Mid-ocean Ridge Research Articles

Copper migration and enrichment in the mantle wedge: Insights from orogenic peridotites and pyroxenites

The refertilized mantle wedge is an important source of ore-forming metals in subduction-related Cu–Au deposits. However, the source and migration of Cu in the mantle wedge are poorly constrained. Here, we present a combined study of the Cu elemental and isotopic compositions (δ65Cu) as well as Fe3+/∑Fe ratios on a well-characterized suite of the Mg-lherzolites, Fe-rich peridotites and pyroxenites from the Bohemian Massif in a Variscan subduction zone. The Mg-lherzolites represent melting residues moderately affected by metasomatism of slab-derived melts/fluids. The Fe-rich peridotites and pyroxenites are, respectively, results of Mg-lherzolite-melt reaction and crystalline products of evolved melts in the lithospheric mantle.The peridotites and pyroxenites display higher Fe3+/∑Fe ratios (0.14–0.56) than the cratonic peridotites and mid-ocean ridge basalts, indicating that the mantle wedge was oxidized by slab-derived components. The Mg-lherzolites have relatively low Cu contents (7.35–39.6 μg/g) and normal mantle-like δ65Cu values (−0.13 to 0.26 ‰), suggesting an insignificant slab-to-mantle wedge Cu transfer. In contrast, the Fe-rich peridotites and pyroxenites have variable but overall high Cu contents (37.0–513 μg/g) and heavier δ65Cu values (up to 0.83 ‰). These signatures are ascribed to secondary sulfide precipitation from the evolved Cu- and 65Cu-enriched melts, which were produced by reaction of Mg-lherzolites with subduction-related oxidative SiO2‐undersaturated basaltic melts. Such melt-peridotite reaction at high oxygen fugacity can cause the partial oxidative decomposition of primary sulfides in peridotites with the preferential release of 65Cu into the evolved melts. Our results thus demonstrate that oxidative melt-rock reaction can result in the Cu migration, redistribution and its local enrichment in the mantle wedge, which may serve as an important source of Cu for subduction-related porphyry copper deposits.

Geodynamic and Climatic Forcing on Late‐Cenozoic Exhumation of the Southern Patagonian Andes (Fitz Roy and Torres del Paine massifs)

AbstractHigh‐relief glacial valleys shape the modern topography of the Southern Patagonian Andes, but their formation remains poorly understood. Two Miocene plutonic complexes in the Andean retroarc, the Fitz Roy (49°S) and Torres del Paine (51°S) massifs, were emplaced between 16.9–16.4 Ma and 12.6–12.4 Ma, respectively. Subduction of oceanic ridge segments initiated ca. 16 Ma at 54°S, leading to northward opening of a slab window with associated mantle upwelling. The onset of major glaciations caused drastic topographic changes since ca. 7 Ma. To constrain the respective contributions of tectonic‐mantle dynamics and fluvio‐glacial erosion to rock exhumation and landscape evolution, we perform inverse thermal modeling of a new data set of zircon and apatite (U‐Th)/He from the two massifs, complemented by apatite 4He/3He data for Torres del Paine. Our results show rapid rock exhumation recorded only in the Fitz Roy massif between 10 and 8 Ma, which we ascribe to local mantle upwelling forcing surface uplift and intensified erosion around 49°S. Both massifs record a pulse of rock exhumation between 7 and 4 Ma, which we interpret as enhanced erosion during the beginning of Patagonian glaciations. After a period of erosional and tectonic quiescence in the Pliocene, increased rock exhumation since 3–2 Ma is interpreted as the result of alpine glacial valley carving promoted by reinforced glacial‐interglacial cycles. This study highlights that glacial erosion was the main driver to rock exhumation in the Patagonian retroarc since 7 Ma, but that mantle upwelling might be a driving force to rock exhumation as well.

Fluid-mediated Cu and Zn isotope fractionation in subduction zones and implications for arc volcanism: Constraints from high pressure veins within eclogites in the Dabie Orogen

High-pressure (HP) veins in eclogites are the products of fluid-rock interaction and provide insight into the composition and evolution of fluids in subduction zones. We here present the Cu and Zn isotope data for different types of HP veins and their host eclogites from Ganghe and Hualiangting in the Dabie Orogen to reveal the behavior of Cu and Zn isotopes during fluid-rock interaction and fluid evolution. The HP veins include omphacite-epidote (Omp-Ep), epidote-quartz (Ep-Qtz), and kyanite-epidote-quartz (Ky-Ep-Qtz) veins. The Omp-Ep veins first crystallized from eclogite-derived, solute-rich fluids with the Ep-Qtz and Ky-Ep-Qtz veins successively crystallizing from the residual fluids after the Omp-Ep vein formation. The early Omp-Ep veins have variably lower δ65Cu (−1.32 to −1.12‰ at Ganghe, −0.70 to −0.66‰ at Hualiangting) but higher δ66Zn (0.36 to 0.38‰ at Ganghe, 0.40 to 0.41‰ at Hualiangting) relative to the host eclogites (δ65Cu: −0.71 vs. 1.84‰, δ66Zn: 0.22 vs. 0.33‰), indicating CuZn isotope fractionation during slab dehydration in subduction zones with the lighter Cu and heavier Zn isotopes preferentially entering the vein-forming fluids from the eclogites. Systematic increase of δ65Cu from the Omp-Ep (−0.70 to −0.66‰) through Ep-Qtz (0.01‰) to Ky-Ep-Qtz veins (0.46 to 0.95‰) can be attributed to isotope fractionation induced by redox changes during the evolution of metamorphic fluids, as revealed by the negative correlations of δ65Cu with redox-sensitive ratios of Fe3+/ΣFe and (Eu/Eu*)N in those veins. Additionally, the higher δ66Zn of the Omp-Ep veins relative to the Ky-Ep-Qtz veins can be explained by equilibrium isotope fractionation between crystallized minerals and evolved metamorphic fluids. Our results thus demonstrate that CuZn isotope fractionation occurred during the evolution of slab-derived metamorphic fluids in subduction zones. Binary mixing calculations show that fluids derived from dehydration of mafic rocks in subducted slabs, represented by the multistage HP veins in the present study, cannot account for the heavier Cu and lighter Zn isotope compositions in most arc magmas than in mid-ocean ridge basalts. This offset can be resolved by addition of forearc serpentinite-derived fluids enriched in heavy Cu and light Zn isotopes into the mantle source of arc magmas.

Evidence for large-scale, long-term highly siderophile element heterogeneities in the Atlantic mantle from Leg 153 and 209 peridotites

Seafloor abyssal peridotites are products after partial melting and melt-rock interaction, providing constraints on upper mantle processes and heterogeneity. Despite extensive studies of ophiolitic peridotites and a burgeoning dataset for dredged abyssal peridotites, limited studies have been undertaken on abyssal peridotite drill core samples. This omission means a lack of comparison between modern ocean mantle lithosphere and that of ophiolites, where field context is possible in the latter, but not the former. Ocean Drilling Program (ODP) Leg 153 near the Kane fracture zone, and ODP Leg 209, near the Fifteen-Twenty fracture zone, both on the mid-Atlantic Ridge but ∼1000 km distant from one another, recovered serpentinized mantle peridotites. We report whole-rock major-, trace- and highly siderophile-element (HSE: Re, Pd, Pt, Ru, Ir, Os) abundances and 187Os/188Os ratios of peridotites from three cores (maximum depth of 200.8 m) from the two Legs to explore mantle heterogeneity within the Atlantic Ocean basin. Peridotites from ODP Leg 153 are relatively fertile, with Al2O3 contents ranging from 1.1 to 2.7 wt%. They are characterized by relatively radiogenic 187Os/188Os (0.1259 ± 0.0017; 2 S.D.) and uniform HSE abundances. The ODP Leg 209 peridotites are highly refractory, with Al2O3 contents ranging from 0.1 to 0.8 wt%, and imply that they record an extensively depleted mantle. They have 187Os/188Os of 0.1207 ± 0.0023 (2 S.D.) and fractionated HSE abundances, indicative of depletion occurring > 1 billion years ago. Marked heterogeneity both in the extent and timing of depletion are therefore evident along a large segment of the mid-Atlantic ridge that produces zero-age basalts. Measurement of Os isotopes in spatially associated mid-ocean ridge basalts (MORB) is challenging due to their sub ng/g Os contents. Instead, Nd isotopes of MORB are used to show that they are unlikely to have formed directly from abyssal peridotite-like sources. Abyssal peridotites therefore represent long-lived refractory residues during mantle upwelling with the sources of MORB being more enriched. Comparison between drilled abyssal peridotites and ophiolitic mantle reveals larger compositional variations in the latter. The overall higher melting extent in ophiolite mantle is likely reflective of a more complex life cycle than the modern oceanic lithosphere.

Evaluation of garnet phenocrysts in volcanic rocks (Görece/İzmir – Western Türkiye) for their usability as a semi-precious gemstone by multi-analytical methods

Garnets are observed as phenocrysts in blocky rhyolites of Cumaovası Volcanites and are reddish-blackish in color, show vitreous luster, and have dodecahedron forms varying between 0.5 and 2.0 cm in size. In optical microscope investigations, they exhibit fractured structures and contain quartz, hematite, chlorite, and acicular rutile inclusions. Garnet phenocrysts are highly consistent with spessartine-type garnet end members in the Raman spectrum. This result is supported by the mineral chemistry results determined as spessartine (Sps)0.50–0.52 almandine (Alm)0.47–0.48 grossular (Grs)0.01–0.02. In the chondrite, primitive mantle, and Mid-Oceanic Ridge Basalt normalized multi element variation diagrams, garnet phenocrysts show enrichment in all elements (except Sr, K, P, and Ti). In contrast, in the upper continental crust normalized multi element variation diagram, garnet phenocrysts show depletion in large ion lithophile elements (Rb, Ba, K, and Sr) relative to high field strength elements. They exhibit slight enrichment in light rare earth elements ((La/Sm)N = 0.11–1.07) relative to heavy rare earth elements ((Sm/Yb)N=0.78–0.97). Furthermore, garnet phenocrysts have significant negative europium (Eu) ((Eu/Eu*)N = 0.01–0.02) and mildly positive cerium ((Ce/Ce*)N = 2.43–13.77) anomalies indicating hot and reduced magma conditions. The Y/Ho ratios have ranged from 18.9 to 20.3 and are close to the chondrite value. The zircon saturation temperatures (TZr) of the garnet’s host rock was determined to be 756 °C. As a result of mineralogical, geochemical and gemological studies, it was concluded that Görece garnet phenocrysts have glassy luster and semi-transparent dodecahedral crystal shapes, so they can be classified as semi-precious gemstones. In addition, the rare earth element content of the garnet phenocrysts is similar to that of industrial garnet sands and it is thought that they may have potential.

Cretaceous Limestone Dolomitization and Argument of Its Mg2+ Sources: Exampling the Bekhme and Qamchuqa Formations in the Zagros Collision Belt

This study unveils new considerations regarding the dolomitization of the Bekhme and Qamchuqa formations (BQFs), two reefal Cretaceous units in the Iraqi Zagros collisional belt. Previous studies proposed the dolomitization of these formations due to the ascent of Mg-rich hydrothermal solutions through deep faults but lacked substantial supporting evidence. This paper present new considerations suggesting that the dolomitization of the BQFs resulted from the Cretaceous environmental conditions and basin paleogeographic setting of the platform on which these formations were deposited. To justify this consideration, seven proofs presented. First is the occurrence of dolomite as vast layers extending tens of kilometers laterally and bounded between limestone beds, which resemble a strata-bound occurrence. Second is the absence of vertical selective dolomitization such as, hydrothermal mineralization, vertical dolomite dykes, hydrothermal vents, tubes, or zones. Third is the barrenness of most of the fault surfaces and their surrounding rocks with selective dolomitization. Fourth is the sharp boundary between the dolomite and limestone layers, indicating a sudden environmental change from lagoon to reef or forereef. Fifth is the record of dolomitization in the sediments reworked by bioturbation, evident in thalassinoides burrows. Sixth is the succession of BQFs underlain by limestone and green marl devoid of dolomitization and hydrothermal upward movement. Seventh is the contradictory notion of hydrothermal dolomitization among the most recent study published in the Science journal which atributed dolomitization to normal temperate on earth surface. In the present study, the source of the Mg is argued and its presence is attributed to the warmth of the Arabian platform (plate) near the equator during the Cretaceous period. Another source is the connection of the Arabian platform with the Neo-Tethys Sea, which was the locus of Mg-rich mafic volcanism in the form of arcs and mid-oceanic ridge topography, which supplied a voluminous amount of Mg to the Arabian carbonate platform through ocean currents.

Geochemistry and zircon U-Pb geochronology of diabase, gabbros, anorthosites and ultramafic rocks from the South Andaman Island ophiolite suite on the South-Eastern margin of the Indian plate

The South Andaman Island is located on the southeastern fringe of the Indian plate. Tectonically, the islands are associated with the Burma-Andaman-Java subduction zone of the Indonesian arc system. Several Mesozoic ophiolitic exposures are preserved in the Burma-Andaman-Java subduction zone. This study reports new petrological, geochemical, and zircon U-Pb geochronological data for the diabases, gabbros, anorthosites, and harzburgites of the ophiolite suite exposed in the South Andaman Island. The diabase is composed of plagioclase and clinopyroxene exhibiting ophitic textures. Anorthosite mainly contains plagioclase (> 90 vol%), pyroxenes and Fe-oxides. Gabbros have plagioclases and clinopyroxenes occurring as the major minerals. Harzburgites consist of olivine, orthopyroxene, clinopyroxene and spinel. Geochemical investigation reveals that these rocks were formed through crystal fractionation and accumulation processes from partial melt generated from a spinel lherzolite source. Gabbro, diabase, and anorthosites are formed by ∼1–5% melting of the, whereas depleted harzburgites were generated by slightly higher degrees of partial melting (∼10–20%) of the spinel lherzolite source. Trace element modelling reveals the influence of mid-oceanic ridge basalt (MORB)-melt interaction and subduction-related mantle alterations.The anorthosite and gabbro samples yield zircon 206Pb / 238U weighted mean ages of 93.2 ± 1.0 Ma and 442.5 ± 4.0 Ma, 383.9 ± 3.3 Ma respectively. However, the harzburgite sample records multiple age population including Paleo-Mesoproterozoic grains ranging in age from 1216 to 1931 Ma as well as Neoproterozoic and Phanerozoic grains of 607 Ma, 594 Ma, 237 Ma, 105 Ma, and 85 Ma suggesting a long-lived supra subduction zone in the Burma-Andaman-Java subduction zone where the South Andaman ophiolite suite was formed, evolved, and was emplaced.

A revolution in understanding SE Asia geodynamics since 20.5–18 Ma

We present an updated evaluation of SE Asian geodynamics that includes the interactions of the South China Sea (SCS) marginal basin with surrounding plates since the end of SCS spreading 20.5–18 Ma. Newly available Ar39/Ar40 ages of SCS oceanic crust drilled at IODP U1431 near the SCS East basin extinct spreading center are older than 18 Ma. Conversely, the oldest ages of the Luzon arc and forearc at Taiwan's Lanyu island, Coastal range and Lichi mélange are 17–18 Ma, suggesting that onset of the Manila subduction zone may have begun a few m.y. earlier. Before ∼20.5 Ma, the northern part of the Manila transcurrent fault (MTF), considered as the western boundary of the Ryukyu subduction zone, was a left-lateral lithospheric-scale shear zone. From ∼20.5–18 Ma to ∼7 Ma, this portion of MTF was connected to the Manila trench. Since ∼7 Ma, the MTF extended into the Taiwan Longitudinal valley and continued southwards to north Luzon island as near-vertical, left-lateral shear zone. Today, south of ∼24°N, the MTF protrudes down to 30 km depths and terminates above the deeper Manila slab. Since ∼7 Ma, the whole MTF shifted 400 km westward with respect to Eurasia and rotated ∼23° clockwise to become oriented ∼NS north of 16°N latitude. We identify a tear fault in the Eurasian (EU) plate north of the Ryukyu trench that is located south of the Myako and Yonaguni islands. Since ∼10 Ma, the tear continuously progressed westward within EU crust, with the Philippine Sea plate progressively subducting northwestward between the two lips of the tear fault. A RFF (ridge-fault-fault) triple junction was active in the EU crust before 20.5 Ma, from 10 to 7 Ma, and since 2 Ma. This triple junction was always located on the MTF with one branch of the MTF on each side of the triple junction, and the third branch being the spreading center.

Spinel chromianowy z dunitów masywu Inagli i ich termobarometria tlenowa (tarcza ałdańska, platforma syberyjska)

The Inagli dunite-peridotite-shonkinite zonal-ring intrusive with platinum-chromite mineralization is located on the Aldan shield of the Siberian Platform. Considering the structure, rock composition and ore mineralization, it is similar to the platinum-bearing zonal massifs of the "Ural-Alaskan" type, but this intrusive differs from the latter in its geological position. In order to clarify the physical and chemical conditions of formation of the Inagli massif, the mineral composition of rocks, especially сhromite-containing dunites, peridotites and shonkinites, as well as platinum-chromitite ore segregations, has been studied in detail. The rocks of the Inagli massif, from dunites to shonkinites, including peridotites, clinopyroxenites, and alkaline syenites, form a single continuous series. This is confirmed by a clear dependence of the composition of olivine, pyroxene, phlogopite and chromian spinel on the content of MgO in rocks. They were formed from the initial high-potassium picrite melt, which, during rising, underwent gradual decompression solidification and formed a cylindrical diapir-like body at the near-surface level in the Early Cretaceous. This occurred as a result of subduction processes related to the formation of the Mongol-Okhotsk orogenic belt along the southern framing of the Siberian craton. The values of oxygen volatility (lgfO2) for dunites, peridotites, shonkinites, chromitites and olivine-chromite inclusions in the isoferroplatinum of the Inagli massif, calculated using the method of the olivine-spinel oxygen thermobarometer of Ballhaus-Berry-Green (BBG), form a single trend FMQ+(2-4) in the range 620-11400C, i.e. along the band by 2-4 units of lgfO2 exceeding the fayalite-magnetite-quartz (FMQ) buffer. Such a rather narrow range of variation in the values of O2 fugacity in a wide interval of temperature indicates good comparability and reliability of the data obtained. At the same time, there is a natural decrease in temperature intervals for the formation of olivine-chromite parageneses (in 0С): with isoferroplatinum – (1140-680); in chromitite segregations – (980-710); in dunites – (930-620); peridotites – (890-770) and shonkinites – (840-710). The results obtained almost completely coincide with the field of values for dunites and chromitites from the Platinum-bearing belt of the Urals, given by other researchers. In terms of redox parameters, platinum-bearing zonal ultramafic-mafic massifs of the Ural-Alaskan and Aldanian types are close to more oxidized peridotites with a long history in the lithosphere. They differ significantly from the peridotites of the Beni-Bousera massif, as well as abyssal peridotites of the oceanic ridge systems, and others, which are formed under more reduced conditions corresponding to the range between FMQ, carbon-oxygen-CO (ССО) and iron-wustite (IW) buffers.

Two Effective Degrees of Freedom Can Represent the Dominant Features of Global Rayleigh Wave Dispersion Maps

AbstractObjectively exploring global variations in crust and upper mantle structure helps constrain fundamental aspects of Earth's plate tectonic and convective processes. Here we adopted a Variational Auto‐Encoder to explore the degrees of freedom of global Rayleigh wave dispersion maps at 4–40 mHz. We found that two latent variables sufficiently represent the global variations, suggesting inherent coupling between crustal and mantle seismic properties. We propose that the two extracted latent variables mostly correspond with crustal thickness and upper mantle thermal structure. The first variable shows low values for continental mountain belts and ocean spreading ridges, contrasted by high values for abyssal plains. The second variable shows low values for most oceanic lithosphere and Phanerozoic continental areas, contrasted by high values for Archean cratons. Latent space correlations indicate that continental lithosphere has more strongly coupled depth features than beneath the oceans, which might be a consequence of its longevity.

Laptev Rift System Composite Tectono-Sedimentary Element, East Siberian Arctic

Abstract The Laptev Sea in the East Siberian Arctic is characterized by a system of extensional structures known as the Laptev Rift System (LRS), developed at the continental prolongation of an active divergent plate boundary - the Gakkel spreading ridge. The LRS hosts as much as 13–14 km of siliciclastic sedimentary strata of supposedly Late Cretaceous to Recent age. The strata accumulated atop of stretched and thinned continental crust that before the rifting onset was a complex tectonic juncture of Late Paleozoic/Early Mesozoic Taimyr and Late Mesozoic Verkhoyansk fold-and-thrust belts formed along the edges of the Siberian Palaeocontinent. In the context of this volume, the LRS is described as a composite tectono-sedimentary element that includes sedimentary rocks accumulated during pre-rift and syn-rift phases. The latter includes at least two syn-rift sedimentary cycles separated by a sedimentary succession formed during a stalled rift phase. In the absence of deep exploration wells, many aspects of the LRS geology and its petroleum prospects remain poorly constrained.

Kaiwi shoreline basalts fed by the west rift zone of East Molokaʻi

Bathymetry and acoustic imagery swath mapping, along with observations and samples from four manned submersible and four ROV dives, confirm that a seafloor slope break on the northern approaches to Kaiwi Channel, between the islands of Oʻahu and Molokaʻi, Hawaiʻi is a former shoreline, now submerged ∼800 m below present sea level. Subaerially emplaced, low-relief basaltic lavas above the slope break transition to submarine morphologies below. The entire region has been tilted about 1° to the SSE (150°), and is cut by an 8–15 m-high, north-facing scarp, 100–400 m south of the slope break. The distribution of platy, table-top, and rarer mounded branching corals indicates the former presence of fringing reefs around low-relief paleo-islands. We infer that the regional tilt resulted from loading by younger Hawaiian volcanoes, compounded by flexural uplift and back tilting away from the unloaded footwall of a flank landslide to the north.Basalt samples collected from both above and below the slope break have petrography, chemical composition, and age (1.64–1.80 Ma) indicating correlation with the (late-shield) Lower Member of the East Molokaʻi Volcanics, rather than with the more proximal volcano of West Molokaʻi. The most likely source of the Kaiwi basalts is a submarine ridge (rift zone) that extends northwest away from ʻĪlio Point on West Molokaʻi. Although the submarine ridge was previously assumed to be an extension of West Molokaʻi's northwest rift, we conclude that regional bathymetry and gravity are consistent with this feature being an extension of the west rift of East Molokaʻi. A corallary of this interpretation is that the shoreline slope break (SSB 7 of Taylor, 2019) in this area is distinct from and younger than the southern SSB 7 formed on West Molokaʻi volcano (∼1.65 Ma vs. ∼1.8 Ma).

Continental flood basalts sample oxidized mantle sources

Large igneous provinces (LIP) are vast (0.2 to >1 Mkm3) outpourings of basaltic lava and voluminous intrusions of magmas that have had important environmental consequences, in many cases leading to immense greenhouse gas release and mass extinctions. Magmatic oxygen fugacity (fO2) influences the chemistry of volcanic gases and is an important parameter for examining the links between LIP eruptions and environmental change. To constrain the fO2 of LIP magmas, we report olivine elemental chemistry of 399 crystals from a set of fifteen olivine-rich LIP samples, spanning in age from the Proterozoic (∼1270 Ma) to the Miocene (∼17 Ma). Concentrations of V in olivine are used to show that mafic LIP lavas erupted at +1.20 ± 0.95 ΔFMQ, on average more oxidized than mid ocean ridge basalts (MORB) at −0.28 ± 0.28 ΔFMQ. Mafic LIP magmas show a much larger range than MORB, however. Additionally, fO2 shows a negative correlation with parental magma MgO content, with high MgO lavas approaching the MORB range. This correlation is likely due to sampling of a heterogeneous mixture of oxidized and reduced lithologies, as also sampled by ocean island basalts (OIB). Correlation between fO2 and isotopic ratios such as 143Nd/144Nd demonstrates that the oxidized endmember is geochemically enriched, and may result from subduction recycling of oxidized surficial materials. The high fO2 of primitive LIP magmas demonstrate that they largely emitted oxidized gases during eruption, and furthermore, that LIP magmas associated with mass extinctions have similar magmatic fO2 to those that are not. Global plate tectonic position, magnitude and duration of LIP volcanic eruptions and magmatic degassing, as well as interaction with sedimentary basins in the crust - but not mantle source fO2 - are likely to be the critical factors for whether a LIP was associated with a mass extinction.

Determining mid-ocean ridge geography from upper mantle temperature

In this study, we examine the influence of the mantle and large-scale tectonics on the global mid-ocean ridge (MOR) system. Using solely seismically-inferred upper mantle temperatures below the melting zone (260-600 km) and an interpretable machine learning model (Random Forest and Principal Component Analysis), we can predict a priori the location (ocean basin and ridge system) of global MOR with up to 90% accuracy. Two features provide > 50% of the discriminative power: the temperature difference between the mid-layer (340-500 km) and other depths, and the depth-averaged temperature of the upper mantle. We suggest long-term (100s Myr) tectonic and large-scale convective processes primarily driven by deep subduction left ample, distinct but hidden fingerprints in the mantle that allow us to separate regions at ∼1000 km scale. Our result implies that the large-scale geophysical and geochemical differences observed along the MOR system are reflective, not primarily of shallow processes associated with melting, but of the integrated long-term tectonic, subduction, and convective flow history that determines the present-day upper mantle temperature structure.

Serpentinization as a Tape Recorder of (Dis)Continuous Mantle Exhumation along the Alpine Tethys Ocean-Continent-Transition

Abstract Serpentinization has been widely documented and investigated at mid-ocean ridges (MOR) and subduction zones. In contrast, at magma-poor rifted margins serpentinization has received much less attention, despite its importance in controlling rheology and mass fluxes during breakup and establishing of a steady-state MOR. In this study, we present new petrological and geochemical data on subcontinental exhumed serpentinized peridotites from the spectacularly exposed Platta, Tasna and Totalp nappes in the Eastern Central Alps in SE Switzerland, belonging to the Alpine Tethys Ocean Continent Transition (OCT). The results testify of a complex history of fluid–rock interactions recorded by several serpentinization events starting with lizardite mesh and bastite textures (S1), subsequently followed by a succession of serpentine-filling veins with distinct textures and serpentine polysomes that include spherical polyhedral serpentine (S2); chrysotile ± polygonal ± lizardite banded veins (S3); lamellar antigorite veins and patches (S4) and chrysotile crack-seal (S5). The serpentinization sequence differs at proximal (i.e. continentwards) and distal (i.e. oceanwards) domains of the OCT. At proximal domains of the OCT (Upper Platta, Tasna) serpentinites record the complete serpentinization sequence (S1 to S5), whereas at distal domains (Lower Platta) serpentinization is restricted to pseudomorphic mesh and bastite (S1) and chrysotile crack-seal (S5). We attribute this discrepancy to contrasted mechanisms of mantle exhumation along the OCT. While at proximal domains mantle is unroofed along continuous and single large offset detachment faults allowing for the formation of all serpentine generations, mantle exhumation at distal domains is a more discontinuous process, controlled by sequential out-of-sequence detachment and flip-flop faults preventing the full development of all serpentine generations. In this frame, the nature and order of formation of the serpentine polysomes are directly controlled by the conditions of serpentinization (i.e. temperature, mantle composition and fluid/rock ratio). We propose that this new conceptual model can be extrapolated to serpentinization at slow to ultra-slow MORs, where close similarities in the serpentinization sequences have been recently reported.

Complex Martinique Intermediate‐Depth Earthquake Reactivates Early Atlantic Break‐Up Structures

AbstractEarthquakes that rupture several faults occur frequently within the shallow lithosphere but are rarely observed for intermediate‐depth events (70–300 km). On 29 November 2007, the Mw7.4 Martinique earthquake struck the Lesser Antilles Island Arc near the deep end of the Wadati‐Benioff‐Zone. The sparse regional seismic network of 2007 previously hampered a detailed examination of this unusually complex event. Here, we combine seismic data from different studies with regional moment tensor inversion results and 3D full‐waveform modeling. We show that the earthquake is a doublet consisting of dip‐slip and strike‐slip motion along two oblique structures, both activated under extensional stress along the strike of the slab. Comparison with tectonic reconstructions suggests that the earthquake ruptured along a re‐activated ridge‐transform segment of the subducted Proto‐Caribbean spreading ridge. The unprecedented resolution of the source process highlights the influence of pre‐existing structures on localizing slab deformation also at intermediate‐depth.

On-land manifestation of along-strike transitioning of the Red Sea from continental rifting to sea floor spreading

This study uses Landsat Thematic Mapper (TM), Shuttle Radar Topography Mission (SRTM) Digital Elevation Model (DEM), and aeromagnetic data to examine possible reactivation of the Ediacaran, NE-trending Ad Damm Fault Zone (AFZ) and the Fatima Fault Zone (FFZ) in the western Arabian Shield. Reactivation is by latest Paleogene to Neogene and Quaternary structures of the Red Sea. The AFZ is the tectonic boundary between the Tonian Jeddah terrane in the northwest and the Asir terrane to the southeast of the Arabian Shield. The AFZ and FFZ coincide with possible onshore continuation of a transform fault that separates the sea floor spreading segment of the Red Sea in the south from its transitional segment to the north. It has been suggested that the AFZ is a candidate for the formation of a future onshore transform fault that would result in an eastward jump of the Red Sea sea floor spreading center onto the Arabian Shield. The future spreading center will follow the latest Neogene to Quaternary volcanic rocks (Harrat) that are exposed on the eastern side of the Red Sea. The Landsat TM image and the SRTM DEM show that the AFZ dissects the Red Sea topographic escarpment, and both the AFZ and FFZ control paleo-drainage system (wadis). The aeromagnetic data show that there is a ∼100 km wide zone between the AFZ and FFZ dominated by NE-trending short wavelength magnetic anomalies, possibly related to regional tectonic fabric. Additionally, the aeromagnetic data show that both fault zones dissect NW-trending short wavelength magnetic anomalies, interpreted as latest Paleogene to earliest Neogene dike swarms associated with the opening of the Red Sea. This dissection also includes possible Red Sea related narrow marginal grabens and horsts that were formed onshore and offshore parallel to the Red Sea shoreline. Red Sea-related structure might have reactivated the AFZ and FFZ.

Earthquake Seismicity Reveals the Location and Significance of the Shona Mantle Plume in the South Atlantic Ocean

AbstractThe South Atlantic Ocean hosts several well‐studied volcanic ridges and seamount chains, but the origin of their associated mantle plumes is debated. Reduced seismicity on the southern Mid‐Atlantic Ridge (MAR) suggests anomalously ductile thermomechanical conditions at 52°S and 47.5°S. These low seismicity patches extend 120–560 km along‐axis, and correspond with axial high spreading ridge morphology, geochemical anomalies, and mantle wave speed patterns likely associated with the Shona and Discovery plumes. Bathymetric data show that the northern extent of the Shona swell is associated with increased volcanism, elevated axial bathymetry, and a series of northward‐propagating rifts, with the overall swell geometry suggesting a buoyancy flux of 0.4–0.5 Mg s−1. The nearby Bouvet Island may be a product of a branch of the larger Shona plume swell, which has influenced crustal accretion on the southern MAR for the past 24 million years.

Geochemistry and magmatic petrology of meta-ophiolites from the Bajgan Complex (Makran Accretionary Prism, SE Iran): new insights on the nature of the Early Cretaceous Middle East Neotethys

The Bajgan Complex in the North Makran Domain (Makran Accretionary Prism) comprises disrupted meta-ophiolitic sequences originating from oceanic crust protoliths. They include ultramafic and mafic cumulates, isotropic gabbros, plagiogranites and basalts. Ultramafic–mafic cumulates and plagiogranites exhibit compositions akin to rocks formed in mid-ocean ridge settings. Isotropic gabbro and basalt protoliths can be subdivided into three distinct geochemical types. Type-1 rocks are sub-alkaline (Nb/Y < 0.1) with low Th, Nb and Ta contents and La N /Yb N ratios <1, resembling those of normal mid-ocean ridge basalts (N-MORB). Type-2 rocks display slight enrichment in Th, Ta, Nb (Nb/Y = 0.36–0.45) and La N /Yb N = 2.12–3.20, resembling the chemistry of enriched (E-) MORB. Type-3 basalts show an alkaline nature (Nb/Y = 0.88–1.82), significant Th, Ta and Nb enrichment, and high La N /Yb N ratios (7.01–20.08), resembling the chemistry of alkaline basalts (ocean island basalts, OIB). Petrogenetic modelling indicates that N-MORB protoliths originated from a depleted MORB mantle source, whereas E-MORB and OIB protoliths were generated from partial melting of sub-oceanic depleted sources that underwent varying degrees of OIB-type enrichment. The Bajgan meta-ophiolitic protoliths were formed within a Late Jurassic to Cretaceous oceanic basin influenced by mantle plume activity and plume–ridge interaction. Supplementary material : Field photographs, micrographs, rocks sampled, analytical methods and results, and supplementary tables are available at https://doi.org/10.6084/m9.figshare.c.7193937 Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists

Geochemical constraints on ridge-plume interaction in the West Philippine Basin

The West Philippine Basin is not only a back-arc basin resulting from the subduction of the paleo-plates, but it has also undergone modification due to intraplate processes. However, the interaction between intraplate processes and back-arc spreading processes remains unclear. In this study, we present geochemical compositions of basaltic lavas from various tectonic sites in the West Philippine Basin. Lavas from the Benham Rise and its adjacent seamount, as well as basement crust samples from the West Philippine Basin, are similar to oceanic island basalts and mid-oceanic ridge basalts, respectively. The lavas from the Central Basin Fault lie between the two aforementioned types. Based on the mixing modeling of geochemical data, morphological structure of the West Philippine Basin, and age data for lavas, we developed a conceptual model for the three-stage tectonic evolution, with the simultaneous influence of back-arc spreading and mantle plume processes.