Coating defects are caused by a series of factors such as the improper operation of workers and the quality of the coating itself. At present, the coating process of all shipyards is inspected and recorded at a specific time after construction, which cannot prevent and control defects scientifically. As a result, coating quality decreases, and production costs increase. Therefore, this paper proposes a knowledge acquisition method based on a rough set (RS) optimized by an improved hybrid quantum genetic algorithm (IHQGA) to guide the ship-coating construction process. Firstly, the probability amplitude is determined according to the individual position of the population, and the adaptive value k is proposed to determine the rotation angle of the quantum gate. On this basis, the simulated annealing algorithm is combined to enhance the local search ability of the algorithm. Finally, the algorithm is applied to rough set attribute reduction to improve the efficiency and accuracy of rough set attribute reduction. The data of 600 painted examples of 210-KBC bulk carriers from a shipyard between 2015 and 2020 are randomly selected to test the knowledge acquisition method proposed in the paper and other knowledge acquisition methods. The results show that the IHQGA attribute approximate reduction algorithm proposed in this paper is the first to reach the optimal adaptation degree of 0.847, the average adaptation degree is better than other algorithms, and the average consumption time is about 10% less than different algorithms, so the IHQGA has more vital and more efficient seeking ability. The knowledge acquisition result based on the IHQGA optimization rough set has 20–50% fewer rules and 5–10% higher accuracy than other methods, and the industry experts have high recognition. The knowledge acquisition method of this paper is validated on a hull segment. The obtained results are consistent with the expert diagnosis results, indicating that the method proposed in this paper has certain practicability.