Large-scale Hydrogen Research Articles

Oxygen-coordinated cobalt single atom steered by doped-O and CoO for efficient hydrogen evolution at industrial current densities

The exploration and design of highly active, low-cost, transition metal-based electrocatalysts are crucial for large-scale green hydrogen production. Here, the heterostructure of oxygen-coordinated cobalt single atoms with O-doped carbon and CoO nanowires (Co-O-C-O/CoO/CF) is constructed for efficient and stable HER at industrial current densities. Benefiting from the synergistic effect of O doping and CoO nanowires, Co-O-C-O/CoO/CF exhibits extremely low overpotentials of 24.8, 229, and 239 mV to achieve current densities of 10, 500, and 1000 mA cm−2 in 1.0 M KOH solution, respectively, and operates stably for 1000 h at 1000 mA cm−2. Additionally, when coupled with NiFe-LDH in a self-assembled electrolyzer, it delivers a high current density of 1000 mA cm−2 at 1.97 V, along with outstanding stability, outperforming Pt/C||NiFe-LDH and most reported electrolyzers. Density functional theory (DFT) calculations reveal that the optimized d-band center and binding strength of H* and OH* intermediates for Co-O-C-O/CoO/CF lower the energy barrier of the rate-determining step. This work provides a new pathway for engineering Co-based catalysts for green hydrogen production at industrial current densities.

A Review of Stoichiometric Nickel Sulfide-Based Catalysts for Hydrogen Evolution Reaction in Alkaline Media

Efficient and cost-effective catalysts for hydrogen evolution reaction (HER) are essential for large-scale hydrogen production, which is a critical step toward reducing carbon emissions and advancing the global transition to sustainable energy. Nickel sulfide-based catalysts, which exist in various stoichiometries, show promise for HER in alkaline media. However, as single-phase materials, they do not demonstrate superior activity compared to Pt-based catalysts. This review highlights recent strategies to enhance the HER performance of nickel sulfides, including heteroatom doping, heterostructure construction, and vacancy engineering, tailored to their different stoichiometric ratios. The study also examines synthesis methods, characterizations, and their impact on HER performance. Furthermore, it discusses the challenges and limitations of current research and suggests future directions for improvement.

Hydrogen enriched natural gas-fueled solid oxide fuel cells supported by Ni-Cu co-doping CeO2-δ catalyst-modified finger-like pore anode

Hydrogen blending in natural gas pipelines is one of the key technologies to realize the long-distance hydrogen transmission, which facilitates the large-scale hydrogen utilization. Solid oxide fuel cells can directly use hydrogen enriched natural gas (HENG, with 20 % H2) to generate electricity without separating and purifying the hydrogen, which enables the efficient conversion of hydrogen energy. In this work, finger-like pore anodes and Ni0.05Cu0.05Ce0.9O2-δ (NCCO) catalyst are prepared to address the need for anode performance and stability with hydrogen-doped natural gas fuels. The results show that NiCu@CeO2 precipitates NiCu nano-alloys on the surface after reduction treatment, which is beneficial for the anode activity. With NCCO catalyst, the maximum power densities of the single cells are 970 mW cm−2 and 700 mW cm−2 at 750 °C under wet H2 and HENG fuel atmospheres, respectively. At 750 °C, the methane conversion is as high as 46 %. More importantly, the single cell can run smoothly for 150 h, with the constant voltage (0.8 V) discharge and HENG as fuel gas. Our results confirm that the synthesized NCCO catalysts have excellent ability to catalyze CH4 and carbon resistance.

Prospects for Long-Distance Cascaded Liquid—Gaseous Hydrogen Delivery: An Economic and Environmental Assessment

As an important energy source to achieve carbon neutrality, green hydrogen has always faced the problems of high use cost and unsatisfactory environmental benefits due to its remote production areas. Therefore, a liquid-gaseous cascade green hydrogen delivery scheme is proposed in this article. In this scheme, green hydrogen is liquefied into high-density and low-pressure liquid hydrogen to enable the transport of large quantities of green hydrogen over long distances. After long-distance transport, the liquid hydrogen is stored and then gasified at transfer stations and converted into high-pressure hydrogen for distribution to the nearby hydrogen facilities in cities. In addition, this study conducted a detailed model evaluation of the scheme around the actual case of hydrogen energy demand in Chengdu City in China and compared it with conventional hydrogen delivery methods. The results show that the unit hydrogen cost of the liquid-gaseous cascade green hydrogen delivery scheme is only 51.58 CNY/kgH2, and the dynamic payback periods of long- and short-distance transportation stages are 13.61 years and 7.02 years, respectively. In terms of carbon emissions, this scheme only generates indirect carbon emissions of 2.98 kgCO2/kgH2 without using utility electricity. In sum, both the economic and carbon emission analyses demonstrate the advantages of the liquid-gaseous cascade green hydrogen delivery scheme. With further reductions in electricity prices and liquefication costs, this scheme has the potential to provide an economically/environmentally superior solution for future large-scale green hydrogen applications.

In-situ exfoliating graphene to anchor Mo2C NPs and modulate crystal planes for hydrogen production

An economical and efficient noble metal-free catalyst is necessary for large-scale hydrogen production. Here, Mo2C nanoparticles (NPs) were well-dispersed on the surface of 2D graphene nanosheets by in-situ propping oxide graphene (GO) layers, anchoring molybdate ions between GO layers and pyrolysis. The exposed crystal planes were also adjusted by above strategy. The results indicate that uniform and well-dispersed Mo2C NPs with a narrow size distribution were anchored on 2D rGO nanosheets and exposed dual crystal planes. The results of hydrogen evolution reaction (HER) show that the optimal Mo2C/rGO catalyst only needs low overpotential (η10, 112 mV) to drive 10 mA cm−2 in alkaline solution, and η10 only increased by 12 mV after 1000 cycles test, indicating high activity and stability for HER. Notably, the overpotential is below than that of Pt/C commercial catalyst when current density is more than 100 mA cm−1. The excellent performance is benefit from low hydrogen adsorption Gibbs free energy (ΔGH∗) on the Mo2C catalyst. Therefore, the proposed strategy is efficient to prepare well-dispersed and dual crystal planes-exposed Mo2C NPs for electrocatalytic hydrogen evolution.

Noble-metal-free Bi-OZIS nanohybrids for sacrificial-agent-free photocatalytic water splitting: With long-lived photogenerated electrons

The production of hydrogen via the hydrogen evolution reaction, reliant on the use of valuable sacrificial agents, is not conducive to large-scale photocatalytic hydrogen generation. A more pragmatic approach involves the creation of catalyst materials free from noble metals, which possess enduring photogenerated electrons suitable for catalyzing hydrogen evolution from undiluted water. In our research, x%Bi-OZIS nanohybrids were effectively synthesized. Remarkably, the hydrogen evolution rate for the 10 %Bi-OZIS sample reached 170.22 μmol g-1h−1, marking an enhancement of 11.8 times over pure ZIS and 3.7 times over OZIS, achieved without resorting to sacrificial agents. Notably, post-light exposure, H2O2 presence was identified in the water solution. The strategy of substituting some of the sulfur with oxygen doping extends the lifespan of the photogenerated carriers. Further, the introduction of Bi spheres onto the OZIS nanosheet surfaces substantially reduces electron-hole interband recombination. These adaptations collectively augment the photogenerated electron lifespan in x%Bi-OZIS nanohybrids, leading to heightened photocatalytic redox proficiency. This research outlines a method for devising an economical solar-driven water splitting mechanism devoid of sacrificial agents.

Chitosan–sodium Tripolyphosphate–CuO Biopolymer–nanocomposite as an Efficient Electrocatalyst for Water Splitting

Background: Fossil fuels have been used extensively as primary energy sources, which has resulted in nearly depleted reserves, a contaminated environment, and a variety of negative health effects globally. Hydrogen has been proposed by researchers as an effective “carbon neutral” fuel. Large-scale hydrogen production through electrochemical water splitting necessitates the use of inexpensive, extremely effective, and earth-abundant electrocatalysts. Method: In this study, chitosan–sodium tripolyphosphate (TPP) nanoparticles are combined with CuO nanostructures to produce chitosan–TPP–CuO (CT/CuO) nanocomposite. Chitosan–TPP nanoparticles were first synthesized using the ionic gelation method. These nanoparticles were then extracted, and CuO was synthesized in situ in polymer nanoparticles using a simple chemical precipitation method. Chitosan and CuO are abundantly available and are environmentally beneficial materials. The porous structure and open channels within the chitosan polymer matrix host the CuO nanostructures, which promote electrolyte penetration, mass transport, and charge transfer, while the metal-oxide nanostructures act as catalytic centers. The structural and morphological properties of the CT/CuO nanocomposite were investigated using XRD, HRSEM, and HRTEM. The band gap and functional groups in the material were measured by UV–Vis DRS and FTIR methods, respectively. Elemental analysis was conducted utilizing EDS, HRSEM, and XPS. Thermal characteristics of the CT/CuO nanocomposite were investigated using TG-DTA and DSC methods. Electrochemical techniques were used to investigate the activities of HER and OER. Results: The XRD examination of the CT/CuO nanocomposite revealed semi-crystalline chitosan peaks and a monoclinic CuO structure. HRSEM and HRTEM pictures indicated that chitosan–TPP nanoparticles and CuO nanostructures were evenly spread and clustered to create a nanoparticulate matrix. UV–Vis DRS indicated that the CT/CuO nanocomposite had a direct band gap of 1.702 eV. The FTIR and XPS studies revealed the various bonds and oxidation states of the nanocomposite. Thermal analyses demonstrated that the inclusion of CuO increased the thermal stability of the CT/CuO nanocomposite. CT/CuO nanocomposite exhibited excellent OER and HER activity, requiring a low overpotential of 444 mV and 379 mV at 10 mA cm−2 and -10 mA cm−2, respectively. Conclusion: Biopolymer metal-oxide nanocomposites could potentially be used as electrocatalysts in water splitting, energy conversion, storage devices, sensors, and several other fields.

Design and Optimization of Large-Scale Green Liquid Hydrogen Production Integrated with Heat Recovery and Absorption Precooling

Design and Optimization of Large-Scale Green Liquid Hydrogen Production Integrated with Heat Recovery and Absorption Precooling

Hydrogen underground storage for grid electricity storage: An optimization study on techno-economic analysis

This study performs a techno-economic analysis of hydrogen underground storage systems for grid electricity storage, evaluating their economic viability at the plant scale using dynamic optimization. It explores the feasibility of various system configurations and revenue models in the context of volatile electricity prices and the necessity for multiple revenue streams. The hypothesis tested is that large-scale hydrogen storage, despite its low round-trip efficiency, can be economically viable with the right mix of revenue streams. This study uses scenario-based analysis to assess the impacts of different system configurations, including engaging in time-shifting arbitrage, ancillary service markets and blending hydrogen with natural gas. Results indicate potential annual net cash flows of up to $1.5 million from ancillary services integration and $5.2 million from natural gas blending, contingent on specific system sizes. The study concludes that hydrogen underground storage for grid electricity storage can be profitable, and emphasizes that proper system design and precise electricity price forecasting are crucial for optimizing system performance and economic returns. This research sets the stage for further investigations into the scalability of hydrogen storage systems and their broader implications for grid electricity storage and energy market dynamics.

Determination of hydrogen fuel production from GIS-based selected ponds using hybrid renewable energy systems in Kayseri

This study offers the feasibility study of large-scale hydrogen production to establish environmentally friendly hybrid energy facilities based on wind and solar energy resources in the vicinity of lakes and rivers within the Kayseri region of Türkiye. The ultimate objective is to enable hydrogen production from lakes and rivers and identify optimal locations for the installation of hydrogen fuel stations. The precise selection of locations for the designated province is based on geographical, environmental, and infrastructural considerations by utilizing GIS technology which allows spatial analysis and superimposition of various layers. The methodology also involves the utilization of the HOMER software to facilitate the integration of wind and solar power, along with hydrogen production, providing a platform for environmentally friendly energy system design and optimization. A comprehensive evaluation has been conducted for the sizing and placement of renewable energy systems based on microgrid analysis, the design of hydrogen production facilities, and the establishment of hydrogen refueling infrastructure. The study also incorporates a financial analysis to assess the economic viability of the project over its lifecycle. Among the five water sources considered, the highest annual hydrogen production is 830 tons in Zamantı River, while Kızılırmak River has the lowest value according to LCOE and LCOH values, 0.030 $/kWh and 3.85 $/kgH2, respectively.

Wetting Preference of Silica Surfaces in the Context of Underground Hydrogen Storage: A Molecular Dynamics Perspective.

The growing interest in large-scale underground hydrogen (H2) storage (UHS) emphasizes the need for a comprehensive understanding of the fundamental characteristics of subsurface environments. The wetting preference of subsurface rock is a crucial parameter influencing the H2 flow behavior during storage and withdrawal processes. In this study, we utilized molecular dynamics simulation to evaluate the wetting preference of the silica surface in subsurface hydrogen systems, with the aim of addressing disparities observed in experimental results. We conducted an initial comprehensive assessment of potential models, comparing the wettability of five common silica surfaces with different surface morphologies and hydroxyl densities in CO2-H2/water/silica systems against experimental data. After introducing the INTERFACE force field as the most accurate potential model for the silica surface, we evaluated the wetting behavior of the α-quartz (101) surface with a hydroxyl density of 5.9 number/nm2 under the impact of actual geological storage conditions (333-413 K and 10-30 MPa), the coexistence of cushion gases (i.e., CO2, CH4, and N2) at various mole fractions, and pH levels ranging from 2 to 11 characterized through considering the negative charges of 0 to -0.12 C/m2 via deprotonation of silanol on the silica surface. Our results indicate that neither pressure nor temperature has a significant impact on the wetness of the silica in the case of pure H2 (single component UHS operations). However, when CO2 coexists with H2, especially at higher mole fractions, an increase in pressure and a decrease in temperature lead to higher contact angles. Moreover, when the mole fraction of cushion gas ranges from 0 to 1, the contact angle increases 20, 9.5, and 4.5° for CO2, CH4, and N2, respectively, on the neutral silica substrate. Interestingly, at higher pH conditions where the silica surface carries a negative charge, the contact angle considerably reduces where surface charges of -0.03 and -0.06 C/m2 result in an average reduction of 20 and 80% in the contact angle, respectively. More importantly, at a pH of ∼11 (-0.12 C/m2), a 0° contact angle is observed for the silica surface under all temperatures, pressures, types of cushion gases, and varying mole fractions.

Fueling Costa Rica’s green hydrogen future: A financial roadmap for global leadership

This study evaluates the financial viability and scalability of green hydrogen production in Costa Rica, focusing on solar and wind energy. The research analyzes seven key provinces using Global Horizontal Irradiance (GHI) and wind speed data to assess energy potential. Monte Carlo simulations were employed to calculate the Net Present Value (NPV), hydrogen production costs, and economic sustainability over multiple project lifetimes. Guanacaste, with solar irradiance of 5.49 kWh/m2/day and wind speeds of 6.59 m/s, emerges as the most favorable region. The analysis reveals an NPV of $1,519.79 USD for onshore wind and $2,320.24 USD for offshore wind over 10 years. These values increase significantly for longer lifetimes, with 25-year NPVs of $3,687.40 USD for onshore wind and $5,890.72 USD for offshore wind, and 50-year NPVs reaching $7,456.21 USD and $11,560.38 USD, respectively. Hydrogen production costs are estimated at $49,696.75 USD from solar and $14,923.19 USD from wind energy. Despite its potential, high costs remain a challenge, requiring policy incentives, international cooperation, and green bonds to drive down costs and scale production. The study offers crucial insights for policymakers, investors, and researchers to support Costa Rica’s leadership in the global green hydrogen economy.

Prospects for a large-scale green hydrogen storage methods development in Poland – a review

Prospects for a large-scale green hydrogen storage methods development in Poland – a review

The role of green ammonia in meeting challenges towards a sustainable development in China

The shift to a sustainable development has become an important issue in China. This paper discusses the role of green ammonia in promoting China's energy, environmental and economic sustainability which has not drawn enough attention. First, key challenges in China's energy transition, decarbonisation and regional sustainable development are explored. The coal-dominated energy consumption has placed great obstacles in achieving energy transition and led to massive CO2 emission since the large-scale industrialization. The high dependency on oil and gas import has threatened China's energy security. Imbalanced and unsustainable regional development is identified with data envelopment analysis. Second, the potential of green ammonia in meeting these challenges is analysed. Ammonia is examined to be a flexible and economic option for large-scale hydrogen transport and storage. Co-firing ammonia in coal power generation at 3 % rate is evaluated as an option for achieving low-carbon transition by 2030. Benefits of developing a green ammonia economy is discussed from energy, environmental and economic aspects. The practice can decline fossil energy consumption, enhance energy security, and facilitate renewable energy delivery and storage, industry decarbonisation, and regional development. We assume the findings and results contribute to addressing sustainability challenges and realizing a hydrogen economy in China.

Evaluating the techno-economic potential of large-scale green hydrogen production via solar, wind, and hybrid energy systems utilizing PEM and alkaline electrolyzers

The study evaluates the potential of solar, wind, and hybrid PV/WT renewable energy systems for green hydrogen production in four Iraqi cities. Through a comparative analysis of six distinct scenarios involving the deployment of 60 MWp solar panels, 30 MWp wind turbines, and 45 MWp hybrid PV/WT systems, the research aims to ascertain the most energy-efficient and cost-effective strategy for hydrogen generation. This evaluation is aligned with the operational capacities of two types of water electrolyzers: Alkaline (AWE) and proton exchange membrane (PEM), each with a 17.5 MWp capacity. Employing the HOMER Pro software for system simulation and optimization, and considering a project timeline from 2022 to 2042, the study identifies Anbar City as the prime location for green hydrogen production, highlighting solar PV panels as the most economical option with the lowest levelized cost of energy at US $4.5/MWh. The analysis further demonstrates that hydrogen production costs are US $1.98/kg for AWE electrolyzers and US $2.72/kg for PEM electrolyzers, with net present costs of US $26.31 million and US $35.91 million, respectively. Moreover, the annual hydrogen output is estimated at 1.11 million kg for AWE and 1.19 million kg for PEM electrolyzers. These insights significantly contribute to the strategic planning and development of Iraqi green hydrogen sector, offering a valuable framework for policymakers and stakeholders invested in sustainable energy transitions.

Catalytic methane decomposition process on carbon-based catalyst under contactless induction heating

Hydrogen obtained from decomposition of natural gas with direct sequestration of carbon in solid form could be an attractive and cost-effective alternative for large-scale hydrogen production. We report here the use of a carbon-based catalyst to achieve the catalytic decomposition of methane (CMD) at medium temperature, 800 °C, under induction heating (IH). Analyses of the catalytic results and characterizations of the spent catalyst have shown that the carbon deposited during the reaction acts as the active phase for the reaction and can, therefore, be recycled infinitely. This autocatalytic effect can only be observed when the carbon catalyst operates under IH because the same catalyst operating under Joule heating (JH) deactivates rapidly in the same way as that already reported in the literature and no autocatalytic effect has been observed. The carbon formed is in the form of a graphene layer with a high degree of graphitization and is completely different from the carbon black powder obtained in other processes. These promising results could lay the groundwork for the development of an industrially and economically viable way to convert natural gas into turquoise hydrogen, using renewable energy and low-cost catalysts, with better resistance to poisoning by impurities present in the processing load. The combination of a carbon-based catalyst and non-contact IH could also lead to combined catalytic processes for many challenging reactions.

The potential role of concentrated solar power for off-grid green hydrogen and ammonia production

This paper investigates the potential role of concentrated solar power (CSP) in off-grid green electrolytic hydrogen and ammonia production using an open-source techno-economic assessment optimisation model. The green ammonia plant comprises a flexible Haber-Bosch loop, an electrolyser park, a desalination plant, storage systems (thermal, electrical, and hydrogen), and a power supply optionally including wind power, solar photovoltaic (PV), and CSP (solar tower or parabolic trough collectors). Various system configurations and cost assumptions are tested to evaluate when CSP technologies are economically viable for green fuel production. Results demonstrate that CSP and thermal energy storage (TES) technologies can play a minor but useful role in providing nighttime power supply to the ammonia plant, in combination with onshore wind power and electrical storage. Solar PV with 1-axis tracking remains the primary power provider, and the optimal system always includes large-scale hydrogen storage. In the cheapest configuration, the LCOA reaches 646 €/tNH3. With an 80% reduction in CSP and TES costs, CSP technology becomes a major player in power production. In scenarios where hydrogen storage is not feasible and the ammonia plant lacks full flexibility, a 20% cost reduction (to 2750 €/kW) is enough for them to become major power providers.

Innovative Charge-Tuning for Highly Dispersed Pt Catalysts: Achieving Deep CO Removal in Industrial H2 Purification for Fuel Cells.

Proton exchange membrane fuel cells have strict requirements for the CO concentration in H2-rich fuel gas. Here, from the perspective of industrial practicability, a highly dispersed Pt catalyst (2-4 nm) supported on activated carbon (AC), which was modified by electronic promoters (K+) and structural promoters (isopropanol), is studied in detail. Compared with traditional metal oxide supports, the K-Pt/AC catalysts, which benefit from the tuned charge distribution, achieve a significant reduction of CO (from 1% to <0.1 ppb) under H2-rich conditions and show potential for used in large-scale industrial hydrogen purification. Experimental results and theoretical calculations reveal that the K atom, with its lower electronegativity, contributes to the shift of surface Pt2+ to a lower binding energy due to the presence of oxygen species on the AC surface. This facilitates oxygen activation and accelerates desorption of the CO2 product, thereby accelerating the reaction process and enabling the deep removal of CO in a hydrogen-rich atmosphere.

Cost of Green Hydrogen

Acting in accordance with the requirements of the 2015 Paris Agreement, Poland, as well as other European Union countries, have committed to achieving climate neutrality by 2050. One of the solutions to reduce emissions of harmful substances into the environment is the implementation of large-scale hydrogen technologies. This article presents the cost of producing green hydrogen produced using an alkaline electrolyzer, with electricity supplied from a photovoltaic farm. The analysis was performed using the Monte Carlo method, and for baseline assumptions including an electricity price of 0.053 EUR/kWh, the cost of producing green hydrogen was 5.321 EUR/kgH2. In addition, this article presents a sensitivity analysis showing the impact of the electricity price before and after the energy crisis and other variables on the cost of green hydrogen production. The large change occurring in electricity prices (from 0.035 EUR/kWh to 0.24 EUR/kWh) significantly affected the levelized cost of green hydrogen (LCOH), which could change by up to 14 EUR/kgH2 in recent years. The results of the analysis showed that the parameters that successively have the greatest impact on the cost of green hydrogen production are the operating time of the plant and the unit capital expenditure. The development of green hydrogen production facilities, along with the scaling of technology in the future, can reduce the cost of its production.

Levelized cost of long-distance large-scale transportation of hydrogen in China

Hydrogen plays a crucial role in supporting the transition to clean energy systems, and effective hydrogen transportation technologies are essential for the development of the hydrogen economy. However, long-distance, large-scale hydrogen transportation costs in China, particularly for liquid hydrogen trucks (LH2 tank trucks) and gaseous hydrogen pipelines (GH2 pipelines), remain unknown. Using the latest data from the ongoing hydrogen project in China and a techno-economic model, this study estimates the delivery costs of hydrogen over long distances for LH2 tank trucks and GH2 pipelines, and compares them with those of GH2 trucks. Specifically, we analyze the levelized cost of hydrogen transportation (LCOT) for these different technologies at varying distances and conduct sensitivity analyses on how these LCOT would change with factors such as vehicle travel speed, electricity prices, and pipeline capacity. Results show that for short distances (<150 km), GH2 trucks are most cost-effective, with costs around 28.96–34.26 CNY/ton-km. For long distances (>200 km), GH2 pipelines and LH2 tank trucks are more suitable, with pipelines being more cost-effective at higher capacity utilization rates. Lower electricity prices further reduce the LCOT for LH2 tank trucks. Policy recommendations on promoting the development and application of hydrogen transportation technologies are also provided.