Abstract

The present paper focusses on the effect of cationic migration in the sintered CoFe2O4/ZnO composite. The increase in lattice parameter of the CoFe2O4 after sintering indicates substitution of Zn. Mӧssbauer analysis of the samples indicates the transformation of composites to paramagnet in the sample sintered at 600 and 750 °C. At 900 °C, a low hyperfine field sextet was evolved complimented by MH loop which is due to redistribution of cations and formation of ferromagnetic phase. Maxwell-Wagner dispersion was identified by the frequency-dependent fluctuation of dielectric constants (ε׳) and dielectric loss (tan δ). Dielectric constant values of 8.66, 7.90, 9.31 and dielectric loss value of 0.11, 0.03, 0.05 were found for CZ6, CZ7 and CZ9 respectively at 1 MHz frequencies. The composite are suitable for high frequency applications due to its low loss, high resistance, low sintering temperature. The mechanisms behind these observations are discussed in this paper.

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