Methane Concentration Research Articles

Characterization and Performance Evaluation of Anaerobic Night Soil Biodegrading Inoculum

The efficiency of anaerobic night soil (human excreta) biodegradation depends on the characteristics of the inoculum used. This anaerobic microbial inoculum (AMI) contains a microbial consortium, including rate-limiting methanogens whose growth depends on various physicochemical and biological parameters necessitating the inoculum characterisation essential for optimum night soil (NS) biodegradation. The inoculum contained 24.567 g/L (±0.07) total solid, 5.022 (±0.57) g/L total dissolved solid, 18.148 (±0.0.058) g/L volatile solid (VS), and 7.0±0.2 pH. The Gas chromatography analysis confirmed the presence of a small amount of volatile fatty acid (VFA), (≤ 4 mM except propionate) showing rapid conversion of VFA to methane, and 55% methane. Further, the presence of methanosaetaceae group of methanogens was detected through Taqman probe-based real-time PCR. The inoculum performance was evaluated for NS biodegradation in semicontinuous mode of feeding in four 2 L anaerobic biodigesters (2D HRT, 4D HRT, 5D HRT, and 10D HRT) with varying hydraulic retention time (HRT) (2, 5, 8, and 10 days, respectively) at mesophilic temperature (35°C). After 5 HRT, VS reduction for 2D HRT and 5D HRT was <40% while for 8D HRT and 10D HRT was >45-50% and >45-60%, respectively. The methane content was <20% in biogas for 2 and 5 days HRT while for 8 and 10 days >45-50% and 50-65% methane, respectively. The % VS reduction and methane content showed the overfeeding of NS in biodigesters 2D HRT and 5D HRT while 8D HRT showed towards optimum and 10D HRT optimum with improved VS reduction and methane content.

Phase change of the Ordovician hydrocarbon in the Tarim Basin: A case study from the Halahatang–Shunbei area

Abstract To clarify the genetic mechanism for phase change of the hydrocarbon in the ultra-deep reservoirs, a case study from the Ordovician hydrocarbon in the Halahatang–Shunbei area (HSA), Tarim Basin, NW China, was conducted. The results show that the Ordovician reservoirs in the HSA are characterized as multi-phase reservoirs with a lateral co-existence of condensates, volatile-oil reservoirs, normal oil reservoirs, and heavy oil reservoirs. From north to south, there are regular variations in the geochemical characteristics of the Ordovician hydrocarbon in different blocks of the HSA, showing an increasing trend in GOR, dryness coefficients, methane contents, methane carbon isotope values, and ethane carbon isotope values, while a decreasing trend in oil densities and wax contents. Because the same Cambrian–Lower Ordovician source for the Ordovician hydrocarbon is observed and the kerogen-cracking gas is dominated in the HSA, the regular variations of the hydrocarbon phases and geochemical characteristics can be interpreted as records of biodegradation and multistage oil–gas filling rather than controlled by the source rock organofacies, oil cracking, and gas invasion. The formation mechanism of the Ordovician multi-phase reservoirs in the HSA suggests that the deep strata of the Tarim Basin hold potential for the exploration of natural gas resources.

Methane Combustion Kinetics over Palladium-Based Catalysts: Review and Modelling Guidelines

Fugitive methane emissions account for a significant proportion of greenhouse gas emissions, and their elimination by catalytic combustion is a relatively easy way to reduce global warming. New and novel reactor designs are being considered for this purpose, but their correct and efficient design requires kinetic rate expressions. This paper provides a comprehensive review of the current state of the art regarding kinetic models for precious metal catalysts used for the catalytic combustion of lean methane mixtures. The primary emphasis is on relatively low-temperature operation at atmospheric pressure, conditions that are prevalent in the catalytic destruction of low concentrations of methane in emission streams. In addition to a comprehensive literature search, we illustrate a detailed example of the methodology required to determine an appropriate kinetic model and the constants therein. From the wide body of literature, it is seen that the development of a kinetic model is not necessarily a trivial matter, and it is difficult to generalize. The model, especially the dependence on the water concentration, is a function of not only the active ingredients but also the nature of the support. Kinetic modelling is performed for six catalysts, one commercial and five that were manufactured in our laboratory, for illustration purposes.

Isolation of a facultative methanotroph Methylocystis iwaonis SD4 from rice rhizosphere and establishment of rapid genetic tools for it.

Methanotrophs of the genus Methylocystis are frequently found in rice paddies. Although more than ten facultative methanotrophs have been reported since 2005, none of these strains was isolated from paddy soil. Here, a facultative methane-oxidizing bacterium, Methylocystis iwaonis SD4, was isolated and characterized from rhizosphere samples of rice plants in Nanjing, China. This strain grew well on methane or methanol but was able to grow slowly using acetate or ethanol. Moreover, strain SD4 showed sustained growth at low concentrations of methane (100 and 500ppmv). M. iwaonis SD4 could utilize diverse nitrogen sources, including nitrate, urea, ammonium as well as dinitrogen. Strain SD4 possessed genes encoding both the particulate methane monooxygenase and the soluble methane monooxygenase. Simple and rapid genetic manipulation methods were established for this strain, enabling vector transformation and unmarked genetic manipulation. Fast growth rate and efficient genetic tools make M. iwaonis SD4 an ideal model to study facultative methanotrophs, and the ability to grow on low concentration of methane implies its potential in methane removal.

CH4 emissions from runoff water of Alaskan mountain glaciers

Recent studies have observed high methane concentrations in runoff water and the ambient air at various glacier sites, including the Greenland Ice Sheet, the glacier forefield in Svalbard, and the ice cap in Iceland. This study extends these findings to smaller mountain glaciers in Alaska. Methane and carbon dioxide concentrations in the ambient air near the meltwater outlet, fluxes of these gases at the surface of runoff water and riverbank sediments, and dissolved methane content in the runoff water were measured at four glaciers. Three of the four glaciers showed conspicuous signals of methane emissions from runoff water, with the Castner Glacier terminus exhibiting a methane concentration three times higher than background levels, along with elevated dissolved methane levels in the runoff water. This study marks the detection of significant methane emissions from small mountain glacier runoff, contributing to the understanding that mountain glaciers also release methane into the atmosphere.

Unraveling the dynamics of atmospheric methane: the impact of anthropogenic and natural emissions

The reduction in methane concentration is crucial for achieving the goals of the Paris agreement. However, its annual growth rate is unstable, and understanding the reasons for changes in methane growth is essential for climate policy-making. Currently, there is considerable uncertainty regarding its attribution. Here, we utilize multi-source data and optimal fingerprinting methods to detect the contributions of several key drivers to the methane trend and interannual variability. We find that the methane growth trend is primarily influenced by anthropogenic emissions, while interannual variability is predominantly determined by wetland and biomass burning emissions. This result underscores the central role of anthropogenic emissions in methane dynamics, providing confidence in the effectiveness of human efforts to control methane atmospheric concentrations through emission reductions. It also helps alleviate concerns about the recent surge in atmospheric methane concentration, as it may be a short-term peak caused by increased wetland emissions rather than a long-term change.

Insights into phage-bacteria interaction in cold seep Gigantidas platifrons through metagenomics and transcriptome analyses

Viruses are crucial for regulating deep-sea microbial communities and biogeochemical cycles. However, their roles are still less characterized in deep-sea holobionts. Bathymodioline mussels are endemic species inhabiting cold seeps and harboring endosymbionts in gill epithelial cells for nutrition. This study unveiled a diverse array of viruses in the gill tissues of Gigantidas platifrons mussels and analyzed the viral metagenome and transcriptome from the gill tissues of Gigantidas platifrons mussels collected from a cold seep in the South Sea. The mussel gills contained various viruses including Baculoviridae, Rountreeviridae, Myoviridae and Siphovirdae, but the active viromes were Myoviridae, Siphoviridae, and Podoviridae belonging to the order Caudovirales. The overall viral community structure showed significant variation among environments with different methane concentrations. Transcriptome analysis indicated high expression of viral structural genes, integrase, and restriction endonuclease genes in a high methane concentration environment, suggesting frequent virus infection and replication. Furthermore, two viruses (GP-phage-contig14 and GP-phage-contig72) interacted with Gigantidas platifrons methanotrophic gill symbionts (bathymodiolin mussels host intracellular methanotrophic Gammaproteobacteria in their gills), showing high expression levels, and have huge different expression in different methane concentrations. Additionally, single-stranded DNA viruses may play a potential auxiliary role in the virus–host interaction using indirect bioinformatics methods. Moreover, the Cro and DNA methylase genes had phylogenetic similarity between the virus and Gigantidas platifrons methanotrophic gill symbionts. This study also explored a variety of viruses in the gill tissues of Gigantidas platifrons and revealed that bacteria interacted with the viruses during the symbiosis with Gigantidas platifrons. This study provides fundamental insights into the interplay of microorganisms within Gigantidas platifrons mussels in deep sea.

High-performance internal circulation anaerobic granular sludge reactor for cattle slaughterhouse wastewater treatment and simultaneous biogas production

This research investigates the efficacy of a high-performance pilot-scale Internal Circulation Anaerobic Reactor inoculated with Granular Sludge (ICAGSR) for treating cattle slaughterhouse wastewater while concurrently generating biogas. The primary objective is to assess the efficiency and performance of ICAGSR in terms of organic pollutant removal and biogas production using granular anaerobic sludge. The research methodology entails operating the ICAGSR system under ambient conditions and systematically varying key parameters, including different Hydraulic Retention Times (HRTs) (24, 12, and 8 h) and Organic Loading Rates (OLRs) (3.3, 6.14, and 12.83 kg COD/m³. d). The study focuses on evaluating pollutants’ removal and biogas production rates. Results reveal that the ICAGSR system achieves exceptional removal efficiency for organic pollutants, with Chemical Oxygen Demand (COD) removal exceeding 74%, 67%, and 68% at HRTs of 24, 12, and 8 h, respectively. Furthermore, the system demonstrates stable and sustainable biogas production, maintaining average methane contents of 80%, 76%, and 72% throughout the experimental period. The successful operation of the ICAGSR system underscores its potential as a viable technology for treating cattle slaughterhouse wastewater and generating renewable biogas. In conclusion, this study contributes to wastewater treatment and renewable energy production by providing a comprehensive analysis of the ICAGSR system’s hydrodynamic properties. The research enhances our understanding of the system’s performance optimization under varying conditions, emphasizing the benefits of utilizing ICAGSR reactors with granular sludge as an effective and sustainable approach. Identifying current gaps, future research directions aim to further refine and broaden the application of ICAGSR technology in wastewater treatment and renewable energy initiatives.

Extraction, purification, and clumped isotope analysis of methane (Δ13CDH3 and Δ12CD2H2) from sources and the atmosphere

Abstract. Measurements of the clumped isotope anomalies (Δ13CDH3 and Δ12CD2H2) of methane have shown potential for constraining methane sources and sinks. At Utrecht University, we use the Thermo Scientific Ultra high-resolution isotope-ratio mass spectrometer to measure the clumped isotopic composition of methane emitted from various sources and directly from the atmosphere. We have developed an extraction system with three sections for extracting and purifying methane from high (> 1 %), medium (0.1 % to 1 %), and low-concentration (< 0.1 %) samples, including atmospheric air (∼ 2 ppm = 0.0002 %). Depending on the methane concentration, a quantity of sample gas is processed that delivers 3 ± 1 mL of pure methane, which is the quantity typically needed for one clumped isotope measurement. For atmospheric air with a methane mole fraction of 2 ppm, we currently process up to 1100 L of air. The analysis is performed on pure methane, using a dual-inlet setup. The complete measurement time for all isotope signatures is about 20 h for one sample. The mean internal precision values of sample measurements are 0.3 ± 0.1 ‰ for Δ13CDH3 and 2.4 ± 0.8 ‰ for Δ12CD2H2. The long-term reproducibility, obtained from repeated measurements of a constant target gas, over almost 3 years, is around 0.15 ‰ for Δ13CDH3 and 1.2 ‰ for Δ12CD2H2. The measured clumping anomalies are calibrated via the Δ13CDH3 and Δ12CD2H2 values of the reference CH4 used for the dual-inlet measurements. These were determined through isotope equilibration experiments at temperatures between 50 and 450 °C. We describe in detail the optimized sampling, extraction, purification, and measurement technique followed in our laboratory to measure the clumping anomalies of methane precisely and accurately. This paper highlights the extraction and one of the first global measurements of the clumping anomalies of atmospheric methane.

METHANE PRODUCTION FROM COW MANURE IN THE PRESENCE OF Bi(III) COMPLEX OF SULFAMIC ACID

The present study examines the process of biomethanization of cow manure in an anaerobic environment, in the presence of small amounts of Bi(III) complex of sulfamic acid. Since this complex has good antimicrobial activity, the purpose of adding the complex is to determine its effect on biogas and methane production. The reference samples (cow manure only) and mixtures of cow manure + 10 mg and cow manure + 20 mg of bismuth complex with a composition [Bi6O4(OH)4](NH2SO3)6 are subjected to biodegradation under the following conditions – duration of 33 days, nitrogen atmosphere and temperature of 34.5 ± 1°C. During the process, the volume of biogas and the percentage content of methane in biogas are measured in 2 - 3 days as well. The analyses performed reveal that until the 10th day, the amount of biogas produced increases constantly and is comparable both for the control samples and for the mixtures. Further, until the end of the experiment, a significant and constant increase in the volume of biogas produced by the mixtures is observed compared to the control samples.Regarding the percentage of methane produced by the reference samples and the mixtures, comparable relative amounts are found by the 7th day. From the 8th day to the 33rd day, the percentage of methane released by the mixtures is visibly greater than that by the reference samples.

Analysis of the explosion risk of low-concentration oxygen-bearing coal bed methane in the low-temperature environment

In the process of deep cooling and liquefaction of low-concentration (concentration <30 %) oxygen-bearing coal bed methan, there is a risk of explosion because the methane concentration in the ultra-low temperature environment is within the explosion limit. It is of great guiding significance to study the occurrence mechanism and accident-causing process of such accidents. Firstly, the experimental system of low-temperature methane explosion characteristics is constructed, and it is found that when ignition energy exceeds a certain range, the process of deep cooling and liquefaction of low-concentration oxygen-bearing coal bed methane will cause explosion. Then, the occurrence of the gas explosion accident in low-temperature environment is briefly described, and the causes of the accident are analyzed preliminarily, and the dynamic characteristics of methane explosion propagation under ultra-low temperature conditions are studied by Fluent numerical simulation, and it is obtained that ultra-low temperature conditions have a promotion effect on the explosion pressure. Finally, based on the analysis of catastrophe theory, the traditional accident causation cusp catastrophe model is improved, and the “experimental safety state" and the “internal causes of explosion-external cause of explosion" are taken as the state variables and control variables respectively, and the explosion risk analysis model for deep cooling and liquefaction of low-concentration oxygen-bearing coal bed methane based on the cusp catastrophe theory is constructed. Based on the accident case, the process of accidents caused by risk factors is described, and the evolution mechanism of such disasters and accidents is clarified. Finally, the hazard state evaluation method for liquefaction explosion of low-concentration oxygen-bearing coal bed methane is proposed based on the catastrophe theory, and this evaluation model is applied to evaluate and analyze the hazard state of accident case. The evaluation results are consistent with the actual hazard state, confirming the rationality and feasibility of this evaluation method. In this paper, the key hazards of such accidents are found out in detail and provides support for safety decision-making in the deep cooling and liquefaction process of low-concentration oxygen-bearing coal bed methane.

Discovery of the first hydrothermal field along the 500-km-long Knipovich Ridge offshore Svalbard (the Jøtul field)

Oceanic spreading centers north of Iceland are characterized by ultraslow spreading rates, and related hydrothermal activity has been detected in the water column and at the seafloor along nearly all ridge segments. An exception is the 500-km-long Knipovich Ridge, from where, until now, no hydrothermal vents were known. Here we report the investigation of the first hydrothermal vent field of the Knipovich Ridge, which was discovered in July 2022 during expedition MSM109. The newly discovered hydrothermal field, named Jøtul hydrothermal field, is associated with the eastern bounding fault of the rift valley rather than with an axial volcanic ridge. Guided by physico-chemical anomalies in the water column, ROV investigations on the seafloor showed a wide variety of fluid escape sites, inactive and active mounds with abundant hydrothermal precipitates, and chemosynthetic organisms. Fluids with temperatures between 8 and 316 °C as well as precipitates were sampled at four vent sites. High methane, carbon dioxide, and ammonium concentrations, as well as high 87Sr/86Sr isotope ratios of the vent fluids indicate strong interaction between magma and sediments from the Svalbard continental margin. Such interactions are important for carbon mobilization at the seafloor and the carbon cycle in the ocean.

Upflow Anaerobic Sludge Blanket (UASB) reactors for Bio-methane production from limed tannery fleshings: Lab and pilot scale reactors

The Upflow Anaerobic Sludge Blanket reactor is a viable high-rate anaerobic digestion design for the treatment of different wastewater with low to high solubility. This can also be used for the treatment of solid wastes with less HRT. In this study, the performance evaluation of a lab-scale UASB reactor was carried out for different hydraulic retention times of 24, 21, 18, 15 and 12 h for obtaining the best HRT for tannery fleshings. The gas production varied between 3.7 – 4.5 L with a methane content of 64.31 – 67.72%. It was observed that the maximum gas production was at 18 h HRT and this optimized condition was applied to the pilot-scale UASB reactor. The performance evaluation of the pilot-scale UASB reactor was carried out with an HRT of 18 h. The gas production of 450 ± 50 L, the maximum specific gas production of 0.274 m3/kg of VS destroyed and 0.239 m3/kg of TS destroyed was obtained and the maximum biogas productivity of 0.495 L was observed at 18 h HRT with the highest methane content of 67.86%. The payback period of the pilot scale reactor is 3.2 years.

Living emission abolish filters (LEAFs) for methane mitigation: design and operation

As one of the most potent greenhouse gases, methane is a critical target for the near-term mitigation of global warming. Efficient, scalable, easy-to-implement, and robust mitigation technologies are urgently needed to assist in reaching methane abolishment. The goal of this research was to test the applicability of active, extremophilic methanotrophic cells as a baseline concept for engineered systems aiming at methane capturing. The system, named living emission abolish filters (LEAFs), represents an array of immobilized biomaterials capable of capturing methane directly from vent streams. The biomaterials were made using cells of Methylotuvimicrobium alcaliphilum 20ZR, a robust halophilic methanotrophic bacterium with the ability to consume methane gas at low concentrations. Several critical parameters were tested, including (i) the composition of the matrix and optimal immobilization to increase catalyst load, (ii) the stability of methanotrophic cells, and (iii) the toxicity of trace gases (i.e. CO). We found that hydrogels coated with 2.3 mg cell dry weight/cm3 methanotrophic cells represent the best-performing biomaterials. The methane reduction potential of LEAFs fluctuated from 20% to 95% and depended on the methane concentration in the gas stream and the stream flow rates. The potential for commercial-scale deployment and emissions reductions was also evaluated. Total greenhouse gas emissions (combined using the global warming potential GWP100) from an example using a ventilation air methane source over a one-year period was shown to be reduced in two LEAF scenarios by 51% and 75%. Over longer time horizons, more significant reductions are possible as consistent methane consumption can be sustained. The study highlights the overall potential of the liquid-free bio-based composite methane mitigation system. Further improvements essential for system assembly and implementations should include (a) optimization of the cell immobilization protocols to improve cell load and the shelf-life of the system and (b) implementation of matrix moldings for cell immobilization to achieve optimal gas flow and increase the cell-gas interface.

High-efficiency anaerobic digestion of soybean curb residue with simultaneous phosphorus recovery by Mg[sbnd]Fe layered double hydroxides addition

Anaerobic digestion of food waste faces several technical problems, such as process failure caused by over-acidification, low heating value of biogas, and high treatment cost of liquid digestate. Layered double hydroxides (LDH) are expected to simultaneously enhance biogas production and quality and immobilize soluble phosphorus in AD due to their excellent anion exchange capability. This study first verified the above hypothesis, indicated by a dramatically enhanced methane yield of 17 folds under a high substrate load and a high quality of generated biogas with 89 % methane content and 90 % lowered hydrogen sulfide. Meanwhile, the soluble phosphorus was efficiently reduced to 3 mg/L after AD. Moreover, the calcined product of LDH showed comparable performance, indicating the possibility of reusing LDH in the AD process. The above results implied the great potential of LDH as a multifunctional material for enhancing the efficiency of waste treatment and energy/resource conversion in the AD process.

Unlocking potential: exploring the methane production potential in anaerobic co-digestion of cassava wastewater and glycerol

This study aimed at evaluating the feasibility of CH4 production in a mesophilic (30 °C) single-stage anaerobic co-digestion of cassava wastewater (CW) and glycerol in an anaerobic fluidized bed reactor (AFBR) with mixing ratio of 50% / 50% CW/Gly on a (chemical oxygen demand)COD basis. Thus, the following strategy was used: increasing the organic loading rate (OLR) (1 to 20g COD.L-1.d-1) by increasing the substrate concentration (1 to 20g COD.L-1) and applying a hydraulic detention time (HRT) of 24h. The AFBR presented a maximum methane (CH4) content of 88.38±1.94% and a CH4 yield (MY) of 293.48±18.37mL of CH4.mL-1CODrem in the OLR of 1g COD.L-1.d-1 and the maximum methane production rate (MPR) of 62.09±2.75mL of CH4.L-1.h-1 in the OLR of 20g COD.L-1.d-1. The conversion of glycerol and carbohydrates remained above 91±0.54% and 82±2.79%, respectively, and the COD conversion was above 80±0.65%. The main metabolites were HAc, HPr, HBu, EtOH and HVa. The most abundant genera identified in the AFBR were Izemoplasmatales and Enterobacteriaceae for the bacteria domain, and Methanosaeta, Methanobacterium for the archaea domain. The single-stage system is robust and can operate with higher OLR without reducing the efficiency of wastewater treatment and CH4 production.

A comparative study on the gas sensing performance of SnO2 and GO-SnO2 sensor devices.

Using Modified Hummer’s technique, eco-friendly carbon derivative (GO) nanoparticles were obtained from polyethylene terephthalate (PET) precursor. Nanocomposite of GO-SnO2 and undoped SnO2 were synthesized using the coprecipitation method. The as-prepared nanoparticles were subjected to diverse analytical processes employing Transmission electron microscopy (TEM) to study the internal morphological properties of the nanoparticles. Energy dispersive X-ray spectroscopy (EDX) was used to examine elemental quantifications of the nanopowders. Fourier-transform infrared (FTIR) spectroscopy was used to analyze bond structures and functional groups. Dynamic responses of various gas sensor devices to 20 ppm concentrations of methane (CH4) and hydrogen (H2) were investigated as a function of time at room temperature. The GO-SnO2 nanocomposite sensing device demonstrated an ideal detection response with values of 5.00 and 5.08, corresponding to methane and hydrogen analyte gases. The doped SnO2 sensor device outperformed the pure SnO2, accounting for the GO-SnO2 > SnO2 order. Regarding the target gases, the synthesized nanocomposite demonstrated stability and selectivity in the following order of magnitude: H2 > CH4. The GO doping effect was found to have introduced surface defects, increased pores, and enabled more oxygen-active sites to be formed on the sensor device’s surface for dynamic gas sensing response, providing a comparatively enhanced sensor response.

Research on Low Concentration Gas Catalytic Oxidation Power Generation System

In response to the difficulties in direct utilization of low concentration gas in coal mines and the slow development of industrial application of catalytic oxidation technology, a new mode of direct utilization of low concentration gas with a methane concentration of 1.0% in coal mines in catalytic oxidation gas turbine power generation is explored. And based on the development of a 30kW low concentration gas catalytic oxidation gas turbine power generation system, this paper introduces the design process of key equipment such as catalytic oxidation burners, low-temperature and low-pressure turbines, and countercurrent regenerators, providing a technical reference for the utilization of low concentration gas catalytic oxidation.

Experimental Study on Ultra-Low Concentration Methane Regenerative Thermal Oxidation

As a major coal country, China faces the issue of significant gas emissions during the coal mining process. This study aims to improve the utilization efficiency of mine gas, reduce greenhouse gas emissions, and promote the low-carbon and green transformation of the coal industry. A 10 kW gas regenerative thermal oxidizer (RTO) experimental system was constructed. The effects of initial methane concentration, low-temperature flue gas proportion, and operating load on combustion temperature, methane oxidation rate, high-temperature flue gas energy, and system thermal efficiency were studied. The results show that when the combustion temperature is below 600 °C, the CH4 combustion reaction cannot proceed effectively, and the system temperature continuously decreases and cannot be maintained stably. The experiment determines the stable operating methane concentration range of the RTO. In this experimental system, the lower limit of the initial methane concentration is 0.28%, corresponding to an 86% methane oxidation rate. As the initial methane concentration decreases, the combustion temperature also decreases, and the methane oxidation rate follows suit. The higher the low-temperature flue gas proportion, the higher the combustion temperature, and the system’s thermal efficiency and output heat decrease with the increase in the low-temperature flue gas proportion. This experiment explores multiple factors affecting regenerative thermal oxidation, providing a basis for ensuring the safe and stable operation of the system and its optimization. Improving the thermal insulation and heat exchange performance of the storage body can expand the lower limit of the initial methane concentration, thereby increasing the stability and thermal efficiency of the system.

Enhancing biomethane quality via the activation of natural zeolite from Lombok Island

&lt;p&gt;This study presents the results of the biogas purification test using the fixed-bed column method. As an adsorbent, natural zeolite from the Lombok island Indonesia was used. Zeolite is used for the purpose of purifying biogas produced from the anaerobic digestion (AD) process. To enhance the adsorption capacity, the zeolite underwent activation using distinct strong base and acid solutions—potassium hydroxide (KOH) and hydrochloric acid (HCl)—with concentrations of 10%, 15%, and 20%, individually. The experiment was carried out until the adsorbent reached saturation, at which point the methane (CH4) concentration began to decline. It was revealed that the typical Lombok zeolite showed good performance in increasing the concentration of CH4 in biogas. Furthermore, zeolites work better when activated with strong base solutions and at high concentrations. This is indicated by the achievement of higher CH4 concentrations and a longer saturation time. The results from analyzing zeolite features and pore characteristics indicate that acidic and base compounds yield distinct outcomes in terms of the surface structure of zeolite pores.&lt;/p&gt;