The effects of gate bias stressing on threshold voltage and mobility in power VDMOSFETs and underlying changes in gate oxide-trapped charge and interface trap densities are presented and analysed in terms of the mechanisms responsible. It is shown that gate bias stressing causes significant threshold voltage shift and mobility degradation in power VDMOSFETs; the negative bias stressing causes more rapid initial changes of both threshold voltage and mobility, but the final threshold voltage shift and mobility reduction are significantly larger in devices stressed by positive gate bias. In the case of positive bias stressing, electron tunnelling from neutral oxide traps associated with trivalent silicon Sio defects into the oxide conduction band is proposed as the main mechanism responsible for positive oxide-trapped charge buildup, while subsequent hole tunnelling from the charged oxide traps Sio+ to interface-trap precursors Sis–H is shown to be the dominant mechanism responsible for the interface trap buildup. In the case of negative bias stressing, hole tunnelling from the silicon valence band to oxygen vacancy defects SioSio is shown to be responsible for positive oxide-trapped charge buildup, while subsequent electro-chemical reactions of interfacial precursors Sis–H with the charged oxide traps Sio+Sio and H+ ions are proposed to be responsible for interface trap buildup.