Expression of the Toarcian Oceanic Anoxic Event in the mixed siliciclastic–carbonate system of the Arabian Plate: Insights from rare-earth element geochemistry and statistical analysis

Abstract

Rare earth elements and yttrium (REEY) are considered powerful indicators of paleo-redox conditions. However, to date, the utilization of REEY remains limited to either pure carbonates or deep marine shales, with little evidence of attempts to test their ability to depict marine anoxia within mixed carbonate–siliciclastic systems. Across the Tethys Ocean, the Toarcian Oceanic Anoxic Event (T-OAE) is widely recorded by black marine shales with strong negative carbon isotopic excursion. Yet, the occurrence and expression of T-OAE across the mixed siliciclastic and carbonate system of the Arabian Plate has not been recorded or even explored. This provides a unique opportunity to test the robustness and viability of REEY, supported by statistical analysis, in revealing marine anoxia in a mixed system. Our results demonstrate a positive Ce anomaly within the middle Marrat, coupled with a positive Eu anomaly and aluminum-normalized Mn enrichment in the underlying lower Marrat carbonates. This could be hypothetically related to volcanic pulses, which triggered the T-OAE. Overall, the REEY geochemical record and detailed statistical analysis of this study indicate, for the first time, the possibility that T-OAE might have extended to the Arabian Plate for brief periods of time during the deposition of the middle Marrat shallow marine red beds.