Sediment export rates are sensitive to different parent materials, changes in land use, human impact and climate, but the landscape response to such changes is difficult to interpret, and more knowledge of soil erosion hot spots is still needed. Special focus should be directed to examine the role of the erosional impact of water movement in mobilising stable elements in soils that become then available to be transferred in agroecosystems. Our main objective was to investigate the mobilisation and redistribution of 15 major and trace elements in the soil along a karstic hillslope in north-eastern Spain. To this purpose, we selected a representative soil catena with two distinctive sections based on the parent material in which the main soil properties and soil erosion patterns are very well characterised. Element contents were determined by ICP-OES and soil redistribution rates were obtained using 137Cs for each of the 12 and 11 soil profiles sampled in the upper and lower sections, respectively. The elemental composition in soil profiles is related to their landscape features and the influence of soil properties and soil redistribution rates are explored. In each section of the soil catena, the distinctive physiographic characteristics of the slope, distribution of land uses, presence of linear landscape elements, and the intrinsic soil properties, namely SOC, HC and grain size, affect runoff and determine the connectivity of eroded sediment, thus affecting the geochemical dynamics. The results of this investigation showed that the different processes governed by infiltration in the upper section versus runoff in the lower section affect elemental mobilisation along the soil catena and contribute to understanding processes of elemental transference in Mediterranean agroecosystems.