Latent Heat Research Articles

Preparation and thermal performance study of a novel hydrated salt composite PCM for space heating

In order to effectively address the mismatch between thermal energy supply and demand in buildings, latent heat storage (LHS) based on phase change material (PCM) stands out as a key technology. While hydrated salt has emerged as a promising PCM, it encounters common issues such as substantial supercooling, phase separation, and low thermal conductivity, hindering its development. To mitigate these limitations, this study focused on modifying Ba(OH)2·8H2O by incorporating various nucleating agents and thickening agents to reduce supercooling, enhancing the composite PCM's thermal properties by introducing expanded graphite (EG) to elevate thermal conductivity. Subsequently, the thermal stability of the PCM was evaluated through accelerated thermal cycling tests, encompassing the assessment of critical thermal parameters, including supercooling degree, enthalpy, and thermal conductivity of the composite PCM. Experimental findings unveiled the effectiveness of incorporating 2 wt% BaCl2·2H2O and 1 wt% CMC to Ba(OH)2·8H2O, effectively diminishing the supercooling degree from 14 °C to 1.42 °C. Further integration of 3.5 wt% EG led to a substantial decrease in the supercooling degree to 0.24 °C. Simultaneously, the addition of EG resulted in an improvement in thermal conductivity, elevating it from 0.62 W/(m·K) to 1.03 W/(m·K), while the enthalpy decreased from 283.68 J/g to 252.81 J/g. Notably, the composite PCM exhibited notable thermal reliability with a latent heat drop of 15.9 % following 1000 accelerated cycles of testing. Moreover, the composite PCM demonstrated superior thermal storage density, measuring at 2.36 times that of traditional paraffin wax, yet with a thermal storage cost merely a quarter of paraffin wax, rendering it more favorable for extensive deployment in building energy systems.

Improving the Statistical Representation of Tropical Cyclone In-Storm Sea Surface Temperature Cooling

Abstract This study uses fixed buoy time series to create an algorithm for sea surface temperature (SST) cooling underneath a tropical cyclone (TC) inner core. To build predictive equations, SST cooling is first related to single variable predictors such as the SST before storm arrival, ocean heat content (OHC), mixed layer depth, sea surface salinity and stratification, storm intensity, storm translation speed, and latitude. Of all the single variable predictors, initial SST before storm arrival explains the greatest amount of variance for the change in SST during storm passage. Using a combination of predictors, we created nonlinear predictive equations for SST cooling. In general, the best predictive equations have four predictors and are built with knowledge about the prestorm ocean structure (e.g., OHC), storm intensity (e.g., minimum sea level pressure), initial SST values before storm arrival, and latitude. The best-performing SST cooling equations are broken up into two ocean regimes: when the ocean heat content is less than 60 kJ cm−2 (greater spread in SST cooling values) and when the ocean heat content is greater than 60 kJ cm−2 (SST cooling is always less than 2°C), which demonstrates the importance of the prestorm oceanic thermal structure on the in-storm SST value. The new equations are compared to what is currently used in a statistical–dynamical model. Overall, since the ocean providing the latent heat and sensible heat fluxes necessary for TC intensification, the results highlight the importance for consistently obtaining accurate in-storm upper-oceanic thermal structure for accurate TC intensity forecasts. Significance Statement The ocean provides the heat and moisture necessary for tropical cyclone (TC) intensification. Since the heat and moisture transfer depend on the sea surface temperature (SST), we create statistical equations for the prediction of SST underneath the storm. The variables we use combine the initial SST before the storm arrives, the upper-ocean thermal structure, and the strength and translation speed of the storm. The predictive equations for SST are evaluated for how well they improve TC intensity forecasts. The best-performing equations can be used for prediction in operational statistical models, which can aid intensity forecasts.

Preparation and characterization of expanded dickite/decanoic acid phase-change materials

The leakage of phase-change materials presents a significant challenge that impedes their application. Loading porous materials onto phase-change materials is an effective approach to addressing this issue. In this study, porous expanded dickite as a carrier was utilized to load decanoic acid and create a composite phase-change material. The loading content of decanoic acid was varied to obtain different composite phase-change materials. Fourier transform infrared spectroscopy analysis confirmed the formation of hydrogen bonds between the expanded dickite carrier and decanoic acid. Scanning electron microscopy images and energy-dispersive X-ray spectroscopy mapping results demonstrated that decanoic acid was evenly dispersed on the expanded dickite carrier without any agglomeration. The expanded dickite carrier effectively immobilized decanoic acid through hydrogen bonding, thereby preventing leakage, as long as the loading content of decanoic acid did not exceed 60%. The higher thermal conductivity of the expanded dickite carrier promoted the thermal conductivity of the expanded dickite/decanoic acid composite phase-change materials, enhancing the responsiveness of the composite phase-change materials to ambient temperature. The composite phase-change material containing 60 wt% decanoic acid exhibited excellent endothermic/exothermic cycle stability, and after six cycles, its latent heat remained stable.

Insights into effect of lignocellulosic biomass framework types on bio-based shape stable composite phase change materials

The utilization of biomass waste as framework materials to inhibit the leakage of phase change material (PCMs) has gained widespread attention. In this work, three new kinds of shape stable composite phase change materials (sscPCMs) were prepared which combined with stearic acid (SA) and peanut shell powders (PSP), poplar wood powders (PWP), and corn straw powders (CSP), respectively. The influence of lignocellulosic biomass types on the thermal energy storage performance of sscPCMs was studied by comparing three types of sscPCMs. The research results indicated that SA/CSP exhibited superior properties in terms of load capacity and thermal energy storage performance. According to leakage experiments the load capacity of SA/PSP, SA/PWP and SA/CSP was 31.67 %, 44.69 %, and 50.09 %, respectively. The phase change latent heat of SA/PSP, SA/PWP, and SA/CSP was 55.78, 84.27 and 98.47 J/g, respectively. In addition, the relationship between biomass component content and load rates was studied. The results showed that there was a positive correlation between the loading rates of SA and the ratio of holocellulose (cellulose + hemicellulose) to lignin. The results provided a promising approach for the selection of lignocellulosic biomass framework materials.

Role of aloe vera based nanofluids for cool thermal energy storage system: A comparative study

The present experimental investigation incorporates the preparation of aloe vera gel-based phase change nanofluid (NFPCM) for a cool thermal energy storage (CTES) system. Two sets of NFPCMs were produced by adding graphene nanoplatelets (GNP) in deionized water and aloe vera gel (0.20 wt%, 0.40 wt%, and 0.60 wt%). The zeta potential analysis shows that the NFPCM with aloe vera gel is more stable even after 60 days from the preparation (−44 mV). The thermal conductivity of NFPCMs was analyzed through the transient hot wire method and the enhancement of 42 %, and 37.5 % were measured in the ice phase for NFPCMs with aloe vera gel and DI water (0.60 wt%) respectively at the heat transfer fluid temperature of −15 °C. The NFPCMs with aloe vera gel show that the addition of GNP prepended the peak melting temperature from −16 °C to −10.5 °C, which is due to the quick formation of nuclei as compared to NFPCMs with DI water. Additionally, a slight reduction in the latent heat of only 7 % was observed. The charging characteristics of NFPCMs were studied in a single spherical capsule at −8 °C. The maximum reduction in total charging time of 25 % was recorded for the aloe vera gel-based NFPCM with a maximum concentration of GNP (0.60 wt%). The green synthesis of aloe vera gel-based NFPCM exhibited noteworthy enhancements in thermophysical properties. Additionally, it was observed that the long-term stability of the NFPCM was achieved by excluding surfactants during the preparation process. The incorporation of graphene nanoplatelets (GNP) into aloe vera gel as the foundational phase change material (PCM) facilitates the partial charging of the CTES system with a reduced energy input.

Design and Implement a BTMS using Phase Change Material - A Review

Abstract: This paper presents a comprehensive review of the design and implementation of Battery Thermal Management Systems (BTMS) utilizing Phase Change Materials (PCM). The thermal management of batteries is crucial for ensuring optimal performance, safety, and longevity, particularly in electric vehicles and renewable energy storage applications. Phase change materials offer unique advantages for thermal management, including high latent heat storage capacity, thermal conductivity, and temperature regulation capabilities. This review discusses the fundamentals of PCM-based BTMS design, including PCM selection, integration methods, and system optimization techniques. Additionally, recent advancements, challenges, and future directions in PCM-based BTMS are explored, providing valuable insights for researchers, engineers, and industry practitioners in the field of energy storage systems.

Performance Analysis and Optimization of Compressed Air Energy Storage Integrated with Latent Thermal Energy Storage

Recovering compression waste heat using latent thermal energy storage (LTES) is a promising method to enhance the round-trip efficiency of compressed air energy storage (CAES) systems. In this study, a systematic thermodynamic model coupled with a concentric diffusion heat transfer model of the cylindrical packed-bed LTES is established for a CAES system, and the numerical simulation model is validated by experimental data in the reference. Based on the numerical model, the charging–discharging performance of LTES and CAES systems is evaluated under different layouts of phase change materials (PCMs) in LTES, and the optimal layout of PCM is specified as a three-stage layout, since the exergy efficiency of LTES and round-trip efficiency are improved by 8.2% and 6.9% compared with a one-stage layout. Then, the proportion of three PCMs is optimized using response surface methods. The optimization results indicate that the exergy efficiency of LTES and round-trip efficiency of the CAES system are expected to be 80.9% and 73.3% under the PCM proportion of 0.48:0.3:0.22 for three stages, which are 7.0% and 13.1% higher than the original three-stage PCMs with equal proportions.

Sustainable All-Day Thermoelectric Power Generation From the Hot Sun and Cold Universe.

Energy conversion from the environment into electricity is the most direct and effective electricity source to sustainably power off-grid electronics, once the electricity requirement exceeds the capability of traditional centralized power supply systems. Normally photovoltaic cells have enabled distributed power generation during the day, but do not work at night. Thus, efficient electricity generation technologies for a sustainable all-day power supply with no necessity for energy storage remain a challenge. Herein, an innovative all-day power generation strategy is reported, which self-adaptively integrates the diurnal photothermal and nocturnal radiative cooling processes into the thermoelectric generator (TEG) via the spectrally dynamic modulated coating, to continuously harvest the energy from the hot sun and the cold universe for power generation. Synergistic with the optimized latent heat phase change material, the electricity generation performance of the TEG is dramatically enhanced, with a maximum power density exceeding 1000mWm-2 during the daytime and up to 25mWm-2 during the nighttime, corresponding to an improvement of 123.1% and 249.1%, compared with the conventional strategy. This work maximizes the utilization of ambient energy resources to provide an environmentally friendly and uninterrupted power generation strategy. This opens up new possibilities for sustained power generation both daytime and nighttime.

Vapor Pressure and Enthalpy of Vaporization of Guanidinium Methanesulfonate as a Phase Change Material for Thermal Energy Storage

This paper reports the vapor pressure and enthalpy of vaporization for a promising phase change material (PCM) guanidinium methanesulfonate ([Gdm][OMs]), which is a typical guanidinium organomonosulfonate that displays a lamellar crystalline architecture. [Gdm][OMs] was purified by recrystallization. The elemental analysis and infrared spectrum of [Gdm][OMs] confirmed the purity and composition. Differential scanning calorimetry (DSC) also confirmed its high purity and showed a sharp and symmetrical endothermic melting peak with a melting point (Tm) of 207.6 °C and a specific latent heat of fusion of 183.0 J g−1. Thermogravimetric analysis (TGA) reveals its thermal stability over a wide temperature range, and yet three thermal events at higher temperatures of 351 °C, 447 °C, and 649 °C were associated with vaporization or decomposition. The vapor pressure was measured using the isothermogravimetric method from 220 °C to 300 °C. The Antoine equation was used to describe the temperature dependence of its vapor pressure, and the substance-dependent Antoine constants were obtained by non-linear regression. The enthalpy of vaporization (ΔvapH) was derived from the linear regression of the slopes associated with the linear temperature dependence of the rate of weight loss per unit area of vaporization. Hence, the temperature dependence of vapor pressures ln Pvap (Pa) = 10.99 − 344.58/(T (K) − 493.64) over the temperature range from 493.15 K to 573.15 K and the enthalpy of vaporization ΔvapH = 157.10 ± 20.10 kJ mol−1 at the arithmetic mean temperature of 240 °C were obtained from isothermogravimetric measurements using the Antoine equation and the Clausius–Clapeyron equation, respectively. The flammability test indicates that [Gdm][OMs] is non-flammable. Hence, [Gdm][OMs] enjoys very low volatility, high enthalpy of vaporization, and non-flammability in addition to its known advantages. This work thus offers data support, methodologies, and insights for the application of [Gdm][OMs] and other organic salts as PCMs in thermal energy storage and beyond.

An improved passive solar still integrated with pulsating heat pipes and phase change materials

This paper presents a theoretical analysis of a novel solar still system, which was previously explored through experimental studies. The experimental results demonstrate that integrating phase change material (PCM) to store latent heat from vapor condensed on sidewalls during sunlight exposure, along with the use of pulsating heat pipes (PHPs) to recover this stored energy after sunset, and cooling the condenser sidewalls with PCM, significantly boosts the system’s efficiency from 23.7 % to 48.5 %. These innovative features, applied for the first time in a single-stage passive solar still, are thoroughly examined using a groundbreaking mathematical model. This model is the first to uniquely account for heat transfer and condensation on sidewalls and to accurately simulate the function of pulsating heat pipes (PHPs) within a passive solar still setup. By incorporating measured radiation intensity and ambient temperatures, the model applies an exhaustive energy balance, utilizing heat transfer correlations and resistances for precise temperature predictions of each component. This detailed analysis highlights the system’s innovative aspects and identifies areas for further refinement, shedding light on potential improvements and the system’s limitations. The results show a water production of 6.7931 kg/m2 and an efficiency of 52.2 %, with a discrepancy of 7.8 % compared to experimental findings. Notably, 37.6 % of the total freshwater production is derived from sidewall condensation, significantly reducing heat loss by capturing latent heat. Additionally, by reallocating 9.3 % of stored energy, the PHPs maintain the saline water temperature 6.2 degrees higher at night, thereby sustaining elevated production rates.

A novel stereotyped phase change material with a low leakage rate for new energy storage building applications

Phase change materials (PCM) have been widely studied in the field of building energy storage. However, industrial grade high latent heat phase change paraffin (PW) has the problem of high melting point and easy leakage, and at the same time, it is necessary to absorb municipal solid waste on a large scale and reduce the damage of waste cellular concrete (WCC) to the urban ecological environment. Using binary paraffin wax (BP) prepared by hot fusion of solid paraffin (SP) and liquid paraffin (LP) as composite phase change materials, polypropylene (PP) and porous material WCC as support materials, a new WCC/PP/BP stereotyped phase change material (FCPCM) with low leakage rate and good stability was prepared by melt blending method and vacuum adsorption method, to meet the energy storage needs of buildings. The chemical compatibility, thermal performance and morphological stability of the prepared FCPCM were tested, and the heat storage/release performance test experiments were carried out to explore the thermal performance of the prepared energy storage concrete. The results show that the Encapsulated WCC/PP/BP has no new substance and good chemical compatibility. The results of scanning electron microscope (SEM) and mercury injection instrument (MIP) show that WCC has good adsorption properties for PP/BP. The melting phase change temperature increases by 14.08%, the latent heat of phase change decreases by 42.94%, and the initial phase change thermal properties are still maintained after several phases of phase change. It can maintain a stable form at 150℃. The 24 h leakage rate remained below 1%, which was nearly 44% lower than that of FCPCM with PP as the support material. Thermogravimetric curve (TGA) shows that the thermal stability of encapsulated FCPCM increases by 25.59%. In addition, the thermal performance test of energy storage concrete shows that compared with traditional concrete, energy storage concrete has greater heat storage density and stronger temperature control ability, which can effectively realize building energy saving.

On the persistence and related mechanisms for day–night compound humid heat extremes in the Northern Hemisphere

Hot extremes pose adverse impacts on human health and ecosystem, leading to aggravated damage when they combine high-humidity and occur in the both daytime and nighttime. Although considerable studies have focused on hot extremes, understandings about day–night Compound humid heat (quantified by Moist Enthalpy) Extremes (CMEEs) are still lacking. This work investigates their frequency, linear trends and temporal persistence in the Northern Hemisphere, and two typical vulnerable regions are selected as Central Europe (CE) and the Arabian Peninsula (AP), both exhibiting high frequency and positive trends, but with contrasting persistence, which is quantified by the bivariate Dynamical System method. Results reveal their regional dependence and physical processes: the dual importance of sensible and latent heat in CE is attributed to the combination of an anomalous anticyclone and evaporation, whereas the dominance of latent heat in AP is largely owing to the convective precipitation. CMEEs in AP can be further divided into two groups with distinct persistence, and this disparity actually depends on the preceding precipitation duration and its associated water vapor supply.

Residual Stress Formation and Distortion in Austenitic AISI304 Steel Pipe Weldment with Consideration of Latent Heat using Novel Prescribed Weld Temperature

Residual Stress Formation and Distortion in Austenitic AISI304 Steel Pipe Weldment with Consideration of Latent Heat using Novel Prescribed Weld Temperature

Multi-stimulus perception and visualization by an intelligent liquid metal-elastomer architecture.

Multi-stimulus responsive soft materials with integrated functionalities are elementary blocks for building soft intelligent systems, but their rational design remains challenging. Here, we demonstrate an intelligent soft architecture sensitized by magnetized liquid metal droplets that are dispersed in a highly stretchable elastomer network. The supercooled liquid metal droplets serve as microscopic latent heat reservoirs, and their controllable solidification releases localized thermal energy/information flows for enabling programmable visualization and display. This allows the perception of a variety of information-encoded contact (mechanical pressing, stretching, and torsion) and noncontact (magnetic field) stimuli as well as the visualization of dynamic phase transition and stress evolution processes, via thermal and/or thermochromic imaging. The liquid metal-elastomer architecture offers a generic platform for designing soft intelligent sensing, display, and information encryption systems.

Phase change-related thermal property characterization and enhancement in carbon-based organic phase change composites

By utilizing the significant amount of energy absorbed and released during their phase transitions, phase change materials (PCMs) can capture and store thermal energy to fill gaps between supply and demand. Due to their many favorable properties, organic PCMs have gained attention in a wide range of applications. Nevertheless, their inherent low thermal conductivity has limited the direct use of organic PCMs in thermal energy storage (TES). Extensive research has been conducted on enhancing organic PCM thermal conductivity by incorporating high thermal conductivity materials. Owing to their high thermal conductivity and low density, carbon-based materials have been extensively used for thermal conductivity enhancement in phase change composites (PCCs). Carbon-based organic PCCs, which incorporate highly thermally conductive carbon allotropes and their direct chemical derivatives with organic PCMs, are a group of diverse PCCs with highly promising potential for TES applications. Adequate latent heat and shape stability performances are crucial to the success of the applicational performances of these PCCs. Much empirical research has pushed efforts to enhance these phase change properties, yet a logical understanding of these enhancement efforts based on the thermodynamics and intermolecular interactions of carbon-based organic PCCs has been elusive. In particular, the effect of characterization methods on the evaluation of phase change properties has been largely understudied. This review strives to provide novel physical and chemical insights into latent heat and shape stabilization evaluation processes and enhancement efforts in carbon-based organic PCCs through a detailed review and analysis of recent literature. The review provides an unprecedented comprehension of newly developed PCCs that challenge the traditional understanding that the latent heat of PCCs cannot exceed that of its base PCM. Efforts on phase change property enhancement driven by these new insights have the potential for carbon-based organic PCCs to succeed in a variety of TES applications, including solar-thermal harvesting, thermal management of batteries and electronics, thermoregulating textiles, and infrared stealth and infrared responsive materials.

Comparative evaluation of four actual evapotranspiration models over different ecosystems and climate zones in China

ABSTRACT To better understand the discrepancies in evapotranspiration (ET) simulations between ET models, we intercompared four models in China: Priestley–Taylor Jet Propulsion Laboratory (PT-JPL), Penman–Montieth–Leuning Version 2 (PML-V2), Sigmoid Generalized Complementary Function (SGCF), Mapping Evapotranspiration at High Resolution with Internalized Calibration (METRIC). Data from 18 flux sites were used to evaluate the model performance at daytime (when incident shortwave radiation is greater than 20 W/m2) scales. To compare more fairly, we took the intersection of the outputs from four models for the analyses in the main text. All models yielded acceptable results, with PML-V2 or SGCF performing best at most sites. The average coefficient of determination and root mean square error among all sites of LE (latent heat of ET) were 0.72 and 51.71 W/m2 for PT-JPL, 0.80 and 46.65 W/m2 for PML-V2, 0.79 and 41.13 W/m2 for SGCF, 0.70 and 51.09 W/m2 for METRIC. PT-JPL and PML-V2 underestimated ET at most sites, whereas SGCF overestimated, potentially due to uncertainties in the vegetation indices and ET constraint parameters. Compared to measurements, PT-JPL underestimated the proportion of transpiration to evapotranspiration (0.81 versus 0.59), while PML-V2 overestimated (0.81 versus 0.90). Furthermore, all models performed best in the semi-arid zone dominated by grassland sites.

An objective identification technique for potential vorticity structures associated with African easterly waves

Abstract. Tropical Africa and the North Atlantic Ocean are significantly influenced by African easterly waves (AEWs), which play a fundamental role in tropical rainfall and cyclogenesis in that region. The dynamics of AEWs can be described in a potential vorticity (PV) framework. The important impact of latent heat release by cloud processes is captured in this framework by the diabatic generation of PV anomalies. This paper introduces an innovative approach for the identification and tracking of PV structures within AEWs. By employing AEW tracking and computing the wave phase of each point within the AEW domain using a Hilbert transform, we are able to effectively identify and collect 3-D PV structures associated with specific AEWs. To facilitate a climatological analysis, performed here over the months of June to October from 2002 to 2022, these structures are subsequently characterized by low-dimensional descriptors, including their location, intensity, and orientation. Our climatological analysis reveals the seasonal evolution and the structural attributes of PV anomalies within AEWs over the study domain. PV feature locations closely align with the African easterly jet's latitudinal shift during the summer season. Analysis of the mean pressure level of the 3-D PV structures shows a remarkable shift during their life cycle, indicating deep moist convection characteristics over land and more shallow convection characteristics over the ocean. On average, PV features identified within AEW troughs tilt downshear over land and equatorward over the ocean. The trough-centered analysis reveals distinct differences between satellite-estimated and model-predicted rainfall. Agreement between the results of a more traditional composite analysis and our new feature analysis provides confidence in our feature approach as a novel diagnostic tool. The feature framework provides a low-dimensional representation of the PV structure of AEWs, which facilitates future statistical analyses of the relation of this structure to, for example, tropical cyclogenesis or the predictability of tropical rainfall.

Thermal storage performance of a novel shell-and-tube latent heat storage system: Active role of inner tube improvement and fin distribution optimization

This study presents a numerical analysis of the melting process in a shell-and-tube latent heat thermal energy storage (LHTES) system, featuring a twisted elliptical inner tube with annular fins. Utilizing paraffin as the phase change material (PCM) and water as the heat transfer fluid (HTF), this research examines the impact of varying twist degrees, fin quantity and fin distribution on the system's thermal performance during melting process. The analysis of the melting process includes complete melting time, temperature, and the contour of the solid-liquid interface. Notably, the study identifies that both fin quantity and distribution play a significant role in the melting process. The findings indicate that an optimal configuration, comprising a 720° twisted degree, 11 fins, and a base number a of 0.80, enhances the melting efficiency of the LHTES system by 156.44 % and reduces ineffective heat loss by 41.36 %. These results highlight the potential advantages of the twisted elliptical inner tube structure and propose an innovative approach with an exponentially non-uniform fin distribution, marking an advancement in the field of thermal energy storage.

Influence of alloy solidification path on melt pool behavior in additive manufacturing

Numerical models used to study transport phenomena in laser-powder bed fusion processes often rely on assumptions and simplifications to reduce their computational expense. One common simplification is in the description of latent heat evolution during the solid-liquid phase change (i.e., the solidification pathway), justified by the fact that the mushy zone thickness is similar to the numerical grid spacing used for continuum transport models. The lack of resolution of transport phenomena in the mushy zone motivates the use of computationally convenient solidification paths such as linear or sigmoidal relationships over pathways derived from fundamental solidification theory such as equilibrium or Scheil models. In the present work, an uncertainty quantification (UQ) framework is used to analyze the influence of solidification pathway selection on the solidification dynamics and melt pool geometries in laser based additive manufacturing (AM) of IN625. Results show the solidification pathway has a quantifiable influence on the cooling rate at the liquidus isotherm, mushy zone thickness, and solidification time. Due to similarities in the latent heat evolution at the beginning of solidification, the equilibrium and Scheil models predict similar cooling rates near the liquidus isotherm, however the wider freezing range of Scheil leads to a wider mushy zone compared to equilibrium. The non-physical latent heat release profiles of sigmoidal and linear paths lead to significant overpredictions of cooling rates at the liquidus isotherm compared to equilibrium and Scheil. These results indicate that careful consideration should be given to the choice of solidification pathway to ensure reliable model predictions.

Latent heat storage bio‐composites from egg‐shell/PE/PEG as feasible eco‐friendly building materials

AbstractIntegrating phase change materials (PCMs), which store thermal energy as latent heat, into renewable energy production is an efficient way to harness solar energy. Thereby, the aim of this work is to develop convenient and efficient method to prepare a bio‐composite phase change materials (BCPCMs) that are eco‐friendly and cheap. The polyethylene glycol (PEG) with large latent heat was used as PCM, eggshell powder (ES) as an energy storage material (bio‐energy resources/bio‐waste is converted into useful energy storage material), the low‐density polyethylene (PE) performed as the supporting material and powder graphite (G) was the additives for improving the thermal conductivity. According to thermal gravimetric analysis (TGA), the use of ES and G improved the thermal stability of BCPCM. On the other hand, the results of the differential calorimetric analysis (DSC) showed that BCPCM6 with the addition of 5 wt% of graphite filler in the mixture PEG/PE/ES (70/20/5 wt%) provides excellent thermal stability and high energy storage density per unit mass. In light of its high latent heat storage capacity of 120.1 J/g as well as its ability to prevent PEG exudation, BCPCM ensures higher thermal conductivity and shape stability during phase transition than ordinary PCM. Significant enhancement in melting‐solidification time shows an improvement in Thermal Energy Storage (TES) response time to the demand by adding ES and G respectively to the PCM. Based on the obtained results, the BCPCM as a potential candidate for an application in buildings of hot and dry climates.Highlights Shape‐stabilized BCPCMs were prepared by blending and impregnating method. The BCPCM combines a high storage capacity and high heat propagation rate. BCPCM6 provides excellent thermal stability and high energy storage density. Enhancement in melting‐solidification time by adding ES and G to the PCM. BCPCM as a candidate for an application in buildings of hot and dry climates.