The aggregation of nanoparticles is a major phenomenon having broad consequences in many fields. In order to fully utilize the capabilities of nanoparticles in a variety of applications and to evaluate the effects that they will have on the environment and biological systems, it is crucial to comprehend and manage aggregation. To develop and improve nanoparticle-based technology, researchers are still learning more about the aggregation processes. Thus, the present study investigates the combined effects of velocity slip and nanoparticle aggregation on Heat transfer (HT) analysis of MHD nanofluid (i.e., TiO2-C2H6O2) flow between porous convergent, divergent channel. The modified Krieger–Dougarty and Maxwell–Bruggeman models were utilized for nanoparticle aggregation. The modeling is based on nonlinear PDEs such as continuity, momentum, and heat equations. These equations are transformed into a system of nonlinear ODEs using similarity transformations and then solved numerically and analytically. The analytical solution has been constructed using the ADM method. The present results in particular cases are compared to results obtained by the HAM- package and by the Runge- Kutta Fehlberg 4th–5th order (RKF-45) for validation. The effects of active parameters on the velocity, temperature, concentration, skin friction, and Nusselt numbers are investigated. It is found that nanoparticle aggregation can limit fluid velocity in converging channels by increasing flow resistance through aggregate formation. Individual nanoparticles generate friction and lower velocity, while aggregated nanoparticles boost fluid density and velocity. In addition, it is found that the magnetic field lowers skin friction and increases HT due to Lorentz force, while porosity increases friction and HT. Nanoparticle concentration inversely affects friction, increasing friction without aggregation and decreasing friction with aggregation, with the HT rate rising with increased nanoparticle concentrations.
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