Magnetic Force Microscopy Research Articles

Exotic Topological Magnetic States in Thin Co/Pd Ferromagnetic Films

AbstractThin ferromagnet/heavy metal multilayer films are considered as prospective media for a magnetic recording and Co/Pd films are a good example of such materials. In this work, the magnetic properties and micromagnetic structure of Co/Pd multilayer films are studied with different bilayer thicknesses ([Co(0.3 × t nm)/Pd(0.5 × t nm)]10), but with the same ratio Co versus Pd. Transmission electron microscope and X‐ray diffraction studies allow authors to suppose that the investigated films are highly mixed alloys. Magnetic force microscopy and Lorentz transmission electron microscopy showed the presence of various micromagnetic features in the films. Along with skyrmions that are well‐known magnetic topological artifacts some new features are revealed, which are interpreted as 360° domain walls, skyrmioniums and the combination of the above two. It is found that the type and density of micromagnetic features strongly depend on the bilayer thickness parameter (t). The effect is associated with the peculiarities of interfacial magnetic interactions in the samples with highly mixed interfaces. The tooling coefficient represents a useful tool of the electron beam evaporation technique enabling wide manipulation of micromagnetic particles, in particular, skyrmioniums that are currently considered a prospective media for current driven magnetic recording.

Magnetic monopole free motion in two-dimensional artificial spin ice

Magnetic monopole motion (without its partner in a pair) as a function of external magnetic fields is presented as a fingerprint of freedom of these emergent quasi-particles in a two-dimensional artificial spin ice material. Such freedom, required, for example, for further application in magnetricity, is only possible due to ground-state degeneracy, which causes an anisotropic string energy reduction in rectangular ice geometries, designed to allow highest equidistance among lateral and diagonal neighbor nanomagnets. By measurements of magnetic force microscopy, we observe magnetic monopole creation, transport, and annihilation in such an arrangement, where monopoles are free to move throughout large regions of the sample, since they are not permanently bound by the string bonds, as commonly observed in conventional artificial spin ice systems. Instead, monopoles leave a wake of elongated tensionless string, which is connected to superficial charges or charges pinned to the array borders.

Topological Spin Textures in an Insulating van der Waals Ferromagnet.

Generation and control of topological spin textures constitutes one of the most exciting challenges of modern spintronics given their potential applications in information storage technologies. Of particular interest are magnetic insulators, which due to low damping, absence of Joule heating and reduced dissipation can provide energy-efficient spin-textures platform. Here, it is demonstrated that the interplay between sample thickness, external magnetic fields, and optical excitations can generate a prolific paramount of spin textures, and their coexistence in insulating CrBr3 van der Waals (vdW) ferromagnets. Using high-resolution magnetic force microscopy and large-scale micromagnetic simulation methods, the existence of a large region in T-B phase diagram is demonstrated where different stripe domains, skyrmion crystals, and magnetic domains exist and can be intrinsically selected or transformed to each-other via a phase-switch mechanism. Lorentz transmission electron microscopy unveils the mixed chirality of the magnetic textures that are of Bloch-type at given conditions but can be further manipulated into Néel-type or hybrid-type via thickness-engineering. The topological phase transformation between the different magnetic objects can be further inspected by standard photoluminescence optical probes resolved by circular polarization indicative of an existence of exciton-skyrmion coupling mechanism. The findings identify vdW magnetic insulators as a promising framework of materials for the manipulation and generation of highly ordered skyrmion lattices relevant for device integration at the atomic level.

Increasing the Q-factor of resonant cantilevers in magnetic force microscopy through helium gas flow

To obtain high-resolution magnetic force microscopy (MFM) images, it is essential to have a cantilever with a high-quality factor. However, conventional vibrating cantilevers typically have quality factor values in the range of a few hundred, which limits their sensitivity for MFM measurements. To address this limitation, numerous studies have explored methods to enhance the quality factor in different environments, including vacuum, air, and liquid. This study introduces a novel approach for improving the quality factor using flowing helium gas. By selecting helium gas with a low viscosity coefficient, we successfully achieved a higher quality factor (Q-factor) of MFM microcantilever oscillations at room temperature in one atmosphere compared with the Q-factor in air. This provides a potential approach for achieving high-resolution MFM measurements under room temperature conditions. By optimizing the gas flow rate at room temperature in one atmosphere, we successfully obtained a higher MFM cantilever oscillation Q-factor and clearer MFM images compared with the air. The experimental results revealed a long and narrow resonant curve, and the quality factor significantly increased to 778.2, which is 3.8 times higher than that observed in air 205.4. Furthermore, systematic investigations demonstrated the capability of this approach to produce high-resolution MFM images of videotape track patterns under the optimized helium gas flow rate of 60 mm/s.

Temperature Studies of the LaMn2Si2 Intermetallide by the Raman Spectroscopy and Magnetic Force Microscopy Methods

Temperature Studies of the LaMn2Si2 Intermetallide by the Raman Spectroscopy and Magnetic Force Microscopy Methods

Covalent Organic Frameworks with Tunable Chirality for Chiral-Induced Spin Selectivity.

Chiral covalent organic frameworks (CCOFs) have attracted extensive interest for their potential applications in various enantioselective processes. However, the exploitation of chirality-induced spin selectivity (CISS) that enables a new technology for the injection of spin polarized current without the need for a permanent magnetic layer within CCOFs remains a largely untapped area of research. Here, we demonstrate that, for the first time, COFs can be an attractive platform to develop spin filter materials with efficient CISS. This facilitates the design and synthesis of a new family of Zn(salen)-based 2D CCOFs, namely, CCOFs-9-12, by imine condensation of chiral 1,2-diaminocyclohexane and tri- or tetra(salicylaldehyde) derivatives. CCOF-9, distinguished by its unique C2 symmetric "armchair" tetrasubstituted pyrene conformation, exhibits the most pronounced chirality among these materials and serves as a solid-state host, enabling the enantioselective adsorption of racemic drugs with an enantiomeric excess (ee) of up to 97%. After substituting diamagnetic zinc(II) ions for paramagnetic cobalt(II), the resulting CCOF-9-Co not only retains its high crystallinity, porosity, and exceptional chirality but also exhibits enhanced conductivity, a crucial factor for the effective observation of CISS. Magnetic conductive atomic force microscopy showed that CCOF-9-Co exhibited a remarkable CISS effect with up to an 88-94% spin polarization ratio. This phenomenon is further confirmed by the increased intensity in the magnetic circular dichroism (MCD) when CCOF-9-Co is under an external magnetic field. This work therefore shows the tremendous potential of CCOFs for controlling spin selectivity and will stimulate the creation of new types of crystalline polymers with strong CISS effects for spin filters.

Charge Puddles Driven Complex Crossover of Magnetoresistance in Non-Topological Sulfur Doped Antimony Selenide Nanowires.

A race to achieve a crossover from positive to negative magnetoresistance is intense in the field of nanostructured materials to reduce the size of memory devices. Here, the unusual complex magnetoresistance in nonmagnetic sulfur-doped Sb2Se3nanowires is demonstrated. Intentionally, sulfur is doped in such a way to nearly achieve the charge neutrality point that is evident from switching of carrier type from p-type to n-type at 13 K as inferred from the low-temperature thermoelectric power measurements. A change from 3D variable range hopping (VRH) to power law transport with α = 0.18 in resistivity measurement signifies a Luttinger liquid transport with weak links through the nanowires. Interestingly, high magnetic field induced negative magnetoresistance (NMR) occurring in hole dominated temperature regimes can only be explained by invoking the concept of charge puddles. Spot energy dispersive spectroscopy (EDS), magnetic force microscopy (MFM) measurements, Tmottand Regel plot indicate an enhanced disorder in these sulfurized nanowires that are found to be the precursor for the formation of these charge puddles. Tunability of conducting states in these nanowires is investigated in the light of interplay of carrier type, magnetic field, temperature, and intricate intra-inter wire transport that makes this nanowires potential for large scale spintronic devices.

Imaging the magnetic nanowire cross section and magnetic ordering within a suspended 3D artificial spin-ice

Artificial spin-ice systems are patterned arrays of magnetic nanoislands arranged into frustrated geometries and provide insight into the physics of ordering and emergence. The majority of these systems have been realized in two-dimensions, mainly due to the ease of fabrication, but with recent developments in advanced nanolithography, three-dimensional artificial spin ice (ASI) structures have become possible, providing a new paradigm in their study. Such artificially engineered 3D systems provide new opportunities in realizing tunable ground states, new domain wall topologies, monopole propagation, and advanced device concepts, such as magnetic racetrack memory. Direct imaging of 3DASI structures with magnetic force microscopy has thus far been key to probing the physics of these systems but is limited in both the depth of measurement and resolution, ultimately restricting measurement to the uppermost layers of the system. In this work, a method is developed to fabricate 3DASI lattices over an aperture using two-photon lithography, thermal evaporation, and oxygen plasma exposure, allowing the probe of element-specific structural and magnetic information using soft x-ray microscopy with x-ray magnetic circular dichroism (XMCD) as magnetic contrast. The suspended polymer–permalloy lattices are found to be stable under repeated soft x-ray exposure. Analysis of the x-ray absorption signal allows the complex cross section of the magnetic nanowires to be reconstructed and demonstrates a crescent-shaped geometry. Measurement of the XMCD images after the application of an in-plane field suggests a decrease in magnetic moment on the lattice surface due to oxidation, while a measurable signal is retained on sub-lattices below the surface.

Microstructure, microchemistry, and micro-magnetism of Dy grain boundary diffused (Nd, Ce)–Fe–B magnets

The microstructure of (Nd, Ce)–Fe–B sintered magnets with different diffusion depths was characterized by a magnetic force microscope, and the relationship between the magnetic properties and the local structure of grain boundary diffused magnets is discussed. The domains perpendicular to the c-axis (easy magnetization direction) show a typical maze-like pattern, while those parallel to the c-axis show the characteristics of plate domains. The significant gradient change is shown in the concentration of Dy with the direction of diffusion from the surface to the interior. Dy diffuses along grain boundaries and (Dy, Nd)2Fe14B layer with a high anisotropy field formed around the grains. Through in-situ electron probe micro-analysis/magnetic force microscopy (EPMA/MFM), it is found that the average domain width decreases, and the proportion of single domain grains increases as diffusion depth increases. This is caused by both the change of concentration and distribution of Dy. The grain boundary diffusion process changes the microstructure and microchemistry inside the magnet, and these local magnetism differences can be reflected by the configuration of the magnetic domain structure.

Observation of zigzag domains in the surface layer of Fe-based microwires by magnetic force microscopy

The magnetic domain structure of the surface layer of Fe-based amorphous microwires with a diameter of 20 µm (after glass removal) was investigated. An approach has been developed to study the domain structure of the curved surface of a microwire by magnetic force microscopy. It was found that in low magnetic fields the domain structure of the surface layer consisted of zigzag-shaped domains elongated along the microwire axis. These domains are inclined to the microwire axis at an angle of 45 degrees. An increase in the magnetic field along the microwire axis resulted in the transformation of the magnetic structure to the structure consisting of ring domains with an opposite orientation of the magnetic moment. The geometric parameters of both types of the domain structure were determined. The width of zigzag-shaped domains was 2 µm. The width of ring domain was 2.5–5 µm.

Subsurface conditioning in BTA deep hole drilling for improved component performance

When bores with high length-to-diameter ratios (l/D > 10) and large diameters (D > 40 mm) are required, usually, the Boring and Trepanning Association (BTA) deep hole drilling process is used. Common industrial applications of this process are aerospace engineering and petrol exploration, where drilled components range from landing gears and engine shafts to drill collars. Since such parts tend to be particularly costly and highly safety–critical, ensuring favorable surface integrity during drilling is crucial to guarantee their reliability and performance. This study aims to identify correlations between the BTA deep hole drilling process and the resulting surface integrity using experimental and simulative approaches. The impact of feed and cutting speed on the thermomechanical loads and the resulting surface integrity are analyzed, also taking into account the occurrence of dynamic process disturbances. Particularly, the formation of white etching layers (WEL) is investigated using well-established, conventional techniques such as optical microscopy and microhardness testing. Additionally, innovative micromagnetic methods are employed. Magnetic Barkhausen noise (MBN) analysis is qualified as a well-applicable approach for rapid, non-destructive detection of WEL. To enhance understanding of MBN analysis and increase its robustness, the underlying mechanisms, governing the magnetic behavior of the subsurface are elucidated in detail by X-ray diffraction (XRD), electron backscatter diffraction (EBSD), magnetic force microscopy (MFM) and magneto-optical Kerr effect (MOKE) microscopy. The methodology will serve as a basis for controlled subsurface conditioning in BTA deep hole drilling.

Incremental Analysis of Magnetic Domains in Multiple Types of Ferromagnetic CoFe Nanolayer Patterns

In this article, the results of incremental analysis on the thickness, aspect ratio, and crystallographic substrate orientation dependence of magnetic domain formation in CoFe nanolayer patterns (NPs) on GaAs (001) substrates by magnetic force microscopy are reported. All the 35 nm thick CoFe NPs show multiple magnetic domains under as‐deposition condition whereas the 13 nm thick CoFe NPs have a single magnetic domain in the case of the patterns with a relatively small size and high aspect ratio. Subsequently, the magnetic fields are applied in the direction parallel to the <110> and <1–10> directions of the substrates to analyze a magnetization switching behavior in the patterns. The results reveal that the magnetic fields required for magnetization switching markedly tend to increase, with decreasing the thickness of the patterns and increasing their aspect ratio. A general tendency is obtained, which a higher magnetic field is needed for a higher aspect ratio and a thinner thickness of the NPs. Even in the case of the patterns with an aspect ratio of unity and a thickness of 35 nm (but, a smaller size), a single magnetic domain is formed at a relatively high applied magnetic field of 1500 Gauss.

Microwave Field-Induced Changes in Raman Modes and Magnetic Force Images of Antiferromagnetic NiO Films

Effective control of domain walls or magnetic textures in antiferromagnets promises to enable robust, fast, and nonvolatile memories. The lack of net magnetic moment in antiferromagnets implies the need for creative ways to achieve such a manipulation. We conducted a study to investigate changes in magnetic force microscopy (MFM) imaging and in the magnon-related mode in Raman spectroscopy of virgin NiO films under a microwave pump. After MFM and Raman studies were conducted, a combined action of broadband microwave (0.01–20 GHz, power scanned from −20 to 5 dBm) and magnetic field (up to 3 kOe) were applied to virgin epitaxial (111) NiO and (100) NiO films grown on (0001) Al2O3 and (100) MgO substrates, following which the MFM and Raman studies were repeated. We observed a suppression of the magnon-related Raman mode subsequent to the microwave exposure. Based on MFM imaging, this effect appeared to be caused by the suppression of large antiferromagnetic domain walls due to the possible excitation of antiferromagnetic spin oscillations localized within the antiferromagnetic domain walls.

Magnetic domain structure of iron-based microwires after removal of the glass shell by chipping and chemical etching

The magnetic domain structure of the surface of microwires with composition Fe73.9B13.2Si10.9C2 was studied by magnetic force microscopy. It has been found that the removal of glass shell by chipping leads to distortion of the original magnetic domain structure. Chemical etching of the glass shell makes it possible to observe the magnetic domain structure due to the stresses that have arisen due to the microwire production. In the absence of an applied magnetic field, a magnetic domain structure of the surface layer is observed, consisting of domain layers inclined to the microwire axis by 45 or 135 degrees. This structure has a shape close to a zigzag. The thickness of the domain layers is not constant and varies from 3 to 5 μm. It has been found that the application of a constant magnetic field along the microwire axis causes the formation of ring domain layers of various thicknesses (from 1 to 5 μm) with different orientations of the magnetic moment relative to the microwire surface. In a field of 60 oersteds along the axis of the microwire, the domain magnetic structure consists of only ring layers of domains. Magnetic field inversion leads to almost complete inversion of the observed domain structure. In this case, the complete removal of the magnetic field leads to the formation of a new domain structure of the surface layer. Such a structure is close in shape and position of the domains to the original one, but does not repeat it.

Evolution of Microscopic Magnetic Domains in Quasi‐2D Cr0.92Te at Room Temperature

Abstract2D materials with long‐range ferromagnetic order hold promises for the development of compact spintronic devices with unprecedented multifunctionality and tunability. Among various 2D magnets, self‐intercalated transition metal chalcogenides Cr1+δTe2 exhibit unique features, especially excellent ambient stability and intrinsic ferromagnetic ordering above room temperature, which are critical requirements for real‐life device applications. Despite the many investigations of the magnetic properties of the Cr1+δTe2 family on the averaging macroscopic level, the domain evolution on the microscale, which is vital to nanoscale spintronics, is yet to be fully understood. Here, the evolution of magnetic behaviors of Cr0.92Te crystals is presented on both macro‐ and micro‐scales under magnetic field and thermal excitation. The crystal exhibits a high Curie temperature (Tc ≈ 343 K) among the Cr1+δTe2 family with weak magnetic anisotropy and in‐plane magnetic easy axis. Utilizing magnetic force microscopy, a pristine multidomain state and typical domain‐switching behavior are observed. Moreover, the evolution of domain texture under thermal excitation shows statistical power‐law scaling as approaching Tc. The results provide microscopic insight into the ferromagnetic behavior of a room‐temperature quasi‐2D crystal, which can be useful for further engineering of domain texture in low‐dimensional magnetic materials.

Synthesis of superhydrophobic carbon sphere by pyrolysis of heavy oil fraction of coal tar/ferrocene mixture and their magnetic nanostructure

This present work describes the ferrocene-catalyzed conversion of heavy oil fraction of coal tar to carbon sphere aggregate films in the form of necklace-like carbon spheres, carbon sphere‑carbon nanotube composite, and pomegranate-like carbon spheres by chemical vapor deposition (CVD). Necklace-like carbon spheres exhibit hydrophobic surfaces, whereas pomegranate-like carbon spheres-CNT composites and pomegranate-like carbon spheres display superhydrophobic surfaces. The as-prepared hydrophobic and superhydrophobic surfaces were carefully characterized by Scanning Electron Microscopy (SEM), High-Resolution Transmission Electron Microscopy (HRTEM), Atomic Force Microscopy (AFM), and Magnetic Force Microscopy (MFM) to confirm the effect of geometric carbon aggregates with thermally decomposed ferrocene (FeCp2) catalysts on their magnetic nanostructure. The surface chemistry as well as oxidation resistance was studied by Fourier Transform Infrared spectroscopy (FTIR), Raman spectroscopy, and Thermal Gravimetric Analysis (TGA). FeCp2 catalyst concentration in the heavy oil fraction of coal tar was observed to have a direct correlation with morphology, disordered level of graphitic structure, magnetic domain pattern arrangement, and thermal oxidation resistance of as-produced carbon sphere aggregate.

Spin reorientation transition in (110)-oriented NiCo2O4 epitaxial thin films

Magnetic anisotropy is an important character for magnetic materials. In this work, magnetic anisotropy of (110)-oriented ferrimagnetic NiCo2O4 (NCO) thin films deposited epitaxially on MgAl2O4 substrates by pulsed laser deposition is studied and compared with (001)-oriented NCO films. While the (001)-oriented films show a perpendicular magnetic anisotropy with the out-of-plane [001] direction as the magnetic easy axis, a jump in magnetic hysteresis loop is observed for the (110)-oriented films with a field applied vertically along the out-of-plane [110] direction. This jump in hysteresis loop is associated with a spin reorientation transition, depending on the applied field and temperature. Magnetic force microscopy reveals that this spin reorientation develops as domains nucleate, grow, and coalesce. This spin reorientation transition is discussed in terms of the competition between different magnetic anisotropy in an external field.

Glovebox-assisted magnetic force microscope for studying air-sensitive samples in a cryogen-free magnet.

Most known two-dimensional magnets exhibit a high sensitivity to air, making direct characterization of their domain textures technically challenging. Herein, we report on the construction and performance of a glovebox-assisted magnetic force microscope (MFM) operating in a cryogen-free magnet, realizing imaging of the intrinsic magnetic structure of water and oxygen-sensitive materials. It features a compact tubular probe for a 50 mm-diameter variable temperature insert installed in a 12T cryogen-free magnet. A detachable sealing chamber can be electrically connected to the tail of the probe, and its pump port can be opened and closed by a vacuum manipulator located on the top of the probe. This sealing chamber enables sample loading and positioning in the glove box and MFM transfer to the magnet maintained in an inert gas atmosphere (in this case, argon and helium gas). The performance of the MFM is demonstrated by directly imaging the surface (using no buffer layer, such as h-BN) of very air-sensitive van der Waals magnetic material chromium triiodide (CrI3) samples at low temperatures as low as 5K and high magnetic fields up to 11.9T. The system's adaptability permits replacing the MFM unit with a scanning tunneling microscope unit, enabling high-resolution atomic imaging of air-sensitive surface samples.

Magnetic behavior of steel studied by in-situ Lorentz microscopy, magnetic force microscopy and micromagnetic simulations

Magnetic behavior of steel studied by in-situ Lorentz microscopy, magnetic force microscopy and micromagnetic simulations

Probing geometry-induced magnetic defects in cylindrical modulated nanowires with optically detected spin resonance in nitrogen-vacancy center in diamond.

Cylindrical magnetic nanowires (NWs) have gained significant interest as building-blocks of spintronics devices and magnetic sensors thanks to their geometry-tunable magnetic properties and anisotropy. While the synthesis and compositional control of NWs have seen major improvements in recent years, considerable challenges remain for the characterization of local magnetic features at the nanoscale. Here, we demonstrate non-perturbative field distribution mapping and minimally invasive magnetic imaging with scanning nitrogen-vacancy magnetometry. This enables a sensitivity down to 3 μT Hz-1/2 used to localize ultra-scaled magnetic defects with lateral dimensions below 50 nm. The imaging reveals the presence of magnetic inhomogeneities in correspondence of periodical geometrical modulations/anti-notches in axial magnetized nanowires that are largely undetectable with standard metrology. The features induce local fluctuations of the NWs' magnetization orientation that are sensed by SNVM and compared with magnetic force microscopy. Finally, the strong magnetic field confinement in the nanowires is leveraged to study the interaction between the stray magnetic field and the fluorescence generated by two nitrogen-vacancies contained in the probe sensor, thus clarifying the contrast formation mechanisms.