Laundry Cycles Research Articles

Assessment of Single-Layer and Three-Layer Reusable Surgical Gowns Performance in Terms of Bacterial Penetration in Wet State

Surgical gowns are a vital part of the protective textile that are applied to preserve surgical group members against infection. Therefore, not only their protective performance, but also their comfort are significant. Reusable gowns usually preferred by people due to their comfort. However; their stability to the laundry and sterilization process determine their useful life-time. In this study, the protective performance of two single-layer and three-layer reusable surgical gowns was investigated after 70 laundry and sterilization cycles. To this end, fabric’s resistance against bacterial penetration in wet state after every 10 laundry and sterilization cycles were evaluated based on the ISO22610 standard test method. Moreover, to assess the fabric structure variation, SEM image was provided after every 10 laundry and sterilization cycles. The results illustrate that laundry and sterilization process lead to the destruction of the single-layer gown’s structure and enhance its pore size, followed by barrier index reduction. However; no considerable variation was obtained in the three-layer gown’s barrier index.

Influence of Laundering on Comfort Characteristics of Moisture Management Finished Microdenier Polyester Knitted Fabrics

In this study an attempt has been made to study the influence of laundry performance on the various comfort characteristics of Moisture Management Finished (MMF) knitted fabrics. The influence of laundering on comfort characteristics of MMF microdenier polyester knitted fabrics was studied to find out the durability of the MMF and its capability to withstand at least 20 home laundry cycles. In order to study this effect, the MMF knitted fabrics were subjected to different laundering cycles. It was observed that 10 wash and 20 wash fabrics exhibited a superior performance thereby fulfilling an important parameter of permanent wash proofness.

Resistance of Commercial Bed Covers against Faecal Pellets of House Dust Mites: Behaviour of Seams and Zippers

This study evaluated the allergen impermeability against airborne allergens of dust mite droppings through all parts of commercial bed covers, including surface seams and zippers. Specimens were taken from places with and without seams and zipper. A novel penetration cell was developed to expose the specimens to an inoculum of purified mite droppings that was assessed for its allergen content Der p1 prior to the penetration tests. Using covers of different construction and material, the penetration level increased significantly in the presence of seams and zippers and could reach up to 6% depending on the seam’s/zipper’s characteristics and quality. Therefore, zippers and seams have to be considered as access points for the penetration of mite droppings. As for the penetration of airborne mite particles through the zipper, the penetration level was greatly attenuated by the presence of a cover strip. Depending on the respective quality and the construction type, the mite allergen Der p1 penetrated most likely through the zipper and seams of the specimens, already after a single laundry cycle. Hence, laundry may compromise the barrier performance and proves to be an important quality feature. In all samples, the textile surface showed sufficient allergen impermeability. Our conclusions provide recommendations to both manufacturers and users.

Fabrication of Visible Light-Induced Antibacterial and Self-Cleaning Cotton Fabrics Using Manganese Doped TiO2 Nanoparticles.

Ordinary textiles are very often malodorous and the origin of cross-infection. Their microclimate, consisting of moisture, contaminants, and sweat, provides favorable conditions for microbial growth. Therefore, simple approaches of surface modification using functional materials are widely adopted to introduce antibacterial properties. This study reports a simple and low cost technique that renders cotton fabrics antibacterial. Manganese (Mn)-doped photocatalytic titanium dioxide (TiO2) nanoparticles of ∼150 nm average diameter have been prepared by sol gel and applied on textile fabrics using a silicone binder. The treated fabrics displayed 100% reduction of Staphylococcus aureus (Gram-positive) and Klebsiella pneumoniae (Gram-negative) populations within 120 min under sunlight, demonstrating first order of reduction kinetics. Moreover, the functionalized fabrics demonstrated complete degradation of a methylene blue (MB) dye adsorbed on their surface, under both UV and visible light irradiation, turning them white. A similar effect was observed when the treated fabrics were immersed in a MB dye solution and subsequently irradiated. Here, the cotton fabrics functionalized with Mn-doped TiO2 nanoparticles were able to discolour the dissolved MB dye, demonstrating a water purification effect. In addition, the modified fabrics were resistant to several laundry cycles. Physical properties like mechanical strength, color, breathability, and aesthetic of the treated cotton fabrics remained unchanged. The modified cotton fabrics can be envisioned as antibacterial, antiodorous, and self-cleaning textiles for sports, medical uses, uniforms, fashion, home furnishing, and leisure activities. Finally, the treated textiles were found to be biocompatible.

Fabricating durable, fluoride‐free, water repellency cotton fabrics with CPDMS

ABSTRACTThe demand for fluoride‐free and durable hydrophobic cotton fabric is dramatically increasing due to environmental and human safety concerns. The current approach to produce water repellent cotton fabrics is applying fluorocarbon compounds in topical treatments. However, the fluorocarbons employed in the water repellent treatments on cotton fabrics have environmental concerns and environmentally friendly technologies are desperately sought. Herein, we report a new approach of fabricating water repellent cotton fabrics with proper washing durability by using poly{dimethylsiloxane‐co‐[2‐(3,4‐epoxycyclohexyl)ethyl]methylsiloxane} (CPDMS) as a hydrophobic agent. Benefiting from formation of robust ether bonds between CPDMS and celluloses, the cotton fabrics could gain promising durability for daily laundry. The resultant cotton fabrics demonstrated simultaneously desired waterproofness (hydrostatic pressure up to 22 mbar), durability (hydrostatic pressure stabled at 12 mbar after five laundry cycles), and breathability. Moreover, the CPDMS modified cotton fabrics also exhibited robust physical property with tensile strength retention up to 73%. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46396.

Green synthesis and characterization of silver nanoparticles by Allium cepa L. to produce silver nano‐coated fabric and their antimicrobial evaluation

This research work was proposed to study the antimicrobial activity of the silver nanocoated fabric with the purpose of producing good dressing and clothing material. We synthesized simple, ecofriendly, cost‐effective and sustainable silver nanoparticles by using the aqueous extract of Allium cepa L. Here, A. cepa L. acts as a good reducing and capping agent that produced stable silver nanoparticles having particle size of range 36 ± 1 to 98 ± 2 nm, Poly dispersiblity index 0.234 ± 0.61 to 1.023 ± 0.33 and Zeta potential ‐12 ± 1.5 mV to ‐26 ± 1.2 mV. The effect of temperature and extract volume used was considered for optimization of synthetic procedure. The nanocoated fabric was characterized for morphological study, size (using transmission electron microscopy (TEM) and field emission scanning electron microscopy (FE‐SEM) and zeta‐potential (Zeta Potentiometer). The presence of functional groups were observed by using attenuated total reflection‐Fourier transform infrared (ATR‐FTIR) and Raman spectroscopy. The crystallinity and structural property of the synthesized silver nanoparticles were studied in terms of Powder X‐ray diffraction (PXRD). An IC50 value and zone of inhibition was studied which demonstrate that the silver nanocoated fabric have an excellent antibacterial property against Gram‐negative (Escherichia coli) and Gram‐positive (Staphylococcus aureus) bacteria. Further nanocoated fabric material was washed (with function of time 0, 10, 25, and 50 laundry cycles) and still retained their anti‐bacterial activity towards both strain. Initially there was 52 μg/ml of silver nanoparticles on the cotton fabric but after 50 laundry cycle in 500 ml of distilled water the fabric showed 92% efficiency against gram positive and 90% efficacy toward gram negative bacteria. It was found that 4.16 μg/ml nano particles leached in case of S. Aureus and 5.2 μg/mL silver nanoparticles leached in case of E. coli. Nanocoated fabric material synthesized using green synthesis was found to be economical with good resistance to washing.

Durable crosslinked omniphobic coatings on textiles via supercritical carbon dioxide deposition

A novel method of creation durable water- and oil- repellent coatings on flexible substrates (such as textiles) by simultaneous deposition of perfluoroalkyl methacrylate/hydroxyalkyl methacrylate statistical copolymers with a diisocyanate crosslinking agent from solutions in supercritical carbon dioxide (SC CO2) is proposed. The morphology of fluropolymer films deposited on nylon fibers from 1,1,2- trichlorotrifluoroethane and from SC CO2 with/without hexamethylene diisocyanate as a crosslinking agent is compared using scanning electron microscopy. Repellent properties of the films are analysed by water contact angle measurements and by performing standard water spray test as well as hydrocarbon resistance tests before and after multiple home laundry cycles. Enhanced uniformity of the SC CO2 deposited coatings results in improved durability and liquid repelling properties in comparison to coatings deposited from a liquid solvent.

Mimicking elephant mud bathing to produce wettable polyester

Bio-inspired and biomimetic surface modifications are identified as one of the fascinating areas of research. In this study, nature’s way of cooling elephants’ body temperature using mud bathing was mimicked to create a superior wettable polyester fabric with improved comfortability. For that, bentonite nanoclay was covalently grafted on polyester fabric using (3-aminopropyl) triethoxysilane as a coupling agent. FTIR spectroscopy and SEM were used to characterize bentonite grafted polyester while the wettability was proved by standard protocols. This fabric coating strongly withstands more than 50 cycles of laundry. It is expected that this bio-inspired wettable polyester fabric may break the barrier of using polyester in various hydrophilic textile applications.

Healable Cotton-Graphene Nanocomposite Conductor for Wearable Electronics.

Electrically conductive materials based on cotton have important implications for wearable electronics. We have developed flexible and conductive cotton fabrics (∼10 Ω/sq) by impregnation with graphene and thermoplastic polyurethane-based dispersions. Nanocomposite fabrics display remarkable resilience against weight-pressed severe folding as well as laundry cycles. Folding induced microcracks can be healed easily by hot-pressing, restoring initial electrical conductivity. Impregnated cotton fabric conductors demonstrate better mechanical properties compared to pure cotton and thermoplastic polyurethane maintaining breathability. They also resist environmental aging such as solar irradiation and high humidity.

Body-monitoring with photonic textiles: a reflective heartbeat sensor based on polymer optical fibres.

Knowledge of an individual's skin condition is important for pressure ulcer prevention. Detecting early changes in skin through perfusion, oxygen saturation values, and pressure on tissue and subsequent therapeutic intervention could increase patients' quality of life drastically. However, most existing sensing options create additional risk of ulcer development due to further pressure on and chafing of the skin. Here, as a first component, we present a flexible, photonic textile-based sensor for the continuous monitoring of the heartbeat and blood flow. Polymer optical fibres (POFs) are melt-spun continuously and characterized optically and mechanically before being embroidered. The resulting sensor shows flexibility when embroidered into a moisture-wicking fabric, and withstands disinfection with hospital-type laundry cycles. Additionally, the new sensor textile shows a lower static coefficient of friction (COF) than conventionally used bedsheets in both dry and sweaty conditions versus a skin model. Finally, we demonstrate the functionality of our sensor by measuring the heartbeat at the forehead in reflection mode and comparing it with commercial finger photoplethysmography for several subjects. Our results will allow the development of flexible, individualized, and fully textile-integrated wearable sensors for sensitive skin conditions and general long-term monitoring of patients with risk for pressure ulcer.

Synthesis and application of a sulfur‐containing phosphoric amide flame retardant for nylon fabric

SummaryA sulfur‐containing flame retardant (SFR) was synthesized from polyphosphoric acid, epoxy chloropropane, and thiourea. Using a water‐soluble isocyanate‐terminated (WIT) cross‐linker, the flame retardant was applied as a flame‐retardant finishing on nylon fabric. WIT is a compound that not only cross‐links SFR and nylon cellulose but also contains no formaldehyde. Comparisons of the main performances of SFR with those of N‐methyloldimethylphosphonopropionamide (known as ‘Pyrovatex CP’) and a bicyclic phosphonite (known as ‘Antiblaze 19T’) indicate that the presence of sulfur in SFR plays a crucial role in decreasing the flammability of the nylon fabric. The limiting oxygen index value and damaged carbon length of the finished nylon fabric were 29.4% and 5.7 cm, respectively, when the concentrations of SFR and WIT were 200 and 40 g/L, respectively, and the baking temperature and time were 150 °C and 3 min, respectively. After 10 laundry cycles, the fabric still retains some flame retardancy. Copyright © 2016 John Wiley & Sons, Ltd.

A novel reactive anti-ultraviolet finishing of cotton fabric based on N-dihydroxy ethylene cyanoguanidine

This study reports a novel ultraviolet (UV) absorber, N-dihydroxy ethylene cyanoguanidine (NDEC), which was synthesized from dicyandiamide and glyoxal. The NDEC compound was characterized by Fourier-transform infrared spectrum and nuclear magnetic resonance. NDEC was grafted onto cotton fabric through covalent bonding by the pad–dry cure method. The optimal finishing conditions were that the mass concentration of NDEC was 5 g/L, baking time 240 s and temperature 140℃. The UPF value of cotton fabric treated under optimal finishing conditions reached 50+ and was minimally reduced (to 47) after 50 laundry cycles. The breaking strength and thermostability of the original cotton fabric were preserved after treatment. Successful grafting of – C≡N and –C=N groups onto the treated fabric was confirmed in the Fourier-transform infrared spectrum. Meanwhile, the finished cotton fiber remained smooth, as confirmed by scanning electronic microscopy.

Superhydrophobic and luminescent cotton fabrics prepared by dip-coating of APTMS modified SrAl2O4:Eu2+,Dy3+ particles in the presence of SU8 and fluorinated alkyl silane

An organic-inorganic composite dip-coating method was adopted in order to obtain ideal water repellent cotton fabrics. To be specific, a dual-functional coating with both superhydrophobic and luminescent properties was prepared on cotton fabric by using a dip-coating solution comprising (3-aminopropyl) trimethoxysilane (APTMS) modified SrAl2O4:Eu2+,Dy3+ particles, SU8, and fluorinated alkyl silane (FAS). The micro/nano-scale roughness generated by SrAl2O4:Eu2+,Dy3+ particles, together with low-surface-energy FAS, rendered the cotton fabric superhydrophobic with a water contact angle of about 160° and a sliding angle as small as 2°. The coated fabric could withstand at least 100 cycles of standard laundry. The emission spectra of the coated fabric showed two emission peaks at 440 and 520 nm, which belonged to the blue and yellow-green color areas, respectively. The afterglow duration of the coated fabric was mainly influenced by the different depths of the trap levels in the SrAl2O4:Eu2+,Dy3+.

Robust, Self-Healing Superhydrophobic Fabrics Prepared by One-Step Coating of PDMS and Octadecylamine.

A robust, self-healing superhydrophobic poly(ethylene terephthalate) (PET) fabric was fabricated by a convenient solution-dipping method using an easily available material system consisting of polydimethylsiloxane and octadecylamine (ODA). The surface roughness was formed by self-roughening of ODA coating on PET fibers without any lithography steps or adding any nanomaterials. The fabric coating was durable to withstand 120 cycles of laundry and 5000 cycles of abrasion without apparently changing the superhydrophobicity. More interestingly, the fabric can restore its super liquid-repellent property by 72 h at room temperature even after 20000 cycles of abrasion. Meanwhile, after being damaged chemically, the fabric can restore its superhydrophobicity automatically in 12 h at room temperature or by a short-time heating treatment. We envision that this simple but effective coating system may lead to the development of robust protective clothing for various applications.

Effect of Variations of Washing Solution Chemistry on Nanomaterial Physicochemical Changes in the Laundry Cycle.

Engineered nanoparticle (ENP) life cycles are strongly dependent on the life-cycle of the nanoenhanced products in which they are incorporated. An important phase for ENP associated with textiles is washing. Using a set of liquid and powdered commercially available detergents that span a wide range of different chemistries, washing studies were performed with one "standard" nanoparticle suspended in wash solution to systematically investigate (changes to) particle size distribution, dissolution, reprecipitation (i.e., "new" particle formation), and complexation to particulate matter. Au ENPs were used as a "tracer" through the system. TEM and EDX analysis were performed to observe morphological and chemical changes to the particles, and single-particle ICP-MS was used to build a size distribution of particles in solution. Varying the washing solution chemistry was found to dictate the extent and rate of dissolution, particle destruction, surface chemistry change(s), and new particle formation. Detergent chemistry, dominated by oxidizing agents, was a major factor. The detergent form (i.e., powder vs liquid) was the other decisive factor, with powder forms providing available surfaces for precipitation and sorption reactions. Control experiments with AgNO3 indicated metallic Ag particles formed during the washing process from dissolved Ag, implying not all Ag-NPs observed in a textile washing study are indicative of released Ag-ENPs but can also be the result of sequential dissolution/reduction reactions.

Clothes Lines

This collaboration, featuring poetry by Christine Wiesenthal and photography by Elena Siemens, connects domestic spaces to the social, public and commercial sphere of the street: to relationships, traffic, gossip, and sundry forms of “dirty laundry.” In his essay on “Naples,” Walter Benjamin states: “Porosity is the inexhaustible law of the life of this city, reappearing everywhere” (170). “Buildings and actions,” he explains, “interpenetrate in the courtyards, arcades, and stairways. In everything they preserve the scope to become a theatre of new, unforeseen constellations” (169). He adds: “The stamp of the definitive is avoided” (169). This unique characteristic of Naples, its porosity, also surfaces in the “unforeseen constellations” of Wiesenthal’s The Laundry Cycle, and 
 Siemens’ images of Tel Aviv.

Cheatgrass (Bromus Tectorum) Seeds are Still Viable after Laundry Cycle

ABSTRACT: Bromus tectorum is expanding across western North America. This spread is due to its own competitive abilities, land management practices, and unintended transport by the public as the plant's spikelets often lodge in clothing. Many assume that washing in a laundry machine makes the seeds nonviable: we decided to test this assumption. We hypothesized that seeds would exhibit lower rates of germination and emergence after being laundered, and the effect would be stronger if bleach was used. We found that washing with detergent, followed by drying, had no effect on germination when seeds were allowed to sprout 20 days later. We also found that a 6.0% solution of sodium hypochlorite bleach reduced germination and growth if planting occurred 180 days after laundering.

Synthesis and application of a formaldehyde-free flame retardant for bamboo viscose fabric

A formaldehyde-free flame retardant (EFFR) for bamboo viscose fabric was synthesized by raw materials of silanol, phosphorus pentoxide, and diethanolamine. The flame retardant had the dual function of imparting fire resistance and softness to bamboo viscose fabric; moreover, it had no halogen and free formaldehyde, and wouldn’t release formaldehyde during processing and end-use. The experimental results about choice of cross-linker stated that the cross-linker played a significant role in decreasing the flammability of bamboo viscose fabrics and improving durability of flame retardance. Cross-linkers of hexamethylol melamine (HMM) or dimethylol dihydroxy ethylene urea (DMDHEU) or water-soluble isocyanate-terminated (WIT) not only cross-linked with flame retardant and bamboo viscose cellulose to enhance durability of inflaming retarding, but also had nitrogen to improve nitrogen–phosphorus synergism. However, HMM and DMDHEU can release free formaldehyde. WIT is a kind of cross-linker which has no formaldehyde. The experimental results showed that the Limiting Oxygen Index (LOI) value of Vis-EFFR–WIT treated fabric was basically above 30%, and the handle of the finished fabric was ameliorated greatly because of its organosilyl constituent part, even after 30 laundry cycles, the fabric still had some flame retardancy and soft feeling.

Effect of Laundry Surfactants on Surface Charge and Colloidal Stability of Silver Nanoparticles

The stability of silver nanoparticles (Ag NPs) potentially released from clothing during a laundry cycle and their interactions with laundry-relevant surfactants [anionic (LAS), cationic (DTAC), and nonionic (Berol)] have been investigated. Surface interactions between Ag NPs and surfactants influence their speciation and stability. In the absence of surfactants as well as in the presence of LAS, the negatively charged Ag NPs were stable in solution for more than 1 day. At low DTAC concentrations (≤1 mM), DTAC-Ag NP interactions resulted in charge neutralization and formation of agglomerates. The surface charge of the particles became positive at higher concentrations due to a bilayer type formation of DTAC that prevents from agglomeration due to repulsive electrostatic forces between the positively charged colloids. The adsorption of Berol was enhanced when above its critical micelle concentration (cmc). This resulted in a surface charge close to zero and subsequent agglomeration. Extended DLVO theory calculations were in compliance with observed findings. The stability of the Ag NPs was shown to depend on the charge and concentration of the adsorbed surfactants. Such knowledge is important as it may influence the subsequent transport of Ag NPs through different chemical transients and thus their potential bioavailability and toxicity.

Robust, electro-conductive, self-healing superamphiphobic fabric prepared by one-step vapour-phase polymerisation of poly(3,4-ethylenedioxythiophene) in the presence of fluorinated decyl polyhedral oligomeric silsesquioxane and fluorinated alkyl silane

A robust, electrically conductive, superamphiphobic fabric was prepared by vapour-phase polymerisation of 3,4-ethylenedioxythiophene (EDOT) on fabric in the presence of fluorinated decyl polyhedral oligomeric silsesquioxane (FD-POSS) and a fluorinated alkyl silane (FAS). The coated fabric had contact angles of 169° and 156° respectively to water and hexadecane, and a surface resistance in the range of 0.8–1.2 kΩ □−1. The incorporation of FD-POSS and FAS into the PEDOT layer showed a very small influence on the conductivity but improved the washing and abrasion stability considerably. The coated fabric can withstand at least 500 cycles of standard laundry and 10 000 cycles of abrasion without apparently changing the superamphiphobicity, while the conductivity only had a small reduction after the washing and abrasion. More interestingly, the coating had a self-healing ability to auto-repair from chemical damages to restore the liquid repellency.