Research on the Influence of Fault Structure on Physical and Chemical Structure of Coking Coal During Spontaneous Combustion

Abstract

ABSTRACT The spontaneous combustion tendency and oxidation combustion properties of coking coal in fault fracture zone and primary coking coal are different. Accordingly, this study uses Thermogravimetric analysis, in-situ Fourier transform infrared spectroscopy, Scanning electron microscope, low-temperature N2 adsorption and Electron spin resonance techniques were used to study the difference of macroscopic and microscopic structural characteristics between coking coal and primary coking coal in fault fracture zone. The results show that: The oxygen absorption capacity of coking coal in fault fracture zone is enhanced and the thermogravimetric characteristic temperature is advanced, and the ignition point temperature is advanced by 5.36°C; the maximum weight loss temperature of coking coal in fault fracture zone is 3.32°C lower than that of primary coking coal. The apparent activation energy of coking coal in oxidation stage and pyrolytic combustion stage decreased by 4.88 and 5.03 kJ/mol, respectively. Compared with primary coking coal, the pore structure of coking coal in fault fracture zone is more complex, which increases the roughness of coal surface and is conducive to oxygen adsorption. In addition, fault tectonics promotes the separation and cracking of oxygen-containing functional groups into small molecules, and the polycondensation of aliphatic hydrocarbon structure promotes the formation of active free radicals, thus promoting spontaneous combustion. This study provides an important reference and theoretical support for further understanding of the structural evolution and oxidation kinetics of highly metamorphic coking coal induced by fault tectonics, which is helpful for fire prevention and control in fault structure-developed mining areas and safe production of coal industry.