Low-temperature Electron Research Articles

Research on the Influence of Fault Structure on Physical and Chemical Structure of Coking Coal During Spontaneous Combustion

ABSTRACT The spontaneous combustion tendency and oxidation combustion properties of coking coal in fault fracture zone and primary coking coal are different. Accordingly, this study uses Thermogravimetric analysis, in-situ Fourier transform infrared spectroscopy, Scanning electron microscope, low-temperature N2 adsorption and Electron spin resonance techniques were used to study the difference of macroscopic and microscopic structural characteristics between coking coal and primary coking coal in fault fracture zone. The results show that: The oxygen absorption capacity of coking coal in fault fracture zone is enhanced and the thermogravimetric characteristic temperature is advanced, and the ignition point temperature is advanced by 5.36°C; the maximum weight loss temperature of coking coal in fault fracture zone is 3.32°C lower than that of primary coking coal. The apparent activation energy of coking coal in oxidation stage and pyrolytic combustion stage decreased by 4.88 and 5.03 kJ/mol, respectively. Compared with primary coking coal, the pore structure of coking coal in fault fracture zone is more complex, which increases the roughness of coal surface and is conducive to oxygen adsorption. In addition, fault tectonics promotes the separation and cracking of oxygen-containing functional groups into small molecules, and the polycondensation of aliphatic hydrocarbon structure promotes the formation of active free radicals, thus promoting spontaneous combustion. This study provides an important reference and theoretical support for further understanding of the structural evolution and oxidation kinetics of highly metamorphic coking coal induced by fault tectonics, which is helpful for fire prevention and control in fault structure-developed mining areas and safe production of coal industry.

In-situ generation of highly-reactive FeIV=O and its contribution during CH4 conversion to CH3OH

Photocatalytic CH4 conversion to CH3OH under mild conditions is undoubtedly an efficient strategy to realize CH4 upgrading. In this work, in-situ formed highly reactive FeIV=O complex with a bound Cl axial ligand was detected at ambient temperature and its contribution to CH4 photoxidation to CH3OH was deeply investigated. Under optimized experimental condition, a high CH3OH yield of 3026.1 mmol molFe−1 (6.76 mmol gcat−1 h−1) with selectivity of 73.6 % was obtained during 8 h. Isotope labeling mass spectroscopy experiments manifested that O2 was the only source of oxygen in products. The formation of Cl-(H2O)4FeIVO complex was confirmed using low-temperature electron spin resonance spectroscopy and cryogenic Raman spectroscopy (ν(FeO) = 828 cm−1). Through density functional theory (DFT) calculation, we showed that the Cl axial ligand acts as an “electron reservoir” during CH4 conversion, i.e., electron acceptor during the process of CH4 oxidation to CH3OH, while electron donor in CH3OH desorption. This not only lowered C-H cleavage energy, but also facilitated CH3OH desoption and inhibited overoxidation. As far as we know, Cl-(H2O)4FeIVO is the first detected FeIVO complex generated directly from O2 and Fe3+ at ambient temperature.

III–V heterostructure tunnel field-effect transistor operation at different temperature regimes

Tunnel field-effect transistors (TFETs) are a potential alternative to MOSFETs for low-temperature electronics. We provide an in-depth experimental characterization of TFETs analyzing the fundamental physical behavior at different temperature regimes. TFET characteristics from 13 to 300 K both in forward and reverse bias are discussed by employing a variation in InAs/InGaAsSb/GaSb heterojunction vertical nanowire devices. Evaluation of the TFET Negative Differential Resistance (NDR) characteristics at different temperatures is established as a technique to probe the dopant incorporation. It is observed that the temperature dependence of the Fermi degeneracy and Fermi-Dirac distribution largely influences the transistor performance at each operating temperature. Our investigation reveals that the TFETs demonstrate lower subthreshold swing than the physical limit of MOSFETs above 125 K. For low-temperature applications, the devices can be operated down to a low operating bias of 0.1 V, while for high temperature, a larger bias of 0.3 V is preferred.

N-changing population of Rydberg states by low-energy electron-Rydberg collisions.

Inelastic n-changing collisions play an important role in the evolution of Rydberg atoms into ultracold plasmas. However, for the initially intermediate n (n ∼ 40) Rydberg states, these collisions can hardly be observed due to the low electron temperature in ultracold plasmas. In this work, we designed an experimental scheme to facilitate collisions between free electrons at 1.5eV and intermediate n Rydberg atoms. Using the field ionization technique, we measured the state distributions resulting from the evolution of initially cold rubidium atoms in the 45P3/2 Rydberg state. The experimentally obtained probability of inelastic collisions excitation agrees well with the Monte Carlo simulation results. In addition, our experimental results indicate that the n-changing population induced by hot electrons is significant for lower nP Rydberg states. Our work plays a significant role in calculating the rates of electron-ion three-body recombination in ultracold plasmas.

Effect of gas injection pattern on magnetically expanding rf plasma source

Abstract Argon gas is injected from a back plate having either a radial center hole or shower-patterned eight holes into a 13.3-cm-diameter and 25-cm-long radio frequency (rf) plasma source attached to a 43.7-cm-diameter and 65cm-long diffusion chamber under an expanding magnetic field, which resembles the magnetic nozzle rf plasma thruster. The source has a double-turn loop antenna powered by a 13.56 MHz rf generator at a maximum power level of ~2.8 kW in low-pressure argon, providing a plasma density of about 1018 m−3 in the source. A high plasma density and a slightly low electron temperature are obtained for the shower-pattered case in both the source tube and the diffusion chamber, compared with the center hole case, suggesting that the neutral density profile significantly affects the plasma density profile. This result will provide an improvement in the thruster performance by the gas injection pattern.

Hysteresis in strongly magnetized N2 discharges

A semi-empirical global model for a nitrogen discharge in a strong magnetic field is developed. The model is based upon experimental data from high-resolution Doppler and extreme-ultraviolet vacuum spectroscopy, which establish the plasma composition, discharge parameters, and, most importantly, electronic transitions. This allows the number of required molecular systems and atomic/ionic states to be reduced, thereby retaining only the essential plasma chemistry reactions. The set of 35 stiff non-linear ordinary differential equations is numerically integrated using an unconditionally stable adaptive method. Simulations show the existence of two solution branches with low and high electron temperature, respectively. A distinct hysteresis is exhibited by the discharge and illustrated for three typical N2 mass flow rates. The dependencies of the plasma parameters on the applied power are presented and discussed in detail, including in the vicinity of the bifurcation points. The efficiency of operation in the opposing limits of N2 discharge behavior as either a source of plasma or light emission is examined, with special emphasis on electric propulsion capabilities.

Transition from Surface to Volume Expansion in Argon Clusters Coulomb Explosion.

The intensity-difference spectrum technique is applied to record charge-state resolved ion energy spectra from the Coulomb explosion of small Ar clusters under well-resolved laser intensity conditions. The far-reaching control of the experimental parameters permits us to identify a striking change in the expansion pattern of the nanoplasma beyond a given intensity. The simultaneous characterization of ion charge state and energy uncovers that a reduction of the laser intensity leads to a development of low energy cuts in the ion yields, not present at higher fluence. The complex interplay of outer ionization, recombination, ion screening, and the phenomenon of ionization saturation favors a surface-driven expansion at low plasma electron temperatures. With increasing laser intensity a transition into a volume-driven Coulomb explosion is observed.

PAN-assisted preparation of Bi2MoO6 with enhanced photocatalytic CO2 reduction performance

In this study, to improve photocatalytic CO2 reduction efficiency of Bi2MoO6-based photocatalysts, Bi2MoO6 (BMO) was synthesized via a solvothermal method with the assistance of polyacrylonitrile (PAN). Scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were utilized to evaluate the microstructures, phases, and elemental compositions of the samples. Additionally, the separation and migration efficiency of photogenerated charge pairs during the photocatalytic process were analyzed in detail using surface photovoltage spectroscopy (SPS), photoluminescence spectrum (PL), transient photocurrent density (TPR), and electrochemical impedance spectroscopy (EIS). In comparison with the reference sample, the specific surface area of 2 % BMO (mass ratios of PAN/Bi(NO3)3·5H2O is 2 %) has been increased to 39.6 m2/g, which increases by 0.9 times compared to the reference sample. The successful introduction of oxygen vacancies (OVs) in Bi2MoO6 was confirmed by low-temperature electron paramagnetic resonance (EPR) and X-ray photoelectron spectroscopy (XPS), and suitable OVs is favorable for separation and migration of the photogenerated carriers. The experimental results indicate that the separation efficiency of photogenerated carriers in the PAN-BMO photocatalyst is significantly boosted in contrast to the reference sample. Furthermore, all photocatalysts exhibit higher photocatalytic CO2 reduction activity than the reference sample. It is noteworthy that the 2 % BMO sample shows the highest photocatalytic CO2 reduction activity, and the average photocatalytic CO2 reduction yield over the 2 % BMO reaches 2.16 μmol g−1 h−1, which is 2.25 times higher than that on the reference sample (0.96 μmol g−1 h−1). In view of the findings, photocatalytic CO2 reduction mechanism for BMO with OVs was rationally proposed.

Abstract Tu123: Redox Biology of the Mitochondrial Protein mitoNEET and Ascorbate

Background: It has been proposed that mitoNEET is an Fe-S transfer/repair enzyme, playing a role under conditions of oxidative stress. mitoNEET protects mitochondria against oxidative stress in cardiomyocytes. Loss of mitoNEET is linked with age-related heart failure. Oxidized mitoNEET, [2Fe-2S] 2+ , exports Fe-S cluster from mitochondria to cytosol. Redox control of mitochondrion is essential for the proper functioning of the organelle/mitochondria. However, the molecular mechanisms involved in the redox biology of mitoNEET is not fully studied. Hypothesis: Ascorbate regulates redox reactions and Fe-S cluster transport function of mitoNEET in the mitochondria. Aims: The objective of this work is to evaluate the redox reactions between mitoNEET and ascorbate. Methods: Room temperature and low temperature (77 K) electron paramagnetic resonance (EPR) spectroscopy techniques were used to measure the oxidation of ascorbate and reduced mitoNEET, respectively. Results: EPR spectroscopic study shows that mitoNEET oxidizes ascorbate to ascorbate radical. The formation of ascorbate radical increases with increasing concentration of ascorbate. The formation of ascorbate radical is decreased in the presence of menadione. Low temperature EPR study shows that one electron reduction of mitoNEET by ascorbate. Conclusion: This study suggest that ascorbate is a substrate/cofactor for mitoNEET. Ascorbate regulates the Fe-S cluster transport function of mitoNEET. Ascorbate plays an important role in the redox biology of mitoNEET under physiological and pathophysiological conditions.

Role of radiation re-absorption in the thermal helium beam diagnostic.

The Thermal Helium Beam (THB) is a diagnostic for simultaneously measuring the electron temperature and density profiles of the plasma edge and scrape off layer (SOL). It exploits the line ratio technique of selected He line intensities, emitted by He gas puffed inside the plasma, to locally estimate the plasma properties through a dedicated collisional radiative model (CRM). Standard THB diagnostics used in nuclear fusion devices measure three HeI emission lines: 667.8, 706.5, and 728.1nm. For the RFP experiment RFX-mod2, a new THB is designed and tested for the first time at the TCV tokamak. It acquires an additional emission line at 501.6nm, which is exploited to estimate the radiation re-absorption, which is not negligible in regions of large neutral He densities (leading to high re-absorption) and simultaneously low electron density and temperature (lack of other excitation channels). It affects the measurements most strongly at the far SOL, while the significance of re-absorption decreases as it approaches the separatrix. In this paper, plasma density and temperature profiles of the plasma edge at the outboard midplane of TCV, measured with this newly designed THB, are presented. For the first time, the effect of radiation re-absorption on the estimation of electron temperature and density profiles is experimentally measured in a tokamak using the 501nm line emission intensity. Different CRMs are compared with and without radiation re-absorption, showing good agreement when re-absorption is included and demonstrating how it plays an important role in the far SOL, as expected.

Abnormal behavior of the plasma potential in an inductively coupled plasma with a DC-biased grid

Abstract The formation of the plasma potential and the generation mechanism of very low electron temperature plasma are investigated in an inductively coupled plasma with a DC biased grid. The electron temperature is controlled from 2.4 eV to 0.2 eV according to the grid voltage (10 V to −40 V). Interestingly, when the grid voltage is negatively biased, the electron temperature decreases and the plasma potential decreases with the grid voltage, but then increases below −10 V which is abnormal. This behavior of the plasma potential is abnormal since the plasma potential is generally proportional to the electron temperature. The main reason for the abnormal increase of the plasma potential is the difference in the flux of electrons and ions below the grid. As the grid is negatively biased, the electron flux is greatly reduced compared to the ion flux, leading to an increase in plasma potential. After −20 V, the plasma potential saturates, because although the number of electrons entering the grid decreases, the electron flux is maintained by secondary electrons generated in the grid mesh. This abnormal increase in plasma potential decreases with pressure. An increase in plasma potential with gas species is also observed. The same behavior is observed for Ar, He, and N2 gases. The abnormal behavior of the plasma potential is explained with the current continuity.

The sound of lichens: ultrasonic acoustic emissions during desiccation question cavitation events in the hyphae.

Lichens are a mutualistic symbiosis between a fungus and one or more photosynthetic partners. They are photosynthetically active during desiccation until relative water contents (RWC) as low as 30% (on dry mass). Experimental evidence suggests that during desiccation, the photobionts have a higher hydration level than the surrounding fungal pseudo-tissues. Explosive cavitation events in the hyphae might cause water movements towards the photobionts. This hypothesis was tested in two foliose lichens by measurements of ultrasonic acoustic emissions (UAE), a method commonly used in vascular plants but never in lichens, and by measurements of photosystem II efficiency, water potential and RWC. Thallus structural changes were characterised by low-temperature scanning electron microscopy. The thalli were silent between 380% and 30% RWCs, i.e. when explosive cavitation events should cause movements of liquid water. Nevertheless, the thalli emitted UAE at approximately 5% RWC. Accordingly, the medullary hyphae were partially shrunk at about 15% RWC, whereas they were completely shrunk below 5% RWC. These results do not support the hypothesis of hyphal cavitation and suggest that the UAE originate from structural changes at hyphal level. The shrinking of hyphae is proposed as an adaptation to avoid cell damage at very low RWCs.

Microstructural modification and enhanced mechanical properties in Zr50-Ti50 alloy via low temperature electron wind force annealing

This study investigates the microstructural transformations and associated property enhancements in a Zr50-Ti50 alloy annealed at only 120 °C with low duty cycle current pulses. Microanalysis with electron backscatter diffraction (EBSD) and X-ray diffraction (XRD) show the formation of alpha lath structure, typically observed in much higher thermal annealing temperatures. EBSD and XRD analyses revealed the formation and/or growth of the lath structure, with notable changes in pole distributions and the appearance of a distinct peak at 52.5° in the XRD spectrum. The lath structure is quantified using FiJi weka segmentation machine learning technique. Nanoindentation data showed an increase in the average hardness from ∼7 to ∼8 GPa and a corresponding increment in the reduced modulus from 127 to 148 GPa. The observed increase in low-angle grain boundaries (LAGBs) from 4% to 12% further complements the findings, suggesting a complex interplay of microstructural features contributing to the overall improvement in the mechanical properties. The proposed low temperature annealing technique demonstrates the predominant role of the electron wind force for tailoring the microstructure and mechanical performance of ZrTi alloys, providing insights that could have implications for the broader field of materials engineering.

Effect of non-square potential profile on three subband electron mobility in AlGaAs quantum well structures

This work analyses the effect of the non-square structure potentials, such as V-shaped (V), parabolic (P), cubic (C), semi-V (SV), semi-parabolic (SP), and semi-cubic (SC) on the low temperature electron mobility (μ) as a function of doping concentrations (N d = 0.1 to 3.0 × 1018 cm−3) in modulation δ-doped quantum well (QW) structures. We calculate μ by adopting screened ionized impurity (ii-) and alloy disorder (al-) scatterings. We consider higher subband occupancy up to three and show that the intersubband effects influence the screened scattering potentials differently, such that μ ii increases while μ al decreases, leading to nonlinear enhancement of μ. Further, there are sudden drops in μ, near the transition of occupation of subbands due to the intersubband effects, and the magnitude of the drop is reduced at the third subband occupancy. The number of occupied subbands (nos), for the considered range of N d , differs with NSQW structures, e.g., nos = 3 in the case of VQW, CQW, and PQW, nos = 2 in SCQW and SPQW, and nos = 1, in SVQW structures. Interestingly, in VQW, the occupation of the second subband starts at a higher N d , compared to CQW and PQW, while, the third subband occupancy shows an opposite trend. Furthermore, the dissimilarity in electron charge distributions in the NSQW structures influences the ii-scattering potential differently, causing μ ii (VQW) > μ ii (PQW) > μ ii (CQW), while for al-scattering the order of μ al reverses.

Rationally construction of Dy2O3/g-C3N4 heterojunctions with largely enhanced photocatalytic hydrogen evolution activity

In this paper, Dy2O3/g-C3N4 photocatalysts with augmented photocatalytic hydrogen evolution activity were obtained by a pore impregnation method after baking. The samples were evaluated via scanning electron microscopy (SEM) and X-ray diffraction (XRD). Separation and migration efficiency of photogenerated carriers was analyzed using surface photovoltage spectroscopy (SPS), transient photocurrent density (TPR) and electrochemical impedance spectroscopy (EIS). Through low-temperature electron paramagnetic resonance (EPR) and X-ray photoelectron spectroscopy (XPS), nitrogen vacancies were successfully introduced into g-C3N4. All Dy2O3/g-C3N4 samples display more stronger photocatalytic activity than the reference g-C3N4. Notably, 3 % DyO/CN exhibits the highest photocatalytic activity. The average photocatalytic hydrogen evolution rate over 3 % DyO/CN reaches 9.9 mmol·g−1·h−1, which is nearly 3 times of that over the reference sample (3.3 mmol·g−1·h−1). In view of the observations, photocatalytic mechanism of Dy2O3/g-C3N4 heterojunction was rationally proposed.

Efficient ECCD non-inductive plasma current start-up, ramp-up, and sustainment for an ST fusion reactor

The elimination of the need for an Ohmic heating solenoid may be the most impactful design driver for the realization of economical compact fusion tokamak reactor systems. However, this would require fully non-inductive start-up and current ramp-up from zero plasma current and low electron temperature of sub-keV to the full plasma current of ∼10–15 MA at 20–30 keV electron temperature. To address this challenge, an efficient solenoid-free start-up and ramp-up scenario utilizing a low-field-side-launched extraordinary mode at the fundamental electron cyclotron harmonic frequency (X–I) is proposed, which has more than two orders of magnitude higher electron cyclotron current drive (ECCD) efficiency than the conventional ECCD for the sub-keV start-up regime. A time dependent model was developed to simulate the start-up scenarios. For the Spherical Tokamak Advanced Reactor (STAR) (Menard et al 2023 Next-Step Low-Aspect-Ratio Tokamak Design Studies (IAEA)), it was found that to fully non-inductively ramp-up to 15 MA, it would take about 25 MW of EC power at 170 GHz. Because of the relatively large plasma volume of STAR, radiation losses must be considered. It is important to make sure that high Z impurities are kept sufficiently low during the early current start-up phase where the temperature is sub-keV range. Since the initial current ramp up takes place at a factor of ten lower density compared to the sustained regimes, it is important to transition into a higher bootstrap fraction discharge at lower density to minimize the ECCD power requirement during the densification. For the sustainment phase an array of eight gyrotron launchers with a total of about 60 MW of fundamental O-mode was found to be sufficient to provide the required axis-peaked external current drive. High efficiencies between 19–57 kA MW−1 were found with optimal aiming, and these were resilient to small changes in aiming angles and density and temperature profiles.

Laser-induced growth of metal oxide films on quartz tubes for photocatalytic water treatments

A solid-state pulsed laser technique was developed to in situ grow arbitrary immobilized catalysts (Fe3O4, CeO2, WO3 etc.) on the inner surface of quartz tube with robust adhering strength. In a case study, anatase/rutile hetero-phase TiO2 film was deposited to serve as immobilized photocatalysts for the effective removal of antibiotics from aqueous environment. The X-ray absorption spectroscopy, low temperature electron paramagnetic resonance and the density functional theory simulation directly confirm a defect-assisted type-II band alignment was established to facilitate the charge transfer at the hereto-interphase. In addition, the oxygen vacancy enriched anatase phase with greater binding energy towards the dissolved oxygen facilitated the O2– generation. Meanwhile, the rutile phase enriched with Ti3+ could effectively activate the antibiotics to promote the direct h+ mediated oxidation. Such integration of unique atomic vacancies prevent defects from becoming electron-hole recombination centers and consequently extend the lifetime of the photoexcited charge carrier. The degradation mechanism of oxytetracycline was thoroughly examined by ultra-high resolution electrospray time-of-flight mass spectrometry and Fukui function, while the ecological structure–activity relationships program assessed the toxicity of contaminant to the environment. Milewhile, a continuous water treatment apparatus employing the catalytic tubes as reactors was established and demonstrated a ∼ 95 % OTC degradation under the natural sunlight adopting river water as the background. The experimental studies also claimed that ∼ 90 % of the initial activity could be retained after 100 cycles reuse, which permits their great potential for the applicational scenarios.

Plasma properties in the vicinity of the last closed flux surface in hydrogen and helium fusion plasma discharges

The origin of the bi-Maxwellian electron energy distribution function (EEDF) observed in the scrape-off layer (SOL) of tokamak plasmas by means of Langmuir probes is still under discussion. It has been assumed that the ionization of hydrogen and deuterium neutrals by thermal electrons penetrating the SOL from the bulk plasma is the main reason for the appearance of a second Maxwellian. To validate this assumption, radial measurements of the electron temperatures and densities, or the plasma properties in helium plasmas in the GOLEM tokamak and the TJ-II stellarator were performed. The radial profiles of the low-temperature electron group densities follow the trend of the calculated radial profiles of the electron sources arising from the ionization of neutrals in both deuterium and helium plasmas in TJ-II. The difference in the radial location where the bi-Maxwellian EEDF appears can be explained by the difference in the rate coefficients for ionization of deuterium and helium. The results of probe measurements in GOLEM and the WEST tokamak divertor, at one radial location in the SOL, are compatible with the hypothesis concerning the ionization of neutral atoms and the type of the EEDF.

Noise reduction of stochastic density functional theory for metals.

Density Functional Theory (DFT) has become a cornerstone in the modeling of metals. However, accurately simulating metals, particularly under extreme conditions, presents two significant challenges. First, simulating complex metallic systems at low electron temperatures is difficult due to their highly delocalized density matrix. Second, modeling metallic warm-dense materials at very high electron temperatures is challenging because it requires the computation of a large number of partially occupied orbitals. This study demonstrates that both challenges can be effectively addressed using the latest advances in linear-scaling stochastic DFT methodologies. Despite the inherent introduction of noise into all computed properties by stochastic DFT, this research evaluates the efficacy of various noise reduction techniques under different thermal conditions. Our observations indicate that the effectiveness of noise reduction strategies varies significantly with the electron temperature. Furthermore, we provide evidence that the computational cost of stochastic DFT methods scales linearly with system size for metal systems, regardless of the electron temperature regime.

Multi‐Instrument Analysis of the Formation and Segmentation of Tongue of Ionization Into Two Consecutive Polar Cap Patches

AbstractThis paper investigates the formation and segmentation of the tongue of ionization into two consecutive polar cap patches using multi‐instrument observations from 27 February 2014. We provide insights into how the interplanetary magnetic field (IMF) variations influence the formation and segmentation of these patches. Our findings reveal that the entry of dayside dense plasma into the polar cap is predominantly driven by the modified convection near the cusp region, which is controlled by the transition of IMF By or the sudden drop of IMF Bz. Furthermore, we observe a rapid north‐westward plasma flow within the patch segmentation region, accompanied by equatorward‐expanded and enhanced convection near the cusp region. This fast‐moving flow, approximately 1.5 km/s, is characterized by low density and high electron temperature and shows a signature of a Subauroral Polarization Stream. This suggests that the fast‐westward flow, in conjunction with the expansion and contraction of ionospheric convection, plays a crucial role in the segmentation of polar cap patches from the dayside plasma reservoir. This study provides a comprehensive observation of the evolution of polar cap patches, thereby advancing our understanding of the dynamic mechanisms governing patch formation and segmentation.