Latent Heat Research Articles

Numerical Study on the Effect of Heat Source and Fin Arrangement on the Melting Performance of Phase Change Materials in a Latent Heat Storage System

Numerical Study on the Effect of Heat Source and Fin Arrangement on the Melting Performance of Phase Change Materials in a Latent Heat Storage System

Intercomparison of sensible and latent heat flux measurements from combined eddy covariance, energy balance, and Bowen ratio methods above a grassland prairie

We present a comparison of four different methods of measuring sensible (H) and latent (LE) heat fluxes for a year over a mixed grass prairie ecosystem in the Nebraska SandHills [eddy covariance (EC), energy balance/Bowen ratio (EBBR), residual energy (RES), modified Bowen ratio (MBR) methods]. Additionally, we developed a set of quality control criteria for each method and present a simplification to the traditional EBBR setup. Using EC as reference, all methods yielded similar estimates of yearly H (regression slopes (m) ~ 2% from unity; HEC > HEBBR, HRES, and HMBR). For yearly LE, EBBR and RES yielded similar estimates with EC (m ~ 2% from unity; LEEC < LEEBBR and LERES), while a larger bias was found from MBR (m ~ 8% from unity; LEEC > LEMBR). At shorter time scales (~ hourly), moderate scatter was found about linear regression fits for H between EBBR and EC (R2 = 0.81), with smaller scatter between RES and MBR, and EC (R2 = 0.91). For LE, smaller scatter was also measured between EC, and EBBR and RES (R2 = 0.89 and 0.87, respectively), with the larger scatter between EC and MBR (R2 = 0.65). This suggests methods other than EC may be well suited to longer-term applications (≥ yearly), but have larger uncertainty on individual measurements.

Highly inhomogeneous interactions between background climate and urban warming across typical local climate zones in heatwave and non-heatwave days

Abstract Urban heat island (UHI) in conjunction with heatwave (HW) leads to exacerbation of thermal stress in urban areas. Prior research on UHI and HW has predominantly concentrated on examining the thermal conditions at the surface and near-surface, with few investigations extending to the radiative and dynamical interactions of UHI and HW, particularly with a focus on the inhomogeneities across local climate zones (LCZs). Here, we analyse the temperature disparity between HW and non-HW conditions across LCZs in the Sydney area by quantifying the contributions of individual radiative and dynamical processes using the coupled surface-atmosphere climate feedback-response analysis method (CFRAM). Three moist HW events in 2017, 2019, and 2020 are simulated using the Weather Research and Forecasting (WRF) model coupled with the Single-Layer Urban Canopy Model (SLUCM). It is found that the maximum surface and 900-hPa temperature difference between HW and non-HW days may reach up to 10 K, with the increased net solar radiation during HWs being comparable to the typical level of anthropogenic heat flux in urban areas. It is also found that the reduction of clouds, the presence of vapor, and the increase of sensible heat contribute to the warming effect to various degrees, with the contribution of clouds being the most dominant. Conversely, the generation of dry convection and the increase of latent heat flux lead to cooling effects, with the latter being more dominant and capable of causing up to 10 K surface temperature difference between LCZ1 (compact high-rise) and LCZ9 (sparsely built). The differences in the contributions of climate feedback processes across different LCZs become more evident during more severe and humid HWs. These findings underscore the necessity of implementing local climate zone-tailored heat mitigation strategies.

Understanding tropical cyclone persistence over land: A case study of Cyclone Gulab

Abstract Tropical Cyclone (TC) Gulab originated in the Bay of Bengal during the post-monsoon season of 2021. Following an unusual westward trajectory, TC Gulab made landfall on the east coast of India, traversed central India, and reintensified over the Arabian Sea into TC Shaheen. This study employed an online Eulerian water vapor tracer (WVT) tool embedded within the Weather Research and Forecasting (WRF) model to investigate the role of land in terms of soil moisture and Land Use Land Cover (LULC) in persistance of TC Gulab over central India. We quantified the contributions of sub-regions and dominant LULC types within the Indian subcontinent to the precipitation associated with TC Gulab. Our findings indicate that evapotranspiration across the entire Indian subcontinent contributed approximately 30% to the post-landfall precipitation associated with TC Gulab. The highest contribution originated from the northwestern region, followed by the northeast. Croplands, the dominant LULC type, were the primary contributors, followed by forests. Despite changing the dominant land cover from cropland to forest, the low-pressure system persisted over land while altering the spatial patterns of precipitation. Sensitivity experiments demonstrated a linear decrease in precipitation originating from land with decreasing soil moisture (SM). Notably, there is a disproportionate decline in total precipitation with decreasing SM. Further analysis separating atmospheric vapor sources into land and ocean contributions using WVT revealed a compensatory mechanism. The contribution of oceanic vapor to atmospheric vapor over land increased when SM decreased due to increase in the latent heat over ocean. However, the total atmospheric vapor remained low, ultimately leading to a lower total precipitation. Although SM plays a role, our results highlight the importance of oceanic and atmospheric processes in determining TC persistence over land. This study offers valuable insights into the dynamics of land-atmosphere interactions during low-pressure systems of TCs.

Monitoring anomalies on large-scale energy and water balance components by coupling remote sensing parameters and gridded weather data.

The SAFER (Simple Algorithm for Evapotranspiration Retrieving) algorithm was applied with MODIS images and gridded weather data from 2007 to 2021, to monitor the energy balance components and their anomalies, in the Atlantic Forest (AF) and Caatinga (CT) biomes inside the coastal agricultural growing zone, Northeast Brazil. Considering the long-term data, the Rn values between the biomes are not significantly different, however presenting distinct Rn partitions into latent (λE), sensible (H), and ground (G) heat fluxes between biomes. The Rn values annual averages are 9.40 ± 0.21 and 9.50 ± 0.23MJm-2 d-1, for AF and CT, respectively. However, for respectively AF and CT, they are respectively 5.10 ± 1.14MJm-2 d-1 and 4.00 ± 0.99MJm-2 d-1 for λE; 3.80 ± 1.12MJm-2 d-1 and 5.00 ± 1.00MJm-2 d-1 for H; 0.50 ± 0.12MJm-2 d-1 and 0.40 ± 0.10MJm-2 d-1 for G, yielding respective mean evaporative fraction (Ef = λE/(Rn - G) values of 0.60 ± 0.12 and 0.50 ± 0.15. Anomalies on λE, H, and Ef were detected through standardized index for these energy balance components by comparing the results for the years 2018 to 2021 with the long-term values from 2007 to each of these years, showing that the energy fluxes between surfaces and the lower atmosphere, and then the root-zone moisture conditions for both biomes, may strongly vary along seasons and years, with alternate positive and negative anomalies. These assessments are important for water policies as they can picture suitable periods and places for rainfed agriculture as well as the irrigation needs in irrigated agriculture, allowing rational agricultural environmental management while minimizing water competitions among other water users, under climate and land-use changes conditions.

Effects of Water Mist on the Initial Evolution of Turbulent Premixed Hydrogen/Air Flame Kernels

In this study, a series of carrier-phase direct numerical simulations are conducted on spherical expanding premixed hydrogen/air flames with liquid water addition. An Eulerian–Lagrangian approach with two-way coupling is employed to describe the liquid–gas interaction. The impacts of preferential diffusion, the equivalence ratio, water loading, and the initial diameter of the water droplets are examined and analyzed in terms of flame evolution. It is observed that liquid water has the potential to influence flame propagation characteristics by reducing the total burning rate, flame area, and burning rate per unit area, attributed to flame cooling effects. However, these effects become discernible only under conditions where water evaporation is sufficiently intense. For the conditions investigated, the influence of preferential diffusion on flame evolution is found to be more significant than the interaction with liquid water. The results suggest that due to the slow evaporation rate of water, which is a result of its high latent heat of evaporation, the water droplets do not disturb the initial flame kernel growth significantly. This has implications for water injection concepts in internal combustion engines and for explosion mitigation.

Paraffin/graphite/boron nitride composite as a novel phase change material for rapid heat absorption in battery thermal management technology

Phase change material (PCM) cooling is widely employed in the thermal management of compact battery packs. Thermal protection triggered by rapid temperature rise shortens the effective discharge time in high-rate discharge, making it essential to prepare PCM that rapidly absorbs heat at high temperatures. However, research on the thermal absorption performance and insulating properties of PCM at high-rate discharge remains limited. Herein, we innovatively propose a thermally conductive and insulating PCM with a wide phase transition temperature to address the overheating issue in batteries at 7 C, 8 C and 9 C discharge rates. The C236 consists of paraffin (PA236), graphite and boron nitride with a ratio of 6: 2: 2, which achieves outstanding thermal performance with a latent heat of up to 138.0 J/g and a high-volume resistivity of 1.6 × 108 Ω·m. It is found that at a discharge rate of 7 C, the C236 with a thickness of 3 mm effectively maintains the temperature below 80 °C. At discharge rates of 8 C and 9 C, the PCM significantly reduces the battery temperature by 26.9 % and 32.5 %, respectively, highlighting the rapid heat absorption capability at high temperatures. Furthermore, after four cycles at a 9 C discharge rate, the temperature differential of the battery remains below 5 °C. The low-cost PCM provides a new experimental reference for battery thermal management in high-rate discharge, with broad application prospects.

Partitions influence on rectangular latent heat thermal energy storage unit performance during melting and solidification

The growing use of renewable energy sources demands efficient storage solutions due to their variability. Thermal energy storage systems utilising phase change materials are emerging as viable options to address this challenge. This study evaluates the impact of various partition types on phase change duration in thermal energy storage systems. The well-known and validated enthalpy-porosity algorithm implemented in the Fluent 2021R2 software was used. The shortest melting time was observed in the case with four vertical tubes and three horizontal partitions, which was 82 % shorter than in the reference case. The highest change in specific enthalpy of phase change material (252.5 kJ/kg) during melting was also noted for this system. The shortest solidification time was observed for the case with four tubes and two diagonal partitions, which was 72 % shorter than in the reference case. The greatest increase in the specific enthalpy of phase change material (240.4 kJ/kg) during the solidification process was also observed in this system. In conclusion, due to the thermal conductivity of the partitions, the temperature distribution throughout the domain becomes more homogeonous, thus contributing to more uniform heat flux extraction and supply throughout the process.

Biomass microcrystalline cellulose based solar evaporator with aligned channels for clean water and electricity co-generation

Solar-driven interfacial evaporation co-generation (SDIE-CG) technology can effectively solve problems such as low latent heat utilization in the evaporation process, which provides a reliable solution to the problem of hydropower shortage in remote areas. Herein, we report a tea residue microcrystalline cellulose (TMCC) aerogel (abbreviated as TCA), in which TMCC is regenerated by dissolution through the co-solvent method, and microcrystalline cellulose is rearranged by the directional slow freezing technique to get a TCA with a directional aligned pore structure, resulting in a good mechanical and salt-resistant property. Due to the internal doping of carbon black particles, the TCA has an average ultra-high absorbance of 97.46 %. The evaporation rate of TCA is up to 3.066 kg m−2h−1 under 3 kW m−2 illuminations. The maximum output voltage of the TCA is 44.801 mV under 2 kW m−2 illuminations through the introduction of a suitable wind-assisted hydropower generation device. In addition, the TCA can effectively purify the wastewater containing traditional Chinese medicine, and the chemical oxygen demand (COD) value in wastewater shows a significant decrease after treatment. It is worth noting that TCA can maintain structural integrity and stable evaporation performance in saltwater under extreme pH conditions (2<pH<11), and has potential application value in water treatment and cogeneration.

Molecular simulation and experimental understanding of piperazine-promoted 2-cyclopentylaminoethanol for energy-efficient carbon capture

With the serious climate change and carbon emissions issues facing the world, it is becoming increasingly important to find effective methods to reduce the post-combustion CO2 concentrations. Piperazine −enhanced aqueous amine solvents are still being developed due to the technology is more applicable to large −scale industry. However, the sustainability of the CO2 capture process is still hindered by high energy consumption and amine losses. To tackle this issue, a novel secondary amine, 2-cyclopentylaminoethanol, was synthesized from a primary amine, monoethanolamine. It has a more stable structure than monoethanolamine and was further activated by piperazine. Its effectiveness was compared with piperazine-enhanced N-methyldiethanolamine, N-methyldiethanolamine/triethylenediamine, and 2-amino-2-methyl-1-propanol. The experimental results showed that 2-cyclopentylaminoethanol/piperazine presents the fastest CO2 mass transfer rate, the largest CO2 cyclic capacity and a lower latent heat. The regeneration energy consumption of the absorbent is approximately 2.44 GJ/ton CO2, which is approximately 37.45% lower than that of 30 wt% monoethanolamine solvent. The results are in accordance with the findings of a laboratory-scale pilot plant study, which demonstrated an average reduction of 35.3% in energy consumption. Molecular simulations have revealed that 2-cyclopentylaminoethanol exhibits the lowest energy barrier for reacting with CO2, rendering it more conducive to CO2 reaction. The intermolecular interactions indicate that the hydrogen bonding in the solution after monoethanolamine reacts with CO₂ becomes more pronounced, coupled with a higher energy barrier. Consequently, a greater amount of energy is required during desorption. It can be inferred that 2-cyclopentylaminoethanol/piperazine is a promising energy-efficient and stable absorbent for post-combustion CO2 capture.

Preparation and thermal properties investigation of pentaerythritol based phase change microcapsules for low and medium temperature thermal energy storage

As one of classic organic compounds, pentaerythritol (PE) has been reported to have two phase-change processes with one solid-solid transition and other solid-liquid transition. To utilize these two phase-change enthalpies and avoid the liquid leakage over heat storage process, this work for the first time proposes to encapsulate PE with use of silicon dioxide (SiO2) as a shell substance through a so-called so-gel technology. The microstructure characterization and thermoproperties as well as the cycling performance of the PE- SiO2 composite are detailedly investigated. The results showed that PE could be successfully covered by SiO2 to form a spherical core-shell structure. Such an encapsulation has a mean size of 0.3 μm and an encapsulated rate of over 77.8 %. Due to the involvement of two phase-transition stages, the latent heat of the PE- SiO2 composite reached to 255 kJ/kg, which is higher than other organic microencapsulations. In addition, the thermal conductivity is largely enhanced by adjusting the ratio of SiO2. For a given SiO2 ratio of 77.8 %, the thermal conductivity of PE-SiO2 composite is 0.93 W/m·K, 36.8 % higher than that of pristine PE. Apart from these, the results also indicated that the composite achieves excellent thermal cycling performance. After one hundred repeated heating-cooling cycles, the latent heat of the PE- SiO2 composite decreases by less than 5 %, demonstrating that this composite material has a large potential for application in the field of thermal energy storage at low and medium temperatures.

Bio-based eutectic composite phase change materials with enhanced thermal conductivity and excellent shape stabilization for battery thermal management

Organic phase change materials (PCMs) are commonly used for battery thermal management. Organic petroleum-based PCMs such as paraffin have an adverse effect on environment. Fatty acids as environmentally friendly bio-based PCMs, have enormous potential in sustainable development strategies. Nevertheless, the application of fatty acids in battery thermal management (BTMS) is restricted by the leakage of liquid PCM, poor thermal performance and the improper phase change temperature. We proposed a novel bio-based eutectic composite phase change materials (CPCM) with enhanced thermal conductivity and excellent shape-stabilization, composed of ethylene-vinyl acetate (EVA), Aluminum nitride (AlN), and the eutectic PCM of Lauric acid (LA) and Stearic acid (SA). Significantly, the screened eutectic PCM of LA-SA possesses a suitable phase change temperature(37.03 °C) corresponding to the battery operating temperature, and long-term thermal cycling stability of up to 100 cycles. And the cross-linked structure of EVA effectively encapsulated the eutectic PCM, whose mass only lost below 4% after being heated at 80 °C for 24 h. Simultaneously, the introduction of AlN can greatly improve their heat transfer ability and mechanical properties. LA-SA/EVA/AlN composites with 5 wt% AlN has adequate latent heat of 107.94 J.g−1 and high thermal conductivity of 0.726 W.(m·K)−1 as well as with low flexural strength of 1.72 MPa. Additionally, the proposed CPCM with 5 wt% AlN achieved the maximum temperature of battery below 45 °C during 4C discharging test. It suggested that the CPCM incorporated with AlN is capable effective cooling battery and dissipate energy inside PCM rapidly.

Triple oxygen isotope reveals insolation-forced tropical moisture cycles.

Tropical oceans are the main global water vapor and latent heat sources, but their responses to radiative forcing remain unclear. Here, we investigate oceanic moisture dynamics of the western tropical Pacific (WTP) over the past 210,000 years through an approach of planktonic foraminiferal triple oxygen isotope (Δ'17O). The Δ'17O record is dominated by the precession cycles (~23,000 years), with lower values reflecting higher humidity in concert with higher Northern Hemisphere summer insolation. Our empirical and modeling results, combined with other geological archives, suggest that the enhanced moisture convergence over the WTP largely intensifies changes in the meridional and zonal hydrological cycles, affecting rainfall patterns in East Asia and northern South America. We propose that the insolation-driven WTP moisture dynamics play a pivotal role in regulating tropical hydroclimate.

Variations of summer extreme high temperatures over the Indochina Peninsula: Roles of oceanic systems

Utilizing the reanalysis data and model simulations, we explore the interannual variations of extreme high temperatures over the Indochina Peninsula during 1960–2022, as well as their responses to critical oceanic systems and corresponding mechanisms. Given the intricate interactions among oceanic regions, this study employs the Generalized Equilibrium Feedback Analysis method to extract the atmospheric responses to key ocean systems, including the tropical Indian Ocean (TIO), El Niño–Southern Oscillation (ENSO), and tropical Atlantic. Results highlight the significant contributions of TIO and ENSO. It is suggested that the anomalous anticyclonic circulation located over the Indochina Peninsula, as a response to the warm TIO and ENSO, favors the local anomalous downward motions, resulting in reduced cloud cover, diminished precipitation, increased net radiative energy to the surface and increased sensible and latent heat flux from the surface to the atmosphere, and finally inducing an increase in extreme high temperatures. These observed patterns are also well simulated by the Community Earth System Model tropical Indian Ocean and tropical Pacific Ocean pacemaker experiments, indicating that the warmer tropical Indian Ocean and ENSO could induce anomalous anticyclonic (cyclonic) patterns at the lower (upper) troposphere over the South China Sea, thereby promoting the subsidence and occurrence of extreme high temperatures over the Indochina Peninsula.

Biennial variability of boreal spring surface air temperature over India

In this study, we report significant biennial variability or oscillation (BO) in the boreal spring (March–May) Surface Air Temperature (SAT) over India and unravelled the causative mechanisms. The positive phase of the BO exhibit significant seasonal warming over India, whereas seasonal cooling is observed during the negative phase of BO. Heat wave days are more during the positive phase of BO compared to negative or neutral phase. The positive (negative) phase of BO is generally coherent with the central (eastern) Pacific warming (cooling) years. The anomalous low-level divergence associated with low-level anticyclonic circulation induces less cloudiness and intense surface solar radiation ovr India during the positive phase, favouring surface warming. The evolution of some positive and/or negative phases of BO without any large scale forcing from the equatorial Pacific suggested the possibility of alternate pathways. The strong anomalous upper-level (at 200 hPa) anticyclonic circulation provoked by mid-latitude Rossby waves is found contributing to the positive phase, thereby highlighting the role of dominant mid-latitude pathways in the biennial SAT variability in addition to El Niño forcing. The sinking motion associated with persistent high, and the associated adiabatic compression also supported surface heating during the positive phase of BO. On the other hand, the mid-latitude Rossby wave induced upper-level cyclonic circulation is found contributing to the negative phase. The sinking motion associated with persistent high, and the associated adiabatic compression also supported surface heating during the positive phase of BO. In contrast, negative soil temperature anomalies and high latent heat flux release to the atmosphere supported surface cooling during the negative phase.

Continuous fibers featuring high phase change enthalpy fabricated by melt spinning for thermal management

High performance continuous phase change fibers are of great significance to promote the development and application of functional fibers. But, it is still a challenge to fabricate continuous phase change fibers with high phase transition enthalpy. Herein, a kind of continuous polyurethane phase change fibers (PUPCFs) was first reported which was prepared through melt spinning from the synthesized polyurethane phase change materials (PUPCMs). PUPCFs not only overcomes the leakage problem of phase change materials, but also exhibits high latent heat (110.54 J/g), superior mechanical properties (maximum strain, ∼141.83 %), outstanding fatigue resistance, and good thermal cycle stability. Furthermore, a phase change thermoregulation textile (PUPCT/PDMS) with high enthalpy, hydrophobicity and breathability can be obtained by weaving PUPCFs and then coating with polydimethylsiloxane (PDMS). This work can provide a new idea for efficient and economical production of continuous phase change fibers and opens up opportunities for wearable thermal management textiles.

Enhanced Peltier refrigerator using an innovative hot-side heat-rejection mechanism; Experimental study under both transient and steady-state conditions

Peltier refrigerators are an environmentally friendly cooling method, as they require no refrigerants and have no moving parts. However, effective cooling requires optimal-strong heat rejection from the hot side of the Peltier module. This research proposes and tests a self-capillary ultra-thin (0.1 mm) water-attracting coated PVC membrane (SCCP) as an innovative effective heat rejection mechanism. The SCCP cools the hot side of the Peltier module to temperatures even lower than ambient air, without external power. The cooling effect is achieved through the evaporation of a thin water film on the hot surface, driven by capillary action, which releases latent heat. This process can occur under natural or forced convection, both of which are investigated under various voltage and temperature conditions. The SCCP method was compared to traditional heatsinks and showed superior performance, with the hot side temperature being not only cooler than that in heatsink mode but also cooler than the ambient temperature in most cases. Additionally, the SCCP method demonstrated reduced sensitivity to ambient temperature changes, with only a 2–3° increase in the hot side temperature when the ambient temperature was raised by 10°. The findings suggest that SCCP is a promising technique, with further results discussed.

Cooling performance enhanced by integrating multicomponent phase change material and compression spring into air-cooled battery module

In order to improve the cooling efficiency and temperature consistency of the air-cooled prismatic battery module, a novel multicomponent phase change material-spring plate (MPCM-SP) was developed in this work. The MPCM was formed by combining lauric acid (LA), polyethylene glycol (PEG), palmitic acid (PA), and carboxylated multi-walled carbon nanotubes (MWCNT-COOH). The melting temperature of MPCM can be adjusted within the range 37 °C to 65 °C, and the associated latent heat of phase change varied from 159 J∙g−1 to 209 J∙g−1. The optimized proportions of LA, PEG, PA, and MWCNT-COOH achieved through multiple-objective optimization were 65.55 %, 7.07 %, 25.38 %, and 2.00 %, respectively. The cooling performance of the MPCM-SP was examined by experimental verification and numerical evaluation. The inclusion of MPCM-SP in the air-cooling system resulted in a reduction of 3.41 °C, 3.74 °C, and 3.32 °C in the maximum temperatures of the U-shaped, Z-shaped, and I-shaped battery modules, respectively. Moreover, the temperature difference was decreased by 3.60 °C, 3.16 °C, and 2.42 °C, respectively. Additionally, in comparison to a single battery, a battery equipped with MPCM-SP had a 32.8 % reduction in thermal deformation in the thickness direction under a thermal expansion coefficient of 4.06 × 10-6 K−1.

MONTPEL: A multi-component Penman-Monteith energy balance model

Mechanistic modelling is gradually replacing empiricism in crop models, focusing on leaf-level physiological processes. This shift necessitates simulating crop surface temperature at infra-canopy sub-daily scales but many crop models still rely on empirical formulations for canopy temperature estimation, typically on a daily basis. We developed MONTPEL, a multi-component Penman-Monteith model that allows simulating the crop energy balance with flexible canopy representations (“BigLeaf” vs. “Layered”, “Lumped” vs. “Sunlit-Shaded”) and accounts for atmospheric stability conditions. We analyzed the model behavior, sensitivity and accuracy, using measurements from four wheat (Triticum aestivum L.) experiments conducted under varying pedoclimatic and water stress conditions. Measurements included hourly energy balance terms (total net radiation, soil heat flux, sensible and latent energy fluxes), hourly temperature of the canopy surface or of leaves at different depths inside the canopy, and sunlit and shaded leaf temperatures around solar noon at different dates. MONTPEL reproduced the measured energy balance terms with a root mean square error (RMSE) between 21 and 87 Wm-2 and a coefficient of determination (R²) exceeding 0.65. The model's accuracy in simulating canopy temperature, with RMSE ≤ 2.2 °C and R² ≥ 0.92, remained consistent regardless of measurement scale. Adjusting the aerodynamic resistance for atmospheric stability minimized simulated canopy temperature errors, notably in semi-arid conditions. Crop latent energy flux and temperature were most sensitive to the maximal stomatal conductance (gs,max) parameter. However, using a single gs,max value across the simulated experiments yielded satisfactory results, suggesting a weak sensitivity to the temporal and site-to-site variability of gs,max. Distinguishing sunlit from shaded canopy fractions systematically resulted in lower latent energy fluxes compared to “Lumped” canopy representation results. Analysis identified limitations in the multi-component approach, particularly an unrealistic uniform temperature shift across leaf layers when soil surface temperature changes.

Hygroscopic hydrogel-based cooling system for photovoltaic panels: An experimental and numerical study

Thermal management is an essential aspect of photovoltaic (PV) system design because of the negative effects of high temperatures on the efficiency of PV panels. The use of hygroscopic hydrogels for the evaporative cooling of PV panels is an emerging technique that has attracted attention owing to the high latent heat and recyclability of these materials. However, a comprehensive understanding of the heat and mass transport mechanisms in hygroscopic hydrogels is necessary. Factors that would ensure the long-term performance of PV panel/hydrogel (PV/HG) systems under real-world conditions are still poorly understood, and the intrinsic properties of hydrogels and the effect thereof on their cooling performance have hitherto remained unexplored. Herein, we propose a mathematical model for hydrogel-cooled PV panels to study the heat and mass transfer mechanisms of PV/HG systems in practical environments. The model is used to examine the impact of the thermal conductivity, diffusion coefficient, and thickness of the hydrogel on the performance of the PV/HG system. Unlike previously reported approaches to enhance the efficiency, in this study, the external heat transfer resistance and internal mass transfer resistance were identified as the primary controlling factors. Enhancement of the thermal conductivity of the hydrogel is shown to have a limited effect on the performance, whereas improving the water diffusion within the hydrogel significantly boosts the system efficiency. Optimally, the thickness of the hydrogel must be such that it balances the heat and mass transfer distances with the available water volume. During the summer in Guangzhou, China, a 6-mm thick layer of hydrogel lowered the temperature of a PV cell by up to 7.5 °C to increase the daily power generation by 2.1%. Analysis of the nationwide situation showed that hydrogels have substantial potential for lowering the peak PV panel temperatures (by as much as 19.3 °C) to mitigate fluctuations in the output power. Our findings offer valuable insights into the design of PV/HG systems towards improving their performance.