Abstract

Tar production is a critical aspect of gasification thermochemistry, and it hinders the widening of biofuel utilisation in several applications. Both the gasifier configuration and the operating conditions influence the quantity of tar in PG. Since temperature plays a major role, this study examines the performance parameters of a gasifier across a spectrum of input air temperatures, from 27 to 627 °C, utilising computational fluid dynamics with species transport and porous media models. Since the deviation of numerical predictions from experimental results is within 10 %, the model's validity is confirmed. CO and H2 gas production increased from 19.23 % to 27.12 % and 9.23 %–16.2 %, respectively, over the tested air temperature range; however, the variation in methane content was not significant. Furthermore, the higher heating values of PG and cold gas efficiency were found to be 5–6.8 MJ/Nm3 and 65–69 %, respectively. The study also investigates reaction rates for gasification, combustion, and volatiles' breakdown under various operating conditions. Among the tar species studied, benzene is the most concentrated at 1.6 g/Nm3, followed by toluene at 0.9 g/Nm3, with naphthalene and phenol present in comparatively smaller amounts. Furthermore, the research indicates that an appropriate temperature of gasifying medium can control tar in PG.

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