Leaf Ash Research Articles

Eco-Friendly Concrete with Improved Properties and Structure, Modified with Banana Leaf Ash

The reduction of carbon footprint, the recycling of agricultural waste, and the development of novel environmentally friendly building materials are urgent matters that necessitate innovative solutions. The objective of this study is to explore the feasibility of utilizing banana leaf ash (BLA) as a partial substitute for cement in conventional density concrete technology. The BLA-modifying additive was produced under laboratory conditions. Its chemical, phase and granulometric composition was assessed. To determine the degree of effectiveness of BLA, eight concrete compositions were developed, where the BLA content varied from 0% to 14% with an interval of 2%. The properties of fresh concrete, such as density and slump, as well as compressive strength, flexural strength, water absorption, and microstructure of hardened concrete, were studied. It has been determined that the BLA additive exhibits pozzolanic activity, with a SiO2 content of 50.83%. It is recommended that the replacement of cement with BLA does not exceed 10% for optimal results. Concrete modified with 6% BLA had the best properties and structure. The study revealed a significant 7.42% increase in compressive strength, a 7.01% increase in flexural strength, and a notable 9.28% decrease in water absorption. Thus, the obtained result proves the possibility of using BLA as a modifying additive in the technology of cement composites. The developed concrete has improved properties and is a more environmentally friendly building material than conventional concrete.

Effects of bamboo leaf ashes on concrete compressive strength, water absorption, and chloride penetration

Bamboo leaves are an agro-waste from the bamboo industry that carries a significant environmental impact, primarily due to its phytotoxic activity. In this paper the pozzolanic potential of bamboo leaf ashes are assessed. Bamboo leaves were calcined at five different temperatures - 500, 600, 700, 900, and 1000 °C. The obtained ashes were characterized using X-ray diffraction, X-ray fluorescence, differential thermal gravimetric analysis, Modified Chapelle's method, and Pozzolanic Activity Index. The ash calcined at 600 °C, exhibiting the highest pozzolanic activity, was used in concrete production as a partial replacement for Portland cement at levels of 5 %, 10 %, and 15 %. Concrete compressive strength, water absorption, and chloride diffusivity were assessed. The results indicate that the use of BLA significantly improves the concrete performance, increasing 28-day compressive strength by up to 18 % and reducing the non-steady state chloride penetration by up to 71.2 %. Overall, the use of bamboo leaf ashes obtained at 600 °C leads to significant improvements in mechanical and durability-related properties of concrete, indicating the viability of using this agro-waste as a supplementary cementitious material.

Strength characteristics of Cocoa Leaf Ash (CLA) blended cement Laterized concrete

Strength characteristics of Cocoa Leaf Ash (CLA) blended cement Laterized concrete

Towards sustainable construction: Strength and microstructural assessment of Dillenia suffruticosa and Acacia auriculiformis leaf ash as novel supplementary cementitious materials

Researchers are exploring local, recycled, and waste materials for construction to address environmental concerns. Concrete heavily depends on cement, contributing to energy consumption and greenhouse gas emissions. Substituting cement with alternatives like recycled materials can cut energy use and minimize the environmental impact on concrete production. This research represents the first investigation into using Dillenia Suffruticosa (DS) and Acacia Auriculiformis (AA) leaf ash as sustainable alternatives to cement in producing eco-friendly mortar, an area that other researchers have not previously explored. The study aims to investigate using DS and AA leaf ash as sustainable alternatives to cement in mortar production. In this study, the incorporation of DS and AA leaf ash as a partial replacement for cement was systematically varied in increments of 5 %, ranging from 5 % to 40 % of the total mortar volume. The ash was systematically incorporated into the mortar in increments of 5 %, ranging from 5 % to 40 % of the total mortar volume. The study further conducted a comprehensive investigation into the physical properties of the mortar, including consistency, bulk density, dry density, water absorption, and flow characteristics, alongside an analysis of its compressive strength. Microstructural behaviour was assessed using scanning electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy and thermogravimetric analysis to provide a comprehensive analysis. Results indicate that the enhancement in compressive strength of DS ash specimens, relative to AA ash, ranged from 1.32 % to 24.49 % at 7 days, 5.81 %–16.86 % at 14 days, and 1.87 %–11.91 % at 28 days. Furthermore, the highest enhancement in compressive strength is observed with a composition containing 10 % DS ash and 5 % AA ash content, underscoring the superior performance of DS ash compared to AA ash. The mineralogical characteristics of DS and AA leaf ashes illustrate their effectiveness as supplementary cementitious materials in sustainable construction. The significant advantages of using DS and AA leaf ash as a cement substitute are environmental sustainability, innovative materials use, and contribution to sustainable construction.

Environmental assessment of alkali-activated materials based on agro-industrial waste as alkaline activators through leaching tests

Global circular economy drives the development of sustainable alkali activated materials (AAM) for use as construction material from industrial by-products and wastes. The assessment of the potentially hazardous substances release of these new material combinations into the soil and groundwater over time is essential. In this study, the aim is the environmental assessment of three AAMs based on blast furnace slag (BFS), activated with almond shell biomass ash (ABA) as potassium source and three solid sources of silica from the agricultural industry, rice husk ash (RHA), spent diatomaceous earth (SDE) and bamboo leaf ash (BLA), using European horizontal leaching tests proposed for construction materials, for monolithic form, Dynamic Surface Leaching Test (DSLT) and for granular form, Up-flow Percolation Test and the Compliance leaching test, by simulating different scenarios of their entire life cycle. The leaching results of the AAM showed the effectiveness of the inertization of all the recycled materials studied, which exceeded some inert materials limits, by means of the activation process. Despite the absence of significant differences in the leaching mechanisms of the oxyanions As, Cr, Mo, Sb, Se and V between the three AAMs developed, they presented different long-term leaching behavior depending on their form, monolithic, or granular, and therefore in their different life cycle stages. Therefore, it is concluded that although the incorporation of agro-industrial waste as alternative activators in BFS based AAM according to the Dutch Soil Quality Decree (for unrestricted use of monolithic and granular materials) is an environmentally acceptable option, the design of waste derived AAMs should be assessed by means of a combination of leaching tests that cover their expected life cycle.

Consequential life cycle assessment of bamboo leaf ash generation: A Brazilian context

The potential of biomass growth, such as from bamboo leaves, as a source of electricity provides an optimistic scenario for the sustainable development of new green building materials. To validate robust life cycle inventory (LCI) data for incoming high-quality silica sources for cementitious materials, a consequential life cycle assessment (CLCA) on the bamboo leaves ash (BLA) with a prospective approach was conducted. The LCI data was collected in Southeastern Brazil with a prospective maturity in biomass electricity system. The data was gathered by analyzing the various stages involved in the production of BLA, including bamboo cultivation, leaf collection, cogeneration, raw BLA beneficiation, and its impact on cement and electricity marginal production systems. According to the multifunctionality solution, the environmental impacts results of CLCA were discussed using a sensibility analysis with two attributional life cycle assessment (ALCA) scenarios as allocation and “zero environmental load” (considering BLA as residue). The scenarios demonstrate the potential for sustainable use of BLA, especially for its impact on climate change, including the biogenic carbon category. Also, consequences such as avoiding BLA landfilling and increasing the potential for bamboo agricultural holdings to become energy independent was included in the study conclusion. While these results are positive, the prospect of maturing electricity production requires the development of other high-quality materials, such as sugarcane bagasse ash, sugarcane leaf ash and rice husk ash. However, the positives consequences did not overcome the negative impacts from the transportation of BLA into its system boundaries, once the highway transport model is the manly in the Brazilian context. Hence, this study provides important and reproducible pathways for developing LCI data on other biomass ashes, assisting future studies on green building materials.

Progression of M30 Strong on Banana Leaf Ash & E-Glass Fibre Infused in Cement

Abstract: In the context of a lack of fabric in concrete production, particularly in India where rapid infrastructure development has led to increased construction activities, the adoption of environmentally friendly practices is essential. India, renowned for its exceptional cement production worldwide, is now grappling with issues posed by the widespread Covid-19 pandemic, which is significantly disrupting the growth of the construction industry. This has led to neighbouring lockdowns and shortages in texture. The massive amounts of banana waste thrown out in India emit toxic quantities of carbon dioxide and methane gas into the atmosphere. Banana leaf ash may be produced after the bananas have been harvested. One possible use for the agriculture waste known as BANANA LEAF ASH (BLA) is to reduce the amount of cement needed to build concrete. E-GF stands for "ELECTRONIC-GLASS FIBER," which might refer to a material made up of many little glass filaments. In addition to increasing the material's flexural, ductile, and affect properties, these strands fulfil a function similar to the strengthening steel present in traditional reinforced concrete. This Paper talks about maintain the variable frequency to makeup BLA with cement 0%, 2.5%, 5%, 7.5%, 10% & 12.5% & EGF with constant frequency of 3%. Moreover the comparison is held with proxy blends like 0%BLA+0%EGF, 2.5%BLA+3%EGF, 5%BLA+3%EGF, 7.5%BLA+3%EGF, 10%BLA+3%EGF & 12.5%BLA+3%EGF. BANANA LEAF ASH and E-GLASS FIBER together provide a sustainable and strength-enhancing solution for concrete. Seeing how cutting-edge materials may revolutionize building methods is fascinating.

Valorization of Fine-Fraction CDW in Binary Pozzolanic CDW/Bamboo Leaf Ash Mixtures for the Elaboration of New Ternary Low-Carbon Cement

This paper presents the characterization of a binary mixture of construction and demolition waste (CDW) and bamboo leaf ash (BLAsh) calcined at 600 °C (novel mixture) and the study of its pozzolanic behavior. Different dosages in a pozzolan/Ca(OH)2 system were employed. The aim is the valorization of fine-fraction CDW that achieves a more reactive binary mixture and allows an adequate use of CDW as waste, as CDW is a material of limited use due to its low pozzolanic activity. The pozzolanic behavior of the mixture was analyzed using the conductometric method, which measures the electrical conductivity in the CDW + BLAsh/CH solution versus reaction time. With the application of a kinetic–diffusive mathematical model, the kinetic parameters of the pozzolanic reaction were quantified. This allowed a quantitative evaluation of the pozzolanic activity based on the values of these parameters. To validate these results, other experimental techniques were used: X-ray diffraction, thermogravimetry and scanning electron microscopy. Also, mechanical compressive strength assays were carried out. The results show an increase in the pozzolanic activity of binary mixes of CDW + BLAsh for all the dosages used in comparison to the pozzolanic activity of CDW alone. The quantitative assessment (kinetic parameters) shows that the binary mixture CDW50 + BLAsh50 is the most reactive (reaction rate constant of 7.88 × 10−1 h−1) and is superior to the mixtures CDW60 + BLAsh40 and CDW70 + BLAs30. Compressive strength tests show higher strength values for the ternary mixes (OPC + CDW + BLAsh) compared to the binary mixes (OPC + CDW). In view of the results, the binary blend of pozzolans CDW + BLAsh is suitable for the manufacture of future low-carbon ternary cements.

The Effect of Adding Bamboo Leaf Ash and Cement on the Stability of Clay Soil

Subgrade soil or clay subgrade is a type of soil with very high pore water characteristics, causing problems for civil structures, both buildings and road pavements. Bamboo leaf ash contains several compounds such as silica (SiO2) at 77.24%, while cement contains several calcium oxide (CaO) compounds at 60%. Bamboo leaf ash has a high silica content which functions as a support for pozzolanic reactions with clay soil. The variations in the mixture of bamboo leaf ash and cement used are 2%, 3%, 4%, 5% and 6% for bamboo leaf ash and 20% for cement by weight of soil, with a curing time of 4 days. From the two tests that have been carried out, namely soil compaction (Standard Proctor) and Unsoaked CBR (California Bearing Ratio), the optimum values ​​obtained for soil compaction (Standard Proctor) and CBR (California Bearing Ratio) Unsoaked are in the variation of soil + cement addition of 20% + Bamboo Leaf Ash 3%. In the soil compaction test (Standard Proctor), the dry volume weight value was 1,728 gr/cm3 and the optimum water content value was 16.02%, while in the Unsoaked CBR (California Bearing Ratio) the optimum CBR percentage value was 10.25%.

Innovative utilization of agro-industrial by-products: Bamboo leaf ash as a pozzolanic material for extruded fiber cement composites

This study aims to promote the valorization of agro-industrial waste and sustainability in the construction industry by evaluating the potential of bamboo leaf ash (BLA) as a partial replacement for Portland cement in extruded fiber cement. Squeeze flow, physical, mechanical, and microstructural analyses (Scanning Electron Microscopy and X-ray microtomography) were conducted. The results showed that the incorporation of fibers and BLA leads to an increased water demand and, consequently, an increase in porosity and pore connectivity. However, the mix design with 10 % replacement exhibited improved mechanical behavior for modulus of rupture (10.2 %) and limit of proportionality (4.5 %), when compared to a formulation without BLA. For the other parameters, the mix design with 10 % BLA showed mechanical behavior with no statical difference to the mix design without ash. Thus, the use of BLA as a partial replacement for Portland cement represents an alternative with technical and environmental improvements for fiber cement.

Intensifikasi Sintesis Diasetin dan Triasetin Melalui Esterifikasi Gliserol Dengan Katalis Berbasis Daun Bambu

The synthesis of acetins from glycerol is achieved through esterification assisted by a solid acid catalyst and microwave irradiation. Diacetin and triacetin, suitable as biofuel additives, are produced using biogenic silica from bamboo leaves, which is chemically activated with strong acid and calcined. No research has utilized silica catalysts derived from bamboo leaf ash to produce diacetin and triacetin. This study aims to employ bamboo leaf-based heterogeneous catalysts to enhance triacetin selectivity, simplify product purification and separation, and enable catalyst reuse. Furthermore, microwave application can accelerate the reaction time. The best total selectivity for diacetin and triacetin was obtained under operating conditions of 3% catalyst concentration, a 1:6 molar ratio, and 60 minutes of microwave irradiation. The yields of diacetin and triacetin under these conditions were 65.80% and 18.70%, respectively. GC-MS and FTIR analysis confirm the presence of monoacetin, diacetin, and triacetin, with a total selectivity for diacetin and triacetin of 84,50%.

Corrosion Behaviour of Commonly Used Epoxy Resin Coated Agro Based Industrial Reinforcements

bstract: In this integrated study, the project aims to develop a novel hybrid green metal matrix composite using stir casting, reinforcing aluminum alloy with Waste materials such as Waste Carbonized Eggshells (WCE), Cow Dung Ash (CDA), Snail Shell Ash (SSA), and Bamboo Leaf Ash (BLA) The experiment incorporates various organic-inorganic mixed coatings, including vinyltrimethoxysilane (VMS), [3-(methacryloxy)propyl] trimethoxy silane (MPMS), and (3-glycidoxyproyl) trimethoxy silane (GPMS), combined with tetraethoxysilane (TEOS), to enhance corrosion resistance. Potentiodynamic polarization curves, SEM images, and salt spray tests are employed to assess coating durability against corrosion. Results indicate significant reductions in corrosion flow with VMS and MPMS coatings, particularly with a 15-20% TEOS ratio, showcasing optimal corrosion resistance against salt spray. This innovative approach combines material recycling and advanced coating techniques to produce a sustainable composite with improved mechanical properties and corrosion resistance.

Development of sustainable interlocking concrete paving blocks using bamboo leaf ash and metakaolin

Eco-friendly interlocking concrete pavement block was developed using the admixture of bamboo leaf ash and metakaolin. This was done to develop an eco-friendly interlocking paving block for sustainable pavement construction. Bamboo leaf ash and metakaolin were added as a supplementary cementitious material. The supplementary cementitious material (bamboo leaf ash and metakaolin) were admixed and added at 0, 5, 10, 15, 20, 25 and 30 % replacement of cement. The workability of the fresh concrete (slump) at the varied percentage additions, and the mechanical properties of the concrete at 7, 14, 28, and 56 days of curing were assessed, including their microstructural characteristics. The outcome of the research showed that increasing the percentage of (bamboo leaf ash + metakaolin) reduces the workability of the concrete. With a 20 % addition of this cementitious material, the developed fresh concrete became unworkable. In addition, replacing up to 10 % of the concrete in the pavement with bamboo leaf ash and metakaolin increased the mechanical strength of the concrete by 28.7 %. At 30 % a percentage increase of 3.6 % was recorded. However, the strength at 5 % was still adequate for pavement construction with a 13.62 % increase in mechanical strength. The compressive strength at 5 % and 10 % addition of the supplementary cementitious material at maturity met the criteria for constructing a semi-rigid pavement, using IRC standards. The microstructural assessment showed that the number of pores in the mature concrete samples decreased at 10 % addition of bamboo leaf ash and metakaolin. The research data provides construction workers, researchers, and highway engineers with vital information regarding the viability of these sustainable materials for pavement improvement.

Comparative performance of M-S-H cement vs. portland cement in fiber cement incorporating bamboo leaf ash and cellulosic fibers

This study evaluates the potential of alternative materials such as Hydrated Magnesium Silicate (M-S-H) cement, bamboo leaf ash (BLAsh), and cellulose fibers to enhance the sustainability and performance of fiber cement composites. Innovative in its approach, the research incorporates BLAsh and cellulose fibers into M-S-H and Portland cement (OPC) matrices using an innovative production process: extrusion. For the characterization of different formulations, a comparative analysis was conducted on samples with M-S-H and Portland cement matrices, with BLAsh replacing limestone and the addition of unbleached pine cellulose fibers. The analysis covered the physical, mechanical, and microstructural properties of the composites. After a 7-day curing period, they were subjected to 200 cycles of accelerated aging to evaluate durability. Microstructural analysis revealed the binding potential of the M-S-H matrix used in this study due to the pronounced formation of M-S-H gel and reduced content of Mg(OH)2 over time. The formation of C–S–H and M-S-H gel as the main phase for each type of cement is even more evident in samples incorporating BLAsh, indicating the interaction between both types of matrices and bamboo leaf ash. The study demonstrated that adding BLAsh to the composites significantly improved the modulus of rupture of the OPC samples (approximately 32 %), while considerably reducing water absorption for the M-S-H samples (around 50 %). Aging affected water absorption differently in OPC and M-S-H samples, with OPC showing decreased absorption and the M-S-H showing increased absorption post-aging. The study proved both types of cement suitable for producing composites that meet NBR 15498 standards for external applications. This demonstrates the technical feasibility of these compounds for their production by 3D printing.

Potency of papaya leaf as green catalyst in biodiesel synthesis for transesterification of coconut oil

Papaya leaf is a promising biomass to be developed into a green catalyst for biodiesel synthesis. This study aimed to evaluate the potential of papaya leaves by calcination at 700°C for 3 hours, and to assess the created papaya leaf ash as a catalyst in biodiesel transesterification. Characterization of papaya leaf ash was carried out using SEM-EDX and FTIR. The results confirmed that papaya leaf ash contains metal oxides such as K2O, MgO and CaO which function as active components that catalyse the reaction. Transesterification of coconut oil was carried out at fixed molar ratio of oil to methanol (OTM) of 1:12, reaction temperature of 55-65°C, and catalyst load of 2-4wt.%. The highest yield of biodiesel was 97.36% with a purity of 99.39%. It was obtained at reaction temperature of 60°C, 3% catalyst load, and 150 min reaction time. The quality of biodiesel obtained was correspondent to European standards (EU 14214). The results confirm that papaya leaf ash may be used as a heterogeneous catalyst in the manufacture of biodiesel.

Properties of ultra lightweight foamed concrete utilizing agro waste ashes as an alkaline activated material

In the present investigation, rice husk ash (RHA), bamboo leaf ash (BLA) and palm oil fuel ash (POFA) known as agricultural-waste materials locally available were used to produce ultra lightweight foamed concretes (ULFCs). BLA, RHA, and POFA were used as replacements for cement in ULFCs at different weight percentages of 0 %, 5 %, 10 %, 15 %, and 20 %. To achieve the target density of 350 kg/m3, cement was substituted with agricultural wastes, and a protein foaming agent was added. The properties of ULFCs were examined including, slump test, setting time, fresh density, splitting tensile, compressive and flexural strengths, thermal insulating, microstructural and transport properties, permeability and pore's structure. The experimental results demonstrated that BLA and POFA ashes significantly outperforms in terms of efficiency and improved the mechanical and transport qualities of ULFCs than RHA ash. By increasing the weight fractions of BLA, RHA, and POFA from 5 % to 20 % in ULFC mixes resulted in an improvement in slump, porosity, capillary sorption, water absorption, bulk density, intrinsic air permeability, and specific heat. The ideal results were seen in terms of compressive strength, bending strength, splitting tensile strength, and UPV when 15 % POFA and BLA, and 10 % RHA were used as substitutes for cement. The increase in weight fraction of BLA, RHA, and POFA resulted in a rise in both thermal conductivity and thermal diffusivity of ULFCs. SEM studies revealed that incorporating different agricultural wastes positively affects the pore size distribution within the microstructure decreasing with increased content of ashes related to the development of ULFCs with stronger matrix. As a result, the formulated ULFCs met the masonry strength criteria while also providing economic and environmental benefits.

Effect of banana tree leaves ash as cementitious material on the durability of concrete against sulphate and acid attacks

The construction industry's rapid growth poses challenges tied to raw material depletion and increased greenhouse gas emissions. To address this, alternative materials like agricultural residues are gaining prominence due to their potential to reduce carbon emissions and waste generation. In this context this research optimizes the use of banana leaves ash as a partial cement substitution, focusing on durability, and identifying the ideal cement-to-ash ratio for sustainable concrete. For this purpose, concrete mixes were prepared with BLA replacing cement partially in different proportions i.e. (0 %, 5 %, 10 %, 15 %, & 20 %) and were analyzed for their physical, mechanical and Durability (Acid and Sulphate resistance) properties. Compressive strength, acid resistance and sulphate resistance testing continued for 90 days with the intervals of 7, 28 and 90 days. The results revealed that up to 10 % incorporation of BLA improved compressive strength by 10 %, while higher BLA proportions (up to 20 %) displayed superior performance in durability tests as compared to the conventional mix. The results reveal the potentials of banana leave ash to refine the concrete matrix by formation of addition C–S–H gel which leads towards a better performance specially in terms of durability aspect. Hence, banana leaf ash (BLA) is an efficient concrete ingredient, particularly up to 10 % of the mix. Beyond this threshold, it's still suitable for applications where extreme strength isn't the primary concern, because there may be a slight reduction in compressive strength.

Potential of Bamboo Leaf Ash for Soil Stabilization - Literature Review

Soil stabilization is an important topic in geotechnical engineering as many problematic soils were found during construction. One of the commonly used soil stabilization is cement, but it is widely known as a non-sustainable material. Much research provided the usage of industrial waste as a substitute for cement, which is then known as a supplementary cementitious material (SCM). One of the alternatives is bamboo, which has the second highest silica content after rice husk. This paper conducted a literature review on the potential of using bamboo leaf ash (BLA), which is the main composition of silica in bamboo. Various studies indicated the usage of BLA, ranging from its initial usage in concrete to its development in soil stabilization. Five studies were pointed out as the extensive research of BLA usage in Nigeria, focusing on lateritic soils. The results indicated that stabilizing lateritic soils with BLA increases the CBR values and the bearing capacity, whereas it decreases plasticity index values. Later studies followed by using other types of soils. The results are all consistent, where the shear strength of soil and CBR values increases with the usage of BLA as SCM.

Experimental investigation of Bamboo Leaf Ash and Rice Husk Ash as partial replacement cement in concrete

Construction work was mostly done in the ancient era using mudstone obtained from industry. The experimental investigation on the strength properties of M30 grade concrete, in which rice husk ash and bamboo leaf ash have largely substituted cement. One of these waste materials produced as a by-product of the rice paddy milling industry is rice husk ash (RHA). and Bamboo is used as scaffolding for the manufacture of domestic goods and construction paper. In this investigation, concrete specimens created with 0%, 5%, 10%, and 15% of the RHAsh and BLAsh as the cement replacement percentages were used to calculate the strength-related parameters such as compressive strength, splitting tensile strength, and flexural strength. Samples were examined at 7, 14, and 28 days old. Finally, it was determined that, when compared to other replacement levels, the 5% RHAsh and BLAsh replacement level in M30 grade concrete demonstrated to be greater.

Geotechnical Properties of Cement-Stabilized Lateritic Soil with Bamboo Leaf Ash in the Takie Area of Ogbomoso

Geotechnical Properties of Cement-Stabilized Lateritic Soil with Bamboo Leaf Ash in the Takie Area of Ogbomoso