Concrete 3D printing, an innovative construction technology, offers reduced material waste, increased construction speed, and the ability to create complex and customized shapes that are challenging to achieve with traditional methods. This study delves into the unique fresh-state performance required for 3D printing concrete, discussing buildability, extrudability, and shape retention in terms of concrete rheology, which can be modified using admixtures. Currently most 3D printing concretes feature high cement contents, with little use of secondary cementitious materials. This leads to high embodied carbon, and addressing this is a fundamental objective of this work. The research identifies attapulgite, bentonite, and sepiolite clay as potential concrete admixtures to tailor concrete rheology. Eight low-carbon concrete mixes are designed to incorporate GGBS at a 50% replacement level and are used to measure the influence of each clay on the concrete rheology at varying dosages. A comprehensive rheological test protocol is designed and carried out on all mixes, together with other tests including slump-flow and compression strength. The objective is to determine the applicability of each clay in improving the printability of low-carbon concrete. The findings reveal that at a dosage of 0.5%, sepiolite was seen to improve static yield stress, dynamic yield stress, and rate of re-flocculation, resulting in improved printability. The addition of attapulgite and sepiolite at a dosage of 0.5% by mass of binder increased compressive strength significantly; bentonite had very little influence. These gains are not repeated at 1% clay content, indicating that there may be an optimum clay content. The results are considered encouraging and show the potential of these clays to enhance the performance of low-carbon concrete in 3D printing applications.