Interband Cascade Lasers Research Articles

Improved device performance of interband cascade lasers with hybrid cladding layers operating in the 3–4 µm wavelength region

In this work, we briefly review the development and status of interband cascade lasers (ICLs) as related to long-standing issues due to the InAs/AlSb superlattice cladding. By focusing on a hybrid cladding approach to alleviate these issues, we demonstrate substantially improved device performance of ICLs compared to earlier reported ICLs of a similar design in the 3–4 µm wavelength region. These improvements include a threshold current density for broad-area devices as low as 134 A/cm2 at 300 K and reduced threshold voltage with a peak voltage efficiency of 80%, which is more than 10% higher than that obtained from previously reported ICLs. Moreover, we have demonstrated continuous wave (cw) operation of a broad-area device up to 278 K, the highest cw operating temperature among epi-side up mounted broad-area type-II ICLs, implying improved thermal dissipation with the hybrid cladding approach. Additionally, by conducting a comparative study of ICLs with different GaSb layer thicknesses in the hole injector, we reveal and discuss an interesting correlation between the carrier transport, threshold voltage, and hole-induced absorption loss, which may help to guide device optimization for operation in a targeted temperature range.

High-temperature continuous-wave operation of InAs-based interband cascade laser

In this work, we report an InAs-based interband cascade laser that emits at λ = 4.58 μm in continuous-wave mode up to a maximum temperature of 64 °C, an increase of 29 °C beyond the previously highest reported value for InAs-based interband cascade lasers. At T = 20 °C, an output power of 20 mW was achieved for a 10-μm × 2-mm ridge waveguide device with one facet coated for high reflection and epilayer-down mounting.

Room temperature operation of single mode GaSb‐based DFB interband cascade lasers beyond 6.1 µm

AbstractSingle‐mode distributed feedback GaSb‐based interband cascade lasers with record emission beyond 6.1 µm are presented. The results are based on an epitaxial design with reduced resonant intersubband absorption in the valence band and rebalanced internally generated carriers. The epi‐down mounted 8 µm wide and 1 mm long laser chip is operated in continuous wave mode at room temperature and covers a bandwidth of over 20 nm with temperature and current tuning. At 25°C more than 4 mW of optical output power was measured.

Multivariate analysis and digital twin modelling: Alternative approaches to evaluate molecular relaxation in photoacoustic spectroscopy

A comparative analysis of two different approaches developed to deal with molecular relaxation in photoacoustic spectroscopy is here reported. The first method employs a statistical analysis based on partial least squares regression, while the second method relies on the development of a digital twin of the photoacoustic sensor based on the theoretical modelling of the occurring relaxations. Methane detection within a gas matrix of synthetic air with variable humidity level is selected as case study. An interband cascade laser emitting at 3.345 µm is used to target methane absorption features. Two methane concentration ranges are explored targeting different absorptions, one in the order of part-per-million and one in the order of percent, while water vapor absolute concentration was varied from 0.3 % up to 2 %. The results achieved employing the detection techniques demonstrated the possibility to efficiently retrieve the target gas concentrations with accuracy > 95 % even in the case of strong influence of relaxation effects.

Interband cascade lasers with advanced waveguides operating in the 3 to 4 μm wavelength region

Interband cascade lasers with advanced waveguides operating in the 3 to 4 μm wavelength region

Low-frequency regular pulse and intermittent oscillation in a mid-infrared interband cascade laser with optoelectronic feedback.

In this work, we experimentally investigate the nonlinear dynamics of a mid-infrared interband cascade laser (ICL) subject to optoelectronic feedback (OEF) through inspecting the time series and power spectrum of the laser output. The results show that, within the range of feedback strength limited by the experiment condition, the ICL sequentially presents stable state, continuously periodical oscillation (CPO), low-frequency regular pulse (LF-RP) and intermittent oscillation state with the increase of feedback strength. For the LF-RP state, the peak-to-peak value and the oscillation period increase with the increase of feedback strength. For the intermittent oscillation state, the time series is composed of the laminar region and burst region appeared alternately, and the average value and standard deviation for the duration of burst region gradually decrease with the increase of feedback strength.

A Portable Laser Spectroscopic System for Measuring Nitrous Oxide Emissions on Fertilized Cropland.

Nitrous oxide (laughing gas, N2O) is a relevant greenhouse gas. Agriculture contributes significantly to its emissions. As nitrogen fertilization has been identified as one of the main sources of N2O, controlled application and reduction of the amount of fertilizer adapted to crop demand is essential to reduce N2O emissions. This requires detailed studies of the local distribution of the N2O emission fluxes on different croplands. Consequently, frequent spatially resolved field measurements of N2O concentrations are needed. A precision in the ppb range close to the ambient N2O level of 333 ppb is necessary. Tunable laser absorption spectroscopy using quantum-cascade lasers (QCL) as a light source is an established technique for the measurement of N2O traces. We present the development and validation of a compact portable setup for on-site measurement of N2O emissions from the soil. The setup differs from previous solutions by using an interband cascade laser (ICL), which has significantly lower power consumption compared to a QCL. The portable measurement setup allows N2O emission fluxes to be determined with a precision of 3.5% with a measuring duration of 10 min. The developed system enables the detection of increased N2O emissions because of the fertilization of fields. High N2O emission fluxes are indicators of the overfertilization of the field. Directly after fertilization, N2O fluxes between 2.9 and 5.3 µL m-2 min-1 depending on the gas acquisition site are measured during the field tests. Over time, the fluxes decrease. The obtained results compare well with data from more precise but also more complex and maintenance-intensive instruments for atmospheric research. With this system, the soil moisture as well as the air humidity and air temperature are recorded. Strong influences on N2O fluxes by soil moisture were observed. The presented measurement system is a contribution to the establishment of mobile N2O screening systems that are robust in the field and suitable for comprehensive and routine detection of N2O emissions from soil.

Pushing the performance limits of long wavelength interband cascade lasers using innovative quantum well active regions

We report significantly enhanced device performance in long wavelength interband cascade lasers (ICLs) by employing a recently proposed innovative quantum well (QW) active region containing strained InAsP layers. These ICLs were able to operate at wavelengths near 14.4 μm, the longest ever demonstrated for III–V interband lasers, implying great potential of ICLs to cover an even wider wavelength range. Also, by applying the aforesaid QW active region configuration on ICLs at relatively short wavelengths, ICLs were demonstrated at a low threshold current density (e.g., 13 A/cm2 at 80 K) and at temperatures up to 212 K near 12.4 μm, more than 50 K higher than the previously reported ICLs with the standard W-shape QW active region at similar wavelengths. This suggests that the QW active region with InAsP layers can be used to improve device performance at the shorter wavelengths.

Quartz tuning fork (QTF) coating enhanced Mid-Infrared laser Induced-Thermoacoustic spectroscopy (LITES) for human exhaled methane detection

Human exhaled methane (CH4) has essential significance in detecting intestinal flora. In this study, a high-precision quartz tuning fork (QTF) based light-induced thermoelastic spectroscopy (LITES) system was developed, a mid-infrared interband cascade laser (ICL) and a QTF detector coated with polydimethylsiloxane (PDMS) and reduced graphene oxide (rGO) were employed for the CH4 detection. Experimental results indicate that the composite coating resulted in a 3-fold increase in 2f signal amplitude and signal-to-noise ratio (SNR), when compared to the bare QTF detector. The system has achieved a minimum detection limit (MDL) of 58.65 ppbv (part per billion volume) and a normalized noise equivalent absorption coefficient (NNEA) of 2.069 × 10−10 cm−1·W·Hz−1/2, Allan deviation analysis indicates that the optimal measurement accuracy is 36.85 ppbv. 24 healthy college students and 10 overweight/obese students were recruited to measure the CH4 concentration in the exhaled breath. The results show that exhaled CH4 concentrations of healthy individuals range from 0.5 to 3 ppmv (part per million volume), with slightly higher levels in males than females, and higher levels in the obese individuals than those in the normal individuals. The mid-infrared LITES CH4 measurement system holds promise as a new non-invasive method for assessing human metabolic states, with potential applications in medical and life sciences.

A mid‐infrared laser absorption sensor for calibration‐free measurement of nitric oxide in laminar premixed methane/ammonia cofired flames

AbstractAn interband cascade laser (ICL)‐based absorption sensor was developed for calibration‐free and high‐fidelity measurement of nitric oxide (NO) in laminar premixed methane/ammonia cofired flames using a combination of a micro‐probe and a low‐pressure, high‐temperature gas cell. The developed sensor, which has been shown to be particularly suitable for kinetic studies of ammonia combustion, used a tunable, continuous, narrow‐linewidth, free‐space ICL operating at ~5.2 μm to target the optimal NO transition centered at 1900.07 cm−1. A direct absorption spectroscopy technique with a reduced line model was implemented for calibration‐free measurements. Comprehensive experiments were first conducted to evaluate the sensor performance against the standard gas mixture at varied pressure from 20 to 101 kPa at 393 K, showing a relative difference of ≤2.5% and a measurement uncertainty of ≤2.0%. Such a sensor shows a minimum detection limit of ~2 ppm at the integration time of 1 s. The sensor was then applied for investigating the NO formation in ammonia‐methane cofiring flames with various ammonia blending ratios; the acquired experimental data was further used as benchmark data for evaluation of literature chemical mechanisms for ammonia combustion. The developed sensor system was demonstrated to be capable of providing quantitative and spatially resolved measurement of NO in ammonia‐methane cofired flames.

High-temperature absorption cross-sections and interference-immune sensing method for formaldehyde near 3.6-µm

Absorption cross-sections of formaldehyde (CH2O) were measured at elevated temperatures near 3.6 µm, a region of strong intensity due to the overlapping QQ5 branch of the v1 band and the PQ7 branch of the v2+v4 combination band. 1,3,5-trioxane was shock-heated in an argon bath gas to produce controlled mixtures of formaldehyde over a range of temperatures (900–1500 K) and pressures (0.4–4.8 atm). Spectrally-resolved absorption measurements of formaldehyde were obtained using a rapidly-tunable distributed-feedback interband cascade laser scanned at 40 kHz over 2778.1–2778.9 cm−1 behind reflected shock waves. The resulting absorption cross-sections were fit with functions reflecting the temperature and pressure dependence of the targeted features, enabling spectral reconstruction at any temperature and pressure within the range of the study. By exploiting the strong temperature and pressure sensitivity of the cross-sections, it is demonstrated that CH2O concentration, temperature, and pressure can be inferred from a measured absorbance spectrum. Cross-sections of common combustion species were also measured over the selected wavelength range to validate that the region is largely free of narrow-band interference. Further, the multi-parameter spectral fitting method is shown to correct for baseline interference and demonstrated in experiments involving transient gas properties.

Theoretical analysis of a mid-infrared Kerr frequency comb in a graphene-on-silicon micro-resonator

Mid-infrared (Mid-IR) Kerr frequency combs have great application potential in sensing and spectroscopy. To generate a Kerr frequency comb, a continuous-wave, wavelength-tunable, narrow-linewidth, low-noise laser is normally utilized to pump a high-nonlinearity micro-resonator to emit a large number of coherent and equally spaced modes. However, chip-based pump lasers in the mid-IR band, namely, quantum cascade lasers and interband cascade lasers, are usually challenging to develop with both high output powers and good wavelength tunability based on a single diode. To overcome the limitation, we theoretically study a mid-IR Kerr frequency comb generation technique based on a graphene-on-silicon micro-resonator by using a monochromatic mid-IR laser. The approach is based on the exploration of an electric-field-assisted resonance scanning technique and graphene-enhanced silicon Kerr nonlinearity. Our result shows that a soliton Kerr frequency comb with a spectral range of 3.23–5.26 μm, 3-dB bandwidth of ∼550 nm, and frequency spacing of 140 GHz could be generated under a pump wavelength of 4 μm. The study paves a promising way toward developing monolithically chip-integrated mid-IR Kerr frequency combs with cost efficiencies and ultrafast tuning speeds.

Optical gain calculation and structure optimization of type-II GaAsSb/InAs/InGaAs quantum well heterostructures

This paper reports an optimization scheme of type-II GaAsSb/InAs/InGaAs quantum wells using the six bands k · p method. By calculating the optical gain, the optimal structures of the quantum wells are obtained. We observed that without an electric field, the thickness values of symmetrical quantum wells designed by the AdaGrad algorithm are 2.97, 2.81, and 6.21 nm, respectively, and the gain intensity is 6489 cm−1 that is about 1600 cm−1 higher than the original empirical design scheme. The thickness of asymmetric quantum wells designed by the Adam algorithm is 5.56, 2.72, 1.88, 3.16, and 2.46 nm under the external electric field of 75 kV/cm, respectively, and the gain intensity is 5729 cm−1 that is about 2300 cm−1 higher than the original empirical design scheme. The optimized scheme effectively suppresses the gain attenuation caused by the electric field and is helpful to improve the performance of interband cascade lasers.

Compact methane sensor using an integrating sphere and interband cascade laser at 3313 nm

We present a sensor for gas detection utilising an integrating sphere and interband cascade laser for tunable diode laser absorption spectroscopy (TDLAS). Measurements were made of the methane absorption line at 3313 nm using an integrating sphere with an effective pathlength of 70.1 cm. Gas concentrations were estimated from normalised absorption spectra with line fitting to 7 absorption lines within the scan. Testing showed that measurements were linear for methane in synthetic air for concentrations in the range 0–50 ppm. With an averaging time of 20 s, the noise-equivalent methane concentration was 180 ppb (1σ). The system requires minimal alignment, with preliminary measurements indicating the system is insensitive to vibration and misalignment of the laser input. The lack of alignment optics also allows it to be compact (190×170×120mm) and robust.

Quartz‐Enhanced Photoacoustic Sensors for Detection of Eight Air Pollutants

A quartz‐enhanced photoacoustic spectroscopy sensor architecture capable of detecting eight different air pollutants (CH4, NO2, CO2, N2O, CO, NO, SO2, and NH3) is reported. Each analyte is targeted using the same sensor components (acoustic detection module, quartz‐tuning fork, etc.) and a dedicated laser source. Both interband cascade lasers and quantum cascade lasers are employed to target a well‐resolved and isolated absorption feature from each investigated gas, in a wavelength ranging from 3.35 to 9.06 μm. The sensor is calibrated with certified concentrations of each gas species, in a wet nitrogen matrix. For each analyte, the optimal pressure is determined. Minimum detection limits of 40, 13, 800, 230, 450, 78, 18, and 5.8 ppb are obtained for CH4, NO2, CO2, N2O, CO, NO, SO2, and NH3, respectively, at 100 ms of integration time.

Highly sensitive measurement of trace methane gas using mid‐infrared tunable diode laser absorption spectroscopy method

AbstractTo monitor the concentration of harmful gas methane (CH4) in the tunnel in real time, a high‐sensitivity measurement method for CH4 trace gas based on tunable diode laser absorption spectroscopy (TDLAS) is designed in this paper. An interband cascade laser with the emission wavelength of 3.29 μm was used to target noninterference CH4 lines at 3038.5 cm−1. To diminish the background noise of the sensor system, wavelength modulation spectroscopy combined with a second harmonic measurement technique was used in this work. Finally, 1.83 parts per billion in volume (ppbv) minimum measurement limit (MML) was obtained with a 4 s integration time based on an Allan‐Werle variance analysis, and the MML can be further improvedto ∼0.4 ppbv by increasing the integration time up to 104 s. Indoor and outdoor environmental data of CH4 acquired using the TDLAS sensor system are also reported.

Interband cascade technology for energy-efficient mid-infrared free-space communication

Space-to-ground high-speed transmission is of utmost importance for the development of a worldwide broadband network. Mid-infrared wavelengths offer numerous advantages for building such a system, spanning from low atmospheric attenuation to eye-safe operation and resistance to inclement weather conditions. We demonstrate a full interband cascade system for high-speed transmission around a wavelength of 4.18 µm. The low-power consumption of both the laser and the detector in combination with a large modulation bandwidth and sufficient output power makes this technology ideal for a free-space optical communication application. Our proof-of-concept experiment employs a radio-frequency optimized Fabry–Perot interband cascade laser and an interband cascade infrared photodetector based on a type-II InAs/GaSb superlattice. The bandwidth of the system is evaluated to be around 1.5 GHz. It allows us to achieve data rates of 12 Gbit/s with an on–off keying scheme and 14 Gbit/s with a 4-level pulse amplitude modulation scheme. The quality of the transmission is enhanced by conventional pre- and post-processing in order to be compatible with standard error-code correction.

Quartz-enhanced photoacoustic spectroscopy (QEPAS) and Beat Frequency-QEPAS techniques for air pollutants detection: A comparison in terms of sensitivity and acquisition time

In this work, a comparison between Quartz Enhanced Photoacoustic Spectroscopy (QEPAS) and Beat Frequency-QEPAS (BF-QEPAS) techniques for environmental monitoring of pollutants is reported. A spectrophone composed of a T-shaped Quartz Tuning Fork (QTF) coupled with resonator tubes was employed as a detection module. An interband cascade laser has been used as an exciting source, allowing the targeting of two NO absorption features, located at 1900.07 cm−1 and 1900.52 cm−1, and a water vapor absorption feature, located at 1901.76 cm−1. Minimum detection limits of 90 ppb and 180 ppb were achieved with QEPAS and BF-QEPAS techniques, respectively, for NO detection. The capability to detect multiple components in the same gas mixture using BF-QEPAS was also demonstrated.

Single-Mode Tunable Interband Cascade Laser Emitting at 3.4 μm With a Wide Tuning Range Over 100 nm

We report a widely tunable monolithically integrated V-coupled cavity interband cascade laser (ICL) emitting near <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$3.4~\mu \text{m}$ </tex-math></inline-formula> . The mode selection is achieved using a half-wave V-coupler designed for the ICL in the mid-infrared range without any grating. The side-mode suppression ratio is demonstrated up to 35.7 dB. In the heat-sink temperature range from 130 K to 140 K, single-mode wavelength tuning range of over 100 nm from 3329.9 nm to 3431.3 nm has been attained by adjusting both current and temperature. These results show that the V-coupled cavity ICLs are very promising for multi-species trace gas absorption spectroscopy with a high sensitivity.

Quartz enhanced photoacoustic spectroscopy gas sensing exploiting beat frequency approach

Quartz-enhanced photoacoustic spectroscopy (QEPAS) is a highly sensitive optical technique, suitable for real-time and in situ trace gas detection. In QEPAS, Quartz tuning forks (QTF) are employed as piezoelectric transducers of sound waves induced by gas non-radiative energy relaxation as consequence of infrared modulated light absorption. The generated electric signal depends on the gas concentration. An accurate and reliable QEPAS measurement requires the QTF characterization, in terms of resonance frequency and quality factor. Furthermore, tens of seconds are required to complete the tuning range scan of the laser employed to detect the selected gas. Beat frequency QEPAS (BF-QEPAS) is an alternative approach to standard QEPAS. In BF-QEPAS, a fast scan of the laser tuning range is employed to generate an acoustic pulse. Gas concentration, QTF resonance frequency, and quality factor can be measured acquiring and analyzing the transient response of the QTF to the acoustic pulse. In this work, a custom T-shaped QTF was employed to detect nitrogen monoxide (NO), targeting its absorption feature at 1900.07 cm−1 with an interband cascade laser. A minimum detection limit as low as 166 ppb of NO, and a highly accurate measurement of the QTF resonance frequency and quality factor were demonstrated using BF-QEPAS.