Quartz enhanced photoacoustic spectroscopy gas sensing exploiting beat frequency approach

Abstract

Quartz-enhanced photoacoustic spectroscopy (QEPAS) is a highly sensitive optical technique, suitable for real-time and in situ trace gas detection. In QEPAS, Quartz tuning forks (QTF) are employed as piezoelectric transducers of sound waves induced by gas non-radiative energy relaxation as consequence of infrared modulated light absorption. The generated electric signal depends on the gas concentration. An accurate and reliable QEPAS measurement requires the QTF characterization, in terms of resonance frequency and quality factor. Furthermore, tens of seconds are required to complete the tuning range scan of the laser employed to detect the selected gas. Beat frequency QEPAS (BF-QEPAS) is an alternative approach to standard QEPAS. In BF-QEPAS, a fast scan of the laser tuning range is employed to generate an acoustic pulse. Gas concentration, QTF resonance frequency, and quality factor can be measured acquiring and analyzing the transient response of the QTF to the acoustic pulse. In this work, a custom T-shaped QTF was employed to detect nitrogen monoxide (NO), targeting its absorption feature at 1900.07 cm−1 with an interband cascade laser. A minimum detection limit as low as 166 ppb of NO, and a highly accurate measurement of the QTF resonance frequency and quality factor were demonstrated using BF-QEPAS.