The polarization of the acoustic field in the ocean waveguide environment is a unique property that can provide new ideas for locating and detecting the underwater target, so it is interesting to study the polarization. This paper extends the Stokes parameters to a broadband form, and uses the non-stationary phase approximation method to simplify the expressions, reducing the complexity of theoretical derivation. A physical phenomenon is observed where polarization exhibits significant variations concerning the sea surface, seafloor, source depth, and the source symmetrical depth. Simulation results demonstrate that the simplified equations using the non-stationary phase approximation are effective. Additionally, by normalizing the broadband Stokes parameters, the effects of horizontal range on the depth distribution law of polarization can be eliminated. Subsequently, using the normalized broadband Stokes parameters, the influence of environmental and source parameters on the depth distribution law of polarization is analyzed. The effectiveness of the non-stationary phase approximation and the range-independence property of the normalized broadband Stokes parameters are verified by processing RHUM-RUM experimental data. Based on the conclusions of this paper, it is expected that the polarization can be used for target depth estimation.