Multiple Input Multiple Output (MIMO) and massive MIMO technologies play a significant role in mitigating five generation (5G) channel propagation impairments. These impairments increase as frequency increases, and they become worse at millimeter-waves (mmWaves). They include difficulties of material penetration, Line-of-Sight (LoS) inflexibility, small cell coverage, weather circumstances, etc. This paper simulates the 5G channel at the E-band frequency using the Monte Carlo approach-based NYUSIM tool. The urban microcell (UMi) is the communication environment of this simulation. Both MIMO and massive MIMO use uniformly spaced rectangular antenna arrays (URA). This study investigates the effects of MIMO and massive MIMO on LOS and Non-LOS (NLOS) environments. The simulations considered directional and omnidirectional antennas, the Power Delay Profile (PDP), Root Mean Square (RMS) delay spread, and small-scale PDP for both LOS and NLOS environments. As expected, the wide variety of the results showed that the massive MIMO antenna outperforms the MIMO antenna, especially in terms of the signal power received at the end-user and for longer path lengths.