Mixed Carbonate Research Articles

Mixed Ownership Reform and Environmental Sustainable Development—Based on the Perspective of Carbon Performance

Mixed ownership reform has contributed greatly to China’s economic development; however, there is little literature on how mixed ownership reform affects carbon performance in the context of environmentally sustainable development. Therefore, this paper takes A-share industrial state-owned enterprises in Shanghai and Shenzhen from 2008 to 2020 as research samples to investigate the impact of mixed ownership reform on carbon performance through empirical tests. The results show that the mixed ownership reform of state-owned enterprises can improve the carbon performance of enterprises. The intermediary test shows that green innovation plays an intermediary role in the relationship between mixed ownership reform and carbon performance. Furthermore, compared with green management innovation, mixed ownership reform has a stronger promoting effect on green technology innovation, and green technology innovation has a greater impact on carbon performance. Heterogeneity analysis shows that in heavily polluted industries and competitive industries, mixed ownership reform of state-owned enterprises has a more significant role in improving carbon performance. Therefore, the mixed ownership reform of state-owned enterprises is of great significance for promoting environmental sustainable development. Overall, this study provides empirical evidence for the environmental sustainable development of state-owned enterprises in emerging markets.

Depositional controls in an ancient, closed lake system: A high-resolution and multi-scalar case study from the Yacoraite Formation (Salta Basin, Argentina)

The Yacoraite Formation (Cretaceous–Paleogene) is a mixed carbonate–siliciclastic microbialite-bearing lacustrine succession deposited in the intra-continental Salta rift basin (Argentina). In the northern sub-basin of Tres Cruces, the spectacular exposures and high lateral continuity of the outcrops provide a suitable setting to investigate and reconstruct the paleoenvironments of deposition and the resulting facies architecture of this closed, saline lake system. The Yacoraite Formation deposited in a predominantly shallow-water ramp-like lake system, characterized by eighteen main facies, classified within four main facies associations, each defining a particular depositional environment along the lake profile. From proximal (shallow) to distal: i) Palustrine Facies Association; ii) Littoral Facies Association; iii) Sub-littoral Facies Association; and lastly iv) Profundal Facies Association. In the Yacoraite paleo-lake extensive fringing mud-flat environments surrounded the lake margins, while the littoral marginal areas hosted extensive wave-dominated oolitic–bioclastic grainstones forming shoals and bars parallel to the lake margins and provided a sheltered environment in the back-shoals that allowed prolific microbialite development. In proximity to river inputs, shallow-water deltas and shoreline sandstones accumulated in the littoral margins. In the sub-littoral zone, mud-supported carbonates such as ostracod wackestones and mudstones deposited below the fair-weather wave base, and in the profundal settings deep-water organic-rich shales deposited. The Yacoraite paleo-lake evolved from a relatively stable and perennial lake system (lake stage 1) into a rapidly fluctuating ephemeral lake system (stage 2), as a result of progressively changing environmental and climatic conditions toward more arid settings. Climate control is also critical in the facies architecture, with the development of short-term cyclicity, represented by meter-scale transgressive–regressive (T–R) cycles being the result of lacustrine expansion–contraction cycles. The regressive hemicycles represent shallowing-upward succession of sub-littoral and littoral carbonate-dominated facies, whereas the transgressive hemicycles are mostly represented by sub-littoral and profundal mudstones and shales. Stacking of short-term cycles resulted in the development of medium- and long-term cyclicity at the scale of tens of meters, which represent the long-term evolution of the lake system. Lastly, a comparison with two well-documented closed lake systems highlights the role of allogenic factors acting at a regional scale (e.g., climate and tectonics) in controlling the lake-basin type, facies association and the resulting architecture. Factors at the lake-basin scale (e.g., lake margin profile, bathymetry) modulate the expression of facies and cyclicity. Ultimately, the characterization of the kilometer-scale outcrops of the Yacoraite paleo-lake provides a reference analog study to support the characterization of similar depositional systems and reservoirs of other ancient, closed lake systems, including the Pre-Salt Carbonates of the South Atlantic.

Feasibility of Endotracheal Extubation Evaluation Form in Predicting Successful Extubation in Neonatal Intensive Care Units: A Retrospective Study.

Given the limited availability of evidence-based methods for assessing the timing of extubation in intubated preterm infants, we aimed to standardize the extubation protocol in this single-center, retrospective study. To accomplish this, we established an extubation evaluation form to assess the suitability of extubation in preterm infants. The form comprises six indicators: improved clinical condition, spontaneous breath rate ≥ 30 breaths per minute, peak inspiratory pressure (PIP) ≤ 15 cmH2O, fraction of inspired oxygen (FiO2) ≤ 30%, blood pH ≥ 7.2, and mixed venous carbon dioxide tension (PvCO2) < 70 mmHg. Each positive answer is given one point, indicating a maximum of six points. We enrolled 41 intubated preterm infants (gestational age < 32 weeks, birth weight < 1500 g) who were receiving mechanical ventilation support for over 24 h. Among them, 35 were successfully extubated, and 6 were not. After completing the extubation evaluation form and adjusting for birth weight and postextubation device, we observed that the total score of the form was significantly associated with successful extubation; the higher the score, the greater the chance of successful extubation. Thus, we infer that the extubation evaluation form may provide a more objective standard for extubation assessment in preterm infants.

Lithostratigraphy, lithofacies and deposition conditions of the late Olenekian-middle Anisian Alam Formation in the Nakhlak area, central Iran

The present study aims to investigate petrography characteristics and sedimental environments of upper Olenekian–middle Anisian deposits of Nakhlak group in the sedimentary-structural zone of central Iran. To this end, a section of these deposits with a thickness of 720 meters was first selected, and 190 samples were taken from this section for preparing thin sections. Also, quantitative and qualitative laboratory tests were performed and 25 samples of sandstone were selected for point counter analysis. The results indicated that the major deposits of this formation are related to siliciclastic, carbonate, and pyroclastic types, which are in the form of two facies associations. The facies association A at the bottom of the studied section with the thickness of 90 meters has a periodicity of clastic, carbonate, and pyroclastic facies. The clastic facies of this association consists of fine-grained sandstone. In addition, the carbonate facies in association A are characterized by two microfacies consisting of intraclast oolitic grainstone and oolitic grainstone. Further, tuffite is the only pyroclastic facies related to association A, which has a laminate structure, cross-bedding lamination, herringbone bedding, and upward-thinning and thickening cycles. The facies association, B which is deposited later, is more in the middle and top part of the section. The facies association B is 660 meters thick and has a periodicity of clastic and limestone facies. Clastic facies of this association includes four lithofacies such as conglomerate, pebble coarse-grained sandstone, medium-grained sandstone to thin layer siltstone and shale. The carbonate facies consists of four microfacies such as sandy intraclastic wackestone and mudstone. Furthermore, slumping structures, cross bedding, turbulence, boudinage structure, and convolute of sediments, along with the effects of erosional channels are observed in facies B. Field and laboratory studies conducted on this succession indicate the structure of facies association A was deposited in a mixed siliciclastic carbonate ramp. Finally, submarine canyons and submarine fan environments were left by increasing the depth of the facies association B in the deep part of sea and turbidity systems.

Hydrothermal synthesis of carbon-coated mixed crystalline phase TiO2 nanoparticle carbon microsphere composites as high performance anode materials for Li-ion batteries

Hydrothermal synthesis of carbon-coated mixed crystalline phase TiO2 nanoparticle carbon microsphere composites as high performance anode materials for Li-ion batteries

Facies character and evolution of a mixed carbonate–siliciclastic shelf: Upper Triassic–Lower Jurassic succession in the eastern Northern Calcareous Alps (Stumpfmauer, Austria)

Western Tethys sedimentary successions constitute fundamental archives of Late Triassic–Early Jurassic environmental, carbonate production and tectonic changes. During the Late Triassic, the Northern Calcareous Alps (Austria) belonged to the Western Tethys passive margin, characterised by the deposition of the early-dolomitized peritidal Hauptdolomit (Norian) adjacent basinward to the Dachstein carbonate shelf and passing upward to the mixed carbonate–siliciclastic Kössen Formation (Upper Norian–Rhaetian). The Kössen Fm. was subdivided into the lower shallow-water Hochalm Member and the upper Eiberg Member, accumulated in an intraplatform basin coeval to shallow-water carbonates (Upper Rhaetian Limestone). The Eiberg Mb. and overlying Jurassic strata were extensively studied as a continuous marine record across the Triassic/Jurassic boundary. In contrast, shallow-water successions, time-equivalent to the Eiberg Mb. and Upper Rhaetian Limestone, located North of the Eiberg Basin, are poorly investigated. This study focusses on the approximately 350 m thick Norian to Lower Jurassic succession cropping out in the eastern Northern Calcareous Alps (Stumpfmauer). The 32 distinguished lithofacies compose seven, vertically superimposed, sedimentary units (A–G), belonging to the Hochalm Mb. of the Kössen Fm. (Unit A peritidal cyclothems, Unit B claystone/marlstone with fossiliferous beds, Unit C coral boundstone to floatstone), Upper Rhaetian Limestone (Unit D subtidal cyclothems with claystone), shallow-water carbonate strata transitional to Lower Jurassic (Unit E ooidal coated grain peloidal grainstone with basal transgressive lag, Unit F bivalve-rich, microbialite and oncoidal lithofacies, previously attributed to the Upper Rhaetian Limestone) and Hettangian–Sinemurian Kalksburg Fm. (Unit G cross-laminated coated grain peloidal grainstone with quartz and chert). The detailed lithofacies characterisation presented in this study contributes to the knowledge on the Northern Calcareous Alps stratigraphy and depositional environments across the Triassic/Jurassic boundary. The identified sedimentary units can be framed in the evolution of Western Tethys and share similarities with depositional systems from the Western Carpathians, Transdanubian Range, Southern Alps and Dinarides suggesting coherent sedimentary response and environmental, climate and tectonic controls in different palaeogeographic domains.

Design and Analysis of Fixed-Segment Carrier at Carbon Thrust Bearing

Abstract: This thesis work aimed to provide a design and analysis of fixed segment carrier at carbon thrust bearing. With increased the bearing efficiency and reduced the frictional loss and wear resistance. Thrust bearings plays vital role in submersible pumps. Thrust bearings are fixed bottom of the submersible pumps so total thrust or axial load acting on the thrust collar. Thrust collar are manufacturing with resin mixed carbon and casting material and the segments are manufacturing with casting material and stainless steel material. Two types of materials combines to manufacture the segment carrier. The materials hardness and density properties are different from on materials to another material. If suddenly power cut is happen the total load acting on thrust collar. The collar under heavy load carbon surface and segment carrier surface are scratched or damaged the carbon surface. This type of damages are affecting submersible pump. Submersible pumps are fixed with maximum 900 feet under the boar well but this damages are happen we spend more money to lifting the pump from well and also time is wasted. Segment carrier segment surface and thrust pad surface in between micron level film thickness. If the loose segment carrier the loose segment will tilt under the load and vibration of pump. The thrust collar surface is scratched with thrust collar is not rotate because the thrust collar is fitted with rotating shaft with key way. In this study the segment carrier were made with same materials and the hardness of the materials is same and making process are compared to normal bearing were reduced. The segment carrier is made with stainless steel 410 material. The materials are bought a rod or using pattern with investment casting. After the materials is after completing machining process will goes to hardening and materials surface will go to grinding process. The segment surfaces are grinded and achieve the required surface finish. The surface finish techniques are available no of methods. Triondur coating system is more effective than other process. The grinded segment carrier surfaces are goes to next process of lapping. Here the surface is lapped and get required level of surface roughness. In this process the surface roughness is get required level. Because the lapping coating ratio is high the material removal and surface roughness is get more level like 0.2 micron. The diamond powder coating using 100 CRT is lapping process to achieve the required surface finish. The main purpose of the study is to reduce the bearing damages and frictional loss and wear loss and pump damages. And increase the pump life and reduce the raw materials usage

Sedimentological Controls on the Reservoir Characteristics of the Mid-Triassic Tredian Formation in the Salt and Trans-Indus Surghar Ranges, Pakistan: Integration of Outcrop, Petrographic, and SEM Analyses

The current study uses an integrated lithofacies, optical microscopy, and scanning electron microscopy (SEM) analysis to investigate the sedimentary processes, depositional architecture, and reservoir rock potential of the Tredian Formation’s (Mid-Triassic) mixed siliciclastic and carbonate succession in the Salt and Trans-Indus Ranges. The formation has been divided litho-stratigraphically into two components: the lower Landa Member, which consists of fine-grained sandstone and shale, and the upper Khatkiara Member, which consists of coarse-grained sandstone. Based on sedimentary structures and lithology, four distinct types of lithofacies are identified. Two lithofacies representing sandstones interbedded with shale (LF1) and thick-bedded sandstone (LF2) lithofacies suggestive of fluvio-deltaic settings are among them. Another two lithofacies of thin-bedded sandstone (LF3) and dolomite (LF4) suggest a tidal flat depositional environment, correspondingly. The petrographic examination of the Tredian sandstones indicates a lithology ranging from sub-feldspathic arenite to feldspathic arenite with moderate packing. The presence of primary calcite cement, silica cement, and iron oxide/hydroxide cements were shown by the diagenetic investigation, which was supported by SEM studies. In addition, secondary cements include ferroan-dolomite, chlorite, and illite, which is linked with chemical alteration of unstable grains. The paragenetic sequence depicts the diagenetic evolution of the Tredian sandstone from early to late diagenetic phases. The reservoir quality of the LF1 and LF4 lithofacies has been destroyed by early-stage calcite cementation, but the lithofacies LF2 and LF3 have a strong reservoir potential owing to the scarcity of calcite cement, dissolution of unstable feldspar grains, and grain fracture.

Formation and Protectiveness of Fe/Ca Carbonate Layer on X80 Steel in High-Pressure CO2 Corrosion Environments

The effect of calcium ions (Ca2+) on the corrosion of API 5L X80 carbon steel in carbon dioxide (CO2)-saturated brines was studied. Tests were performed in brines containing 0 ppm, 1,000 ppm, or 5,000 ppm of calcium ions with a constant chloride ion concentration at temperatures of 35°C and 60°C, and pressure of 80 bar. The corrosion rates were determined by mass loss, and the protective properties of the film were evaluated by performing electrochemical measurements in a separate vessel containing a standard brine. The results showed that adding Ca2+ to the brine slightly reduced the average corrosion rate, even without a crystalline corrosion product scale. For longer exposure times, it promoted the growth of a mixed iron-calcium carbonate (FexCayCO3) scale with increasing calcium molar mass, shifting the scale morphology from prismatic crystals (pure FeCO3) to globular (mixed carbonate). At 35°C the mixed iron-calcium carbonate scale offered better protection when compared to the pure FeCO3 scale counterpart. However, at 60°C, where a thicker carbonate scale was formed, the increased Ca2+ content had a minimal effect on the corrosion rate.

In-Cell NMR Approach for Real-Time Exploration of Pathway Versatility: Substrate Mixtures in Nonengineered Yeast.

The central carbon metabolism of microbes will likely be used in future sustainable bioproduction. A sufficiently deep understanding of central metabolism would advance the control of activity and selectivity in whole-cell catalysis. Opposite to the more obvious effects of adding catalysts through genetic engineering, the modulation of cellular chemistry through effectors and substrate mixtures remains less clear. NMR spectroscopy is uniquely suited for in-cell tracking to advance mechanistic insight and to optimize pathway usage. Using a comprehensive and self-consistent library of chemical shifts, hyperpolarized NMR, and conventional NMR, we probe the versatility of cellular pathways to changes in substrate composition. Conditions for glucose influx into a minor pathway to an industrial precursor (2,3-butanediol) can thus be designed. Changes to intracellular pH can be followed concurrently, while mechanistic details for the minor pathway can be derived using an intermediate-trapping strategy. Overflow at the pyruvate level can be induced in nonengineered yeast with suitably mixed carbon sources (here glucose with auxiliary pyruvate), thus increasing glucose conversion to 2,3-butanediol by more than 600-fold. Such versatility suggests that a reassessment of canonical metabolism may be warranted using in-cell spectroscopy.

Lipid Accumulation by Snf-β Engineered Mucor circinelloides Strains on Glucose and Xylose.

Sucrose non-fermenting 1 (SNF1) protein kinase plays the regulatory roles in the utilization of selective carbon sources and lipid metabolism. Previously, the role of β subunit of SNF1 in lipid accumulation was evaluated by overexpression and knockout of Snf-β in oleaginous fungus M. circinelloides. In the present study, the growth and lipid accumulation of Snf-β overexpression and knockout strains were further analyzed and compared with glucose or xylose as a single or mixed carbon sources. The results showed that the lipid contents in Snf-β knockout strain improved by 23.2% (for glucose), 28.4% (for xylose), and 30.5% (for mixed glucose and xylose) compared with that of the control strain, respectively. The deletion of Snf-β subunit also altered the transcriptional level of acetyl-CoA carboxylase (ACC). The highest transcriptional levels of ACC1 in Snf-β knockout strain at 24h were increased by 2.4-fold (for glucose), 2.8-fold (for xylose), and 3.1-fold (for mixed glucose and xylose) compared with that of the control strain, respectively. Our results indicated that Snf-β subunit enhanced lipid accumulation through the regulation of ACC1 in response to xylose or mixed sugars of glucose and xylose more significantly than that of response to glucose. This is the first study to explore the effect of Snf-β subunit of M. circinelloides in regulating lipid accumulation responding to different carbon nutrient signals of glucose and xylose. This study provides a foundation for the future application of the Snf-β engineered strains in lipid production from lignocellulose.

Expression of the Toarcian Oceanic Anoxic Event in the mixed siliciclastic–carbonate system of the Arabian Plate: Insights from rare-earth element geochemistry and statistical analysis

Rare earth elements and yttrium (REEY) are considered powerful indicators of paleo-redox conditions. However, to date, the utilization of REEY remains limited to either pure carbonates or deep marine shales, with little evidence of attempts to test their ability to depict marine anoxia within mixed carbonate–siliciclastic systems. Across the Tethys Ocean, the Toarcian Oceanic Anoxic Event (T-OAE) is widely recorded by black marine shales with strong negative carbon isotopic excursion. Yet, the occurrence and expression of T-OAE across the mixed siliciclastic and carbonate system of the Arabian Plate has not been recorded or even explored. This provides a unique opportunity to test the robustness and viability of REEY, supported by statistical analysis, in revealing marine anoxia in a mixed system. Our results demonstrate a positive Ce anomaly within the middle Marrat, coupled with a positive Eu anomaly and aluminum-normalized Mn enrichment in the underlying lower Marrat carbonates. This could be hypothetically related to volcanic pulses, which triggered the T-OAE. Overall, the REEY geochemical record and detailed statistical analysis of this study indicate, for the first time, the possibility that T-OAE might have extended to the Arabian Plate for brief periods of time during the deposition of the middle Marrat shallow marine red beds.

A Plio‐Pleistocene eustatic and storm‐controlled mixed carbonate–siliciclastic marine ramp deposit in south‐west Florida: An example of sediment homogenisation with maintenance of carbonate‐producing organisms

AbstractMixed siliciclastic and carbonate sediments are common in the stratigraphic record, but fully homogenised mixes are not. Many occurrences of mixed sediment sequences are dominated by end‐members with stacking of ‘nearly pure’ lithfacies (e.g. cyclothems containing alternating sandstone, limestone and coal units). The Plio‐Pleistocene sediments within south‐west Florida provide insights into the occurrence of fully homogenised siliciclastic/carbonate deposits. In all defined environments from lagoon to supratidal to inner tidal to beach to offshore to coral reef, quartz sand coexists with carbonates. Perhaps the key feature that allowed full homogenisation of the sediments within all facies and subfacies was the relatively shallow water (&lt;10 m), which facilitated mixing during low‐order eustatic sea‐level events and storms. However, four factors contributed to the full homogenisation of the sediment types without termination or inhibition of carbonate organism growth. These factors are (1) the shallow water allowing wave‐driven sediment transport (all environments within the wave orbital depth), (2) close proximity and perhaps irregular nature of the depositional environment boundaries, (3) low influx rate of quartz sand via longshore transport, and (4) the lack of significant terrigenous mud transport into the system. Mixing processes at the large‐scale included movement of sediments from one depositional environment to another during storms, mixing along facies boundaries, and in situ mixing within autochthonous and parautochthonous mollusc death assemblages. At the smaller scale, mixing occurred by bioturbation and diagenetic dissolution of carbonate skeletal grains during minor high sea‐level stands.

Structure optimization: Configuring optimum performance of randomly distributed mixed carbon nanotube bundle interconnects

SummaryThis paper presents an efficient optimization strategy based on the Stoyan and Yaskov algorithm to maximize the tube density of randomly distributed mixed carbon nanotube bundles (RMCBs) for configuring optimum performance of on‐chip interconnects. Optimizing tube density has proposed eight different RMCB (RMCB1–RMCB8) structures of a varying number of carbon nanotubes (CNTs), where RMCB1 has the maximum CNTs. Moreover, the ABCD technique adequately analyzes the temperature‐dependent frequency and stability characteristics of a three‐line RMCB interconnect placed on smooth and rough substrates (SiC, BN, and SiO2). The smooth substrate material has the best 3‐dB bandwidth compared with rough SiC substrate, followed by BN and SiO2 for all RMCB structures, and among all structures, the RMCB8 has the best 3‐dB bandwidth. The relative stability of RMCB1 is improved by 134.2% and 22.7% w.r.t. RMCB8 placed on a smooth and rough SiC substrate, respectively. Whereas bandwidth of the RMCB1 is reduced by 26% and 88.5% w.r.t. RMCB8 placed on a smooth and rough substrate, respectively. Hence, there is a tradeoff between the bandwidth and the relative stability as the number of CNT increases. Therefore, RMCB3 placed on a smooth substrate and RMCB4 placed on a rough SiC substrate are considered the best‐optimized RMCB interconnects to maintain a balance between the two.

Petrographic and geochemical characteristics of the Middle−Upper Cambrian Xixiangchi dolomites in the central Sichuan Basin, southwest China: Implications for dolomite origins and dolomitization mechanisms

The Middle−Upper Xixiangchi Formation of the Sichuan Basin consists of mixed carbonates and siliciclastics. The carbonates are dominated by dolomitized lime-mudstones and dolo–grainstones of shallow warm-water environments. Petrographic examination of carbonates reveals two types of dolomite: (i) fabric retentive dolomicrite (D1, micritic to near-micritic, 4–50 μm) and (ii) fabric-destructive dolomite (eu-to subhedral crystals with cloudy cores and clear rims, 50–300 μm). The mean ∑REE values of D1 (15.3 ± 6.3 ppm) and D2 (14.6 ± 7.1 ppm) and the nearly identical mean PAAS-normalized patterns that coincide at some points, suggest an origin from similar parent fluids that were not dramatically changed by water-rock interaction through basinal sedimentary rocks. The estimated Sr/Ca molar ratios of D1 (0.0043–0.0055) parent fluids and their estimated δ18O values imply an origin from a mixture of meteoric and seawaters, which is also consistent with the petrographic evidence. The partially coinciding normalized REE pattern of D2 with that of the earlier D1 suggests that the latter was formed at a mid-burial setting rather than deep burial, which is consistent with higher homogenization temperatures of primary two-phased fluid inclusions retained in D2 (Th = 118.1 ± 5.3 °C). Therefore, D1 is suggested to have formed (1) during a penecontemporaneous period that resulted from a slight evaporative pumping effect within a near-surface diagenetic environment, and/or (2) during post-penecontemporaneous or penecontemporaneous seepage-reflux dolomitization, induced by sea-level fluctuations, during early stages of diagenesis at near-surface conditions. D2 formed likely through the recrystallization of D1 or a continuation of reflux dolomitization of the same precursor at mid-burial rather than deep burial settings.

Integration of geoscience data to delineate quality of the Asmari reservoir, Iranian part of the Persian Gulf basin

The Hendijan Field is an asymmetric structure located in the northwestern Persian Gulf and consists of several oil and gas-bearing intervals. Oligocene to Miocene successions in the field host large volumes of hydrocarbons. The Asmari Formation comprises the mixed siliciclastic and carbonate members formed in a shallow marine carbonate ramp depositional environment. The siliciclastic part displays the best reservoir quality within the Asmari Formation. Through petrophysical, sedimentological, and geophysical analysis, this study divides the Asmari Formation into six, third-order depositional sequences. By doing so, it clarifies the relationships between depositional sequences and reservoir characteristics, particularly porosity and water saturation. Detailed petrographical analysis, core description, well log analysis, and seismic interpretation distinguish eight microfacies, two petrofacies, and six third-order sequences within the Asmari Formation. 3D reservoir-property models are developed that incorporate elements of the sequence stratigraphical framework. Within the six identified sequences, high reservoir quality zones are associated with AS-4 and AS-5, which comprise mostly grain-supported lithologies associated with shoal facies. The supratidal, intertidal, and lagoonal facies of AS-2, which are often associated with the occurrence of anhydrite and mud-supported fabrics, reflect lower reservoir quality. Hydraulic flow units (HFU) are delineated to assist in characterizing reservoir heterogeneity and porosity/permeability prediction. Five HFU were identified by applying the flow-zone-indicator method to evaluate reservoir quality. Both the transgressive system tract (TST) of AS-2 and early TST plus late highstand system tract (HST) of AS-6 contain elements of HFU-A. The most productive units of AS-4 and AS-5 belong to HFU-E.

Ultrasound and H2O assisted scCO2 foaming technology for preparation of PS/PMMA composite foams with ultra-lightweight and super thermal-insulation

Porous polymer with lower density is more favorable for practical thermal insulation. In this work, a judicious combination of mechanical mixing and supercritical carbon dioxide foaming was applied to prepare ultra-lightweight polymer microcellular foam. The polymer foaming behavior is improved by adding water and ultrasound as an external energy source. The presence of water greatly increases the efficiency of ultrasound propagation, resulting in an almost two-fold increase in expansion ratio of foams. With the assistance of water and ultrasonic irradiation, the prepared foams have a 79-fold foaming expansion ratio and an average thermal conductivity as low as 26.79 mW/mK. The ultrasound also affects the process of foaming in both the saturation and release stage, but is more effective in the release stage than in the saturation stage. Consequently, this study provides a novel, facile, versatile, green approach for the preparation of microcellular polymers with ultra-lightweight and super thermal insulation.

A Metal‐Free Mesoporous Carbon Dots/Silica Hybrid Type I Photosensitizer with Enzyme‐Activity for Synergistic Treatment of Hypoxic Tumor

AbstractAs a less O2‐dependent photodynamic therapy (PDT), type I PDT is an effective approach to overcome the hypoxia‐induced low efficiency against solid tumors. However, the commonly used metal‐involved agents suffer from the long‐term biosafety concern. Herein, a metal‐free type I photosensitizer, N‐doped carbon dots/mesoporous silica nanoparticles (NCDs/MSN, ≈40 nm) nanohybrid with peroxidase (POD)‐like activity for synergistic PDT and enzyme‐activity treatment, is developed on gram scale via a facile one‐pot strategy through mixing carbon source and silica precursor with the assistance of template. Benefiting from the narrow bandgap (1.92 eV) and good charge separation capacity of NCDs/MSN, upon 640 nm light irradiation, the excited electrons in the conduction band can effectively generate O2•− by reduction of dissolved O2 via a one‐electron transfer process even under hypoxic conditions, inducing apoptosis of tumor cells. Moreover, the photoinduced O2•− can partially transform into more toxic •OH through a two‐electron reduction. Moreover, the POD‐like activity of NCDs/MSN can catalyze the endogenous H2O2 to •OH in the tumor microenvironment, further synergistically ablating 4T1 tumor cells. Therefore, a mass production way to synthesize a novel metal‐free type I photosensitizer with enzyme‐mimic activity for synergistic treatment of hypoxic tumors is provided, which exhibits promising clinical translation prospects.

Physical and chemical properties of carbon-based sorbents that affect the removal of per- and polyfluoroalkyl substances from solution and soil

Removal of per- and polyfluoroalkyl substances (PFASs) from water or their immobilization in soil using carbon-based sorbents is one of the cost-effective techniques. Considering the variety of carbon-based sorbents, identifying the key sorbent properties responsible for PFASs removal from solution or immobilization in the soil can assist in the selection of the best sorbents for management of contaminated sites. This study evaluated the performance of 28 carbon-based sorbents including granular and powdered activated carbon (GAC and PAC), mixed mode carbon mineral material, biochars, and graphene-based materials (GNBs). The sorbents were characterized for a range of physical and chemical properties. PFASs' sorption from an AFFF-spiked solution was examined via a batch experiment, while their ability to immobilize PFASs in soil was tested following mixing, incubation and extraction using the Australian Standard Leaching Procedure. Both soil and solution were treated with 1 % w/w sorbents. Comparing different carbon-based materials, PAC, mixed mode carbon mineral material and GAC were the most effective in sorbing PFASs in both solution and soil. Among the different physical characteristics measured, the sorption of long-chain and more hydrophobic PFASs in both soil and solution was best correlated with sorbent surface area measured using methylene blue, which highlights the importance of mesopores in PFASs sorption. Iodine number was found to be a better indicator of the sorption of short-chain and more hydrophilic PFASs from solution but was found to be poorly correlated with PFASs immobilization in soil for activated carbons. Sorbents with a net positive charge performed better than those with a net negative charge, or no net charge. This study showed that surface area measured by methylene blue and surface charge are the best indicators of sorbent performance with respect to sorption/reducing leaching of PFASs. These properties may be helpful in selecting sorbents for PFASs remediation of soils/waters.

Svalbard Composite Tectono-Sedimentary Element, Barents Sea

Abstract The Svalbard Composite Tectono-Sedimentary Element (SCTSE) is located on the northwestern corner of the Barents Shelf and comprises a Carboniferous–Pleistocene sedimentary succession. Due to Cenozoic uplift, the succession is subaerially exposed in the Svalbard archipelago. The oldest parts of the succession consist of Carboniferous–Permian mixed siliciclastic, carbonate and evaporite, and spiculitic sediments that developed during multiple phases of extension. The majority of the Mesozoic succession is composed of siliciclastic deposits formed in sag basins and continental platforms. Episodes of Late Jurassic and Early Cretaceous contraction are evident in the eastern part of the archipelago and in nearby offshore areas. Differential uplift related to the opening of the Amerasian Basin and the Cretaceous emplacement of the High Arctic Large Igneous Province created a major hiatus spanning from the Late Cretaceous and early Danian throughout the Svalbard CTSE. The West Spitsbergen Fold and Thrust Belt and the associated foreland basin in central Spitsbergen (Central Tertiary Basin) formed as a response to the Eurekan Orogeny and the progressive northward opening of the North Atlantic during the Paleogene. This event was followed by the formation of yet another major hiatus spanning the Oligocene–Pliocene. Multiple reservoir and source-rock units exposed in Svalbard provide analogues to the prolific offshore acreages in the SW Barents Sea, and are important for the de-risking of plays and prospects. However, the archipelago itself is regarded as a high-risk acreage for petroleum exploration. This is due to Paleogene contraction and late Neogene uplift of the western and central parts in particular. There is an absence of mature source rocks in the east, and the entire region is subjected to strict environmental protection.