefficient is calculated to be 6.6 × 10-9 W•cm-1•Hz-1/2. The L-HCF based PA cell was proved to own merits of compact size, high cell constant, small gas volume and low cost.