Hybrid Nanofibers Research Articles

Investigation of the wavelength dependent nonlinear absorption mechanisms of polyvinylpyrrolidone and cadmium selenide hybrid nanofibers

Investigation of the wavelength dependent nonlinear absorption mechanisms of polyvinylpyrrolidone and cadmium selenide hybrid nanofibers

Boosting the Power of Na0.44MnO2: Unlocking Its Potential for Aqueous Sodium-Ion Storage through Nanostructuring and Hybridization

We report an effective processing route, combining nanostructure formation and hybridization, to improve the rate performance of the tunnel-structure sodium manganese oxide Na0.44MnO2 (NMO) as a cathode material for aqueous sodium ion storage. We use hydrothermal synthesis to prepare an NMO/CNF (Carbon NanoFiber) hybrid, consisting of uniform oxide nanowires with an average width of 70 nm and length in the range of several tenths of µm. The highly dispersed CNFs impart high conductivity to the NMO/CNF electrode, allowing high-rate performance at a C-rate of up to 20 C, with a delivered capacity of more than half the theoretical value in a 1 M Na2SO4 electrolyte. Moreover, the NMO/CNF hybrid shows good electrochemical stability under several hundred cycles at a high C-rate. However, the NMO nanowire electrodes reveal a lower-than-expected capacity, probably as a result of the tendency of nanowires to form bundles, which prevents direct contact with conductive fibers and induce the under-utilization of active material. With this study, we demonstrate a strong improvement of the otherwise inherently low-rate performance of NMO through oxide nanostructuring and hybridization with carbon fibers, paving the way for further research on NMO-based materials for aqueous sodium ion storage.

Chitosan/poly (3-hydroxy butyric acid-co-3-hydroxy valeric acid) electrospun nanofibers with cephradine for superficial incisional skin wound infection management

The belated and compromised incisional skin wound healing caused by the invading of methicillin-resistance staphylococcus aureus is a serious problem in clinic. Designing a new therapeutic strategy to inhibit the growth of invading bacteria at post-surgical site might be helpful in fast healing of post-surgical wounds. In this study, we developed cephradine (Ceph) encapsulated chitosan and poly (3-hydroxy butyric acid-co-3-hydroxy valeric acid, (PHBV)) hybrid nanofibers (Ceph-CHP NFs) employing an electrospinning method to revamp the Ceph bioavailability at the post-surgical wound site to prevent the growth of invading bacteria and trigger the wound healing process. The fabricated nanofibers revealed smooth and uniform surface with a diameter range of 160 ± 25 to 190 ± 55 nm, depending on Ceph concentration. Further, the electrospun hybrid nanofibers exhibited a higher entrapment efficiency (EE) and drug loading capacity (DLC) nearly 72.8 ± 5.2 % and 16.5 ± 3.2 %, respectively. Moreover, the Ceph-CHP NFs showed high swelling rate and biodegradation in presence of lysozyme in contrast to blank CHP NFs. Ceph-CHP NFs exhibited fast drug release in initial few hours followed by slow and controlled drug release drug up to 48 h with a constant rate. In-vitro antimicrobial studies indicated the heightened efficacy of Ceph-CHP NFs against MRSA clinical isolates and exhibited no visible cytotoxicity against keratinocytes, HC11 and L929 cells. Lastly, Ceph-CHP NFs showed the enhanced wound healing and bacterial clearance from post-surgical wound compared to Ceph in C57BL/6 mice skin model. Overall, our results showed that Ceph-CHP NFs might be used as a promising wound dressing material for MRSA-infected post-surgical wounds.

Evaluation of contact angle and mechanical properties of resin monomers filled with graphene oxide nanofibers.

This in vitro study synthesized hybrid nanofibers embedded in graphene oxide (GO) and incorporated them into experimental resin composite monomers to evaluate their physical-mechanical properties. Inorganic-organic hybrid nanofibers were produced with precursor solutions of 1% wt. GO-filled Poly (d,l-lactide, PLA) fibers and scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) characterized the morphology and chemical composition of the spun fibers. Resin composite monomers were developed and a total of 5% nanofibers were incorporated into the experimental materials. Three groups were developed: G1 (control resin monomers), G2 (resin monomers/PLA nanofibers), and G3 (resin monomers/inorganic-organic hybrid nanofibers). Contact angle (n=3), flexural strength (n=22), elastic modulus (n=22), and Knoop hardness (n=6) were evaluated. The mean of the three indentations was obtained for each sample. The normality of data was assessed by QQ Plot with simulated envelopes and analyzed by Welch's method (p<0.05). Overall, SEM images showed the regular shape of nanofibers but were non-aligned. Compositional analysis from EDS (n=6) revealed the presence of carbon and oxygen (present in GO composition) and Si from the functionalization process. The results of contact angle (°) and hardness (Kg/mm2) for each group were as follow, respectively: G1 (59.65±2.90; 37.48±1.86a), G2 (67.99±3.93; 50.56±1.03b) and G3 (62.52±7.40; 67.83±1.01c). The group G3 showed the highest Knoop hardness values (67.83 kg/mm2), and the flexural strength of all groups was adversely affected. The experimental resin composite composed of hybrid nanofibers with GO presented increased hardness values and hydrophilic behavior.

Investigating S-scheme charge transfer pathways in NiS@Ta2O5 hybrid nanofibers for photocatalytic CO2 conversion

Investigating the charge-transfer behavior of photocatalysts is important to promote the photoreduction of CO2 into solar fuels. Therefore, in this study, hybrid Ta2O5 nanofibers were produced through the in situ growth of freestanding NiS nanosheets. The charge separation and CO2 photoreduction mechanisms of these nanofibers were investigated using in situ X-ray photoelectron spectroscopy and density functional theory calculations. The results suggested that the NiS@Ta2O5 nanohybrids formed an S-scheme heterojunction, which promoted the efficient separation of electron-hole pairs and enhanced CO2 photoreduction. Compared to the pristine Ta2O5 nanofibers, the hybrid nanofibers exhibited a significantly higher CO2-reduction rate (43.27 μmol g−1 h−1 for CO; 6.56 μmol g−1 h−1 for CH4). In situ diffuse reflectance infrared Fourier-transform spectroscopy results confirmed the process of CO2 hydrogenation and S-scheme charge transfer pathways in NiS@ Ta2O5 nanohybrids.

Investigation of the influence of Eu, Yb, and Eu:Yb codoping on ZnO highly-crystalline nanofibers prepared by electrospinning method

Facile synthesis method of undoped and rare earth metals (REM) doped (RE = Yb, Eu and Eu:Yb) one-dimensional ZnO nanostructures with high REM concentration using electrospinning followed by calcination at 500 °C were carried out. One-dimensional (1D) ceramic nanostructures were characterized in terms of morphology, structure, and optical properties. The analysis carried out revealed highly crystalline nature of ZnO wurtzite structure and hybrid nanofibers with a mixture of crystalline phases. High-resolution X-Ray Photon Spectroscopy spectra confirmed successful Eu and Yb modification of ZnO lattice revealing the existence of Eu2+, Eu3+ and Yb3+ ions. The optical properties results showed reduction in optical energy band gap from 3.02 eV to 2.55 eV for undoped and Eu:Yb doped ZnO 1D nanostructures, respectively. The influence of Eu, Yb, and Eu:Yb codoping on ZnO electrospun nanostructures was investigated, and potential application of such obtained nanofibers was proposed as photon upconversion material for photocatalysis.

Enhanced Thermal and Mechanical Properties of Electrospun PA-6 Nanofibers by Embedding Alumina and Tungsten Carbide Particles

Electrospinning is a process in which solid fibers are prepared from polymer solution. In recent decades, studies have focused on improving the properties of electrospun nanofibers by exploring the possibilities of electrospinning different polymers. Two critical properties that have been studied in relation to this technique are thermal stability and mechanical properties. In this study, polyamide-6 (PA-6) nanofibers were prepared by embedding combinations of alumina and tungsten carbide particles. The morphology of the resulting hybrid nanofibers was analyzed using scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM), Energy-dispersive X-ray spectroscopy (EDX), differential scanning calorimetry (DSC) and Thermogravimetric (TGA) techniques, and tensile tests were performed to evaluate their mechanical properties. The results showed that the sample containing tungsten carbide with a weight ratio of 4:10 had the highest melting standard enthalpy. The analysis also revealed that hybrid fibers containing equal ratios of alumina and tungsten carbide, each with a weight ratio of 2:10, had higher degradation temperatures and melting enthalpy compared to other nanofibers. Tensile testing showed that nanofibrous mats containing tungsten carbide had higher Young’s modulus, PA-6 fibers.

Double-layer hybrid nanofiber membranes by electrospinning with sustained antibacterial activity for wound healing

Bacterial infection is a general problem that increases the burden of wound treatment. It has been intensely expected to fabricate bioactive wound dressings with good antibacterial effect. In this work, double-layer hybrid nanofiber membranes (DHNM) of PVA/COL@ZnONPs and PCL/Gt@TiO2NPs were built by continuous electrospinning. The matrix membranes with acceptable tensile strength and moisture permeability property were obtained by optimizing the formulation and spinning conditions. The matrix membranes exhibited Young’s modulus of 91.93 MPa and tensile stress of 2.61 MPa. The water vapor transmittance rate (WVTR) of matrix membranes was 1140.45 g/m2·day. ZnONPs in the inner layer were released quickly in 2 hours to destroy the bacteria in the wound. TiO2NPs in the outer layer were sustainably released within 7 days to resist the bacterial attack outsides. The double-layer membranes showed good biocompatibility and enhanced the migration of cells. The cell migration rate of double-layer hybrid membranes (DHNM) was higher than that of single layer membranes. The double-layer membrane showed 93% elimination of the wound specific P. aeruginosa, over 99% inhibition to E. coli and over 97% to S. aureus. This study provides a potential approach for wound dressings to improve antibacterial effect.

Graphene quantum dots functionalized Ce-ZnO nanofibers with enriched oxygen vacancy sites morphology to improve the efficiency of selective electrochemical detection of Hg (II)

Herein, GQD functionalized Ce-ZnO hybrid nanofibers (GQD/Ce-ZnO NFs) towards selective Hg2+ ion detection through DPV technique was investigated. The hybrid NFs were synthesized via a facile electrospinning process and their physical properties were investigated through XRD, SEM-EDS, HR-TEM with SAED pattern, XPS, UV-DRS, and ESR techniques. Notably, the plane value, phase recognition, and purity of the GQD/Ce-ZnO NFs were examined through XRD analysis. The chemical states, chemical composition, and weight percentage of the elements were examined by the XPS and EDS analysis. Similarly, the width of the hybrid NFs and structural morphology were elucidated through SEM and HR-TEM analysis. The existence of oxygen vacancies (vo) was verified using UV-DRS and ESR techniques. The electrochemical characteristics of GQD/Ce-ZnO NFs-modified glassy carbon electrode (GCE) was investigated using diverse electrochemical methodologies like cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV). Remarkably, DPV studies depict that GQD/Ce-ZnO NFs modified GCE achieved high anodic peak current 3.48 × 10−4 A upon successive addition of Hg2+ (0.1–100 μM). The anodic peak current was directly proportional to the mercury ions concentration throughout a wide range of 0.1 × 10−6 to 100 × 10−6 M with a LOD of 267 nM in an optimized experimental condition. The GQD/Ce-ZnO NFs modified GCE showed remarkable reproducibility, with an RSD value of 1.81 %. Additionally, it maintained a strong current retention rate of 71.5 % over 12 days, indicating commendable long-term stability.

Natural-Wood-Inspired Ultrastrong Anisotropic Hybrid Hydrogels Targeting Artificial Tendons or Ligaments.

Hydrogels are able to mimic the flexibility of biological tissues or skin, but they still cannot achieve satisfactory strength and toughness, greatly limiting their scope of application. Natural wood can offer inspiration for designing high-strength hydrogels attributed to its anisotropic structure. Herein, we propose an integrated strategy for efficient preparation of ultrastrong hydrogels using a salting-assisted prestretching treatment. The as-prepared poly(vinyl alcohol)/cellulose nanofiber hybrid hydrogels show distinct wood-like anisotropy, including oriented molecular fiber bundles and extended grain size, which endows materials with extraordinarily comprehensive mechanical properties of ultimate breaking strength exceeding 40 MPa, strain approaching 250%, and toughness exceeding 60 MJ·m-3, and outstanding tear resistance. Impressively, the breaking strength and toughness of the reswollen preoriented hydrogels approach 10 MPa and 25 MJ·m-3, respectively. In vitro and in vivo tests demonstrate that the reswollen hydrogels do not affect the growth and viability of the cells, nor do they cause the inflammation or rejection of the mouse tissue, implying extremely low biotoxicity and perfect histocompatibility, showcasing bright prospects for application in artificial ligaments or tendons. The strategy provided in this study can be generalized to a variety of biocompatible polymers for the fabrication of high-performance hydrogels with anisotropic structures.

Bimetallic copper-cobalt MOFs anchored carbon nanofibers hybrid mat based electrode for simultaneous determination of dopamine and tyramine

Early monitoring of histamine and tyramine levels in foodstuffs could protect against several diseases. In the present study, a self-standing copper-cobalt(2-methylimidazole) MOF anchored carbon nanofiber hybrid mat (Cu-Co(2-Meim)MOF@CNF) was prepared for the simultaneous detection and quantification of dopamine and tyramine in cheese and banana samples. As-prepared Cu-Co(2-Meim)MOF@CNF hybrid mats are highly porous with a large surface area, and also possess excellent hydrophilicity, which allows the analyte molecules to easily access the redox-active metal sites of the MOF matrix and subsequently enhance the sensitivity. The functional groups within the MOF matrix can also function as active adsorption sites during electrocatalysis. At the acidic condition (pH = 5.0), the Cu-Co(2-Meim)MOF@CNF exhibited improved catalytic activity and strong electrochemical sensitivity toward dopamine (DA) and tyramine (TY) with faster electron transfer kinetics and significant fouling resistance. The oxidation reactions of dopamine and tyramine at the hybrid electrode were irreversible and diffusion-controlled. The Cu-Co(2-Meim)MOF@CNF/GCE sensor demonstrated a broad linear range from 5 to 800 µM along with a low LOD of 44.2 nM and 52.7 nM for dopamine and tyramine, respectively. The hybrid sensor exhibited excellent anti-interference properties and long-term storage stability for up to 30 days. It is noteworthy that the Cu-Co(2-Meim)MOF@CNF/GCE sensor has demonstrated the capability of detecting dopamine and tyramine in cheese and banana samples, respectively, which would be helpful for food analysis and food safety.

Optimization of electrospun chitosan/polyethylene oxide hybrid nanofibril composite via response surface methodology

The present study is an attempt to optimize the electrospinning parameters to fabricate chitosan/polyethylene oxide hybrid nanofiber composite with minimum diameter and coefficient of variation (homogeneity) by using response surface methodology (RSM). Based on central composite design (CCD), four factors (the chitosan/PEO ratio, the applied voltage, the needle-to-collector distance, and the spinning angle) was applied to evaluate the individual and combined effects of the parameters on the average diameter of nanofibers. Chitosan (CH) was blended with Polyethylene oxide (PEO) at weight ratios of 1:1, 2:1, 3:1, 4:1, and 5:1. As the composition ratio of chitosan was reduced, the viscosity of the chitosan/PEO blend solution also dropped. The RSM model identified the following conditions as necessary to produce the desired and most uniform CS/PEO fiber diameter: a CS/PEO blend ratio of 2:1 (w/w), a voltage of 25 kV, a distance of 20 cm, and a spinning angle of 45°. The average nanofiber diameter and homogeneity under these conditions were calculated to be 73 nm and 20.5%, respectively, compared to the predicted values of 71 nm and 15.58%, respectively.

Cooperative assembly of a designer peptide and silk fibroin into hybrid nanofiber gels for neural regeneration after spinal cord injury.

Local reconstruction of a permissive environment with biomaterials is a promising strategy to treat spinal cord injury (SCI). We reported a hybrid hydrogel fabricated from a small functional self-assembling peptide (F-SAP) and large silk fibroin (SF). The diffusion of SF micelles into F-SAP solution was driven by the dynamic synergy between osmotic pressure and F-SAP/SF electrostatic interactions, resulting in the rearrangement of SF micelles and the formation of rod-like filaments with axes nearly perpendicular to F-SAP nanofibers. Spectroscopy analysis, including circular dichroism, Raman and fluorescence, indicated conformation changes of SF from random coil to β sheet, which contributed to enhanced mechanical properties of the resultant hybrid hydrogel. Furthermore, the F-SAP/SF hybrid hydrogel coupled with controlled release of NT-3 provided a permissive environment for neural regeneration by providing nanofibrous substrates for regenerating axons, inflammatory modulation and remyelination, consequently resulting in improved locomotion and electrophysiological properties. This hydrogel could be used as a long-term stent in vivo for the treatment of SCI.

A Review Study of the Mechanical Characteristics of Nano Concrete Reinforced with Hybrid Fiber

Due to poor strength and hardness, low tensile strength, and inadequate cracking resistance, conventional concrete has recently posed a significant barrier to the modernization of the structural sector. To solve these issues, researchers investigated and found ways of implementing nanotechnology in concrete production. Nano concrete can be produced by incorporating nanomaterials in the concrete mix. This concrete type can also be reinforced by incorporating hybrid fibers and nanofibers. This review paper conducted an in-depth study on two types of nanomaterials that could be used in the production of nano concrete. Additionally, hybrid fibers were used to strengthen nano concrete. The objective of this paper was to identify some nanomaterials used in the production of nano concrete. Even though this unique hybrid material has been the subject of several investigations, there have only been a few reviews on its production procedures, effectiveness, and performance of this type of concrete. To identify these nanomaterials, their potential, and their properties, a review method was used to study previous works of some researchers and scientists on related and similar works. Some properties of these nanomaterials were discussed in this paper. Summarizing and concluding the research works of previous authors and this current study, it was found that nano concrete has better properties compared to normal conventional concrete. However, there are some limitations associated with the uses and applications of these nanomaterials in concrete for mass production. By tracking the beginning and spread of cracks, it was discovered that mixing various fiber types into a concrete mix enhances the cementitious matrix's strength qualities. The mechanical and toughness characteristics of fiber-reinforced concrete mixtures may be significantly improved by incorporating composites hybrid fiber composites that utilize the synergistic impact of nano- and micro-additives.

Synthesis mechanism and ‘orthodoxy’ test based field emission analysis of hybrid and pristine graphene nanowalls deposited on thin Kovar wires

Graphene nanowalls (GNWs) also known as carbon nanowalls (CNWs) and GNWs‑carbon nanofibers (CNFs) hybrid nanostrucrures are grown on metallic wires using a two-step microwave plasma enhanced chemical vapour deposition (MW-PECVD) process. Here, plasma is generated in two steps (first at lower pressure and then at higher operating pressure) to avoid arcing on the metallic wire during the growth. Combination of Raman and transmission electron microscopy studies revealed presence of herringbone CNFs in the hybrid nanostructures that are grown with −100 V bias compared to pristine GNWs that are grown without any bias. A new approach for field emission (FE) analysis is created by combining FN equation with ‘orthodoxy test’ in a modified approach to avoid spurious results. Here, hybrid nanostructures exhibited higher current and more repeatable field emission characteristics over 4 cycles of operation. Post FE investigations indicate that while pristine GNWs underwent many deformities and structural changes, hybrid structures remain almost unscathed. These investigations point out that a novel synthesis mechanism can be used to grow GNW based hybrid nanostructures for different applications like X-ray sources which involves FE at the core.

Photocatalytic hydrogen evolution coupled with tetracycline photodegradation over S-scheme BaTiO3/Ag2S dual-function nanofibers: Performance and mechanism

Utilizing solar energy for the hydrogen evolution with synchronous pollutant degradation is an extremely promising strategy to address environmental pollution and energy shortages. In this study, novel S-scheme BaTiO3/Ag2S dual-function nanofibers were developed for the highly efficient photocatalytic hydrogen evolution coupled with pollutant degradation via electrospinning and hydrothermal methods. Thanks to increased light absorption capacity, stronger photothermal performance, enhanced charge carrier separation efficiency and appropriate band structure, optimized BaTiO3/Ag2S hybrid nanofibers showed a photocatalytic hydrogen evolution activity of 133 μmol h−1 g−1 synchronously with the degradation of 57.9 % tetracycline in 3 h. Moreover, the results of density functional theory calculations and experiments have demonstrated that the photoexcited electrons in BaTiO3/Ag2S hybrids follow the S-scheme electron transfer mechanism, which significantly facilitates charge carrier separation. Thus, this work can provide some useful hints for designing efficient dual-function photocatalysts.

Structural Engineering of Hierarchical Aerogels Hybrid Networks for Efficient Thermal Comfort Management and Versatile Protection (Small 25/2023)

Hierarchical Aerogels Hybrid Networks Silica nanofiber aerogels functionalized P(VDF-HFP) membrane (SFP membrane), inspired by constructional engineering is constructed. As the host material for thermal comfort management and versatile protection, the SFP membrane features a large surface area, porous structure, and a robust skeleton that can render excellent mechanical properties. Additionally, the SFP membrane exhibits exceptional solar reflectivity (0.95) and strong mid-infrared emittance (0.98). More details can be found in article number 2301164 by Qinghua Zhang and co-workers.

Synthesis of Polyvinyl Alcohol/Coal Fly Ash Hybrid Nano-Fiber Membranes for Adsorption of Heavy Metals in Diesel Fuel.

Some studies have shown that the heavy metal emissions (HMEs) emitted from diesel engines can seriously threaten human health. HMEs are mainly related to the content of heavy metal ions in diesel fuel. Therefore, in order to reduce HMEs from diesel engines, a nano-fiber membrane filtration technology for diesel fuel was investigated. Herein, coal fly ash (CFA) from coal-fired power plants combined with polyvinyl alcohol (PVA) was successfully fabricated into nano-fibrous membranes using green electrospinning technology. In order to evaluate the adsorption properties, various hybrid membranes with different mixing ratios (PVA/CFA = 10/0, 10/1, 10/3, 10/5, and 10/7 by weight) were fabricated. The results show that eight metal ions with different concentrations are found in the diesel fuel, including Pb, Cu, Zn, Al, Fe, Cr, Ba, and Ni. All PVA/FA membranes have different adsorption capacities for metal ions, following the order: Cu > Fe > Pb > Al > Zn > Cr > Ba > Ni. In addition, the adsorption capacity of CFA3 (PVA/CFA = 10/3) is the largest. The super lipophilicity of the PVA/FA membranes also provide more adsorption sites for the contact of HMs with the membranes. The above research results provide guidance for development of ultra-fine filters in the future.

Fabrication of an Electrocatalyst Based on Rare Earth Manganites Incorporated with Carbon Nanofiber Hybrids: An Efficient Electrochemical Biosensor for the Detection of Anti-Inflammatory Drug Mefenamic Acid

Pharmaceutical and personal care products are emerging as a new category of environmental pollution. Analytical drug detection from a biological sample for detection is still crucial today. Mefenamic acid (MA) is an anti-inflammatory drug utilized for its antipyretic and analgesic properties, which is harmful to patients at higher dosages and is also recognized as a chemical pollutant that harms the environment. In this view, Dysprosium manganite/carbon nanofiber (DMO/CNF) was prepared by hydrothermal method for the electrochemical detection of MA. DMO/CNF/GCE exhibits high selectivity, excellent anti-interference, good stability, and reproducibility toward the detection of MA. The enhanced electrochemical performance of DMO/CNF/GCE was attributed to their synergetic interaction. Under optimized conditions, DMO/CNF/GCE shows a wide linear range of 0.01–741 μM and a low LOD of 0.009 μM. Satisfactory recoveries were obtained for human blood and tablet samples. Thus, the proposed DMO/CNF nanocomposite emerges as a promising material for the detection of MA.

Flexible core-shell PAN/CNTs@PVDF-HFP/Uio-66-NH2 hybrid nanofibers membrane for advanced lithium-ion batteries separator

Flexible core-shell polyacrylonitrile (PAN)/carbon nanotubes (CNTs)@Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP)/Uio-66-NH2 (PC@PU) hybrid nanofiber membrane was prepared by coaxial electrospinning technology. PAN polymer and CNTs particles were used as core to improve the membrane structure stability for further ensuring the thermal stability of the separator. PVDF-HFP and Uio-66-NH2 nanoparticles were applied to reinforce the affinity of separator to electrolyte. The PC@PU composite membrane delivered high thermal stability and fantastic electrolyte affinity (545.76%). Furthermore, compared with Celgard 2325 commercial membrane, the PC@PU composite membrane exhibited higher porosity (80.22%) and higher Li+ conductivity (3.43 mS/cm), leading to superior rate performance and long-term cycle stability. The cell with the PC@PU hybrid membrane displayed high specific capacity of 143 mAh/g at 1C and only 0.0259% capacity attenuation of each cycle after 1000 cycles. In addition, the PC@PU composite membrane demonstrated remarkable flexibility, and the cells with bent separators exhibited outstanding electrochemical performance. Hence, the PC@PU hybrid nanofiber membrane can pave a way for the further application in the field of secondary batteries separator.