Low Threading Dislocation Density Research Articles

Impact of growth and annealing conditions on the parameters of Ge/Si(001) relaxed layers grown by molecular beam epitaxy

Influence of the Ge layer thickness and annealing conditions on the parameters of relaxed Ge/Si(001) layers grown by molecular beam epitaxy via two-stage growth is investigated. The dependences of the threading dislocation density and surface roughness on the Ge layer thickness, annealing temperature and time, and the presence of a hydrogen atmosphere are obtained. As a result of optimization of the growth and annealing conditions, relaxed Ge/Si(001) layers which are thinner than 1 μm with a low threading dislocation density on the order of 107 cm–2 and a root mean square roughness of less than 1 nm are obtained.

Growth and fabrication of semi-polar InGaN/GaN multi-quantum well light-emitting diodes on microstructured Si (001) substrates

Semi-polar (1 − 101) InGaN/GaN light-emitting diodes were prepared on standard electronic-grade Si (100) substrates. Micro-stripes of GaN and InGaN/GaN quantum wells on semi-polar facets were grown on intersecting {111} planes of microscale V-grooved Si in metal–organic vapor phase epitaxy, covering over 50% of the wafer surface area. In-situ optical reflectivity and curvature measurements demonstrate that the effect of the thermal expansion coefficient mismatch was greatly reduced. A cross-sectional analysis reveals low threading dislocation density on the top of most surfaces. On such prepared (1 − 101) GaN, an InGaN/GaN LED was fabricated. Electroluminescence over 5 mA to 60 mA is found with a much lower blue-shift than that on the c-plane device. Such structures therefore could allow higher efficiency light emitters with a weak quantum confined Stark effect throughout the visible spectrum.

Influence of TMIn flow rate on structural and optical quality of AlInGaN/GaN epilayers grown by MOCVD

In this paper, nearly lattice-matched AlInGaN/GaN epilayers grown on sapphire substrate by metal organic chemical vapor deposition have been studied. The structural and optical properties of these epilayers have been investigated and compared. The TMIn flow is believed to have a direct influence on the quality of the AlInGaN epilayer. By increasing indium composition in AlInGaN epilayer, dislocations have been found to decrease, indicating lower threading dislocation density confirmed by HRXRD. Reciprocal space mapping analysis has confirmed that the growth of AlInGaN on GaN buffer is a fully strained growth. Room temperature photoluminescence from AlInGaN exhibits two emissions originating from In(Ga)N clusters and the AlInGaN random matrix, respectively. Upon increasing the TMIn flow, red shift has been observed in the photoluminescence peak confirming the decrease in bandgap of AlInGaN epilayers. In the Raman spectra, the mode at 751 cm−1 is attributed to the A1 (LO) mode of AlInGaN. The mode at 632 cm−1 is attributed to In(Ga)N clustering and assigned as A1 (LO) mode. V-shaped defect pits with different density and size have been observed on the surface of AlInGaN epilayers.

Low Dislocation Density AlGaN Epilayers for UV Laser Diodes and Devices for Power Electronics

The AlGaN alloy system has been the material system of choice for development of solid-state UV emitters and has promising properties for high-voltage power electronics. The performance and reliability of both optical emitters and power devices are critically dependent on the density of threading dislocations. While the binary substrates, GaN and AlN, are becoming commercially available, only a limited range of AlGaN compositions can be grown pseudomorphicly to device-relevant thicknesses of a micron or more. This his restricts the range of heterostructures available for designing advanced devices, and creates a need for a ternary-like pseudo-substrate with a tunable lattice constant. We present a method for fabricating crack-free AlxGa1-xN templates over the entire alloy range with threading dislocation densities (TDD) in the low 108 cm-2 ranges. We employ AlxGa1-xN overgrowth of previously grown AlxGa1-xN/AlN/sapphire templates that have been patterned with parallel trenches on a 2 μm pitch consisting of submicron-wide-mesas.1 Following overgrowth, the remaining threading dislocations are uniformly distributed over 2-inch-wafer-size areas enabling large area devices such as LEDs and PIN diodes to consist of only low TDD material. As a result, laser diodes do not need to be aligned to the underlying trench pattern. Wafer bow is reduced to less than 15 μm and epilayer cracking is essentially eliminated by using 1.3 mm-thick sapphire substrates (three times thicker than typical 2-inch wafers). The utility of the described overgrowth process for various alloy compositions is demonstrated by growing 5 to 10 μm thick Al0.3Ga0.7N, Al0.7Ga0.3N and AlN epilayers on sapphire substrates. While AlN substrates continue to improve, they are still relatively immature, expensive, and small in area compared to GaN substrates. Using the described overgrowth process and a modest growth temperature of 1100 °C, AlN epilayers grown on sapphire have achieved FWHM linewidths < 300 arc seconds for the (10-11) x-ray diffraction reflection and an RMS roughness of 1 Å over a 10 x 10 μm2region. Such x-ray linewidth and surface roughness values are comparable to AlN grown in specialized MOCVD reactors capable of growth in excess of 1300 °C. These low TDD AlGaN layers have been used for various devices. For example, the AlN overgrowth templates are used to demonstrate 2DEG formation in MODFETs formed by Al0.85Ga0.15N / Al0.7Ga0.3N heterostructures. Additionally, UV laser diodes were grown on Al0.3Ga0.7N overgrowth templates that achieved room-temperature, pulsed-current operation with emission at 352 nm and peak output powers > 2.5 mW per facet. Finally, we will also discuss the potential of using >10 μm thick Al0.3Ga0.7N overgrowth templates for PIN diodes. [1.] Allerman, et. al. J. Crystal Growth 38876 (2014). This work was supported by the Laboratory Directed Research and Development (LDRD) program at Sandia. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

CMOS Compatible Growth of High Quality Ge, SiGe and SiGeSn for Photonic Device Applications

Epitaxial growth of group IV materials on Si has been widely explored for integration of active and passive opto-electronic devices in integrated circuits. In order to meet the limitations imposed by complementary-metal-oxide-semiconductor (CMOS) technology, low temperature growth (below 450 ºC) has been pursued through different methods [1]. Achieving high quality growth at low temperatures is a challenge due to low decomposition rate of SiH4 and GeH4 and lower surface mobilty of adatoms. Propagation of threading dislocations and poor crystallinity of the films deteriorates optical efficiency and electronic transport properties of the film. Reduction of threading dislocation density of the Ge films have been achieved by different methods such as graded SiGe buffer layers, low-temperature:high-temperature (LT:HT) growth of Ge layer and annealing at elevated temperatures [2-4]. In this paper, we report on the role of different carrier gases (Ar, N2 and H2) in LT:HT growth of Ge layers by chemical vapor deposition (CVD) to attain low threading dislocation density (TDD) films. The optimized growth conditions have been applied for the growth of SiGe and SiGeSn films using SnD4 as Sn precursor. Propagation of defects in Ge rich films are mainly due to the threading of the screw dislocation throughout the film. Growth of a sacrificial layer like SiGe or LT Ge, results in reduction of threading dislocation through graded lattice change or merging of the defects [5]. The transport and reactions of the precursors are highly affected by the carrier gas in CVD processes. The carrier gases play a significant role in transferring the energy to the precursor molecules in the gas phase as well as affecting the deposition on the surface [6]. Larger gas molecules have higher cross-section with the precursors to transfer the energy and break the bonds before reaching the surface. On the other hand, presence of hydrogen in the precursor gases cause, the surface of the sample to be covered with hydrogen after the ad-species are bonded with the surface. Hydrogen as carrier gas increases the partial pressure of hydrogen which lowers the adsorption of ad-species to and desorption of byproducts from the surface. Ar or N2 gases lower the partial pressure of hydrogen and change the balance in favor of ad-species adsorption and hydrogen desorption during deposition. This results in a lesser competition between ad-species adsorption and hydrogen desorption. Fig.1 a shows the X-ray diffraction (XRD) patterns of the Ge films deposited using different carrier gases. The growth was performed using a HT:LT mechanism at 300-550 ºC temperature. The results show that Ge growth in Ar ambient has higher quality in comparison with N2 and H2 which is attributed to the larger size of Ar and lower hydrogen partial pressure at the surface. The cross-sectional transmission electron microscopy (TEM) image of growth with Ar ambient shows TDD as low as 1.3×107 cm-2 [Fig.1(b)]. Growth in N2 and H2 show poor quality as seen in the XRD patterns [Fig.1(a)]. SiGe and SiGeSn films were grown using the optimized conditions for Ge growth. A complete study of growth from 0.1 torr to 1 torr, at temperatures from 350-450 ºC for different precursor flow rates is performed. Silicon incorporation in Ge films varied from 1% to 28% for SiGe films [Fig.1(a)]. Tin incorporation of 2% was observed in the films with 13% to 17% Si incorporation [Fig.1(a)]. Investigation of film quality has been done using etch pit measurement with Schimmel solution for 10 minutes. The comparison of TDD using TEM (1.3×107 cm-2) and SEM images (1.7×107 cm-2) for Ge films confirm the accuracy of the measurements. Figs.1 (c), (d), and (e) show the scanning electron microscopy image (SEM) of etch pit Ge, SiGe and SiGeSn films respectively. The TDD of SiGe growth is 2.3 ×107 cm-2 , while the TDD of SiGeSn film is 4.0 ×107 cm-2. Our investigations show that high quality growth of Ge, SiGe and SiGeSn films has been achieved using Ar carrier gas at CMOS compatible temperatures. The material characterization of Ge films show optimized growth condition using Ar carrier gas. Low TDD of SiGe and SiGeSn films show high quality material growth that can be used for optoelectronic device applications.

Threading dislocation degradation of InSb to InAsSb subchannel double heterostructures

In this paper, we report the transport properties of an InAsSb quantum well channel double heterostructure. We propose a structure of the InAsSb quantum well with an AlInSb/AlInSb double matrix barrier. The quantum well is investigated for an Al x In1−x Sb/Al0.24In0.76Sb/In y As1−y Sb/Al0.24In0.76Sb composition over a variable interpolation range (y = 0–0.3) of the InAsSb channel region. With the smallest threading density of 1.4 × 108 cm−2 and the highest electron mobility of 43000 cm2/Vs at 15 nm quantum well thickness, a small lattice mismatch is shown between the double matrix AlInSb barrier and the InAsSb channel. This is the lowest threading dislocation density and the highest mobility among those reported for all InSb-based heterostructure devices. This device is further proven to be defec-free due to better lattice match with the InAsSb channel quantum well. Therefore, this device could be used for a wide range of ultra-low power applications. Open image in new window

Epitaxial growth of low threading dislocation density InSb on GaAs using self-assembled periodic interfacial misfit dislocations

We report a fully relaxed low threading dislocation density InSb layer grown on a GaAs substrate using self-assembled periodic interfacial misfit dislocations. The InSb layer was grown at 310°C by molecular beam epitaxy. The AFM measurement exhibited a root mean square (r.m.s.) roughness of 1.1nm. ω−2θ scan results from x-ray diffraction measurement indicated that the InSb layer is 98.9% relaxed. Images from the transmission electron microscope measurement showed a threading dislocation density of 1.38×108cm−2. The formation of highly uniform interfacial misfit dislocation array was also observed and the separation of dislocations is consistent with theoretical calculation. The InSb layer exhibited a 33,840cm2/Vs room temperature electron mobility.

Growth of c-plane ZnO on γ-LiAlO2 (1 0 0) substrate with a GaN buffer layer by plasma assisted molecular beam epitaxy

C-plane ZnO epilayers were grown on LiAlO2 (100) substrate with a GaN buffer layer by plasma assisted molecular beam epitaxy. Both the X-ray rocking curves and the transmission electron microscopy analyses indicate that the ZnO epilayers exhibit a lower threading dislocation density (∼1×1010cm−2) as compared to those grown on LiAlO2 substrate without the buffer layer. A high Zn/O flux ratio is beneficial for reducing the density of screw-type dislocations. Reciprocal space maps demonstrate that the misfit strain has been relaxed. No interfacial layer is formed at the ZnO/GaN interface by using a Zn pre-exposure strategy. The ZnO epilayers exhibit a strong near band edge emission at 3.28eV at room temperature with a negligible green band emission.

(Invited) Advanced Germanium Epitaxy for Photonics Application

Investigations of low threading dislocation density (TDD) Ge growth using reduced pressure chemical vapor deposition for photonics application are reviewed. By interrupting the Ge growth process and annealing for several times during Ge epitaxy (cyclic annealing), TDD of below 1×106 cm-2 is achieved for 4.7 µm thick Ge. Root mean square of roughness below 0.5 nm is realized. Thin and low TDD Ge layer fabrication is demonstrated by depositing thick Ge with cyclic annealing process followed by HCl etching. Dislocation-free area of local Ge on insulator is formed between [110] and [1-10] direction by lateral selective Ge growth in cavity between SiO2 cap and buried oxide, which is formed by sacrificial Si etching. Using an atomic-layer-doping approach, self-limitation of incorporated P dose at ~1/4 monolayer is obtained offering heavy n-doping in Ge. P diffusion suppression by delta-doped Si in Ge is observed. By Ge growth followed by HCl etching process, photodiode with one order of magnitude lower dark current compared to standard Ge growth with cyclic annealing is fabricated.

N-face GaN/AlN/GaN/InAlN and GaN/AlN/AlGaN/GaN/InAlN high-electron-mobility transistor structures grown by plasma-assisted molecular beam epitaxy on vicinal substrates

Since on-axis GaN-on-sapphire substrates with low threading dislocation density are not available in the N-face orientation, we explored the growth of InAlN on vicinal (4° miscut along GaN GaN-on-sapphire substrates. The microstructure of In0.18Al0.82N layers grown by plasma-assisted molecular beam epitaxy at different temperatures was studied using scanning transmission electron microscopy (STEM). The cross-sectional and plan-view STEM images revealed lateral variations in the InAlN composition along (perpendicular to the step edges). Also, step bunching was observed in InAlN layers thicker than 10 nm. N-face high-electron-mobility transistor structures with lattice-matched InAlN backbarriers were then grown on these vicinal substrates with different InAlN thicknesses. Transmission line measurements showed that step bunching and lateral variation of InAlN composition degraded the two-dimensional electron gas (2DEG) mobility in the directions parallel and perpendicular to the steps. A 2DEG charge density of 1.1 × 1013 cm−2 and mobility of 1850 cm2 V−1 s−1 were achieved on a GaN/AlN/InAlN/GaN structure with 7.5 nm thick In0.18Al0.82N. By designing a double backbarrier (In0.18Al0.82N(7.5 nm)/Al0.57Ga0.43N(7 nm)), a 2DEG charge density of 2 × 1013 cm−2 and mobility of 1360 cm2 V−1 s−1 were attained, which resulted in a sheet resistance of 230 Ω/□.

Recent Progress in AlGaN‐Based Deep‐UV LEDs

SUMMARYDeep‐ultraviolet (DUV) light‐emitting diodes (LEDs) are in demand for a wide variety of potential applications, such as sterilization, water and air purification, medical uses, and so on. We have demonstrated 222–351 nm AlGaN and quaternary InAlGaN‐based DUV‐LEDs by developing a low threading dislocation density (TDD) AlN crystal. We achieved an external quantum efficiency (EQE) of about 4% and an output power greater than 30 mW in DUV‐LEDs for use in sterilization applications by developing new crystal growth techniques.

Characteristics of the epitaxy of InGaN-based light-emitting diodes grown by nanoscale epitaxial lateral overgrowth using a nitrided titanium buffer layer

In this work, a buffer layer of nitrided titanium (Ti) achieved through the nitridation of a Ti metal layer on a sapphire substrate was used for the epitaxial growth of InGaN-based light-emitting diodes (LEDs) achieved by low pressure metal-organic chemical vapor deposition. The effect of in-situ Ti metal nitridation on the performance of these InGaN-based LEDs was then investigated. It was very clear that the use of the nitrided Ti buffer layer (NTBL) induced the formation of a nanoscale epitaxial lateral overgrowth layer during the epitaxial growth. When evaluated by Raman spectroscopy, this epi-layer exhibited large in-plane compressive stress releasing with a Raman shift value of 567.9 cm-1. Cathodoluminescence spectroscopy and transmission electron microscopy results indicated that the InGaN-based LEDs with an NTBL have improved crystal quality, with a low threading dislocations density being yielded via the strain relaxation in the InGaN-based LEDs. Based on the results mentioned above, the electroluminescence results indicate that the light performance of InGaN-based LEDs with an NTBL can be enhanced by 45% and 42% at 20 mA and 100 mA, respectively. These results suggest that the strain relaxation and quality improvement in the GaN epilayer could be responsible for the enhancement of emission power.

Mixed-anion GaAs1−ySby graded buffer heterogeneously integrated on Si by molecular beam epitaxy

The growth, strain relaxation, and defect properties of a step-graded mixed-anion GaAs1−ySby buffer with a lattice misfit of >12% on a 6° off-cut (100) Si substrate grown by molecular beam epitaxy (MBE) have been investigated. This metamorphic graded buffer exhibited efficient strain relaxation and low threading dislocation densities of ≤107 cm−2 in the investigated range of misfits. High-resolution X-ray diffraction measurement demonstrated nearly ideal strain relaxation behavior with a surface rms roughness of ∼3.5 nm, which is attributed in part to dislocation glide. Thus, MBE-grown GaAs1−ySby anion-graded buffers are a promising “virtual substrate” technology for extending the performance and application of 6.1 Å device technology.

Growth of High Quality Ge Layer on Silica Nano-Spheres Integrated Ge/Si Template Using UHV-CVD

We have investigated the growth of high quality Ge layer on Si substrate using silica nano-spheres (NSs), which behaved as masks to directly block threading dislocations. Two-step growth after the silica NS incorporation into the surface led to a coalesced Ge layer with low threading dislocation density (TDD). TDD in the resultant Ge layer was reduced from 6.4 × 108 to 6.9 × 107 cm−2, and decreased further to 1.4 × 107 cm−2 by post annealing. In addition to the TDD reduction, we speculated that the suppression of {111} facet during the growth restricted significantly the generation of planar defects.

Quadruple-Junction Inverted Metamorphic Concentrator Devices

We present results for quadruple-junction inverted metamorphic (4J-IMM) devices under the concentrated direct spectrum and analyze the present limitations to performance. The devices integrate lattice-matched subcells with rear heterojunctions, as well as lattice-mismatched subcells with low threading dislocation density. To interconnect the subcells, thermally stable lattice-matched tunnel junctions are used, as well as a metamorphic GaAsSb/GaInAs tunnel junction between the lattice-mismatched subcells. A broadband antireflection coating is used, as well as a front metal grid designed for high concentration operation. The best device has a peak efficiency of (43.8 ± 2.2)% at 327-sun concentration, as measured with a spectrally adjustable flash simulator, and maintains an efficiency of (42.9 ± 2.1)% at 869 suns, which is the highest concentration measured. The V <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">oc</sub> increases from 3.445 V at 1-sun to 4.10 V at 327-sun concentration, which indicates high material quality in all of the subcells. The subcell voltages are analyzed using optical modeling, and the present device limitations and pathways to improvement are discussed. Although further improvements are possible, the 4J-IMM structure is clearly capable of very high efficiency at concentration, despite the complications arising from utilizing lattice-mismatched subcells.

Analysis of nonradiative recombination mechanisms and their impacts on the device performance of InGaN/GaN light-emitting diodes

We investigate the nonradiative recombination mechanisms of two conventional InGaN/GaN-based blue light-emitting diodes with different threading dislocation densities (TDDs). The current–voltage, the ideality factor, and the slope of the light-versus-current curve on log scales are analyzed to distinguish the dominant nonradiative recombination mechanisms at room temperature. Through the analysis, we infer the dominant nonradiative recombination mechanisms to be the Shockley–Read–Hall process for the sample with a low TDD (∼1 × 108 cm−2) and the defect-assisted tunneling for the sample with a high TDD (∼1 × 109 cm−2). For more detailed analysis of the nonradiative recombination mechanisms and their impacts on the device performance, we execute the temperature-dependent photovoltage and temperature-dependent electroluminescence efficiency experiments. The sample with a low TDD is found to be more prone to the carrier spill-over at cryogenic temperatures due to the deactivation of point defects, while the sample with a high TDD is more robust to the operation at cryogenic temperatures owing to the relative insensitiveness of the defect-assisted tunneling to temperature.

Low temperature growth of the epitaxial Ge layers on Si(100) by Hot Wire Chemical Vapor Deposition

In the present paper, we report on the growing of thick (~0.2-3.0 μm) epitaxial Ge/ Si(100) layers by Hot Wire Chemical Vapor Deposition (HWCVD) at low growth temperatures (350°C). The single crystal epitaxial Ge layers with low threading dislocation density (~105 cm−2) and surface roughness (< 0.5 nm) have been obtained.

Thin, relaxed Si1−xGex virtual substrates on Si grown using C-doped Ge buffers

Ultrathin C-doped Ge (Ge:C) buffers are used as effective buffer layers to grow thin and smooth Si1−xGex relaxed virtual substrates on Si over a wide range of Ge content (x = 0.23, 0.38, 0.50, 0.65, 1) by ultrahigh vacuum chemical vapor deposition. High degree of relaxation (≥90%) in thin Si1−xGex films (∼50 nm thick) is demonstrated using this approach without additional annealing. Raman data suggest that the Ge:C buffers are still under compressive stress with the subsequent Si1−xGex layer growth. A low threading dislocation density of the order of ∼6 × 104 cm−2 is obtained from the relaxed 500-nm Si0.77Ge0.23 film grown using this method.

Fabrication and characterization of germanium-on-insulator through epitaxy, bonding, and layer transfer

A scalable method to fabricate germanium on insulator (GOI) substrate through epitaxy, bonding, and layer transfer is reported. The germanium (Ge) epitaxial film is grown directly on a silicon (Si) (001) donor wafer using a “three-step growth” approach in a reduced pressure chemical vapour deposition. The Ge epilayer is then bonded and transferred to another Si (001) wafer to form the GOI substrate. The Ge epilayer on GOI substrate has higher tensile strain (from 0.20% to 0.35%) and rougher surface (2.28 times rougher) compared to the Ge epilayer before transferring (i.e., Ge on Si wafer). This is because the misfit dislocations which are initially hidden along the Ge/Si interface are now flipped over and exposed on the top surface. These misfit dislocations can be removed by either chemical mechanical polishing or annealing. As a result, the Ge epilayer with low threading dislocations density level and surface roughness could be realized.

Epitaxial Growth and Layer Transfer of InP through Electrochemically Etched and Annealed Porous Buried Layers

Heterogeneous material integration, especially for III-V semiconductors, has enabled more possibilities in designing optoelectronic and electronic devices, and the ability to exfoliate the bonded devices layers and reuse the expensive substrates makes it economically advantageous. In our case, we propose a method using easily fractured porous layer to transfer an InP thin film from an InP substrate to an alternate substrate; e.g., glass or a flexible structure such as PDMS. Here, we demonstrate the formation of such a porous InP layer which exhibits a surface that is nearly fully dense as well as the ability to grow InP overlayers with low (< 106 cm-2) threading dislocation density. Also, we were able to transfer large area (> 1 cm2) InP layers onto PDMS substrates and glass slides.In our studies on (001) InP, we have demonstrated that the pore formation can be controlled as a function of depth during electrochemical etching. For as-etched porous layers, AFM scans on a 40 X 40 μm2 area show the lowest surface r.m.s. less than 40 Å despite of the pore features. In order to achieve both high-quality epitaxial growth and facile layer fracture, a dual porous layer structure with a more porous (mechanically weaker) under-layer was designed and fabricated by either adjusting the etching current density or changing the switching electrolyte concentration. The structures were annealed to understand the morphological evolution of the pore structure and to test the structural stability under simulated epitaxial growth condition. Under N2-purged environments, we observed that the surface remains stable (no change in surface pore morphology) with even slight improvement on roughness up to 550 °C and the layer maintained its porous structure at 650 °C. Large voids were observed after annealing at the interface between the high porosity buried layer and substrate, which is consistent with the ease by which it is to remove top layers from the substrate after annealing. Epitaxial layers were grown about 2 μm thick on porous surfaces with different porosities and both a cross-section TEM sample and a plan-view sample (> 35 μm2) were used to characterize the epitaxial growth. Since no observable threading dislocations were found in the plan-view sample, it sets a limit on the threading dislocation density in the mid-106 cm-2 range.Samples with dual porous layers were bonded to flexible PDMS substrates and easily peeled off due to the fracture at the high porosity layer. Another set of samples were bonded to glass slides with epoxy glue and the fractured surface was characterized under SEM.