Interfacial Shear Research Articles

Microstructure evolution and enhanced mechanical properties of CF/Mg composites with optimized fiber/matrix interfacial adhesion

In this study, the optimal carbon fiber/matrix (CF/matrix) interfacial adhesion was explored by tailoring sintering pressures, aiming to enhance the ultimate tensile strength (UTS) of CF/Mg composites. With increasing the pressure, the interfacial shear strength (IFSS) gradually increased from 28.8 MPa to 43.6 MPa. Remarkably enhanced UTS (152 MPa) of the composite was achieved, which was 120.3 % higher than that of the matrix, through optimizing the IFSS to 39.7 MPa. Correspondingly, the main failure mechanism was fiber pulling-out and direct fiber-cutting. Whereas, excessive IFSS (43.6 MPa) deceased the UTS of the composite, with the dominant failure mechanism of direct fiber-cutting.

Particle-Solid Transition Architecture for Efficient Passive Building Cooling.

Electricity consumption for building cooling accounts for a significant portion of global energy usage and carbon emissions. To address this challenge, passive daytime radiative cooling (PDRC) has emerged as a promising technique for cooling buildings without electricity input. However, existing radiative coolers face material mismatch issues, particularly on cementitious composites like concrete, limiting their practical application. Here, we propose a cementitious radiative cooling armor based on a particle-solid transition architecture (PSTA) to overcome these challenges. The PSTA design features an asymmetric yet monolithic morphology and an all-inorganic nature, decoupling radiative cooling from building compatibility while ensuring UV resistance. In the PSTA design, nanoparticles on the surface serve as sunlight scatterers and thermal emitters, while those embedded within a cementitious substrate provide build compatibility and cohesiveness. This configuration results in enhanced interfacial bonding strength, high solar reflectance, and strong mid-infrared emittance. Specifically, the PSTA delivers an enhanced interfacial shear strength (0.93 MPa), several-fold higher than that in control groups (metal, glass, plastic) along with a cooling performance (a subambient temperature drop of ∼6.6 °C and a cooling power of ∼92.8 W under a direct solar irradiance of ∼680 W/m2) that rivals or outperforms previous reports. Importantly, the design concept of the PSTA is applicable to various particles and solids, facilitating the practical application of PDRC technology in building scenarios.

Statistical Evaluation and Reliability Analysis of Interface Shear Capacity in Ultra-High-Performance Concrete Members

Statistical Evaluation and Reliability Analysis of Interface Shear Capacity in Ultra-High-Performance Concrete Members

The effect of relative density, granularity and size of geogrid apertures on the shear strength of the soil/geogrid interface

The increasing use of geogrid in various geotechnical projects has made the evaluation of the shear behavior of soil reinforced with geogrid become particularly important. In this article, a series of large-scale direct shear tests have been performed on sand and gravel samples reinforced with geogrid. The purpose of the experiments was to investigate the impact of the geogrid mesh size and the relative density of the samples on the shear strength coefficient of the interface between soil and geogrid. In this study, 5 geogrids with different mesh sizes and one type of geotextile were used. According to the results, the average shear strength coefficient of sand and gravel samples reinforced with geogrid for different normal stresses and different relative densities was obtained between 0.72 and 0.94. As the relative density increases, the interface shear strength coefficient decreases, this means that the denser the sand, the more the shear strength of the sand/geogrid interface decreases. Based on the results, it was found that the contribution of particle interlocking in the shear resistance of the sand/geogrid interface is particularly important, so that the shear resistance coefficient of the interface increases with the increase in the size of the geogrid mesh.

Interlaminar fracture properties of UV and plasma‐treated glass fiber epoxy composites

AbstractDespite the low density and high specific strength properties, the fiber‐reinforced composites are characterized by a relatively low interlaminar fracture toughness and their ultimate properties are strongly affected by the fiber matrix adhesion. This study aims to investigate the influence of fiber surface treatments, such as UV and atmospheric plasma, and of the interfacial shear strength, on the flexural properties and Mode I interlaminar fracture toughness of glass fiber epoxy composites. The vacuum‐assisted resin infusion technique is used for the composite fabrication. Scanning Electron Microscopy analysis is used to observe and to explain the changes in the morphology of the fibers after surface treatment. Remarkably, the results showed an overall reduction in the mechanical properties. The interfacial shear strength values of the UV and plasma‐treated samples were reduced by 34.9% and 49.5% respectively. The flexural strength was reduced by 7.9% and 5.9% respectively. The Mode I fracture toughness values for the UV and plasma‐treated samples were also reduced by 49.8% and 62.2% respectively.Highlights UV and plasma treatments were performed on glass fibers to improve performance. Push‐out tests were carried out to evaluate fiber/matrix adhesion. An aerospace grade epoxy resin curing in thermal press‐clave was used. Mechanical tests related Interfacial Shear Strength to composites performance.

Influences of the normal loading condition and surface texture on interface shear behavior between sand and suction caisson wall

The mechanical behavior of the interface between soil and the suction caisson wall determines the installation behavior and bearing capacity. A series of interfacial shear tests are conducted to study the effects of the normal loading condition and the interface texture on the sand-suction caisson interface shear characteristics. The relative density of the sand used in the test is 0.9. It is found that with the increase of shear displacement, the shear stress-displacement curve under a constant normal load condition (CNL) has an obvious strain-softening trend. On the contrary, the shear stress increases linearly with increasing the shear displacement under a variable normal load condition (VNL). The stress ratio between shear and normal stress, the broken zone thickness, and the shear deformation zone thickness for a convex suction caisson wall-sand interface are significantly larger than those of the grooved interface. However, when the roughness increases to a certain value, the stress ratio between shear and normal stress would decrease. Under large displacement shearing, the degree of sand particle breakage becomes significantly higher than that under small displacement shearing. These results help understand the shear characteristics of the sand-suction caisson wall and invent the new type of the suction caisson.

Behavior of steel-plate concrete wall-reinforced concrete slab joint with UHPC-strengthened lap-splice connection

The comprehensive integration of modular technology is the crucial pathway for advancing the upgraded Hua-long Pressurized Reactor (HPR1000). However, previous studies are limited and numerous challenges remain concerning the modular curved steel-plate concrete (SC) wall-reinforced concrete (RC) slab joint. This paper focuses on the behavior and design of the SC wall-RC slab joint through large-scale tests and numerical simulation. Two UHPC-strengthened non-contact lap splice (NS) connections, including versions with normal and headed rebars, were proposed to ensure effective load transfer and modular construction performance. The test results indicated that the four joint specimens subjected to cyclic loading did not experience lap splice failure but instead suffered interface shear failure and shear failure of the RC slab under shear-span ratios of 1.5 and 3.0, respectively. The excellent load transfer performance demonstrated by these two NS connections validates them as effective methods for this joint, with lap lengths of 21d for normal rebar and 13d for headed rebar deemed adequate. Besides, the developed three-dimensional FE model with non-linear spring element accurately simulated the test failure modes and F-Δ curves. The parametric study results recommended that the volumetric steel ratio of tie-bar should not be lower than 1.03 %. The tension of longitudinal rebars for normal and headed rebars can be fully transferred within 80 % of the designed lap length. Furthermore, a complete design method was established based on the load-transfer model, encompassing interfacial shear, lap length calculation and tie-bar configuration, and is applicable to SC-to-RC connections or joints.

Modulating Carbon Fiber Surfaces with Vinyltriethoxysilane Grafting to Enhance Interface Properties of Carbon Fiber/Norbornene-Polyimide Composites.

In this study, vinyltriethoxysilane (TEVS) was introduced onto the surface of carbon fiber using liquid-phase oxidation and impregnation methods to incorporate vinyl groups onto the carbon fiber, thereby enhancing the chemical bonding between the carbon fiber and norbornene-polyimide (PI-NA). Through a systematic study of the hydrolysis conditions and concentration of the TEVS solution, the optimal modification conditions were determined. These conditions were used to graft TEVS onto the surface of oxidized carbon fiber to prepare carbon-fiber-reinforced PI-NA composites (CF/PI-NA). The results show that when carbon fiber was treated with a 0.4 wt% TEVS solution, the interlaminar shear strength (ILSS) of the composites reached 65.12 MPa, and the interfacial shear strength (IFSS) reached 88.58 MPa, representing increases of 27.58% and 35.62%, respectively, compared to the CF/PI-NA composite materials prepared from untreated carbon fiber. It is worth noting that the modification method described in the study is simple and easy to implement, and it has the potential for large-scale continuous production applications.

New analytical model for multi-layered composite plates with imperfect interfaces under thermomechanical loading

AbstractA new analytical model for thermoelastic responses of a multi-layered composite plate with imperfect interfaces is developed. The composite plate contains an arbitrary number of layers of dissimilar materials and is subjected to general mechanical loads (both distributed internally and applied on edges for each layer) and temperature changes, which can vary from layer to layer and along two in-plane directions. Each layer is regarded as a Kirchhoff plate, and each imperfect interface is described using a spring-layer interface model, which can capture discontinuities in the displacement and stress fields across the interface. Unlike existing models, the governing equations and boundary conditions are simultaneously derived for each layer by using a variational procedure based on the first and second laws of thermodynamics, which are then combined to obtain the global equilibrium equations and boundary conditions for the multi-layered composite plate. A general analytical solution is developed for a symmetrically loaded composite square plate with an arbitrary number of layers and imperfect interfaces by using a new approach that first determines the interfacial normal and shear stress components on one interface. Closed-form solutions for two- and three-layer composite square plates are obtained as examples by directly applying the general analytical solution. Numerical results for two-, three- and five-layer composite plates under different loading and boundary conditions predicted by the current model are provided, which compare well with those obtained from finite element simulations using COMSOL, thereby validating the newly developed analytical model.

Investigation of pull-out and mechanical performance of fibre reinforced concrete with recycled carbon fibres

This paper presents the pull-out bonding behaviour and mechanical performance of recycled carbon fibre (rCF) reinforced concrete based on the recent investigation of fibre reinforced concrete (FRC) with rCF recovered from pyrolysis. Single fibre pull-out tests have been carried out to identify the apparent interfacial shear strength of different types of rCF and virgin carbon fibre (vCF) to identify the fibre matrix connection. Furthermore, a series of tests have been carried out to identify the workability, compressive strength and tensile strength of FRC. Besides rCF, also vCF and steel fibre were used for fabrication of FRC test specimens. rCF have shown the same adhesion behaviour and strength like vCF. Furthermore, the use of unsized or acrylate-based sized rCF creates an adhesion between fibre and matrix material. During the pull-out tests, the failure does not occur as an adhesive crack between fibre and cement matrix, but as a cohesive crack in the cement matrix. The mechanical performance of FRC with rCF was compared with mortar and FRC with vCF and steel fibres. The results of compressive test conducted for FRC with vCF and rCF indicated that the influence of vCF and rCF on the compressive strength of FRC was insignificant. On the other hand, the results of tensile test conducted for FRC with vCF and rCF indicated that the tensile strength of FRC with rCF was at least 14.9% greater than that of FRC with vCF.

Enhancing the interlaminar property of carbon fiber/poly(aryl ether ketone) composites with water‐soluble polyimide oligomer sizing agent

AbstractNovel water‐soluble polymer‐based sizing agents for carbon fiber/poly(aryl ether ketone) composites (CF/PAEK) have gained attention. However, a challenge remains: the sized CF bundles lack flexibility, and the effect of this on the properties of the composite has not been discussed. Herein, a water‐soluble polyimide oligomer (OL) sizing agent was developed, and the sizing effect was comprehensively evaluated. The conventional molecular weight polyimide (HP) sizing agent was also assessed for comparison. Although the interfacial shear strength of the sized CF monofilaments is enhanced due to improved surface roughness and wettability, the effect of the OL sizing agent on the composite's interlaminar shear strength (ILSS) and tow's flexibility differed from that of the HP sizing agent. Compared with HP‐CF, the yarn spreading rate of OL‐CF tow is increased by about eight times, and the ILSS of OL‐CF/PAEK composites with 2 and 5 MPa molding pressure is increased by 69% and 222%, respectively. The HP sizing agent weakens the tow's flexibility and yarn spreading ability, which is not conducive to the resin penetration in the tow, resulting in lower ILSS. In contrast, the OL sizing agent considers the tow's flexibility and composite's interlaminar property, showing great application potential.Highlights Two PI‐based sizing agents with diverse film‐forming capacities were prepared. The ILSS of CF/PAEK with OL sizing agent was significantly improved. HP sizing agent weakened the tow flexibility and interlaminar property. The interaction of sizing layer—resin penetration—ILSS was proposed.

A theoretical model for the load-transfer analyses of load distributive compression anchor integrating DSC-based interface nonlinear model

An innovative anchorage technology named load distributive compression anchor (LDCA) has recently been employed in a multitude of geotechnical engineering. The anchoring structure comprises multiple anchor bodies, thereby overcoming the bearing defects associated with conventional load-concentrated anchors and providing superior bearing performance. The complex structural configuration of LDCA considerably complicates the process of load-transfer theoretical modeling. A lack of relevant studies from theoretical solution perspective is yet evident in previous works. In this paper, a theoretical model was proposed for the load-transfer analyses of LDCA, of which the soil-anchor interface mechanical behavior was specially characterized by a disturbed state concept (DSC)-based nonlinear model. The mechanical simulation for the connections in different anchor bodies was incorporated into the theoretical analysis framework through the utilization of finite difference method. Three groups of 3D finite element (FE) models were established to simulate the load-transfer behaviors of LDCAs with different numbers of anchor bodies. The theoretical calculations agree well with the FE numerical results and the in-situ pullout test data, thereby confirming the applicability of the load-transfer theoretical model. The axial force and interface shear stress distributions, as well as the bearing capacity for LDCAs, were discussed based on theoretical calculations and FE simulations. Sensitivity analysis of several key design parameters was conducted to investigate their effects on the bearing capacity of LDCAs. The findings achieved in this study can provide insights into the understanding of the load-transfer behaviors of LDCA, and contribute to the bearing performance evaluation.

Consideration of Different Soil Properties and Roughness in Shear Characteristics of Concrete–Soil Interface

To investigate the impact of diverse soil characteristics and surface irregularities on interfacial shear strength attributes, a large-scale straight shear apparatus and particle flow software were employed to conduct interfacial shear experiments with varying soil properties and surface irregularities. The results demonstrated that, under an identical R and normal stress conditions, the clay and silty clay shear stress–displacement curves exhibited strain softening, while the silt curve exhibited strain hardening. An increase in R can markedly enhance the peak shear strength at the interface, although a critical value exists beyond which this effect is no longer observed. The Rc is primarily contingent upon the soil properties. Numerical simulations demonstrate that the internal shear displacement and deformation resulting from the diverse soil properties are distinct. Clay particles are constituted of varying-sized particle aggregates that collectively resist shear. Silt particles resist shear through interfacial friction generated by shear. The practicality of Duncan and Clough’s constitutive model for interfacial shear with roughness influence is verified, and the constitutive model under strain hardening is modified.

An Atomistic Level Investigation of the PFDTES-Graphene Interfacial Shear Strength and the Stick-Slip Mechanism.

1H,1H,2H,2H-Perfluorodecyltriethoxysilane (PFDTES) is the most widely used coating material with low surface energy and has the potential to be used as a dust-mitigating coating material during lunar landing missions. Graphene can be added to the PFDTES matrix to improve its mechanical properties. In this study, molecular dynamics simulations were performed to investigate the interfacial shear strength and friction mechanism between the PFDTES matrix and graphene. A systematic molecular dynamics (MD) simulation has been performed to calculate the interfacial shear strength of the PFDTES-graphene interface with considering the effect of graphene sliding velocity and vacancy defect density. For a pristine graphene layer with a size of 10 nm × 10 nm, the interfacial force between graphene and the PFDTES matrix is around 3 nN. Like other polymeric materials, the interfacial shear force exhibited stick-slip behavior under loading. The interfacial shear force will start to increase after the graphene starts sliding against the PFDTES matrix and reaches a stable plateau in a very short distance. It has been found that the influence of the interfacial shear strength from the sliding velocity of graphene is minimal. However, a significant increase in the interfacial shear strength has been observed after the graphene defect density increased; i.e., the magnitude of the shear force increased from 3 nN to around 14 nN after the defect density increased from 0% for pristine graphene to 40%. It has been found that vacancy defects will increase the fluctuation in the interfacial shear force, and it is due to not only the increased roughness near defects but also the stretched bonds in graphene under loading according to the distribution of the bond length. This study concluded that interfacial stick-slip behavior also exists in the PFDTES-graphene interface, and vacancy defects will have a significant improvement in the interfacial shear strength.

Sizing-agent control of the high-focusing and spread-ability of a melt-spun polyacrylonitrile-based carbon fiber and its interfacial shear strength

Sizing-agent control of the high-focusing and spread-ability of a melt-spun polyacrylonitrile-based carbon fiber and its interfacial shear strength

Unveiling the reinforcement benefits of innovative textured geogrids

The smooth surface texture of the commercially available geogrids limits the shear strength mobilization at the interfaces. This study presents the design, manufacturing, and interface performance evaluation of innovative textured geogrids. Geogrids with square, triangular, and hexagonal apertures with and without inherent surface texture were manufactured through additive manufacturing (3D printing) technique, using PLA (Poly Lactic Acid) filament. The texture includes elevated pins of 3 mm height at the junctions and inherent diamond pattern of 1 mm height on the ribs. The individual and combined effects of surface texture and aperture shape on the stress–displacement relationship, dilation angle, and the thickness of shear zone are quantified using large-scale direct shear tests and Particle Image Velocimetry (PIV) analysis. Results showed that the textured geogrid with hexagonal aperture has exhibited the maximum interface coefficient of 0.96 with sand followed by the geogrids with triangular and square apertures. Irrespective of the aperture shape, provision of the surface texture resulted in an overall increase of interface shear strength by more than 13%. Further, PIV analysis revealed that the shear zone is 25% thicker for textured geogrids of different aperture shapes, suggesting higher interlocking and passive resistance offered by their textured surfaces.

Experimental studies on the interfacial shear characteristics between joint concrete and foamed polymer in cross-river shield tunnel

The inadequate grouting performance in cross-river shield tunnels is primarily due to the insufficient bonding strength between the grouting material and the tunnel segments. In this study, a series of tests were conducted to compare foamed polymer and common grouting materials, focusing on the tangential bonding performance of the interface with tunnel segment concrete under varying humidity conditions. The applicability of polymer for treating leaks in cross-river shield tunnels was explored. The effects of polymer density, interfacial humidity, interfacial roughness, and normal stress on the shear strength of the polymer-concrete interface were investigated. A mathematical model reflecting the interface shear characteristics between polymer and concrete was established and validated. The test results have shown that, due to the fast reaction speed and high expansion rate, foamed polymer was found to be a feasible solution for addressing leakage in cross-river shield tunnels. Compared with common grouting materials, the density of foamed polymer is controllable, and the shear strength between foamed polymer and concrete segments is less affected by humid conditions. The minimum shear strength of the interface between foamed polymer and concrete is 1.2 MPa, while the maximum is 2.0 MPa. Foamed polymer can meet the needs of leakage treatment of cross-river shield tunnel. The interfacial shear strength between foamed polymer and concrete segments is directly proportional to the polymer density, interfacial roughness, and normal stress, and inversely proportional to the level of humid in the tunnel. The influence of various factors on interfacial strength is ranked as follows: polymer density > interfacial humidity > normal pressure > interfacial roughness. The residual error of linear regression mathematical model for the shear strength of interface between foamed polymer and segment concrete follows a normal distribution. The fitting results were proven to be accurate, allowing for the intuitive prediction of the quantitative relationship between shear strength and multiple influencing factors.

Molecular dynamics simulation of interfacial interaction mechanisms between ground tire rubber and styrene-butadiene rubber enhanced by nanomaterial incorporation

The recycling of ground tire rubber (GTR) is an effective method for addressing black pollution. In this study, we investigated and compared the effects of acidic oxidation treatments and different nanomaterial contents on the interfacial properties of styrene-butadiene rubber (SBR) and GTR. Molecular models of GTR modified by acidic oxidation and nanomaterials, as well as SBR, were established. The interfacial interaction mechanisms between SBR and GTR were studied through tensile and shear behaviors. The results indicated that the properties of SBR-GTR interface were enhanced through acidic oxidation and nanomaterial modification, with the latter demonstrating superior advantages in augmenting the interfacial strength. Specifically, the addition of a carbon nanotube and graphene increased the interfacial cohesion strength by 55.12 % and 82.93 %, and the interfacial shear strength by 29.87 % and 43.05 %, respectively. Moreover, graphene exhibited superior performance in enhancing interfacial interactions compared to carbon nanotubes and increasing the nanomaterial content did not positively impact the improvement of interfacial properties. The interfacial properties of SBR and GTR were quantitatively analyzed using molecular dynamic (MD) simulations. This study provides a theoretical foundation for enhancing the mechanical properties of recycled rubber by using nanomaterials, thereby guiding the experimental preparation of recycled rubber.

Revisiting the sequential evolution of sizing agents in CFRP manufacturing to guide cross-scale synergistic optimization of interphase gradient and infiltration

Using sizing agents instead of various nanoparticles to modify carbon fibers is widely recognized as the most practical approach to address processing issues and improve interfacial properties in carbon fiber reinforced polymer composites. However, a limited understanding of sizing agent evolution during composite manufacturing hinders comprehensive theoretical guidance for sizing treatment, thereby limiting further enhancement of composite performance. Here we disentangled the sizing agents into chemical anchoring and physical adsorption components, and elucidated the sequential wetting, diffusion, and crosslinking evolution processes of sizing agents across scales. By manipulating the proportion of chemical anchoring and physical adsorption in the sizing agents, the interfacial modulus gradient and infiltration efficiency were synergistically optimized. Consequently, significant improvements of 26.2 % in interfacial shear strength (IFSS) and 52.9 % in transverse fiber bundle tensile (TFBT) strength were achieved, indicating enhanced interfacial stress transfer and reduced internal defects in the composites. In summary, this work revisited the cross-scale evolution and mechanism of sizing agents during composite manufacturing, and thus provided a new paradigm for optimizing composite performance.

Effects of Minor Zn Dopants in Sn-10Bi Solder on Interfacial Reaction and Shear Properties of Solder on Ni/Au Surface Finish.

Sn-10Bi low-bismuth-content solder alloy provides a potential alternative to the currently used Sn-Ag-Cu series due to its lower cost, excellent ductility, and strengthening resulting from the Bi solid solution and precipitation. This study primarily investigates the interfacial evolution and shear strength characteristics of Sn-10Bi joints on a Ni/Au surface finish during the as-soldered and subsequent isothermal aging processes. To improve the joint performance, a 0.2 or 0.5 wt.% dopant of Zn was incorporated into Sn-10Bi solder. The findings demonstrated that a 0.2 or 0.5 wt.% Zn dopant altered the composition of the intermetallic compound (IMC) formed at the interface between the solder and Ni/Au surface finish from Ni3Sn4 to Ni3(Sn, Zn)4. The occurrence of this transformation is attributed to the diffusion of Zn atoms into the Ni3Sn4 lattice, resulting in the substitution of a portion of the Sn atoms by Zn atoms, thereby forming the Ni3(Sn, Zn)4 IMC during the soldering process, which was also verified by calculations based on first principles. Furthermore, a 0.2 or 0.5 wt.% Zn dopant in Sn-10Bi significantly inhibited the Ni3(Sn, Zn)4 growth after both the soldering and thermal aging processes. Zn addition can enhance the shear strength of solder joints irrespective of the as-soldered or aging condition. The fracture mode was determined by the aging durations-with the brittle mode occurring for as-soldered joints, the ductile mode occurring for aged joints after 10 days, and again the brittle mode for joints after 40 days of aging.