Pauli Equation Research Articles

Mapping of the classical kinetic balance equations onto the Pauli equation

Here we find a mapping onto the Pauli equation of the first two balance equations derived from the classical Boltzmann equation. The essence of this mapping, which we previously used to obtain the particular case of the Sturm–Liouville operator known as Schrödinger's equation, consists of applying a Fourier transform to the momentum coordinate of the distribution function. This procedure introduces a natural parameter η with units of angular momentum. The main difference between the two cases is the conditions imposed on the probability distribution function, a difference most clearly understood at the level of the hydrodynamic equations generated in the first steps of the mapping. The case leading to the Sturm–Liouville operator corresponds to an irrotational flow, while here the ansatz leading to the Pauli equation corresponds to a fluid with non-zero vorticity. In the context of fluid dynamics, the magnitude of the angular momentum associated with the vorticity is η/2. To perform the mapping we follow the standard technique common in hydrodynamic problems, namely writing the Lagrangian for the Euler equations with the corresponding constraints expressed in terms of the Clebsch variables.

Extended theory of Kapitza-Dirac scattering

The standard theoretical treatment of the Kapitza-Dirac effect---that is, the scattering of an electron passing through a standing-wave laser field---is extended here through the use of the Pauli equation to account for the interaction of the electron spin with the magnetic field of the standing wave. Prescriptions for determining unitarity-preserving approximations for the transition probabilities for scattering both with and without rotation of the electron spin direction are provided. This formalism is used to develop a perturbation theory for the spin-flip probability which, in the strong-field limit of interest here, reduces to a fairly simple relation between $S$-matrix elements for scattering with and without change in spin orientation, each expressed in terms of a Bessel function. A similar perturbative procedure is applied to estimate corrections to the standard theory for scattering in the absence of spin-flip processes, in which interactions that change the net number of photons in the field are ignored.

Supersymmetric quantum mechanics on non-commutative plane

We study the Pauli equation on non-commutative plane. It is shown that the supersymmetry algebra holds to all orders in the non-commutative parameter θ in case the gyro-magnetic ratio g is 2. Using Seiberg–Witten map, the first order in θ correction to the spectrum is obtained in the case of uniform magnetic field. We find that the eigenstates in the non-commutative case are identical to the commutative case provided the magnetic field B is everywhere replaced by B (1+ Bθ ).

Y(sl(2)) Algebra Application in Extended Hydrogen Atom and Monopole Models**The project supported in part by National Natural Science Foundation of China under Grant No 10201015 and the Science Foundation of Young Teachers of Northeast Normal University

We present the extended hydrogen atom and monopole-hydrogen atom theory through generalizing the usual hydrogen atom model and with a monopole model respectively, in which Y(sl(2)) algebras are realized. We derive the Hamiltonians of the two models based on the Y(sl(2)) and the generalized Pauli equation. The energy spectra of the systems are also given in terms of Yangian algebra and quantum mechanics.

Supersymmetric quantum mechanics on non-commutative plane

We study the Pauli equation on non-commutative plane. It is shown that the supersymmetry algebra holds to all orders in the non-commutative parameter θ in case the gyro-magnetic ratio g is 2. Using Seiberg–Witten map, the first order in θ correction to the spectrum is obtained in the case of uniform magnetic field. We find that the eigenstates in the non-commutative case are identical to the commutative case provided the magnetic field B is everywhere replaced by B(1+Bθ).

Quasi-exact solvability of Dirac–Pauli equation and generalized Dirac oscillators

In this paper we demonstrate that neutral Dirac particles in external electric fields, which are equivalent to generalized Dirac oscillators, are physical examples of quasi-exactly solvable systems. Electric field configurations permitting quasi-exact solvability of the system based on the sl(2) symmetry are discussed separately in the spherical, cylindrical, and Cartesian coordinates. Some exactly solvable field configurations are also exhibited.

Quantum–classical transition in scale relativity

The theory of scale relativity provides a new insight into the origin of fundamental laws in physics. Its application to microphysics allows us to recover quantum mechanics as mechanics on a non-differentiable (fractal) spacetime. The Schrodinger and Klein-Gordon equations are demonstrated as geodesic equations in this framework. A development of the intrinsic properties of this theory, using the mathematical tool of Hamilton's bi-quaternions, leads us to a derivation of the Dirac equation within the scale-relativity paradigm. The complex form of the wavefunction in the Schrodinger and Klein-Gordon equations follows from the non-differentiability of the geometry, since it involves a breaking of the invariance under the reflection symmetry on the (proper) time differential element (ds <-> - ds). This mechanism is generalized for obtaining the bi-quaternionic nature of the Dirac spinor by adding a further symmetry breaking due to non-differentiability, namely the differential coordinate reflection symmetry (dx^mu <-> - dx^mu) and by requiring invariance under parity and time inversion. The Pauli equation is recovered as a non-relativistic-motion approximation of the Dirac equation.

Static electric-field effects in the photodetachment ofCs−at the3Presonance region

We calculated near-threshold photodetachment cross sections for ${\mathrm{Cs}}^{\ensuremath{-}}$ in the presence of a dc electric field using three different approaches: the frame-transformation method with and without rescattering effects and the Kirchhoff-integral approach. Radial wave functions for the electronic motion were obtained using the Pauli equation method with a model potential describing the effective electron-atom interaction. Our results demonstrate the inadequacy of the frame-transformation method in the ${}^{3}P$ resonance region even for weak fields $(E&lt;10\mathrm{k}\mathrm{V}/\mathrm{c}\mathrm{m}).$ We show that the triplet and singlet contributions to the total cross section can be manipulated by varying the external electric field. This can enhance spin-orbit effects in the photodetachment process and create more favorable conditions in the experiment for the observation of the lowest ${}^{3}P$ resonance in ${\mathrm{Cs}}^{\ensuremath{-}}.$

Transformed Dirac equation for the hydrogen atom, comparison with previous approaches in momentum space, and the anomalous Zeeman effect in momentum representation

AbstractThe solution of a unitarily transformed Dirac equation for the hydrogenic electron in zero magnetic field is investigated here. The momentum‐space representation is adopted as a natural recourse. The spinor part of the transformed wavefunction in momentum space can be easily prescribed for a central potential. Hence, for the Coulomb potential, a pair of equations is obtained for the radial components in momentum space. It is shown that starting from these radial equations, one can recover the equations previously derived by Rubinowicz, Lévy, and Lombardi for the problem of the Dirac hydrogen atom in momentum space. This establishes equivalence among different approaches based on the momentum representation, including the current treatment. The recovery of the equations due to Rubinowicz permits the exact eigenvalues to be written down and exact expressions to be derived for the radial components of the transformed wavefunction in momentum space. A new approach is adopted to carry out a reduction to the nonrelativistic regime and the nonrelativistic limit. At first the transformed momentum‐space equation for the hydrogen atom is rewritten in terms of the hyperspherical coordinates. The zeroth‐order solutions of the new equation are recovered in the limit c → ∞ where c is the speed of light. These are manifestly separable into positive‐ and negative‐energy forms. For positive energy, these solutions have nonvanishing upper components that are two‐component spinors. The latter exactly correspond to the single‐component, nonrelativistic, momentum‐space solutions derived by Fock. It is shown that when the upper component is corrected through first order in v2/c2 but the separability is still maintained for the transformed wavefunction, one retrieves the Pauli equation in momentum space. It is also shown that for a hydrogen atom placed in a uniform magnetic field, the nonvanishing momentum‐space matrix elements representing the anomalous Zeeman effect have a simple form, namely, the product of a radial integral and an angular integral. These integrals are equal to the well‐known radial and angular integrals in coordinate representation. The matrix elements can be easily evaluated. © 2003 Wiley Periodicals, Inc. Int J Quantum Chem, 2003

Quasi-exact solvability of the Pauli equation

We present a general procedure for determining possible (nonuniform) magnetic fields such that the Pauli equation becomes quasi-exactly solvable (QES) with an underlying $sl(2)$ symmetry. This procedure makes full use of the close connection between QES systems and supersymmetry. Of the ten classes of $sl(2)$-based one-dimensional QES systems, we have found that nine classes allow such construction.

The non-relativistic limits of the Maxwell and Dirac equations: the role of Galilean and gauge invariance

The aim of this paper is to illustrate four properties of the non-relativistic limits of relativistic theories: (a) that a massless relativistic field may have a meaningful non-relativistic limit, (b) that a relativistic field may have more than one non-relativistic limit, (c) that coupled relativistic systems may be “more relativistic” than their uncoupled counterparts, and (d) that the properties of the non-relativistic limit of a dynamical equation may differ from those obtained when the limiting equation is based directly on exact Galilean kinematics. These properties are demonstrated through an examination of the non-relativistic limit of the familiar equations of first-quantized QED, i.e., the Dirac and Maxwell equations. The conditions under which each set of equations admits non-relativistic limits are given, particular attention being given to a gauge-invariant formulation of the limiting process especially as it applies to the electromagnetic potentials. The difference between the properties of a limiting theory and an exactly Galilean covariant theory based on the same dynamical equation is demonstrated by examination of the Pauli equation.

Pauli equation and the method of supersymmetric factorization

We consider different variants of factorization of a 2x2 matrix Schroedinger/Pauli operator in two spatial dimensions. They allow to relate its spectrum to the sum of spectra of two scalar Schroedinger operators, in a manner similar to one-dimensional Darboux transformations. We consider both the case when such factorization is reduced to the ordinary 2-dimensional SUSY QM quasifactorization and a more general case which involves covariant derivatives. The admissible classes of electromagnetic fields are described and some illustrative examples are given.

Semiclassical quantisation rules for the Dirac and Pauli equations

We derive explicit semiclassical quantisation conditions for the Dirac and Pauli equations. We show that the spin degree of freedom yields a contribution which is of the same order of magnitude as the Maslov correction in Einstein–Brillouin–Keller quantisation. In order to obtain this result a generalisation of the notion of integrability for a certain skew product flow of classical translational dynamics and classical spin precession has to be derived. Among the examples discussed is the relativistic Kepler problem with Thomas precession, whose treatment sheds some light on the amazing success of Sommerfeld’s theory of fine structure [Ann. Phys. (Leipzig) 51 (1916) 1].

On a construction of a good parametrix for the Pauli equation

The superanalysis stands for doing elementary and real analysis on function spaces over the superspace Rm|n with value R or C. Here, R and C are ∞-dimensional Frechet-Grassmann algebras which play the role of R and C in the standard theory, respectively. Using this analysis, we construct a parametrix of the Pauli equation (=the Schrodinger equations with spin) on R3 from ‘classical objects’. More precisely, by using the differential operator representations of the Clifford algebra on the Grassmann algebra, we define the symbol of the Pauli equation as a super Hamiltonian function on the superspace. Solving the Hamilton-Jacobi and continuity equations corresponding to that Hamiltonian function, we construct a certain Fourier Integral Operator on superspace, which gives a parametrix of the Pauli equation. This parametrix is called “good” because it has not only the ordinary approximation properties but also has the explicit dependence on the Planck constant . The Lie product formula for these parametrices yields a desired evolutional operator of the Pauli equation in the L2-scheme. In other words, we propose a quantization procedure of Feynman type for “classical mechanics with spin” using superanalysis.

Spin-dependent Bohm trajectories for Pauli and Dirac eigenstates of hydrogen

The de Broglie-Bohm causal theory of quantum mechanics is applied to the hydrogen atom in the fully spin-dependent and relativistic framework of the Dirac equation, and in the nonrelativistic but spin-dependent framework of the Pauli equation. Eigenstates are chosen which are simultaneous eigenstates of the energy H, total angular momentum M, and z component of the total angular momentum Mz. We find the trajectories of the electron, and show that in these eigenstates, motion is circular about the z-axis, with constant angular velocity. We compute the rates of revolution for the ground (n=1) state and the n=2 states, and show that there is agreement in the relevant cases between the Dirac and Pauli results, and with earlier results on the Schrodinger equation.

Nonrelativistic Wave Equations with Gauge Fields

We illustrate a metric formulation of Galilean invariance by constructing wave equations with gauge fields. It consists of expressing nonrelativistic equations in a covariant form, but with a five-dimensional Riemannian manifold. First we use the tensorial expressions of electromagnetism to obtain the two Galilean limits of electromagnetism found previously by Le Bellac and Levy-Leblond. Then we examine the nonrelativistic version of the linear Dirac wave equation. With an Abelian gauge field we find, in a weak field approximation, the Pauli equation as well as the spin—orbit interaction and a part reminiscent of the Darwin term. We also propose a generalized model involving the interaction of the Dirac field with a non-Abelian gauge field; the SU(2) Hamiltonian is given as an example.

Near-threshold photodetachment of heavy alkali-metal anions

We calculate near-threshold photodetachment cross sections for Rb{sup -}, Cs{sup -}, and Fr{sup -} using the Pauli equation method with a model potential describing the effective electron-atom interaction. Parameters of the model potential are fitted to reproduce ab initio scattering phase shifts obtained from Dirac R-matrix calculations. Special care is taken to formulate the boundary conditions near the atomic nucleus for solving the Pauli equation, based on the analytic solution of the Dirac equation for a Coulomb potential. We find a {sup 3}P{sub 1}{sup o} resonance contribution to the photodetachment cross section of Rb{sup -}, Cs{sup -}, and Fr{sup -} ions. Our calculated total photodetachment cross sections for Cs agree with experiments after tuning the resonance position by 2.4 meV. For Rb{sup -} and Fr{sup -} the resonance contribution is much smaller than for Cs. We therefore also provide angle-differential cross sections and asymmetry parameters which are much more sensitive to the resonant contribution than total cross sections.

Is the anomalous magnetic moment the consequence of a non-classical transformation for rotating frames?

We consider the anomalous magnetic moment from an 'optical viewpoint' using an analogy between the motion of a particle with a magnetic moment in a magnetic field and the propagation of an optical pulse through an electro-optical crystal in an electric field. We show that an optical experiment similar to electron magnetic resonance is possible in some electro-optical crystals possessing the Faraday effect. This phenomenon is described by an analogue of the Pauli equation extracted from the Maxwell equation in the slowly varied amplitude approximation. In such an experiment the modulation by rotating fields plays a significant role. From the optical viewpoint the modulation assumes introducing the concept of a point rotation frame with the rotation axis at every point originated from the concept of the optical indicatrix (index ellipsoid). We discuss the connection between the non-classical transformation by transition from one such frame to another and an anomalous magnetic moment.

On separable Pauli equations

We classify (1+3)-dimensional Pauli equations for a spin-12 particle interacting with the electro-magnetic field, that are solvable by the method of separation of variables. As a result, we obtain the 11 classes of vector-potentials of the electro-magnetic field A(t,x⃗)=(A0(t,x⃗), A⃗(t,x⃗)) providing separability of the corresponding Pauli equations. It is established, in particular, that the necessary condition for the Pauli equation to be separable into second-order matrix ordinary differential equations is its equivalence to the system of two uncoupled Schrödinger equations. In addition, the magnetic field has to be independent of spatial variables. We prove that coordinate systems and the vector-potentials of the electro-magnetic field providing the separability of the corresponding Pauli equations coincide with those for the Schrödinger equations. Furthermore, an efficient algorithm for constructing all coordinate systems providing the separability of Pauli equation with a fixed vector-potential of the electro-magnetic field is developed. Finally, we describe all vector-potentials A(t,x⃗) that (a) provide the separability of Pauli equation, (b) satisfy vacuum Maxwell equations without currents, and (c) describe non-zero magnetic field.

Erratum: Boundary Conditions for the Pauli Equation: Application to Photodetachment ofCs−[Phys. Rev. Lett. 87, 123003 (2001)

Erratum: Boundary Conditions for the Pauli Equation: Application to Photodetachment of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi>Cs</mml:mi></mml:mrow><mml:mrow><mml:mo>−</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>[Phys. Rev. Lett. 87, 123003 (2001)