The midrapidity transverse momentum distributions of the charged pions, kaons, protons, and antiprotons, measured by ALICE Collaboration at ten centrality classes of Pb + Pb collisions at snn = 5.02 TeV in the Large Hadron Collider (LHC, CERN, Switzerland), are successfully analyzed using combined minimum χ2 fits with a thermodynamically non-consistent, as well as thermodynamically consistent, Tsallis function with transverse flow. The extracted non-extensivity parameter q decreases systematically for all considered particle species with increasing Pb + Pb collision centrality, suggesting an increase in the degree of system thermalization with an increase in collision centrality. The results for q suggest quite a large degree of thermalization of quark–gluon plasma (QGP) created in central Pb + Pb collisions at snn = 5.02 TeV with the average number of participant nucleons ⟨Npart⟩ > 160. The obtained significantly different growth rates of transverse flow velocity, ⟨βT⟩, in regions ⟨Npart⟩ < 71 ± 7 and ⟨Npart⟩ > 71 ± 7 with the temperature parameter T0 remaining constant within uncertainties in region ⟨Npart⟩ > 71 ± 7 probably indicates that ⟨Npart⟩ ≈ 71 ± 7 (corresponding to ⟨dNch/dη⟩ ≈ 251 ± 20) is a threshold border value for a crossover transition from a dense hadronic state to the QGP phase (or mixed phase of QGP and hadrons) in Pb + Pb collisions at snn = 5.02 TeV. The threshold border value for transverse flow velocity ⟨βT⟩ ≈ 0.46 ± 0.03 (corresponding to ⟨Npart⟩ ≈ 71 ± 7), estimated by us in Pb + Pb collisions at snn = 5.02 TeV, agrees well with the corresponding border value ⟨βT⟩ ≈ 0.44 ± 0.02, recently obtained in Xe + Xe collisions at snn = 5.44 TeV, and with almost constant ⟨βT⟩ values extracted earlier in the Beam Energy Scan (BES) program of the Relativistic Heavy-Ion Collider (RHIC, Brookhaven, GA, USA) in central Au + Au collisions in the snn = 7.7 − 39 GeV energy range, where the threshold for QGP production is achieved. The correlations between extracted T0 and ⟨βT⟩ parameters are found to be greatly different in regions ⟨βT⟩ < 0.46 and ⟨βT⟩ > 0.46, which further supports our result obtained for the threshold border value in Pb + Pb collisions at snn = 5.02 TeV.