Low Field Research Articles

A High-Power Relativistic Ka-Band Millimeter-Wave Coaxial Transit Time Oscillator With Stable Repetitive Operation at Low Guiding Magnetic Field

A High-Power Relativistic <i>Ka</i>-Band Millimeter-Wave Coaxial Transit Time Oscillator With Stable Repetitive Operation at Low Guiding Magnetic Field

Whistler‐Mode Waves Inside Short Large‐Amplitude Magnetic Field Structures: Characteristics and Generation Mechanisms

AbstractShort large‐amplitude magnetic structures (SLAMS) frequently appear near the bow shock. Inside steepening SLAMS, whistler‐mode waves are coherently generated at their leading edges. These waves are crucial for electron dynamics, energy conversion and magnetic reconnection near the shock. Nevertheless, the characteristics and generation of the whistler‐mode waves inside SLAMS are still unclear. In this study, we conducted a statistical analysis of whistler‐mode waves within SLAMS near the Earth's bow shock to investigate their properties and generation mechanisms. We found that these waves are mainly excited by electron temperature anisotropy with 99% of them falling below the nonlinear resonant threshold. The combination of a low background magnetic field and intense steepening at SLAMS' leading edge makes it the main source region of whistler‐mode waves and may induce the nonlinear resonance of whistler‐mode waves.

Fulfilling X9R specification in CeO2 modified BNBST-based relaxor ferroelectric energy storage ceramic capacitors

Future low-voltage driven capacitor devices are appealed to employ the eco-friendly ceramics featured with high-stable dielectric energy storage capabilities. Herein, the dielectric energy storage properties of (Bi0·5Na0.5)0.65(Ba0·3Sr0.7)0.35(Ti0·98Ce0.02)O3+8 wt% K0·5Na0·5NbO3+x wt% CeO2 (BNBSTCK + Cx) lead-free relaxor ferroelectric ceramics were comprehensively investigated. By maintaining the relaxor ferroelectric phases near room temperature and disrupting the ferroelectric long-range order via CeO2 additive, the EIA X9R specification was fulfilled at the best composition of x = 8 over a wide range of −74∼208 °C with a relatively high dielectric constant εr = 904 and low loss tanδ = 10−3 (@25 °C & 1 kHz). Meanwhile, the good recoverable energy storage density Wrec = 0.77 J/cm3 and high efficiency η = 91.6% were achieved only at a low electric field of 95 kV/cm. Furthermore, these ceramics exhibited exceptional frequency and cycle dependent energy storage stability, which could guide the design ideas of long-life X9R ceramic capacitors suitable for high and low working temperature environments in low-voltage driven energy storage applications.

Rapid Changes in Strength and Direction of Earth's Magnetic Field Over the Past 100,000 Years

AbstractPrevious studies of rapid geomagnetic changes have highlighted the most extreme changes in direction and field strength found in paleomagnetic field models over the past 100 ky. Here we study distributions of rates of change in both time and space. Field models based on direct observations provide the most accurate values for rates of change, but their short duration precludes a complete description of field behavior. Broader representation is provided by time‐varying paleofield models, here including GGF100k, GGFSS70, LSMOD.2, CALS10k.2, HFM.OL1.A1, pfm9k.2, and SHAWQ‐iron age although variability across models and lack of temporal and spatial resolution of fine scale variations make direct comparisons difficult. For the paleofield we define rapid changes as exceeding the peak overall value of 0.4° yr−1 for directional changes and 150 nT yr−1 for intensities as established by the gufm1 model spanning 1590–1990 CE. We find that rapid directional changes are associated with low field strength and can spread across all latitudes during such episodes. Distributions of directional rates of change exhibit high skewness for models that include excursions. Rates of change in field intensity exceeding 150 nT yr−1 arise in brief intervals during the Holocene particularly associated with the strong field Levantine Iron Age Anomaly. Around the Laschamp excursion there are also rare localized occurrences of rapid intensity change. Limitations in current models make it difficult to define absolute rates for past changes, but we see that rapid changes are essential field characteristics not observed in the modern field that should nevertheless be regarded as an essential for Earth‐like dynamo simulations.

Long-term Evolution of Relativistic Unmagnetized Collisionless Shocks

We study a relativistic collisionless electron–positron shock propagating into an unmagnetized ambient medium using 2D particle-in-cell simulations of unprecedented duration and size. The shock generates intermittent magnetic structures of increasingly larger size as the simulation progresses. Toward the end of our simulation, at around 26,000 plasma times, the magnetic coherence scale approaches λ ∼ 100 plasma skin depths, both ahead and behind the shock front. We anticipate a continued growth of λ beyond the time span of our simulation, as long as the shock accelerates particles to increasingly higher energies. The post-shock field is concentrated in localized patches, which maintain a local magnetic energy fraction ε B ∼ 0.1. Particles randomly sampling the downstream fields spend most of their time in low field regions (ε B ≪ 0.1) but emit a large fraction of the synchrotron power in the localized patches with strong fields (ε B ∼ 0.1). Our results have important implications for models of gamma-ray burst afterglows.

Spin-related negative magnetoresistance in germanium films

Herein, we report the transport properties of Ge films. The variable-range hopping transport at low temperatures (T≲50K) and thermal activation transport at high temperatures (T≳50K) are observed in our Ge films. In the different temperature regimes, the anomalous magnetotransport properties are observed. In the low-temperature regime (T≲15K), the negative magnetoresistance (MR) at low field and positive MR at high field can be seen. In the moderate-temperature regime (15K≲T≲100K), the positive MR curve gradually evolves from a linear curve to a parabolic curve with increasing temperature, and the MR magnitude appears to be insensitive to temperature. In the high-temperature regime (T≳100K), the positive MR value increases with increasing temperature. By considering the angular-dependent MR, we can determine that the negative MR comes from the spin-related mechanism, and the positive MR is caused by the orbital-related mechanism. However, further study is required to determine the exact mechanisms behind the anomalous magnetotransport properties.

Magnetism and magnetocaloric effects in tetragonal structure of RE5Ni2Sb (R = Er, Ho) compounds

In this work, the RE5Ni2Sb (RE = Er, Ho) compounds with tetragonal structure were successfully synthesized and the magnetism, magnetic phase transition and magnetocaloric effects were investigated. It was demonstrated that antiferromagnetic interaction undergoes a field-induced metamagnetic transition from antiferromagnetism to ferromagnetism in RE5Ni2Sb (RE = Er, Ho) under a magnetic field higher than 3 T. Moreover, the Er5Ni2Sb and Ho5Ni2Sb undergo an antiferromagnetic to paramagnetic magnetic phase transition at approximately 18 K and 25 K, and exhibit considerable magnetocaloric effects. The maximum magnetic entropy changes are 9.8 J/kg K and 10.6 J/kg K under varying magnetic fields of 0–5 T. Therefore, the large reversible MCE under low magnetic field change indicates the potential application of RE5Ni2Sb (RE = Er, Ho) in hydrogen liquefaction magnetic refrigerators. Prime Novelty StatementThis work investigates the synthesis, magnetism, and magnetothermal effects of R5Ni2Sb (R = Er, Ho) compounds. The R5Ni2Sb (R = Er, Ho) compounds have been demonstrated for the first time to have a potential application as magnetic refrigeration materials.

Quantum Liquid States of Spin Solitons in a Ferroelectric Spin-Peierls State.

In this study, we performed high-magnetic-field magnetization, dielectric, and ultrasound measurements on an organic salt showing a ferroelectric spin-Peierls (FSP) state, which is in close proximity to a quantum critical point. In contrast to the sparsely distributed gaslike spin solitons typically observed in conventional spin-Peierls (SP) states, the FSP state exhibits dense liquidlike spin solitons resulting from strong quantum fluctuations, even at low fields. Nevertheless, akin to conventional SP systems, a magnetic-field-induced transition is observed in the FSP state. In conventional high-field SP states, an emergent wave vector results in the formation of a spin-soliton lattice. However, in the present high-field FSP state, the strong quantum fluctuations preclude the formation of such a soliton lattice, causing the dense solitons to remain in a quantum-mechanically melted state. This observation implies the realization of a quantum liquid-liquid transition of topological particles carrying spin and charge in a ferroelectric insulator.

Effect of interstitial iron on Jc and Hc2 anisotropy and magnetic relaxation of Fe1+yTe0.6Se0.4 single crystal

For a long time, the second peak effect in FeTe0.6Se0.4 has attracted the interest of researchers. The role of interstitial iron which is unique to FeTe0.6Se0.4 compared to FeSe superconductors, in the second peak effect remains unknown. In this study, we controlled the content of interstitial iron through flowing oxygen and prolonged vacuum annealing, and subsequently conducted investigations on the magnetic flux dynamics and superconducting properties with anisotropies. After reducing the interstitial iron content, Tc increased from 12.6 K to 13.8 K. The critical current density at 4.5 K increased from 1.2×105 A/cm2 to 1.76×105 A/cm2. At low fields (H<Honset), interstitial iron as weak pinning centers can rapidly trap magnetic flux and exhibit fast relaxation through elastic motion. At high fields, strong pinning centers lead to collective pinning of magnetic flux and demonstrate a reduction in relaxation rate through plastic motion. The presence of interstitial iron hinders the transition from elastic to plastic motion for magnetic flux. Furthermore, reducing the interstitial iron expands the field range of the second peak effect and leads to a noticeable change in the pinning behavior, with a transition from δl-type to δTc-type pinning and enhances the anisotropy of the system. Finally, our study provides a reference for understanding the origin of the second peak in FeTe0.6Se0.4 and offers guidance for the practical application of FeTe0.6Se0.4.

Cationic migration effect on the dielectric and magnetic properties of CoFe2O4/ZnO composites

The present paper focusses on the effect of cationic migration in the sintered CoFe2O4/ZnO composite. The increase in lattice parameter of the CoFe2O4 after sintering indicates substitution of Zn. Mӧssbauer analysis of the samples indicates the transformation of composites to paramagnet in the sample sintered at 600 and 750 °C. At 900 °C, a low hyperfine field sextet was evolved complimented by MH loop which is due to redistribution of cations and formation of ferromagnetic phase. Maxwell-Wagner dispersion was identified by the frequency-dependent fluctuation of dielectric constants (ε׳) and dielectric loss (tan δ). Dielectric constant values of 8.66, 7.90, 9.31 and dielectric loss value of 0.11, 0.03, 0.05 were found for CZ6, CZ7 and CZ9 respectively at 1 MHz frequencies. The composite are suitable for high frequency applications due to its low loss, high resistance, low sintering temperature. The mechanisms behind these observations are discussed in this paper.

Response of maize yield and nitrogen recovery efficiency to nitrogen fertilizer application in field with various soil fertility.

Appropriate nitrogen (N) management system is essential for effective crop productivity and minimizing agricultural pollution. However, the underlying mechanistic understanding of how N fertilizer regulates crop yield via soil properties in soils with different fertilities remains unresolved. Here, we used a field experiment that spanned 3 cropping seasons to evaluate the grain yield (GY), aboveground biomass and N recovery efficiency (NRE) after treatment with five N fertilizer application rates (N0, N75, N112, N150, and N187) in soils with three levels of fertility. Our results indicated that the highest GY across low, moderate, and high fertility soils were 1.5t hm-2 (N150), 4.9t hm-2 (N187), and 5.4t hm-2 (N112), respectively. The highest aboveground biomass and NRE were observed at N150 for all three levels of soil fertility, while only the N uptake by aboveground biomass of low and high fertility soils decreased at N187, confirming that excessive N fertilization results in a further decline in crop N uptake. The relationship between GY, NRE and N fertilizer application rates fit the unary quadratic polynomial model. To achieve a balance between grain production and environmental benefits in N fertilizer, appropriate N fertilizer rates were determined to be 97.5kg hm-2, 140kg hm-2 and 131kg hm-2 for low, moderate and high fertility soils, respectively. Structural equation modeling suggested that GY was significant correlated with soil microbial biomass carbon (SMBC) and N directly in low fertility field, with SMBC directly in moderate fertility field, and via SOC and NO3 -N in high fertility field. Therefore, a soil-based management strategy for N fertilizers could enhance food security while reducing agricultural N fertilizer inputs to mitigate environmental impacts.

Improved electro‐actuation property of dielectric elastomer composites regulated by one‐dimensional CaCu3Ti4O12@TiO2 core–shell construction

AbstractDielectric elastomers (DEs) are typical electro‐active polymers that can achieve an electro‐actuated deformation under an applied electric field. However, obtaining a large low‐field‐actuated strain of DEs is still a key challenge, which is critical to their practical application range. Herein, a typical CaCu3Ti4O12@TiO2 (CCTO@TiO2) core–shell‐structured nanowires were synthesized by the micro‐emulsion method. Additionally, a series of polydimethylsiloxane (PDMS)‐based DE composites combining variable proportions of CCTO@TiO2 were prepared. The CCTO@TiO2 nanowires with the design of both decreasing dielectric constant from core to shell and a high aspect ratio can provide larger heterogeneous interfaces for the DE composites, leading to a promoted interfacial polarization. The maximum electro‐actuated strain of 37.66% is achieved from the DE composite incorporated with 20 wt% CCTO@TiO2 when subjected to a relatively low electric field of 40 V/μm, which is 14 times higher than that of pure PDMS (strain ~2.5%). Moreover, the composite exhibits the largest electro‐actuated strain (45.83%) under the electric field approaching its breakdown strength of 43.57 V/μm. The results demonstrate that the one‐dimensional core–shell nanowires have a positive effect on improving the low‐field‐actuated strain of DE composites. This research reveals an effective and feasible method to prepare the DE composites exhibiting enhanced low‐field electro‐actuated characteristics.

An Extended Kolmogorov-Avrami-Ishibashi (EKAI) Model to Simulate Dynamic Characteristics of Polycrystalline-Ferroelectric-Gate Field-Effect Transistors.

A physics-based model on polarization switching in ferroelectric polycrystalline films is proposed. The calculation results by the model agree well with experimental results regarding dynamic operations of ferroelectric-gate field-effect transistors (FeFETs). In the model, an angle θ for each grain in the ferroelectric polycrystal is defined, where θ is the angle between the spontaneous polarization and the film normal direction. Under a constant electric field for a single-crystal film with θ = 0, phenomena regarding polarization domain nucleation and wall propagation are well described by the Kolmogorov-Avrami-Ishibashi theory. Since the electric fields are time-dependent in FeFET operations and the θ values are distributed in the polycrystalline film, the model in this paper forms an extended Kolmogorov-Avrami-Ishibashi (EKAI) model. Under a low electric field, the nucleation and domain propagation proceed according to thermally activated processes, meaning that switching the time scale of a grain with the angle θ is proportional to an exponential form as exp(const./Ezcosθ) [Ez: the film-normal electric field]. Wide θ distribution makes the time response quite broad even on the logarithmic scale, which relates well with the broad switching time experimentally shown by FeFETs. The EKAI model is physics based and need not assume non-physical distribution functions in it.

Dielectric properties and excellent energy storage density under low electric fields for high entropy relaxor ferroelectric (Li0.2Ca0.2Sr0.2Ba0.2La0.2)TiO3 ceramic

High entropy relaxor ferroelectrics, are a representative type of dielectric with exceptional properties and play an indispensable role in the next-generation pulsed power capacitor market. In this paper, a high-entropy relaxor ferroelectric ceramic (Li0.2Ca0.2Sr0.2Ba0.2La0.2)TiO3 successfully designed and synthesized using the traditional solid-state reaction method. The microstructure, dielectric properties, and energy storage characteristics of the ceramics were systematically investigated. The ceramic exhibited a dense microstructure with a single-phase perovskite structure and small grain size. The unique microstructure and high insulation not only wides the band gap, but also minimizes residual polarization and resulting in higher energy density (Eb) 1.51 J/cm3 and efficiency (η) of 89.6% at a low field strength of 260 kV/cm. Furthermore, the observed anomalous behavior in dielectric relaxation was explained within the context of high entropy ceramics. The material also exhibited excellent temperature/frequency stability and fast charging-discharging speed (∼35 ns). These results demonstrate the effectiveness of high entropy strategy to develop high-performance energy storage capacitors.

Low-Field-Driven Superior Energy Storage Effect with Excellent Thermal Stability by Constructing Coexistent Glasses.

In this work, we found that the defreezing coexistent glassy ferroelectric states hold significant potential for achieving superior energy storage performance, especially under low fields, by using phase field simulations and experimental approaches. A remarkable room-temperature energy recoverable storage density Wr exceeding 2.7 J/cm3 with a high efficiency η surpassing 80% under a low electric field of 170 kV/cm was obtained in the x = 6-12% compositions of x[Bi(Mg2/3Nb1/3)O3]-(1-x)[0.94(Bi0.5Na0.5)TiO3-0.06BaTiO3-1%MnO2] (BNBT-BMN) ceramics due to the combination of low Pr and high Pm of the coexistent ferroelectric glasses. Intriguingly, the superior Wr and η of the coexistent state of glasses can also be maintained in a wide temperature range of 293-430 K, indicating the excellent thermal stability of the energy storage behavior. Importantly, the Wr and η of this glass coexistent composition increase upon heating from room temperature to 360 K due to the defreezing process, leading to maximum Wr ∼ 2.9 J/cm3 with high efficiency η ∼ 90% of x = 10% at 360 K. When considering both energy storage behavior and thermal stability under low fields (<250 kV/cm), the BNBT-BMN ceramics outperform nearly all lead-free counterparts available today. Consequently, our work not only expands the research scope of ferroic glasses but also establishes a new paradigm for developing superior lead-free dielectrics suitable for high-temperature energy storage devices.

Bridging the gap: improving correspondence between low-field and high-field magnetic resonance images in young people.

Portable low-field-strength magnetic resonance imaging (MRI) systems represent a promising alternative to traditional high-field-strength systems with the potential to make MR technology available at scale in low-resource settings. However, lower image quality and resolution may limit the research and clinical potential of these devices. We tested two super-resolution methods to enhance image quality in a low-field MR system and compared their correspondence with images acquired from a high-field system in a sample of young people. T1- and T2-weighted structural MR images were obtained from a low-field (64mT) Hyperfine and high-field (3T) Siemens system in N = 70 individuals (mean age = 20.39 years, range 9-26 years). We tested two super-resolution approaches to improve image correspondence between images acquired at high- and low-field: (1) processing via a convolutional neural network ('SynthSR'), and (2) multi-orientation image averaging. We extracted brain region volumes, cortical thickness, and cortical surface area estimates. We used Pearson correlations to test the correspondence between these measures, and Steiger Z tests to compare the difference in correspondence between standard imaging and super-resolution approaches. Single pairs of T1- and T2-weighted images acquired at low field showed high correspondence to high-field-strength images for estimates of total intracranial volume, surface area cortical volume, subcortical volume, and total brain volume (r range = 0.60-0.88). Correspondence was lower for cerebral white matter volume (r = 0.32, p = 0.007, q = 0.009) and non-significant for mean cortical thickness (r = -0.05, p = 0.664, q = 0.664). Processing images with SynthSR yielded significant improvements in correspondence for total brain volume, white matter volume, total surface area, subcortical volume, cortical volume, and total intracranial volume (r range = 0.85-0.97), with the exception of global mean cortical thickness (r = 0.14). An alternative multi-orientation image averaging approach improved correspondence for cerebral white matter and total brain volume. Processing with SynthSR also significantly improved correspondence across widespread regions for estimates of cortical volume, surface area and subcortical volume, as well as within isolated prefrontal and temporal regions for estimates of cortical thickness. Applying super-resolution approaches to low-field imaging improves regional brain volume and surface area accuracy in young people. Finer-scale brain measurements, such as cortical thickness, remain challenging with the limited resolution of low-field systems.

Impact of local plastic deformation on thermo-magnetic instability of high-J c Nb3Sn strand

The future fusion reactor devices built by Institute of Plasma Physics, Chinese Academy of Science will be a compact burning plasma facility to fill the gap between ITER and the China Fusion Engineering Test Reactor, with the mission of studying the deuterium–tritium plasma in steady-state operation. The winding-package (WP) of its toroidal field coil is graded into high-field WP and low-field WP, and the high critical current density (J c) Nb3Sn strand will be applied to the high-field WP based on the current design. The thermo-magnetic instability is the main issue in the application of high-J c Nb3Sn strand, which may induce premature quenching in the low field regions. This issue can be improved by reducing the effective filament diameter (d eff) to suppress flux jumps and increasing the residual resistivity ratio (RRR) to enhance the release of heat generated by flux jumps. However, in the conductor manufacturing process, local plastic deformations (indentation) of strands can impact the sub-element layout and degrade the RRR of the strand, which would increase again the risk on instability. In this study, magnetization measurements and V–I tests were performed on samples with different indentation depths. The hysteresis loss and d eff of the indented sample was obtained from the test results. The impact of local plastic deformation on the thermo-magnetic instability of two types of Nb3Sn strand was confirmed by cross-sectional metallographic observation and quantitative microstructure analysis. It was shown that flux jumps were suppressed at indentation depths below 0.3 mm. Further indentation increase leads to severe flux jumps.

Large low-field magnetocaloric performances of the ErCu1.95T0.05Si2 (T = Mn, Fe, Co and Ni) compounds

Magnetocaloric materials are at the heart of magnetic refrigeration (MR) technology. However, there is a scarcity of materials with a large magnetocaloric effect (MCE) at magnetic fields below 2 T. To address this limitation, we investigate the effect of doping in the ErCu2Si2 compound with relatively inexpensive neighboring atoms of Mn, Fe, Co, and Ni in the Cu position, respectively. The results show a significant enhancement in the MCE at low fields. Under the magnetic field change of 0–2 T, the values of maximum magnetic entropy change (−ΔSMmax) for the ErCu1.95T0.05Si2 (T = Mn, Fe, Co and Ni) compounds are 16.4 J/kg·K, 17.5 J/kg·K, 17.8 J/kg·K, and 18.6 J/kg·K, respectively. Compared to those of the parent compound ErCu2Si2, the −ΔSMmax of the ErCu1.95T0.05Si2 (T = Mn, Fe, Co and Ni) compounds exhibit enhancements of 3%, 11%, 13%, and 17%, respectively. Additionally, the magnetic transition temperatures of these doped compounds are lower than that of the parent compound ErCu2Si2, occurring below 2 K. Therefore, ErCu1.95T0.05Si2 (T = Mn, Fe, Co and Ni) compounds with large low-field MCE and negligible loss of hysteresis have the potential to serve as candidate materials for cryogenic magnetic refrigeration.

Numerical simulations for thermally developed double diffusion flow of nanoparticles due to elongated cylinder with multiple slip effects: Applications to energy storage system

Based on peak thermal performances of nanofluid, different mathematical models are developed. In current analysis, the investigation for heat and mass transfer phenomenon associated to the magnetized nanofluid is examined. The analysis for heat transfer is addressed with applications of radiative phenomenon. The multiple slip effects are entertained for governing problem. The cause of induced flow is stretched cylinder. Mathematical model is solved shooting scheme. The validation for predicted results is presented to justify the solution. The analysis is observed for specific range of parameters like 0 ≤ M ≤ 1.5 , 0 ≤ γ ≤ 0.6 , 0 ≤ S ≤ 0.3 , 0 ≤ R ≤ 0.5 , 0 ≤ Nt ≤ 0.4 , 0.5 ≤ A ≤ 2 , and 0.2 ≤ B ≤ 0.8 . The significance of thermally entertained nanofluid problem is physically inspected. It is evaluated that heat and mass transfer enhances due to curvature parameter. Low concentration field is examined for solutal stratification parameter. The obtained results present applications in enhancing thermal efficiency of solar systems, energy applications, heat transfer devices, chemical processes, cooling phenomenon, etc.

Magnetic properties and cryogenic magnetocaloric effect of pyrochlore structure RE2Ti2O7 (RE = Gd, Tb, and Ho) compounds

Magnetic refrigeration technology is regarded as one of the ideal solutions for cryogenic refrigeration, while magnetocaloric materials are the crucial ones. A series of polycrystalline RE2Ti2O7 (RE = Gd, Tb, and Ho) compounds were prepared by a simple one-step solid-phase reaction method in the atmosphere. The crystal structure, magnetic properties, and magnetocaloric effect (MCE) of these compounds were systematically investigated. Crystallographic research indicates that these compounds crystallized in a pyrochlore structure. Meanwhile, magnetic measurements illustrate that this class of pyrochlore oxides is highly frustrated magnetic materials and exhibits complex magnetic behavior. In addition, under the field change of 0–1 T, the values of the maximum magnetic entropy change (−ΔSMmax) and the refrigeration capacity are calculated to be 0.9 and 5.8 J/kg for Gd2Ti2O7, 9.0 and 32.9 J/kg for Tb2Ti2O7, 9.9 and 29.9 J/kg for Ho2Ti2O7, respectively. Therefore, RE2Ti2O7 (RE = Tb and Ho) pyrochlores exhibit excellent MCEs under low magnetic fields, providing candidate materials for the application of cryogenic magnetic refrigeration technology.