ABSTRACTIn 2017 Princeton University Library’s Department of Rare Books and Special Collections acquired a 1483 Venetian edition of the Opera of Horace, preserved in a late fifteenth century German binding. The binding contained previously undetected vellum binding waste fragments derived from an early Gutenbergian edition of the Ars minor of Aelius Donatus. Extensive portions of the printed fragments were attached to each of the wooden boards and remained hidden beneath the book’s paper pastedowns. In the paper conservation laboratory of the Department of Rare Books and Special Collections, the pastedowns were subsequently safely lifted from the boards via Gore-Tex damp packs to confirm the presence of unique remnants from an otherwise lost mid-fifteenth century Mainz edition of the Ars minor, a Latin grammar manual. The Ars minor was printed with the same typeface used around 1455 to print the Gutenberg Bible. The fragments featured black oil-based printing ink and a large Gothic two-line initial letter A printed in blue ink. The design of the typeface of the initial letter A mirrored the work of Johann Fust and Peter Schoeffer, one-time partners of Gutenberg. The pair produced the Mainz Psalter (1457), the first book printed in more than one color.The printing inks of the Ars minor were subsequently analyzed in the paper conservation laboratory in situ noninvasively by X-ray fluorescence spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy and fiber optic Raman spectroscopy. The analysis found amounts of copper and lead, in addition to amber resin and linseed oil, in the black oil-based printing ink. The copper-lead aspect of the Ars minor’s black printing ink formulation appeared to be the same basic recipe composition conceived by Johannes Gutenberg for printing with movable metal type. Indigo (indigotin) and lead white (basic lead carbonate) were identified as the components in the blue printing ink of the two-line initial letter A, and vermilion (mercury sulfide) in manually rubricated red ink. The Ars minor represents a very important find of a previously unknown early Gutenbergian work.
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