The scarcity and rising costs of fossil fuels, coupled with increasing pollution levels, have prompted the exploration of innovative biofuel blends. While binary and ternary fuels have been studied extensively in proportions of 5–20%, replacing up to 30–40% of fossil fuel dependency without significant engine modifications remains a challenge. One potential solution is to investigate an optimal quaternary blend (QB) through experimental methods. This study investigates the impact of increased injection pressure (IOP) and quaternary fuel blends on a common rail direct injection (CRDI) engine's performance and emissions. Different blends, including diesel fuel, vegetable oil, mahua methyl ester and normal-butanol, were tested to replace 30–40% of diesel and enhance combustion, reduce exhaust emissions and improve overall performance. Experiments used a 1-cylinder CRDI engine at high IOPs (400, 500, 600 and 700 bar). Results at 600 bar IOP showed that the optimal blend, QB3–QB4, increased brake thermal efficiency (BTE) by 9% and reduced brake-specific fuel consumption (BSFC) by approximately 11% compared to other blends. Emissions at 600 bar included a 16% reduction in hydrocarbons (HC) and a 24% decrease in carbon monoxide (CO) at full load. However, nitrogen oxide (NOx) emissions slightly increased with higher IOP. Significantly employing the QB3–QB4 blend at 600 bar improved control over HC, CO and smoke emissions. Overall, performance was enhanced and comparable to conventional diesel fuel, with only a minor increase in NOx emissions.
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