Corrosion Inhibition Of Mild Steel Research Articles

Shrimp shell waste as a potential corrosion inhibitor for mild steel in acid solution

Application of corrosion inhibitor is a common method to minimize corrosion reaction of steel in aqueous environments. Research for an effective eco-friendly corrosion inhibitor is required due to the toxicity issues of the most commercially available corrosion inhibitors. Many recent studies have shown that various food waste can be utilized as corrosion inhibitors. Extracting inhibitor compounds from food waste is definitely low cost, less harm, and environmentally beneficial. One example of corrosion inhibitor derived from food waste is a water-soluble chitosan (WSC) inhibitor, which can be extracted from Crustacean shells. This study used shrimp shell waste to extract WSC and test the effectiveness on inhibiting corrosion of mild steel in acid solution. The weight loss method was employed at various inhibitor concentrations and solution types. The overall findings in this study indicate that the WSC extracted from shrimp shell exhibits a good inhibition performance in 0.5 M HCl solution with the efficiency up to 94.31% at a concentration of 3 g/l at room temperature. Fourier Transform Infrared Spectroscopy and 2.2.7 UV-visible spectroscopy analysis showed that WSC molecules adsorbed on the steel surface and hinder the corrosion reactions.

Examining the effects of tert-butylamine under different circumstances an inhibitor of mild steel corrosion in HCl acid

Examining the effects of tert-butylamine under different circumstances an inhibitor of mild steel corrosion in HCl acid

Green Synthesis and Zinc-Oxide Nanoparticles for Corrosion Inhibition and Modeling Corrosion Inhibition of Mild Steel in HCl Solutions

Green Synthesis and Zinc-Oxide Nanoparticles for Corrosion Inhibition and Modeling Corrosion Inhibition of Mild Steel in HCl Solutions

Surface Corrosion Inhibition of Mild Steel in an Acidic Environment by an Anthelmintic Drug: Experimental, RSM, DFT and MD Simulation Studies

Surface Corrosion Inhibition of Mild Steel in an Acidic Environment by an Anthelmintic Drug: Experimental, RSM, DFT and MD Simulation Studies

INHIBITORY EFFECTS OF CUSCUTA REFLEXA (AMERBEL) ON THE CORROSION OF IRON IN 1M HYDROCHLORIC ACID: A GREEN APPROACH

The corrosion inhibition properties of Cuscuta reflexa (Amerbel) leaf extract as a green inhibitor for iron corrosion in hydrochloric acid were investigated using gravimetric and surface techniques. Results show that the extract's inhibition efficiency varied with concentration and temperature. The Langmuir adsorption isotherm model was followed, and the adsorption was physical and spontaneous. The studies suggest that Cuscuta reflexa extract exhibits great potential as a mild steel corrosion inhibitor in HCl environments.

Experimental and Computational Investigation of Novel Triazole-Pyrazole Derivative as a Synthetic Corrosion Inhibitor for M-Steel in 1.0M HCl

TzPz, a newly synthesized ethyl 2-(3-(3,5-dimethyl-1H-pyrazol1-yl)-H-1,2,4-triazol-1-yl) ethan-ol, was evaluated as a mild steel corrosion inhibitor in 1.0 HCl environment. The synthesis objective for this type of molecule-type was to create a triazole-based molecule with a simple yet effective structure, as well as to increase the number of nitrogen donors to boost adsorption affinities at the metal surface. This investigation began with electrochemical techniques such as EIS & PDP. The results obtained suggest that TzPz is a good inhibitor, with a maximal effectiveness (91.9%) at 303 K. The inhibitory efficacy increases dramatically with increasing concentration and decreases with increasing temperature. According to electrochemical data, TzPz functions as a mixed inhibitor, and the corrosion process is controlled by charge transfer. In addition, the adsorption isotherm adheres to the Langmuir model. UV-visible spectroscopy is used to evaluate the probability of Fe-inhibitory molecule interactions. Theoretical calculations using the DFT technique were performed and discussed for the molecule TzPz in order to understand its interfacial approach and compare them to experimental data.

A combination of experimental and theoretical methods in evaluating triazole derivatives' mild steel corrosion inhibition ability in an acidic solution

A comprehensive study was conducted, both experimentally and theoretically, to evaluate the corrosion inhibition ability of 4-amino-5-phenyl-4H-1,2,4-triazole-3-thiol (AT) and 4-amino-5-(pyridine-4-yl)-4H-1,2,4-triazole-3-thiol (AP) on mild steel. The findings show that AT and...

Artequick as Inhibitor of ASTM A36 Mild Steel Corrosion through Anodic Sites Dissolution: Computational and Electrochemical Approach

Artequick as Inhibitor of ASTM A36 Mild Steel Corrosion through Anodic Sites Dissolution: Computational and Electrochemical Approach

Study of the effectiveness of a mild steel corrosion inhibitor in H2S medium

Study of the effectiveness of a mild steel corrosion inhibitor in H2S medium

Unveiling the multifaceted incorporation of Musa acuminata peduncle juice as a bio-corrosion inhibitor of mild steel in seawater-simulated solution.

This work assessed the ability of Musa acuminata peduncle juice extract to sustainably inhibit mild steel under salinized conditions. The effort sought to ascertain the new active material's inhibitory efficacy for inhibiting metal corrosion in seawater. M. acuminata peduncle juice was extracted from the M. acuminata peduncle. The functional group of the M. acuminata pedal juice was determined using Fourier transform infrared spectroscopy. The corrosion behavior was assessed using electrochemical impedance spectroscopy and potentiodynamic polarization by varying the M. acuminata peduncle juice at 0.1, 0.2, and 0.3 g L-1 for 300 K, 310 K, and 320 K, respectively. Scanning electron microscopy provided an image of the surface morphology of mild steel. Reduced corrosion current (icorr) was observed when M. acuminata pedal juice was present according to potentiodynamic polarization and studies. Moreover, adding M. acuminata peduncle juice increases resistance capacity transfer (Rct). The potentiodynamic polarization approach was used to obtain the optimum inhibitory efficiency (%IE) at 0.3 g L-1 doses with 88.0% efficiency at 300 K. The addition of M. acuminata peduncle juice results in a smoother, mild steel morphology than the surface without inhibitor additions. The molecules of active chemicals adhering to the steel surface were linked to increased corrosion inhibition. The study's findings demonstrated that M. acuminata peduncle juice is a promising biomaterial for mild steel corrosion inhibitors in a salty environment.

Unravelling adsorption potential of expired clindamycin as corrosion inhibitor at mild Steel/HCl interface via response surface methodology, artificial neural network, electrochemical, and computational strategies

Corrosion has produced unprecedented disintegration of metals, constituting an imminent danger to mankind and triggering catastrophic global economic losses. The effectiveness of expired clindamycin (ECLI) as a low-cost corrosion control agent for mild steel was investigated utilising response surface methodology (RSM), artificial neural network (ANN), potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), quantum chemical computation (QCC), and molecular dynamic simulation (MDS) studies in conjunction with thermometric and gasometric protocols at different HCl concentrations. The RSM model demonstrated an outstanding level of accuracy in predicting the mild steel corrosion inhibition efficiency (IE), the volume of hydrogen gas (VHG), reaction number (RN), and corrosion rate (CR). The model was significantly influenced by the operational parameters that were investigated, such as temperature (299–333 K), ECLI concentrations (100–500 mg/L), immersion time (1–6 h), and acid concentration (0.5–2.5 M). It was observed that as ECLI concentration increases, the VHG, RN, and CR decreased per time as well as % IE increased. The thermometric, gasometric, PDP, and EIS results showed percentage inhibition efficiency of 69.10, 69.49, 83.17, and 77.87 %, respectively. PDP revealed that ECLI operates as a mixed type of inhibitor, and EIS indicated that the inhibition process involves charge transfer. The Langmuir isotherm suits better and accurately describes the ECLI adsorption process on mild steel. The electron transfer propensity of the ECLI on the metal surface is measured by QCC using the DFT approach. MDS was implemented to establish the optimal adsorption orientation between ECLI and Fe (110). The inspection of surface morphology by SEM displayed the formation of a blanket-like layer on the steel by ECLI. To validate the experimental results, RSM and ANN prediction models were utilised, which were evaluated using a normal plot of residual, predicted versus actual, and residual versus run, and were found to be effective modelling tools. This study illustrates that ECLI can be utilised as a potent and affordable mild steel inhibitor, even at high acid concentrations.

Corrosion Inhibition Performance of Euphorbia pulcherrima Bark Extract in 1M H2SO4 on Mild Steel

The bark of the attractive flower Euphorbia pulcherrima (Lalupate), which is widely accessible in Nepal, can be used to extract an alkaloid that acts as a corrosion inhibitor. The methanolic extract of Euphorbia pulcherrima (EP) in 1M H2SO4 was employed to study corrosion inhibition of mild steel (MS) by weight loss and potentiodynamic technique. The immersion time and EP extract concentration consequences on corrosion inhibition were explored. The weight loss of MS is significantly reduced in the presence of EP inhibitors caused by the adsorption of inhibitor molecules. The findings exhibited that the increasing immersion time and EP concentration resulted in an increment in inhibition efficiency (IE). The maximal IE from the weight loss method was determined to be 90.38% for 1000 ppm extract immersed for 6 hours at room temperature and 86.36% IE was obtained for 1000 ppm concentration of the EP extract after 1hr of immersion by potentiodynamic polarization. The open circuit potential (OCP) of the MS in the inhibitor solution confirmed the EP extract behaving as a mixed inhibitor. The current density decreased with the addition of the EP, which reflected the inhibitive nature of inhibitor molecules. Similarly, the corrosion current density decreased as the EP extract concentration increased. Hence, it implied that the bark extract of EP is a potent inhibitor of MS corrosion, even after just one hour of immersion. Because of the reduction of hydrogen ions and the adsorption of inhibitor molecules on the MS surface, EP extract is effective in inhibiting corrosion current on the cathodic and anodic polarization curves, forming a barrier that stops the evolution of hydrogen gas and metal dissolution. Fourier Transform Infrared (FTIR) spectroscopic analysis showed the presence of N-H and C=O functional groups in the EP attributed to the adsorption on MS and consequently reducing the dissolution of MS.

Comparative evaluation of freeze-dried and hot air-dried Spirulina Platensis extracts as green inhibitors for mild steel corrosion

ABSTRACT Spirulina, a commercially farmed cyanobacteria, offers potential as a nontoxic corrosion inhibitor. However, traditional drying methods deteriorate its protective feature and this challenge must be overcome to enhance corrosive resistance. The present study compares the corrosive inhibitor performance of Spirulina extracts from freeze (SP1) and hot air drying (SP2). The electrochemical and microscopic techniques revealed that freeze-dried-derived Spirulina inhibited over 90% of corrosion through the chemisorption process where freeze-dried-derived Spirulina maximises the inhibitory compounds binding to steel. Polarisation measurements showed that SP1 provided higher inhibition efficiencies of over 93% at certain concentrations compared to around 88% for SP2. At the optimal concentration of 2 g/L, Rp values increased from 35.17 Ω/cm2 (uninhibited) to 531.3 Ω/cm2 for SP1 and 282.7 Ω/cm2 for SP2. Negative ΔGads values (−42.4 kJ/mol for SP2, −46.3 kJ/mol for SP1) and Langmuir isotherm fit indicated chemisorption-controlled adsorption. SEM/EDX showed SP1 and SP2 formed barrier layers inhibiting surface damage compared to blank steel. SP1 layer provided better protection. In short, through innovative applications of marine resources, greener corrosion management is enabled.

Inhibitory Effect of Stachytarpheta mutabilis Extracts on the Corrosion of Mild Steel in Acidic Media

The anticorrosive potential of Stachytarpheta mutabilis leaf extract (SMLE) as a corrosion inhibitor for corrosion of mild steel (MS) in 1 M HCl was investigated using weight loss measurement as well as gasometric techniques at 30 and 60 oc. Relevant thermodynamic equations were employed to estimate the activation energy, enthalpy change and entropy change. The adsorption isotherms were used to determine the Gibbs free energy change. Results obtained showed that SMLE functioned as an excellent corrosion inhibitor for mild steel in the acidic environment. Temperature studies revealed a decrease in inhibition efficiency with increase in temperature and activation energies increased in the presence of the extract. The adsorption of SMLE on mild steel was approximated using Freundlich, Flory-Huggins, Frumkin, El-Awary’s and Temkin isotherms but Langmuir gave the best fit. Both kinetic and thermodynamic parameters governing the adsorption process were calculated and discussed. The adsorption followed a first order kinetics. As concluded from the results, the adsorption of S. mutabilis on mild steel in 1M HCl medium is feasible, spontaneous and it occurred by physical adsorption. From the experimental results obtained, it can be concluded that SMLE inhibit corrosion effectively when compared well with many reported green inhibitors for MS corrosion.

Evaluation of the efficiency of coconut dust extract as a corrosion inhibitor for steel reinforcement in concrete by mass spectrometry

Ethanol extraction was employed to isolate a range of compounds from waste products derived from coconut fiber production (coconut dust) in Ben Tre, Vietnam. Phytochemical screening confirmed the presence of flavonoids, tannins, polyphenols, saponins, alkaloids, flobatannins, and anthraquinones among the extracted substances. FT-IR spectroscopy analysis supported the identification of oxygen and nitrogen atoms within functional groups (e.g., O–H, N–H, C–O) and aromatic rings, characteristic of typical corrosion inhibitors. Mass spectrometry investigations indicated that when St3 steel was exposed to an alkaline solution lacking chlorides, a passive film composed of FeOOH formed on the surface. However, upon the addition of NaCl at a concentration of 1.00 mol/dm3, FeCl, FeCl2Cl–, and FeCl3Cl– compounds were detected across the analyzed surface, while peaks corresponding to FeOO– were absent. Remarkably, areas with the highest concentration of particles corresponded to regions exhibiting visible corrosion damage under magnification. The addition of 2.00 g/dm3 of coconut dust extract to the chloride solution prevents the formation of Fe and Cl compounds on the steel surface. Consequently, only peaks characteristic of FeOO– and organic fragments containing oxygen atoms from the extract were observed. Based on these results, it can be assumed that coconut dust extract has the potential to inhibit local (pitting) corrosion of low-carbon steel (St3) when exposed to aqueous alkaline solutions simulating concrete pore liquid containing chlorides. The addition of 2.00 g/dm3 of the extract has been shown to prevent pitting formation at a chloride concentration of 1.00 mol/dm3. Conversely, in the absence of the extract, visible local corrosion damage was observed upon magnification. These findings provide a basis for further exploration of the protective properties of coconut dust extract as an environment-friendly corrosion inhibitor for mild steel in concrete environments containing chlorides.

Synergistic effect of Gleichenia linearis Burm. leaf extract and iodide ion as eco-friendly corrosion inhibitor of mild steel in hydrochloric acid medium

Synergistic effect of Gleichenia linearis Burm. leaf extract and iodide ion as eco-friendly corrosion inhibitor of mild steel in hydrochloric acid medium

Experimental and theoretical investigation of 5-(5-bromothiophen-2-yl)oxazole as a highly effective corrosion inhibitor for mild steel in 1 M hydrochloric acid

Experimental and theoretical investigation of 5-(5-bromothiophen-2-yl)oxazole as a highly effective corrosion inhibitor for mild steel in 1 M hydrochloric acid

Experimental and theoretical investigation of (E)-5-{[4-(dimethylamino)benzylidene]amino}-1,3,4-thiadiazole-2(3H)-thione (DATT) as an acid corrosion inhibitor of mild steel

Experimental and theoretical investigation of (E)-5-{[4-(dimethylamino)benzylidene]amino}-1,3,4-thiadiazole-2(3H)-thione (DATT) as an acid corrosion inhibitor of mild steel

Unleashing the power of polymer surfactants: novel corrosion inhibitors for mild steel in hydrochloric acid

Unleashing the power of polymer surfactants: novel corrosion inhibitors for mild steel in hydrochloric acid

Mild steel corrosion inhibition by nicotinamide as a green inhibitor: An electrochemical, thermodynamic and theoretical insight

Mild steel corrosion inhibition by nicotinamide as a green inhibitor: An electrochemical, thermodynamic and theoretical insight