Near-field Optics Research Articles

Self-organized patterning on azo molecular glass film via optical near-field effect

Self-organized surface patterning has attracted great research interest ranging from scientific understanding to various applications. Here, we report a unique patterning behavior observed on an azo molecular glass film with polystyrene microspheres on the surface upon irradiation with a circularly polarized laser beam. Photoinduced submicron hillocks are found to organize into concentric arrays around isolated polystyrene spheres, while more complex patterns are observed around two or more spheres close to each other. The irradiation first creates surface relief rings encircling the spheres and then the rings split into hillocks arranged in circular arrays with increasing exposure time. Pattern formation is shown to be controlled by synergy from the optical near-field of polystyrene spheres with the spontaneous hillock formation characteristics of the molecular glass film upon light irradiation. This work is beneficial to deepening the understanding of light–matter interactions and is expected to be applied in different areas.

Optomechanical Heating and Cooling via Tip-Enhanced Raman Scattering in Epsilon-Near-Zero Medium

Media with the dielectric permittivityclose to zero (epsilon-near-zero or ENZ) maintain conditions for enhanced light-matter interactions. In this paper, we propose to use these media to enhance the optomechanical coupling of vibrational excitations of the medium with the optical near-field of the nanoantenna. It is shown that the ENZ medium significantly increases the optically induced decay rate of a vibration, which can be used for cooling (when the incident light frequency is less than the ENZ frequency) or heating (when the incident light frequency is greater than the ENZ frequency). Due to the proximity of the refractive index to zero as well, oscillations of the polarization of the medium are coherent, which further enhances the optomechanical effects. Analytical expressions are obtained for the optical shift of the resonance and the induced decay rate.

Probing the optical near-field interaction of Mie nanoresonators with atomically thin semiconductors

Optical Mie resonators based on silicon nanostructures allow tuning of light-matter-interaction with advanced design concepts based on complementary metal–oxide–semiconductor (CMOS) compatible nanofabrication. Optically active materials such as transition-metal dichalcogenide (TMD) monolayers can be placed in the near-field region of such Mie resonators. Here, we experimentally demonstrate and verify by numerical simulations coupling between a MoSe2 monolayer and the near-field of dielectric nanoresonators. Through a comparison of dark-field (DF) scattering spectroscopy and photoluminescence excitation experiments (PLE), we show that the MoSe2 absorption can be enhanced via the near-field of a nanoresonator. We demonstrate spectral tuning of the absorption via the geometry of individual Mie resonators. We show that we indeed access the optical near-field of the nanoresonators, by measuring a spectral shift between the typical near-field resonances in PLE compared to the far-field resonances in DF scattering. Our results prove that using MoSe2 as an active probe allows accessing the optical near-field above photonic nanostructures, providing complementary information to sophisticated near-field microscopy equipment.

Experimental and numerical polarization analysis of the 3D transfer behavior in microsphere-assisted interferometry for 1D phase gratings

Enhancing the lateral resolution in optical microscopy and interferometry is of great interest in recent research. In order to laterally resolve structures including feature dimensions below the Abbe resolution limit, microspheres in the optical near-field of the specimen are shown to locally improve the resolution of the imaging system. Experimental and simulated results following this approach are obtained by a high NA Linnik interferometer and analyzed in this contribution. They show the reconstructed surface of a 1D phase grating below the resolution limit. For further understanding of the transfer characteristics, measured interference data are compared with FEM (finite element method) based simulations with respect to the polarization dependency of the relevant image information for 1D phase gratings. Therefore, the implemented Koehler illumination as well as the experimental setup utilize polarized light.

Near-Field Evolution of Optical Vortices and Their Spatial Ordering behind a Fork-Shaped Grating

Fork-shaped gratings are periodic structures containing a spatial dislocation known to be used for the production of optical vortices in a far field. Spatial overlapping of diffraction orders in a near field results in complex spatial evolution of optical vortices. In this paper, we report the results of near-field diffraction on fork-shaped gratings with different topological charges and analyze the evolution of specific optical vortices during propagation. Optical vortices have been shown to form two-dimensional well-ordered spatial configurations in specific transverse planes. The locus of points of optical singularities has been shown to form two helical lines twisted around the ±1 diffraction order directions. Our results demonstrate that the spatial behaviour of optical vortices is in close connection with the spatial ordering arising from the Talbot effect. The quantity of optical vortices demonstrates complex spatial dynamics, which includes spatial oscillations and decreasing along the propagation direction. These results provide a foundation towards a deeper understanding of near-field singular optics phenomena.

Near-field terahertz nonlinear optics with blue light

The coupling of terahertz optical techniques to scattering-type scanning near-field microscopy (s-SNOM) has recently emerged as a valuable new paradigm for probing the properties of semiconductors and other materials on the nanoscale. Researchers have demonstrated a family of related techniques, including terahertz nanoscopy (elastic scattering, based on linear optics), time-resolved methods, and nanoscale terahertz emission spectroscopy. However, as with nearly all examples of s-SNOM since the technique’s inception in the mid-1990s, the wavelength of the optical source coupled to the near-field tip is long, usually at energies of 2.5 eV or less. Challenges in coupling of shorter wavelengths (i.e., blue light) to the nanotip has greatly inhibited the study of nanoscale phenomena in wide bandgap materials such as Si and GaN. Here, we describe the first experimental demonstration of s-SNOM using blue light. With femtosecond pulses at 410 nm, we generate terahertz pulses directly from bulk silicon, spatially resolved with nanoscale resolution, and show that these signals provide spectroscopic information that cannot be obtained using near-infrared excitation. We develop a new theoretical framework to account for this nonlinear interaction, which enables accurate extraction of material parameters. This work establishes a new realm of possibilities for the study of technologically relevant wide-bandgap materials using s-SNOM methods.

New Horizons of Near-field Optical Microscopy

Structure, functions, dynamics, and interactions are the basic properties to systematically understand physical systems existing in nature. In particular, there have been many scientific adventures to understand optical properties of materials and light-matter interactions, yet in the classical regime at the microscale due to the diffraction-limited optical resolution. Near-field optical microscopy enables to probe them at the nanoscale and even induces light-matter interactions in a reversible fashion. In this article, we introduce the fundamental concept of various types of near-field microscopy and several applications studies reported recently. Furthermore, we provide several new directions of nano-spectroscopy and -imaging based on tip-enhanced approach, which have not been thought in the near-field optics community before.

Near-Field IPO for Analysis of EM Scattering from Multiple Hybrid Dielectric and Conductor Target and High Resolution Range Profiles

Aiming at improving the accuracy and efficiency of scattering information from multiple targets in near-field regions, this paper proposes a near-field iterative physical optics (IPO) method based on a modified near-field Green’s function for the composite electromagnetic scattering analysis of multiple hybrid dielectric and conductor targets. According to the electric field and magnetic field integral equation, the electric and magnetic current were updated utilizing the Jacobi iteration method. Then, by introducing an expansion center lying in the neighborhood of the source point, Green’s function was modified for near-field scattering between multiple hybrid dielectric and conductor targets. To accelerate the implementation of the procedure, the multilevel fast multipole method, the fast far-field approximation, and parallel multicore programming were introduced. Numerical results indicate that there is good agreement between the results calculated by the near-field IPO method and MLFMM solver in commercial software FEKO while significantly reducing the computational burden. To fully exploit the scattering information, the high resolution range profiles (HRRP) of different targets under different conditions were analyzed, which can be further applied for automatic target detection and recognition.

Optimally Configured Optical Fiber Near‐Field Enhanced Plasmonic Resonance Immunoprobe for the Detection of Alpha‐Fetoprotein

The detection of trace biomarkers is an important supplementary approach for early screening and diagnoses of tumors. An optical fiber near-field enhanced plasmonic resonance immunoprobe is developed for the detection of the hepatocellular carcinoma biomarker, i.e., the alpha-fetoprotein. Generic principles based on dispersion models and finite element analysis (FEA) models are developed to realize the optimized configuration of spectral characteristics of the immunoprobe. Dispersion models provide theoretical guidance for the design of the multilayer sensing structure from the perspective of the ray optics theory. FEA models provide theoretical guidance for the selection of coating materials from the perspective of the self-defined dielectric constant ratio, i.e., the ratio of the real part to the imaginary part. The optimized configuration of the antibody coupling further improves the biosensing performance of the immunoprobe. The limit of detection (LOD) can reach down to 0.01ng mL-1 , which is one order of magnitude lower than those relevant reported works. Such a low LOD can more effectively avoid the accuracy degradation of detection results due to measurement errors. Human serum samples have also been detected, with the good precision achieved. This work shows promising prospects in applications of label-free, low-cost, rapid, and convenient early screening of tumors.

Tailoring near-field-mediated photon electron interactions with light polarization

Inelastic interaction of free-electrons with optical near fields has recently attracted attention for manipulating and shaping free-electron wavepackets. Understanding the nature and the dependence of the inelastic cross section on the polarization of the optical near-field is important for both fundamental aspects and the development of new applications in quantum-sensitive measurements. Here, we investigate the effect of the polarization and the spatial profile of plasmonic near-field distributions on shaping free-electrons and controlling the energy transfer mechanisms, but also tailoring the electron recoil. We particularly show that polarization of the exciting light can be used as a control knop for disseminating the acceleration and deceleration path ways via the experienced electron recoil. We also demonstrate the possibility of tailoring the shape of the localized plasmons by incorporating specific arrangements of nanorods to enhance or hamper the transversal and longitudinal recoils of free-electrons. Our findings open up a route towards plasmonic near-fields-engineering for the coherent manipulation and control of slow electron beams for creating desired shapes of electron wavepackets.

Probing the optical near-field of plasmonic nano structure using scanning thermal microscopy

Scanning thermal microscopy (SThM) enables to obtain thermal characteristic information such as temperature and thermal conductivity from the signals obtained by scanning a thermometer probe over a sample surface. Particularly, the precise control of the thermometer probe makes it possible to study near-field radiative heat transfer by measuring the near-field thermal energy, which implies that when light is used as a local heat source, photothermal energy can be detected from the optical near-field by approaching the probe in the near-field region. In this study, SThM is applied to generate sub-wavelength near-field optical image in the plasmonic grating coupler. Herein, by controlling the surface plasmon polariton generation, we show that the dominant component of SThM signal is from the optical response rather than the thermal response. The obtained near-field optical images have a spatial resolution of 40 nm and signal to noise ratio of up to 19.8. In addition, field propagation images in the Z-direction can be visualised with the precise control of the distance between the thermometer probe and the sample

Spin-Momentum Properties in the Paraxial Optical Systems

Spin angular momentum, an elementary dynamical property of classical electromagnetic fields, plays an important role in spin-orbit and light-matter interactions, especially in near-field optics. The research on optical spins has led to the discovery of phenomena such as optical spin-momentum locking and photonic topological quasiparticles, as well as applications in high-precision detection and nanometrology. Here, we investigate spin-momentum relations in paraxial optical systems and show that the optical spin angular momentum contains transverse and longitudinal spin components simultaneously. The transverse spin originates from inhomogeneities of field and governed by the vorticity of the kinetic momentum density, whereas the longitudinal spin parallel to the local canonical momentum is proportional to the polarization ellipticity of light. Moreover, the skyrmionlike spin textures arise from the optical transverse spin can be observed in paraxial beams, and their topologies are maintained free from the influence of the Gouy phase during propagation. Interestingly, the optical singularities, including both phase and polarization singularities, can also affect the spin-momentum properties significantly. Our findings describe the intrinsic spin-momentum properties in paraxial optical systems and apply in the analysis of the properties of spin-momentum in optical focusing, imaging, and scattering systems.

Optical phase singularities: Physical nature, manifestations and applications

Over the past 30 years, physical optics has been enriched by the appearance of singular optics as a new branch approved in scientific classifiers. This review briefly outlines the main concepts of the singular optics, their role in physical research and applications, and prospects of further development. The wave singularities are considered as a sort of structured-light elements and analyzed based on the generic example of screw wavefront dislocation (optical vortex). Their specific topological and mechanical properties associated with the transverse energy circulation are discussed. Peculiar features of the non-linear optical phenomena with singular fields are exhibited, with the special attention to generation of multidimensional entangled quantum states of photons. Optical fields with multiple singularities, especially, the stochastic speckle fields, are discussed in the context of optical diagnostics of random scattering objects. The exact and approximate correspondences between characteristic parameters of the optical-field intensity and phase distributions are analyzed with the aim of recovering phase information from the intensity measurements (“phase problem” solution). Rational singularity-based approaches to informative measurements of the scattered-field distribution are discussed, as well as their employment for the objects’ diagnostics. In particular, the practical instruments are described for the high-precision rough-surface testing. Possible enhancements of the singular-optics ideas and concepts in a wider context, including the transformation optics, near-field optics (surface waves), partially-coherent fields, and wave fields of other physical nature, are briefly exposed.

Dipole-forbidden transitions induced by the gradient of optical near fields

The electric-field spatial gradient is a very important property of an optical near-field (ONF). In this study, its effect on the single-photon ionization is theoretically investigated via the three-dimensional time-dependent Schr\"odinger equation and perturbation theory. The results show that the field gradient can lead to dipole-forbidden transitions, which competes with the usual dipole transition and results in changes of the photoelectron momentum distribution. Additionally, we establish a relationship between the field gradient with the angular distribution of the photoelectrons. Through this mapping, the field gradient can be accurately retrieved. Furthermore, a way for extracting the phase difference between the partial waves with odd and even parity from the photoelectron momentum distribution is proved to be feasible. We find that the Cooper minimum can enhance the effect of the field gradient and thus improves the accuracy of our proposed retrieval procedure. Our results pave the way to exploit atomic structural properties as a probe of the gradient of the ONF.

Super-resolved three-dimensional near-field mapping by defocused imaging and tracking of fluorescent emitters

Abstract Near-field optics is essential in many nanotechnology applications, such as implementing sensitive biosensing and imaging systems with extreme precision. Understanding optical near-fields at the nanoscale has so attracted the considerable research interest, which use a variety of analytical approaches, most notably near-field scanning microscopy. Here, we show defocused point localization mapped accumulation (DePLOMA), which can overcome many weaknesses of conventional analytical methods. DePLOMA is based on imaging fluorescence emitters at an out-of-focal plane. The acquisition, collection, and accumulation of the position and fluorescence intensity of emitters moving above nanostructures can generate three-dimensional near-field maps of light distribution. The idea enables super-resolution liquid-phase measurements, as demonstrated by reconstruction of near-field created by nanoslits with a resolution determined by emitter size. We employed fluorescent emitters with a radius of 50 and 100 nm for confirmation. The axial resolution was found to be enhanced by more than 6 times above that of diffraction-limited confocal laser scanning microscopy when DePLOMA was used.

Controlled optical near-field growth of individual free-standing well-oriented carbon nanotubes, application for scattering SNOM/AFM probes

Abstract Exploiting localized heat-generation density and the resulting enhanced temperature-rise for controlled growth of carbon nanotubes (CNTs) is reported, and its potentials for batch-production of high-quality CNT probes are demonstrated. Optical near field chemical vapor deposition (ONF-CVD) benchtop fabrication schemes are developed for the localized integration of individual well-aligned carbon nanotubes without bending/buckling exactly at desired nanoscale sites. It is demonstrated that generating self-aligned catalyst nanoparticles superimposed on top of silicon nanotips, along with near-field induced absorption confinement, provide the ability to localize the generated heat at the nanotips apexes, and control the CNT growth locations. The nanoscale maskless controllability of the growth site is shown by properly tailoring ONF-CVD conditions to overcome overall heat exposure of the substrate for selective activation of catalyst nanoparticles located at apexes, from those dispersing all over the tips. The calculated local power densities and temperature profiles of the simulated tips, clearly demonstrate the confined heat and optimal gradient of generated temperature rise as the main factors affecting the growth. In addition to determining necessary processing conditions to control the localization and orientation of the growth, parameters affecting the length and diameter of the localized individually grown nanotubes are also presented. Optical near-field-based growth schemes can be extended for localized maskless fabrication of other nanoscale devices, beyond the diffraction limit, using photothermal effects.

Plasmofluidic-Based Near-Field Optical Trapping of Dielectric Nano-Objects Using Gold Nanoislands Sensor Chips.

Near-field optical manipulation has been widely used for guiding and trapping nanoscale objects close to an optical-active interface. This near-field manipulation opens opportunities for next-generation biosensing with the capability of large-area trapping and in situ detection. In this article, we used the finite element method (FEM) to analyze the motion mechanism of nano-objects (50-500 nm) in the near-field optics, especially localized surface plasmon resonance (LSPR). The size-dependent optical forces and hydrodynamic forces of subwavelength nanoparticles (<500 nm) in different hydrodynamic velocity fields were calculated. When the strength of the local electric field was increased, LSPR with two-dimensional gold nanoislands (AuNIs) showed improved capability for manipulating nano-objects near the vicinity of the AuNI interface. Through the experiments of in situ interferometric testing 50-500 nm nano-objects with constant number concentration or volume fraction, it was confirmed that the local plasmonic near-field was able to trap the dielectric polystyrene beads smaller than 200 nm. The plasmofluidic system was further verified by testing biological nanovesicles such as exosomes (40-200 nm) and high- and low-density lipoproteins (10-200 nm). This concept of direct dielectric nano-objects manipulation enables large-scale parallel trapping and dynamic sensing of biological nanovesicles without the need of molecular binding tethers or labeling.

Collection of propagating electromagnetic fields by uncoated probe

Understanding light-matter interaction at the nanoscale by observation of fine details of electromagnetic fields is achieved by bringing nanoscale probes into the nearfield of light sources, capturing information that is lost in the far field. Although metal coated probes are often used for nearfield microscopy, they strongly perturb the electromagnetic fields under study. Here, through experiment and simulation, we detail light collection by uncoated fiber probes, which minimize such perturbation. Second-harmonic light from intensely-irradiated sub-wavelength sub-surface features was imaged to avoid otherwise dominating fundamental light background, yielding clear nearfield details through a 50 nm aperture uncoated probe with ∼23 nm optical resolution. Simulations show how a metallic coating distorts optical nearfields and limits optical coupling into the probe in comparison to an uncoated probe.

Doped semiconducting polymer nanoantennas for tunable organic plasmonics

Optical nanoantennas are often based on plasmonic resonances in metal nanostructures, but their dynamic tunability is limited due to the fixed permittivity of conventional metals. Recently, we introduced PEDOT-based conducting polymers as an alternative materials platform for dynamic plasmonics and metasurfaces. Here, we expand dynamic organic plasmonic systems to a wider class of doped polythiophene-based semiconducting polymers. We present nanodisks of PBTTT semiconducting polymer doped with a dicationic salt, enabling a high doping level of around 0.8 charges per monomer, and demonstrate that they can be used as nanooptical antennas via redox-tunable plasmonic resonances. The resonances arise from the polymer being optically metallic in its doped state and dielectric in its non-conducting undoped state. The plasmonic resonances are controllable over a 1000 nm wavelength range by changing the dimensions of the nanodisks. Furthermore, the optical response of the nanoantennas can be reversibly tuned by modulating the doping level of the polymer. Simulations corroborate the experimental results and reveal the possibility to also modulate the optical nearfield response of the nanoantennas.

Composite Electromagnetic Scattering and High-Resolution SAR Imaging of Multiple Targets above Rough Surface

Aiming at the high efficiency of composite electromagnetic scattering analysis and radar target detection and recognition utilizing high-range resolution profile (HRRP) characteristics and high-resolution synthetic aperture radar (SAR) images, a near-field modified iterative physical optics and facet-based two-scale model for analysis of composite electromagnetic scattering from multiple targets above rough surface have been presented. In this method, the coupling scattering of multiple targets is calculated by near-field iterative physical optics and the far-field scattering is calculated by the physical optics method. For the evaluation of the scattering of an electrically large sea surface, a slope cutoff probability distribution function is introduced in the two-scale model. Moreover, a fast imaging method is introduced based on the proposed hybrid electromagnetic scattering method. The numerical results show the effectiveness of the proposed method, which can generate backscattering data accurately and obtain high-resolution SAR images. It is concluded that the proposed method has the advantages of accurate computation and good recognition performance.