Near-constant Temperature Research Articles

Chemical Heating for Minimally Instrumented Point-of-Care (POC) Molecular Diagnostics

The minimal instrumentation of portable medical diagnostic devices for point-of-care applications is facilitated by using chemical heating in place of temperature-regulated electrical heaters. The main applications are for isothermal nucleic acid amplification tests (NAATs) and other enzymatic assays that require elevated, controlled temperatures. In the most common implementation, heat is generated by the exothermic reaction of a metal (e.g., magnesium, calcium, or lithium) with water or air, buffered by a phase-change material that maintains a near-constant temperature to heat the assay reactions. The ability to incubate NAATs electricity-free and to further to detect amplification with minimal instrumentation opens the door for fully disposable, inexpensive molecular diagnostic devices that can be used for pathogen detection as needed in resource-limited areas and during natural disasters, wars, and civil disturbances when access to electricity may be interrupted. Several design approaches are reviewed, including more elaborate schemes for multiple stages of incubation at different temperatures.

Optimization of the annular fin arrangement in phase change heat storage units based on response surface methodology

Latent heat thermal energy storage (LHTES) technology is of increasing industrial interest due to its advantages such as high heat storage density and near-constant temperature during the phase change process. However, the latent heat storage technology is impacted by the low thermal conductivity of the phase change material (PCM), leading to delays and heat loss in the heat transfer process within LHTES. This limitation reduces the efficiency of heat transfer and diminishes the performance of the heat storage unit. To address this issue, this paper employs numerical simulation and response surface methodology to investigate different types of annular fin phase change heat storage units, aiming to derive the optimal configuration for enhancing unit performance. Therefore, the effect of fin type and number on the melting and solidification process is analyzed in detail. The research results indicate that among the five different types of fins studied, the total time required for the unit to complete melting and solidification is the least with type “e” fins, only 51.78 h, demonstrating that type “e” fins have the best effect on improving unit performance. For type “e” fins, when the number of fins n is 15, it can most effectively shorten the melting and solidification time of the phase change heat storage unit, reducing it to only 47.81 h. In addition, the response surface methodology was utilized to derive the optimal fitting formulas for different types of annular fins and to validate these formulas, and the error between the validation analysis and the numerical simulations was within 5%, which confirms the reliability of the fitting formulas developed in this study. This approach facilitates the selection of various annular fin models for subsequent experimental and simulation studies, thereby reducing the time and cost associated with model selection.

Flow Boiling Enhancement Using Three-Dimensional Contact-Line Pinning on Hierarchical Superbiphilic Micro/Nanostructures.

Flow boiling is a promising method for the cooling of sensitive computational and industrial components, facilitating the transportation of large quantities of heat at near-constant temperature and in a small form factor. The prevention of vapor film formation is a fundamental challenge for the enhancement of boiling systems, and an impetus therefore exists for the discovery of new techniques to segregate nucleating bubbles during their formation. Herein, we utilize the strong capillary forces generated by nanostructures to pin the liquid/vapor interface in three dimensions and thereby control the coalescence and flow interactions of developing bubbles. We demonstrate this principle on both symmetrical and asymmetrical superbiphilic microstructures, showing enhancement of peak heat transfer coefficient by 81% and 113%, respectively, when compared to the best superhydrophilic and superhydrophobic analogues. Our approach shows a potential future direction for engineered boiling micro/nanostructures, wherein bubble dynamics are directly manipulated on bespoke, three-dimensional substrates.

Scalable and paint-format microparticle–polymer composite enabling high-performance daytime radiative cooling

Radiative cooling, a process in which the Earth maintains a near-constant temperature despite significant solar flux, is a promising technology with no requirement of any input energy for sub-ambient cooling as well as no emission of greenhouse gas. Here, we demonstrate a paint-format microparticle–polymer composite with a low fabrication cost, simple structure, and high radiative cooling performance. Harnessing intrinsic optical properties of aluminum oxide and silicon oxide particles with large energy bandgaps and complementary IR emission properties within the atmospheric transparency window, the proposed radiative cooling paint has an extremely low solar absorptivity of 0.032 and strong IR emission of 0.935 in the atmospheric transparency window. Furthermore, many outdoor measurements proved the RC paint provided high-performance radiative cooling effect for comparison with commercial white paint even in hot summer season detrimental for daytime raditaive cooling, enabling the practical use of radiative cooling.

Sensitivity analysis of design parameters for erythritol melting in a horizontal shell and multi-finned tube system: Numerical investigation

Latent heat storage systems using phase change materials (PCMs) store large amounts of thermal energy at a near-constant temperature in a compact space. However, PCMs possess relatively low thermal conductivity which prolongs their phase change process; consequently, their applications have been limited. To address this, a numerical investigation was conducted in this study on the heat transfer mechanism in a horizontal shell and multi-finned tube heat exchanger. Erythritol (melting point of 117 °C) was selected as the PCM and Therminol-55 was used as the heat transfer fluid. ANSYS Fluent v. 19.0 was used to numerically solve the governing equations. Once validated by comparing with experimental data, the developed numerical model was then used to investigate the effect of several design parameters regarding tubes and fins on the storage performance. It was found that number of tubes, fin height as well as rotation of fins and tubes significantly influence the melting process. Overall, the melting duration could be decreased by about 44% when the number of tubes increased from 5 to 9. Moreover, the melting time could be decreased by about 31% when the fin height increased from 6 to 15 mm.

Phase-Change Materials/HDPE Composite Filament: A First Step Toward Use With 3D Printing for Thermal Management Applications

Phase-change materials (PCMs) are a useful alternative to more traditional methods of thermal management of various applications. PCMs are materials that absorb large amounts of latent heat and undergo solid-to-liquid phase change at near-constant temperature. The goal of the research is to experimentally investigate the thermal properties of a novel shape-stabilized PCM/HDPE composite extruded filament. The extruded filament can then be used in a 3D printer for custom PCM/HDPE shapes. The PCM used in the study is PureTemp PCM 42, which is an organic-based material that melts around 42 °C. Four PCM/HDPE mixtures were investigated (all percentages by mass): 20/80, 30/70, 40/60, and 50/50. Preliminary findings include differential scanning calorimeter (DSC) measurements of melting temperature and latent heat as well as scanning electron microscope (SEM) pictures of filament composition.

Core-sheath structural carbon materials for integrated enhancement of thermal conductivity and capacity

Energy storage capacity and heat transfer ability are two important indexes for shape-stabilized phase change materials (ss-PCMs). In this paper, a core-sheath CNT@PC was prepared via carbonation of CNT@ZIF-8, simultaneously 3D structural supports were obtained due to the porous carbon (PC) sheath stabilized the CNT@PC network structure. Porous carbon (PC), derived from carbonized metal organic frameworks (MOFs), exhibited high porosity and large specific surface area. PCMs, absorbed by capillary force of porous structure, was stabilized in the pores of PC sheath. Further, the interaction between PCMs and CNTs reduced the interfacial thermal resistance greatly. Carbon nanotubes (CNTs), acting as heat transfer pathways, provided continuous channels for phonons transfer and realized rapid heat transformation between ss-PCMs and external environment. The obtained SA/CNT@PC ss-PCMs exhibited excellent thermal conductivity (1.023 W/mK), large phase change enthepy (155.7 J g−1) and high thermal storage capabilities (99.9%). The thermal conductivity of SA/CNT@PC was improved 222.6% and phase change enthalpy was increased 92.6% over SA/PC ss-PCM. SA/CNT@PC with large energy storage density, flexible designation, simple operation and near-constant temperature properties during phase change process shows great potential in waste heat utilization.

An Experimental Facility to Validate Ground Source Heat Pump Optimisation Models for the Australian Climate

Ground source heat pumps (GSHPs) are one of the most widespread forms of geothermal energy technology. They utilise the near-constant temperature of the ground below the frost line to achieve energy-efficiencies two or three times that of conventional air-conditioners, consequently allowing a significant offset in electricity demand for space heating and cooling. Relatively mature GSHP markets are established in Europe and North America. GSHP implementation in Australia, however, is limited, due to high capital price, uncertainties regarding optimum designs for the Australian climate, and limited consumer confidence in the technology. Existing GSHP design standards developed in the Northern Hemisphere are likely to lead to suboptimal performance in Australia where demand might be much more cooling-dominated. There is an urgent need to develop Australia’s own GSHP system optimisation principles on top of the industry standards to provide confidence to bring the GSHP market out of its infancy. To assist in this, the Queensland Geothermal Energy Centre of Excellence (QGECE) has commissioned a fully instrumented GSHP experimental facility in Gatton, Australia, as a publically-accessible demonstration of the technology and a platform for systematic studies of GSHPs, including optimisation of design and operations. This paper presents a brief review on current GSHP use in Australia, the technical details of the Gatton GSHP facility, and an analysis on the observed cooling performance of this facility to date.

Carbonate “clumped” isotope signatures in aragonitic scleractinian and calcitic gorgonian deep-sea corals

Abstract. Deep-sea corals are a potentially valuable archive of the temperature and ocean chemistry of intermediate and deep waters. Living in near-constant temperature, salinity, and pH and having amongst the slowest calcification rates observed in carbonate-precipitating biological organisms, deep-sea corals can provide valuable constraints on processes driving mineral equilibrium and disequilibrium isotope signatures. Here we report new data to further develop “clumped” isotopes as a paleothermometer in deep-sea corals as well as to investigate mineral-specific, taxon-specific, and growth-rate-related effects. Carbonate clumped isotope thermometry is based on measurements of the abundance of the doubly substituted isotopologue 13C18O16O2 in carbonate minerals, analyzed in CO2 gas liberated on phosphoric acid digestion of carbonates and reported as Δ47 values. We analyzed Δ47 in live-collected aragonitic scleractinian (Enallopsammia sp.) and high-Mg calcitic gorgonian (Isididae and Coralliidae) deep-sea corals and compared results to published data for other aragonitic scleractinian taxa. Measured Δ47 values were compared to in situ temperatures, and the relationship between Δ47 and temperature was determined for each group to investigate taxon-specific effects. We find that aragonitic scleractinian deep-sea corals exhibit higher values than high-Mg calcitic gorgonian corals and the two groups of coral produce statistically different relationships between Δ47–temperature calibrations. These data are significant in the interpretation of all carbonate clumped isotope calibration data as they show that distinct Δ47–temperature calibrations can be observed in different materials recovered from the same environment and analyzed using the same instrumentation, phosphoric acid composition, digestion temperature and technique, CO2 gas purification apparatus, and data handling. There are three possible explanations for the origin of these different calibrations. The offset between the corals of different mineralogy is in the same direction as published theoretical predictions for the offset between calcite and aragonite although the magnitude of the offset is different. One possibility is that the deep-sea coral results reflect high-Mg and aragonite crystals attaining nominal mineral equilibrium clumped isotope signatures due to conditions of extremely slow growth. In that case, a possible explanation for the attainment of disequilibrium bulk isotope signatures and equilibrium clumped isotope signatures by deep-sea corals is that extraordinarily slow growth rates can promote the occurrence of isotopic reordering in the interfacial region of growing crystals. We also cannot rule out a component of a biological “vital effect” influencing clumped isotope signatures in one or both orders of coral. Based on published experimental data and theoretical calculations, these biological vital effects could arise from kinetic isotope effects due to the source of carbon used for calcification, temperature- and pH-dependent rates of CO2 hydration and/or hydroxylation, calcifying fluid pH, the activity of carbonic anhydrase, the residence time of dissolved inorganic carbon in the calcifying fluid, and calcification rate. A third possible explanation is the occurrence of variable acid digestion fractionation factors. Although a recent study has suggested that dolomite, calcite, and aragonite may have similar clumped isotope acid digestion fractionation factors, the influence of acid digestion kinetics on Δ47 is a subject that warrants further investigation.

A room-temperature processed parylene-patterned helical ionic polymer–metal composite spring actuator with selectable active region

This paper presents a novel helical ionic polymer metal composite (IPMC) spring actuator. A room-temperature fabrication process is developed to selectively grow in situ nickel metal electrode on a coiled Nafion strip, which is patterned with parylene as a masking layer to delineate the inactive region. This method allows the helical spring actuator to be shaped in a near-constant temperature environment and minimizes the residual stress effect on the Nafion polymer, compared to other processes using thermal treatment. The developed process ensures that short-circuiting never occurs between the outer and inner electrodes of the actuator, and the active region can be designed via parylene patterning. The motion of the fabricated spring actuator is measured, and the maximal displacement reaches 1 mm at the endpoint of the spring under a 0.1 Hz 6 V square wave actuation. A microtensile experiment is performed for characterizing the stress and strain relation. The resulting Young’s moduli of the Nafion and fabricated IPMC strips are 183 and 227 MPa, respectively. Analysis based on Castigliano’s theorem is executed to derive equations related to the moment, force output, strain energy, and displacement of an arbitrary point of the fabricated spring actuator. Results show the produced moment, force, and strain energy of the operated spring actuator are in the level of 1.5 μN m, 300 mN, and 20−100 μJ, respectively.

Contribution of solar radiation to decadal temperature variability over land

Global air temperature has become the primary metric for judging global climate change. The variability of global temperature on a decadal timescale is still poorly understood. This paper examines further one suggested hypothesis, that variations in solar radiation reaching the surface (Rs) have caused much of the observed decadal temperature variability. Because Rs only heats air during the day, its variability is plausibly related to the variability of diurnal temperature range (daily maximum temperature minus its minimum). We show that the variability of diurnal temperature range is consistent with the variability of Rs at timescales from monthly to decadal. This paper uses long comprehensive datasets for diurnal temperature range to establish what has been the contribution of Rs to decadal temperature variability. It shows that Rs over land globally peaked in the 1930s, substantially decreased from the 1940s to the 1970s, and changed little after that. Reduction of Rs caused a reduction of more than 0.2 °C in mean temperature during May to October from the 1940s through the 1970s, and a reduction of nearly 0.2 °C in mean air temperature during November to April from the 1960s through the 1970s. This cooling accounts in part for the near-constant temperature from the 1930s into the 1970s. Since then, neither the rapid increase in temperature from the 1970s through the 1990s nor the slowdown of warming in the early twenty-first century appear to be significantly related to changes of Rs.

Physical and chemical drivers of vegetation in groundwater-source pools on the Bogong High Plains, Victoria

The wetland communities intimately associated with groundwater sources in the Australian alps are poorly documented compared with the broader (and more obvious) alpine peatlands. In the present work, we report on the vegetation observed immediately around such sources and the characteristics of the supplying groundwater so as to understand the likely factors controlling the observed vegetation assemblage. Thirty-two groundwater sources were identified across three catchments on the Bogong High Plains, Victoria (Australia), and the vegetation associated with these sources surveyed. Groundwater sources occurred across a range of altitudes (1667–1854 m), independent of aspect, and were hydrologically connected to (upstream of) peatlands. Localised mounding adjacent to the groundwater sources resulted in the formation of pools (‘groundwater source pools’). The vegetation within the pools was dominated by bryophytes, with the aquatic bryophyte Blindia robusta the most common species. The groundwater was deficient in major ions, and similar to rainwater apart from elevated concentrations of CO2 accumulated in the groundwater-recharge process. The high CO2 concentrations, combined with the near-constant temperature conditions provided by sustained groundwater flow, are thought to be likely drivers for the high abundance of B. robusta. Although the relative contributions of rain and snow to aquifer recharge are not fully understood for the Australian Alps, these ecosystems are likely to be vulnerable to the changes in precipitation regime that are predicted under climate-change scenarios.

Thermomagnetic and magnetorotational instabilities of thin Keplerian discs in poloidal magnetic fields

AbstractStability of thin hot Keplerian discs is investigated asymptotically in small disc's aspect ratio, ε. The study is carried out in the local approximation for short vertical waves in the disc‐thickness scale. Besides the radial rotation shear and the vertical magnetic field, the background configuration is characterized by a vertically near‐constant temperature profile with a small vertical gradient. The temperature‐gradient term in Ohm's law, which characterizes the thermomagnetic transport is found to be of the order of ε. The effect of the thermomagnetic transport slightly modifies the conventional magnetorotational instability (MRI), while a new thermomagnetic instability (TMI) emerges in regions of the wavenumber space where MRI is absent. Explicit solutions are obtained for a wide range of values of plasma beta, β, and thermomagnetic transport coefficient, λ. In particular, it is shown for λ ≪ 1 that the MRI dominates in weak magnetic fields, β ≫ 1, while the TMI is exhibited in strong magnetic fields, β ∼ 1, also with the growth rate of the order of inverse rotation period (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Condensation character of a stratified flow inside a horizontal tube

A series of experiments was performed to investigate the steam condensation phenomenon of stratified flow inside horizontal tube in vacuum condition. Using segmented cooling mode to maintain a near-constant temperature of cooling water. Based on the experimental results, this paper analyses the influence of temperature difference and the inlet velocity of vapor on both heat flux density ratio and heat transfer coefficient ratio between water side and vapor side. It is found that inlet velocity and condensate quantity has obvious effect on both heat flux density ratio and heat transfer coefficient ratio.

An experimental and theoretical study of particle deposition due to thermophoresis and turbulence in an annular flow

The paper describes an experimental and theoretical study of the deposition of small particles from a turbulent annular-flow with cross-stream temperature variation, focusing on the effects of thermophoresis. Various expressions for the thermophoretic force on a spherical particle are critically discussed. The well-known composite formula of Talbot et al. (1980) does not include the ‘second mechanism of thermophoresis’ and it is concluded that the more recent theoretical approach of Beresnev and Chernyak (1995) is probably more reliable. New experimental measurements of particle deposition from a turbulent flow with cross-stream temperature gradients are then presented. The measurement technique is similar to the method of Liu and Agarwal (1974) but in the test section the aerosol flows vertically downwards in an annular gap between two concentric pipes. By heating the outer pipe and cooling the inner it is possible to establish a substantial, near-constant temperature difference between the two walls and hence a thermophoretic force which varies only with radius. Numerical calculations provide a comparison of theory with experiment. The theory is based on the turbulent deposition models of Young and Leeming (1997) and Slater et al. (2003) modified to include thermophoresis and the annular geometry. The theory of Beresnev and Chernyak gives good agreement with the experimental measurements.

SN 1994W: an interacting supernova or two interacting shells?

We present a multi-epoch quantitative spectroscopic analysis of the Type IIn supernova (Type IIn SN) 1994W, an event interpreted by Chugai et al. as stemming from the interaction between the ejecta of a SN and a 0.4 M⊙ circumstellar shell ejected 1.5 yr before core collapse. During the brightening phase, our models suggest that the source of optical radiation is not unique, perhaps associated with an inner optically thick cold dense shell and outer optically thin shocked material. During the fading phase, our models support a single source of radiation, an hydrogen-rich optically thick layer with a near-constant temperature of ∼7000 K that recedes from a radius of 4.3 × 1015 at a peak to 2.3 × 1015 cm 40 d later. We reproduce the hybrid narrow-core broad-wing line profile shapes of SN 1994W at all times, invoking an optically thick photosphere exclusively (i.e. without any external optically thick shell). In SN 1994W, slow expansion makes scattering with thermal electrons a key escape mechanism for photons trapped in optically thick line cores, and allows the resulting broad incoherent electron-scattering wings to be seen around narrow-line cores. In SNe with larger expansion velocities, the thermal broadening due to incoherent scattering is masked by the broad profile and the dominant frequency redshift occasioned by bulk motions. Given the absence of broad lines at all times and the very low 56Ni yields, we speculate whether SN 1994W could have resulted from an interaction between two ejected shells without core collapse. The high conversion efficiency of kinetic to thermal energy may not require a SN-like energy budget for SN1994W.