Local Transition Research Articles

Functionally varied negative-stiffness metamaterial core sandwich structures with three-phase bending deformation

Abstract This paper introduces a novel class of negative-stiffness (NS) core sandwich composite structures that exhibit unique mechanical performance, including shape recovery, superelasticity, and energy absorption (EA) in bending and shear mode. The core of these structures consists of a periodic cellular arrangement of double-curved beams that undergo consecutive local snap-buckling transitions between multiple equilibrium states, enabling the structures to change shape reversibly between their initial and deformed configurations. To characterize the force-displacement relationship of the core, a comprehensive analysis was conducted using a combination of 3D printed models and finite-element simulations. The metamaterial core with gradient-thickness negative-stiffness beams were examined under uniform compression, demonstrating that the snap-through behavior of the curved beams was intricately controlled by the beam thickness in each row. The numerical simulations accurately predicted the deformation characteristics of the graded cellular core, supporting the design of a metamaterial core with functionally varied beam thickness for nonuniform transverse loading. This led to spatially controlled NS core material with specific EA of around 50 J kg−1 and an apparent core shear strength of 0.1 MPa, all mainly within the reusable elastic regime. The resulting sandwich structures efficiently mitigated the localized effect from concentrated compressive forces and achieved complete snap-through buckling in all curve beams. Three-point bending response revealed three distinct phases of flexural deformation: the local facial bending phase, the sequential core-snapping superelastic phase, and the global bending phase.

Business Character Implementation Strategy for The Community of Teluk Patipi District

This research focuses on evaluating the preparedness of the inhabitants of Patipi Pasir village and its vicinities within East Fakfak district to cultivate their entrepreneurial spirit. The pivotal aim is to harness their potential in managing local natural resources effectively, thereby contributing significantly to the economic acceleration of the Fakfak district. Employing a descriptive research methodology, the study utilizes a semi-qualitative analysis method, with the gap analysis technique depicted through a fishbone diagram to pinpoint areas requiring improvement. Moreover, the strategic implementation for nurturing business character among the local populace is devised through the innovative use of the Ishikawa diagram, integrated with the Balanced Score Cards approach, providing a comprehensive framework for development. The findings reveal that the Patipi Bay District boasts considerable human resource potential that, if adequately nurtured, can lead to the effective management of its natural resources into sustainable businesses. The study underscores the necessity of developing a robust entrepreneurial ecosystem that supports the local community's transition towards sustainable economic practices. This entails providing adequate training, resources, and support systems to empower the community, ensuring they are well-equipped to capitalize on the intrinsic value of their natural resources. Through strategic planning and targeted development programs, the research envisions transforming the Patipi Bay District into a model for sustainable business development, leveraging its natural assets for long-term economic prosperity

Effect of Ce2O3 phase transition on the catalytic oxidation for toluene over CeO2 catalysts

Cerium oxide was a potential replacement for precious metals as a catalyst for VOCs. Here, we prepared CeOx-350, CeOx-450, CeOx-550 and CeOx-650 catalysts by controlling the calcination temperature, the occurrence of Ce2O3 localized phase transitions at CeOx-350 and CeOx-550 was confirmed by XRD, HRTEM and TGA. This localized phase transition caused the change in specific surface area and crystallinity, and prolonged the Ce-O-Ce bond lengths at the heterogeneous interfaces, enhancing the redox capacity and activity of oxygen species. CeOx-550 exhibited the optimal low-temperature activity towards toluene due to the highest Ce3+ content, oxygen vacancy content and the best activity of reactive oxygen species. The oxidation of toluene experienced intermediates of benzyl alcohol, benzaldehyde, benzoate, maleic acid and carbonates. Among them, benzoic acid was the decisive step in the toluene oxidation pathway. Combined with the reaction pathway of toluene, the reaction stages of different oxygen species were determined. The active oxygen species located at the heterogeneous interface would serve as an adsorption site for toluene. The Ce2O3 phase would participate in the deep oxidation of toluene as an active site, which was equivalent to the oxygen vacancies. This study was conducted to explore the effect of local phase transition on catalytic activity, which provided a new strategy for the synthesis of highly active cerium oxide catalysts.

Nano-scale corrosion mechanism of T91 steel in static lead-bismuth eutectic: A combined APT, EBSD, and STEM investigation

T91 steel is a candidate material for structural components in lead-bismuth-eutectic (LBE) cooled systems, for example fast reactors and solar power plants [1]. However, the corrosion mechanisms of T91 in LBE remain poorly understood. In this study, we have analysed the static corrosion of T91 in liquid LBE using a range of characterisation techniques at increasingly smaller scales. A unique pattern of liquid metal intrusion was observed that does not appear to correlate with the grain boundary network. Upon closer inspection, electron backscatter diffraction (EBSD) reveals a change in the morphology of grains at the LBE-exposed surface, suggesting a local phase transition. Energy dispersive X-ray (EDX) maps show that Cr is depleted in the T91 material near the LBE interface. Furthermore, we observed the dissolution of all Cr-enriched precipitates in this region. Although the corrosion is conducted in an oxygen deficient environment, both scanning transmission electron microscopy (STEM) and atom probe tomography (APT) reveal a thin surface oxide layer (presumably wüstite) at the LBE-steel interface. Using electron energy loss spectroscopy (EELS) in the STEM, as well as APT, the atomic scale elemental redistribution and 3D morphology of the corrosion interface is investigated. By combining results from these different techniques, several types of oxide phases and structures can be identified. Based on this detailed nano-scale information, we propose potential mechanisms of T91 corrosion in LBE.

Introduction to this special section: Gravity, electrical, and magnetic methods

Geophysics plays an important role in all aspects of geologic analysis, spanning from regional exploration and tectonic mapping to local prospect-level studies and energy transition projects. Out of a variety of geophysical techniques, seismic methods often play the most central role, while less expensive nonseismic methods are less frequently applied. One of the objectives of SEG's Gravity and Magnetics Committee is to promote nonseismic geophysical methods and showcase their value in various geologic applications. As members of that committee, we, the editors of this special section, assert that gravity, magnetic, and electrical methodologies are powerful yet often undervalued tools. We present this special section focused on nonseismic geophysical methods and the impact they can make on various geoscience projects. Included here are a regional tectonic study in Antarctica, a local mining exploration mapping project in Canada, and an analytical methodology capable of providing critical information about subsurface geology and helping to determine the depths of important geologic structures. Although our scope is to provide a broader discussion of different types of nonseismic techniques, all of the papers presented in this special section focus on magnetic surveying.

Origin of discrete donor–acceptor pair transitions in 2D Ruddlesden–Popper perovskites

Two-dimensional (2D) van der Waals nanomaterials have attracted considerable attention for potential use in photonic and light–matter applications at the nanoscale. Thanks to their excitonic properties, 2D perovskites are also promising active materials to be included in devices working at room temperature. In this work, we study the presence of very narrow and spatially localized optical transitions in 2D lead halide perovskites by μ-photoluminescence and time-decay measurements. These discrete optical transitions are characterized by sub-millielectronvolt linewidths (≃120μeV) and long decay times (5–8 ns). X-ray photoemission and density-functional theory calculations have been employed to investigate the chemical origin of electronic states responsible of these transitions. The association of phenethylammonium with methylammonium cations into 2D Ruddlesden–Popper perovskites, (PEA)2(MA)n−1PbnI3n+1, particularly in phases with n≥2, has been identified as a mechanism of donor–acceptor pair (DAP) formation, corresponding to the displacement of lead atoms and their replacement by methylammonium. Ionized DAP recombination is identified as the most likely physical source of the observed discrete optical emission lines. The analysis of the experimental data with a simple model, which evaluates the Coulombic interaction between ionized acceptors and donors, returns a donor in Bohr radius of the order of ≃10 nm. The analysis of the spectral and electronic characteristics of these single donor–acceptor states in 2D perovskites is of particular importance both from the point of view of fundamental research, as well as to be able to link the emission of these states with new optoelectronic applications that require long-range optically controllable interactions.

First-order localization and quantum phase transition induced by quasicrystal imaginary domain

First-order localization and quantum phase transition induced by quasicrystal imaginary domain

Manipulation of Weyl Points in Reciprocal and Nonreciprocal Mechanical Lattices.

We introduce feedback-measurement technologies to achieve flexible control of Weyl points and conduct the first experimental demonstration of Weyl type I-II transition in mechanical systems. We demonstrate that non-Hermiticity can expand the Fermi arc surface states from connecting Weyl points to Weyl rings, and lead to a localization transition of edge states influenced by the interplay between band topology and the non-Hermitian skin effect. Our findings offer valuable insights into the design and manipulation of Weyl points in mechanical systems, providing a promising avenue for manipulating topological modes in non-Hermitian systems.

Quadrupole excitation of atoms with tightly focused Laguerre-Gaussian beams.

This article investigates the quadrupole excitation of a trapped atom exposed to the tightly focused Laguerre-Gaussian (LG) beams with parallel and antiparallel spin angular momentum (SAM) and orbital angular momentum (OAM) under nonparaxial conditions. The Rabi frequency profile of allowed quadrupole transition channels, modified by SAM and OAM interaction, in the focal plane is provided. In the case of antiparallel SAM and OAM, the excitation probability undergoes substantial modification due to the considerable contribution of longitudinal intensity variations in tightly focused condition. The findings offer insights into controlling localized atom transition, including OAM transfer, with potential applications in qudit-based technologies.

Beyond scalable impacts: Roles of mobility experiments in local transition governance

The impact of short-term, localized real-world experiments on sustainable change is debated. Our analysis of three mobility experiments shows that even in the absence of quantifiable results, these experiments are still perceived as successful. By highlighting the underlying collective discursive strategies, we emphasize the different roles of experimentation in local mobility transitions and the importance of social learning and collective understanding in urban experimentation.In this article, we explore the role of real-world experiments in local transition governance, focusing on the negotiation between measurable impacts and the evaluation of localized, tangible outcomes. In our qualitative comparative analysis, we examine three distinct mobility experiments aimed at advancing sustainable transformation in mobility and urban planning, namely the co-creative research project City2Share in Munich, the political program of the Superblocks in Barcelona, and the real-world test bed for automated shuttles Digibus Austria in Koppl near Salzburg. Despite the structural limitations of the temporal, spatial, and legal framework and the uncertainties in measuring the impact, all experiments were presented as successful. This success was negotiated and re-framed via five discursive strategies: mobilizing citizen engagement, highlighting small achievements, manifesting institutional embedding, generating political momentum, and delegating responsibility. As we argue, success and scaling are not just the result of scientific proof, but also a matter of negotiating the political issues raised by the experiment.

Harnessing EU legal concepts for the energy transition on islands

Abstract The European Commission plans to achieve the decarbonization of dozens of European Union (EU) islands by 2030. This would reduce greenhouse gas emissions, lower the dependency of islands on imported fuels, and potentially reduce local energy prices. At the same time, it may accelerate the mainland’s own energy transition through the import of surplus energy from renewable sources, the provision of aggregated flexibility services, and the testing of both technologies and policies on islands for replication and adaptation on the continent. Although islands are not even a legal category per se in EU energy law, the existing legal framework already allows to harness various concepts to foster the energy transition of EU islands. This article reviews available legal qualifications and regimes such as small systems’ exemptions, energy communities, positive energy districts, and local flexibility markets in the context of the decarbonization of EU islands. Potentially, they could open many different ways to tailor local energy transitions, channelling local actions to accelerate the whole process.

The forgotten bread oven: local bakeries, forests and energy transition in Nigeria

The forgotten bread oven: local bakeries, forests and energy transition in Nigeria

Single-particle excitations across the localization and many-body localization transition in quasiperiodic systems

Single-particle excitations across the localization and many-body localization transition in quasiperiodic systems

The role of Ca/Zr ratio on the local structure and phase transitions in lead-free (Ba,Ca)(Zr,Ti)O3

In this study, the structural phase transitions are investigated as a function of composition and temperature for polycrystalline x(Ba0.7Ca0.3)TiO3-(1 − x)Ba(Zr0.2Ti0.8)O3 (x = 0.40, 0.45, 0.50, 0.55, and 0.60) through a combination of Raman spectroscopy, synchrotron X-ray diffraction, and dielectric spectroscopy. The aim is to gain insight into the complex phase boundary region responsible for the excellent electromechanical properties. The results demonstrate the correlation between local site substitutions based on the stoichiometric variations to the microstructure and dielectric properties. The dielectric response has been correlated with the BCT/BZT content displaying a maximum depending on the phase content. Additionally, in situ temperature-dependent Raman, permittivity, and pair distribution function (PDF) studies were performed from −60 °C to 130 °C to highlight the structure and phase evolution. In particular, the in situ temperature-dependent Raman measurements reveal sudden discontinuities in the vibrational modes that correspond to the structural changes in the perovskite structure. Therefore, the results of the permittivity response, based on the average of a large volume, are consistent with the local structural changes obtained by other techniques. Indeed, correlations of Raman, X-ray diffraction, and PDFs obtained from synchrotron X-ray total scattering data, along with permittivity measurements allowed the identification of the discrete ferro- to paraelectric phase transitions and a more robust characterization. The rotation and distortion of the octahedral caused by oxygen displacement are driving forces behind symmetry changes and phase transitions, explaining the mechanism of polymorphic phase transition based on A- and B-site substitution. Therefore, this work provides a comprehensive understanding of temperature and composition-dependent phase transitions in BCZT.

A significant increase in carrier concentration in TiO2 by Sm doping

Sm-doped TiO2 thin films were synthesized by pulsed laser deposition. The luminescence and donor-generation properties of thin films annealed at various temperatures were investigated. The results showed that Sm-related emissions occurred in the temperature range 500 °C–800 °C. The donor densities in this temperature range were two orders of magnitude higher than that of the undoped TiO2 thin film. The effect of annealing within the temperature window indicates a local fine structural transition of the ligands around Sm3+ ions from T d symmetry to the lower C 4v one; these ions are effective luminescence centers in TiO2:Sm thin films. This local structural distortion also increases defect generation, and this increases the donor density in the same temperature region.

Microstructure Characterization and Mechanical Properties of Polymer‐Derived (HfxTa1−x)C/SiC Ceramic Prepared upon Field‐Assisted Sintering Technique/Spark Plasma Sintering

The high‐temperature microstructural evolution and mechanical properties of two SiC‐based polymer‐derived ceramics with different Hf:Ta molar ratios are investigated using electron microscopy techniques and manipulated by nanoindentation. The as‐pyrolyzed ceramic powder consists of an amorphous Si(HfxTa1−x)C(N,O) structure (where x = 0.2, 0.7) with localized nanocrystalline transition metal carbides (TMCs). Subsequent application of the field‐assisted sintering technique (FAST) for high‐temperature consolidation results in a crystalline (HfxTa1−x)C/SiC ultra‐high temperature ceramic nanocomposite. The microstructure contains powder particle‐sized grains and sinter necks between the former powder particles. The powder particles consist of a β‐SiC matrix and small TMCs. Large TMCs are observed on the internal surfaces of former powder particles. This is due to the pulsed direct current and the resulting Joule heating that facilitates diffusion as well as oxygen impurities. Sinter necks of large β‐SiC grains form during the FAST process. The microstructural regions are assessed using high‐throughput nanoindentation. The hardness for SiC/(Hf0.7Ta0.3)C is measured on the formed grains and the sinter necks giving mean hardness values of about 27 and 37 GPa, respectively.

Prerequisite-Enhanced Category-Aware Graph Neural Networks for Course Recommendation

The rapid development of Massive Open Online Courses (MOOCs) platforms has created an urgent need for an efficient personalized course recommender system that can assist learners of all backgrounds and levels of knowledge in selecting appropriate courses. Currently, most existing methods utilize a sequential recommendation paradigm that captures the user’s learning interests from their learning history, typically through recurrent or graph neural networks. However, fewer studies have explored how to incorporate principles of human learning at both the course and category levels to enhance course recommendations. In this article, we aim at addressing this gap by introducing a novel model, named Prerequisite-Enhanced Catory-Aware Graph Neural Network (PCGNN), for course recommendation. Specifically, we first construct a course prerequisite graph that reflects the human learning principles and further pre-train the course prerequisite relationships as the base embeddings for courses and categories. Then, to capture the user’s complex learning patterns, we build an item graph and a category graph from the user’s historical learning records, respectively: (1) the item graph reflects the course-level local learning transition patterns and (2) the category graph provides insight into the user’s long-term learning interest. Correspondingly, we propose a user interest encoder that employs a gated graph neural network to learn the course-level user interest embedding and design a category transition pattern encoder that utilizes GRU to yield the category-level user interest embedding. Finally, the two fine-grained user interest embeddings are fused to achieve precise course prediction. Extensive experiments on two real-world datasets demonstrate the effectiveness of PCGNN compared with other state-of-the-art methods.

Low voltage grid resilience: Evaluating electric vehicle charging strategies in the context of the grid development plan Germany

The ongoing transition to decentralized renewable energy sources and sector-coupled consumers is reshaping the energy system. Changes at lower grid levels can stress lines and transformers. Crucial for a successful local energy transition are grid relief measures. Battery electric vehicles contribute to higher loads on grid equipment but also offer flexibility. This paper assesses the influence of four different charging strategies for battery electric vehicles across five representative low-voltage grids based on the grid development plan in Germany for the years 2021, 2037, and 2045. Results indicate that grid stress, specifically capacity stress, will emerge by 2037 and 2045. Decentralized photovoltaic systems are the primary contributors to this stress due to high simultaneous generation. Up to nearly 20% of photovoltaic power may need to be curtailed in 2045, especially in rural grids during the summer, to prevent overloads.Charging strategies linked to wholesale power market prices can inadvertently lead to higher consumption-induced grid overloads, necessitating the consideration of local grid restrictions. Implementing grid-friendly charging strategies, such as reduced charging power or alignment with local photovoltaic production, can mitigate those grid overloads from almost 8% down to 0.11%. However, these charging strategies have limited impact on photovoltaic-induced overloads due to the low number of connected battery electric vehicles during the day.In summary, appropriate charging strategies can ease low-voltage grid stress and are suitable measures to manage the challenges of decentralized energy transition and battery-electric vehicle adoption.

Localized Dynamics in the Floquet Quantum East Model.

We introduce and study the discrete-time version of the quantum East model, an interacting quantum spin chain inspired by simple kinetically constrained models of classical glasses. Previous work has established that its continuous-time counterpart displays a disorder-free localization transition signaled by the appearance of an exponentially large (in the volume) family of nonthermal, localized eigenstates. Here we combine analytical and numerical approaches to show that (i)the transition persists for discrete times, in fact, it is present for any finite value of the time step apart from a zero measure set; (ii)it is directly detected by following the nonequilibrium dynamics of the fully polarized state. Our findings imply that the transition is currently observable in state-of-the-art platforms for digital quantum simulation.

Dynamical localization transition in the non-Hermitian lattice gauge theory

Local constraint in the lattice gauge theory provides an exotic mechanism that facilitates the disorder-free localization. However, the understanding of nonequilibrium dynamics in the non-Hermitian lattice gauge model remains limited. Here, we investigate the quench dynamics in a system of spinless fermions with nonreciprocal hopping in the Z2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${{\\mathbb{Z}}}_{2}$$\\end{document} gauge field. By employing a duality mapping, we systematically explore the non-Hermitian skin effect, localization-delocalization transition, and real-complex transition. Through the identification of diverse scaling behaviors of quantum mutual information for fermions and spins, we propose that the non-Hermitian quantum disentangled liquids exist both in the localized and delocalized phases, the former originates from the Z2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${{\\mathbb{Z}}}_{2}$$\\end{document} gauge field and the latter arises from the non-Hermitian skin effect. Furthermore, we demonstrate that the nonreciprocal dissipation causes the flow of quantum information. Our results provide valuable insights into the nonequilibrium dynamics in the gauge field, and may be experimentally validated using quantum simulators.