History Of Mars Research Articles

The early geodynamic evolution of Mars-type planets

It is not clear whether Mars once possessed active tectonics, yet the question is critical for understanding the thermal evolution of Mars, and the origin and longevity of its early dynamo. To address these issues, we have coupled mantle flow simulations, together with parameterized core evolution models, to simulate the early evolution of Mars-like planets, and constrain the influence of early mobile-lid tectonics on core evolution. We have explored a wide parameter suite, encapsulating a range of uncertainties in initial conditions, rheological parameters, and surface strength. We present successful models that experience early mobile-lid behaviour, with a later transition into a stagnant-lid mode, which reproduce core dynamo histories similar to the magnetic history of early Mars.

Shock effects in plagioclase feldspar from the Mistastin Lake impact structure, Canada

AbstractShock metamorphism, caused by hypervelocity impact, is a poorly understood process in feldspar due to the complexity of the crystal structure, the relative ease of weathering, and chemical variations, making optical studies of shocked feldspars challenging. Understanding shock metamorphism in feldspars, and plagioclase in particular, is vital for understanding the history of Earth's moon, Mars, and many other planetary bodies. We present here a comprehensive study of shock effects in andesine and labradorite from the Mistastin Lake impact structure, Labrador, Canada. Samples from a range of different settings were studied, from in situ central uplift materials to clasts from various breccias and impact melt rocks. Evidence of shock metamorphism includes undulose extinction, offset twins, kinked twins, alternate twin deformation, and partial to complete transformation to diaplectic plagioclase glass. In some cases, isotropization of alternating twin lamellae was observed. Planar deformation features (PDFs) are notably absent in the plagioclase, even when present in neighboring quartz grains. It is notable that various microlites, twin planes, and compositionally different lamellae could easily be mistaken for PDFs and so care must be taken. A pseudomorphous zeolite phase (levyne‐Ca) was identified as a replacement mineral of diaplectic feldspar glass in some samples, which could, in some instances, also be potentially mistaken for PDFs. We suggest that the lack of PDFs in plagioclase could be due to a combination of structural controls relating to the crystal structure of different feldspars and/or the presence of existing planes of weakness in the form of twin and cleavage planes.

Assessing the Spectral Sensitivity of Martian Terrains to Iron Oxide Variations Using the SPLITS Model

The mineralogy and environmental history of Mars are being extensively studied through remote sensing observations paired with laboratory and in situ experiments. A significant portion of these experiments is being devoted to the identification and mapping of different iron oxides present in the Martian terrains. Among these compounds, goethite has been an object of great interest since its occurrence can be interpreted as mineralogical evidence of past aqueous activity on those landscapes. Although such experiments can provide valuable information regarding the presence of these minerals, the scope of the resulting observations may be hindered by logistics and cost-related constraints. We believe that predictive computer simulations can be employed to mitigate some of these constraints and contribute to the generation and validation of hypotheses in this area. Accordingly, we propose the use of SPLITS (Spectral Light Transport Model for Sand) in investigations involving the spectral signatures of iron-bearing regions of Mars. In this paper, we initially demonstrate the predictive capabilities of the SPLITS model in this context through qualitative comparisons of modeled results with actual observations and measured data. Using the resulting modeled reflectance curves as our baseline data, we then perform a series of controlled computational experiments to investigate how variations on goethite and hematite content affect the spectral responses of Martian sand-textured soils.

Spatial distributions of secondary minerals in the Martian meteorite MIL 03346,168 determined by Raman spectroscopic imaging

AbstractMiller Range (MIL) 03346 is a nakhlite meteorite that has been extensively studied due to its unique complex secondary mineral phases and their potential implications for the hydrologic history of Mars. We conducted a set of Raman spectroscopic and Raman imaging studies of MIL 03346,168, focusing on the secondary mineral phases and their spatial distributions, with a goal to better understand the possible processes by which they were generated on Mars. This study revealed three types of calcium sulfates, a solid solution of (K, Na)‐jarosite and two groups of hydrated species with low crystallinity (HSLC) in the veins and/or mesostasis areas of the meteorite. The most abundant Ca‐sulfate is bassanite that suggests two possible paths for its direct precipitation from a Ca‐S‐H2O brine, either having low water activity or with incomplete development (producing bassanite with gypsum microcrystals) on Mars. The second most abundant Ca‐sulfate is soluble γ‐CaSO4 which raises a new question on the origins of this phase in the Martian meteorite, since γ‐CaSO4 readily hydrates in the laboratory but is apparently stable in Atacama Desert. The close spatial relationship of (K, Na)‐jarosite solid solutions with rasvumite (KFe2S3), magnetite, HSLC, and fine‐grained low‐crystallinity alkali feldspar in mesostasis suggests a potential in situ formation of mesostasis jarosite from these Fe‐K,Na‐S‐O‐H2O species.

Volcanic hydrothermal systems as potential analogues of Martian sulphate-rich terrains

AbstractRemote sensing observations and rover missions have documented the presence of sulphate-rich mineral associations on Mars. Many of these minerals are paleo-indicators of hydrous, acidic and oxidising environments that must have prevailed in Mars´ distant past, contrary to the present conditions. Furthermore, occurrences of silica together with high Cl and Br concentrations in Martian soils and rocks represent fingerprints of chemically atypical fluids involved in processes operating on the surface or at shallow depth. From field observations at representative active volcanoes in subduction settings, supported by geochemical modelling, we demonstrate that volcanic hydrothermal systems are capable of producing Mars-like secondary mineral assemblages near lakes, springs and fumaroles through the action of acidic fluids. Water–gas-rock interactions, together with localised flow paths of water and fumarolic gas emitted from associated subaerial vents, lead to deposition of a range of sulphates, including gypsum, jarosite, alunite, epsomite and silica. Evaporation, vapour separation and fluid mixing in (near-) surface environments with strong gradients in temperature and fluid chemistry further promote the diversity of secondary minerals. The mineralogical and chemical marks are highly variable in space and time, being subject to fluctuations in ambient conditions as well as to changes in the status of volcanic-hydrothermal activity. It is concluded that active processes in modern volcanic-geothermal systems may be akin to those that created several of the sulphate-rich terrains in the early history of Mars.

Stratigraphy of Aeolis Dorsa, Mars: Stratigraphic context of the great river deposits

Unraveling the stratigraphic record is the key to understanding ancient climate and past climate changes on Mars (Grotzinger, J. et al. [2011]. Astrobiology 11, 77–87). Stratigraphic records of river deposits hold particular promise because rain or snowmelt must exceed infiltration plus evaporation to allow sediment transport by rivers. Therefore, river deposits when placed in stratigraphic order could constrain the number, magnitudes, and durations of the wettest (and presumably most habitable) climates in Mars history. We use crosscutting relationships to establish the stratigraphic context of river and alluvial-fan deposits in the Aeolis Dorsa sedimentary basin, 10°E of Gale crater. At Aeolis Dorsa, wind erosion has exhumed a stratigraphic section of sedimentary rocks consisting of at least four unconformity-bounded rock packages, recording three or more distinct episodes of surface runoff. Early deposits (>700m thick) are embayed by river deposits (>400m thick), which are in turn unconformably draped by fan-shaped deposits (<100m thick) which we interpret as alluvial fans. Yardang-forming layered deposits (>900m thick) unconformably drape all previous deposits.River deposits embay a dissected landscape formed of sedimentary rock. The river deposits are eroding out of at least two distinguishable units. There is evidence for pulses of erosion during the interval of river deposition. The total interval spanned by river deposits is >(1×106–2×107) yr, and this is extended if we include alluvial-fan deposits. Alluvial-fan deposits unconformably postdate thrust faults which crosscut the river deposits. This relationship suggests a relatively dry interval of >4×107yr after the river deposits formed and before the fan-shaped deposits formed, based on probability arguments. Yardang-forming layered deposits unconformably postdate all of the earlier deposits. They contain rhythmite and their induration suggests a damp or wet (near-) surface environment. The time gap between the end of river deposition and the onset of yardang-forming layered deposits is constrained to >1×108yr by the high density of impact craters embedded at the unconformity. The time gap between the end of alluvial-fan deposition and the onset of yardang-forming layered deposits was at least long enough for wind-induced saltation abrasion to erode 20–30m into the alluvial-fan deposits. We correlate the yardang-forming layered deposits to the upper layers of Gale crater’s mound (Mt. Sharp/Aeolis Mons), and the fan-shaped deposits to Peace Vallis fan in Gale crater. Alternations between periods of low mean obliquity and periods of high mean obliquity may have modulated erosion–deposition cycling in Aeolis. This is consistent with the results from an ensemble of simulations of Solar System orbital evolution and the resulting history of the obliquity of Mars. 57 of our 61 simulations produce one or more intervals of continuously low mean Mars obliquity that are long enough to match our Aeolis Dorsa unconformity data.

Forsterite dissolution rates in Mg‐sulfate‐rich Mars‐analog brines and implications of the aqueous history of Mars

AbstractHigh salinity brines, although rare on Earth's surface, may have been important in the geologic history of Mars. Increasing evidence suggests the importance of liquid brines in multiple locations on Mars. In order to interpret the effect of high ionic strength brines on olivine dissolution, which is widely present on Mars, 47 new batch reactor experiments combined with 35 results from a previous study conducted at 25°C from 1 &lt; pH &lt; 4 in magnesium sulfate, sodium sulfate, magnesium nitrate, and potassium nitrate solutions with ionic strengths as high as 12 m show that very high ionic strength brines have an inhibitory effect of forsterite dissolution rates. Multiple linear regression analysis of the data suggests that the inhibition in dissolution rates is due to decreased water activity at high ionic strengths. Regression models also show that mMg up to 4 m and mSO4 up to 3 m have no effect on forsterite dissolution rates. The effect of decreasing dissolution rates with decreasing aH2O is consistent with the idea that water acts as a ligand that participates in the dissolution process. Less available water to participate in the dissolution reaction results in a slower dissolution rate. Multiple linear regression analysis of the data produces the rate equation . Forsterite in dilute solutions with a water activity of one dissolves twice as fast as those in brines with a water activity of 0.8.

The effects of mantle composition on the peridotite solidus: Implications for the magmatic history of Mars

At a given pressure, terrestrial peridotites of varying composition may have solidus temperatures that differ by up to 100°C. Based on meteorite evidence, the mantle of Mars is believed to be enriched in Na and K and to have a higher Fe/Mg ratio (lower magnesium number, Mg#) than Earth. These differences all favor a mantle solidus temperature on Mars that is lower than on Earth and are important in understanding the volcanic history of Mars. We parameterize the peridotite solidus at 1 and 3GPa as a function of Mg# and total alkali content, using existing measurements of peridotite melting at 1 and 3GPa for Mg# between 75 and 91 and total alkali content between 0.06 and 1.17 weight percent. The solidus on early Mars was likely 30–40°C lower than on Earth, which increases the predicted crustal production by about 20% over martian history, relative to a Mars model that uses a solidus calculated for terrestrial peridotite composition. Because Na is incompatible and migrates to the crust over time, the present-day martian solidus is higher than the primitive solidus but is still ∼15°C less than on Earth. This enhances the present-day magma production rate at martian mantle plumes by a factor of 2–3.

Highly siderophile element (HSE) abundances in the mantle of Mars are due to core formation at high pressure and temperature

AbstractHighly siderophile elements (HSEs) can be used to understand accretion and core formation in differentiated bodies, due to their strong affinity for FeNi metal and sulfides. Coupling experimental studies of metal–silicate partitioning with analyses of HSE contents of Martian meteorites can thus offer important constraints on the early history of Mars. Here, we report new metal–silicate partitioning data for the PGEs and Au and Re across a wide range of pressure and temperature space, with three series designed to complement existing experimental data sets for HSE. The first series examines temperature effects for D(HSE) in two metallic liquid compositions—C‐bearing and C‐free. The second series examines temperature effects for D(Re) in FeO‐bearing silicate melts and FeNi‐rich alloys. The third series presents the first systematic study of high pressure and temperature effects for D(Au). We then combine our data with previously published partitioning data to derive predictive expressions for metal–silicate partitioning of the HSE, which are subsequently used to calculate HSE concentrations of the Martian mantle during continuous accretion of Mars. Our results show that at midmantle depths in an early magma ocean (equivalent to approximately 14 GPa, 2100 °C), the HSE contents of the silicate fraction are similar to those observed in the Martian meteorite suite. This is in concert with previous studies on moderately siderophile elements. We then consider model calculations that examine the role of melting, fractional crystallization, and sulfide saturation/undersaturation in establishing the range of HSE contents in Martian meteorites derived from melting of the postcore formation mantle. The core formation modeling indicates that the HSE contents can be established by metal–silicate equilibrium early in the history of Mars, thus obviating the need for a late veneer for HSE, and by extension volatile siderophile elements, or volatiles in general.

Glaciation in the Late Noachian Icy Highlands: Ice accumulation, distribution, flow rates, basal melting, and top-down melting rates and patterns

Geological evidence for extensive non-polar ice deposits of Amazonian age indicates that the current cold and dry climate of Mars has persisted for several billion years. The geological record and climate history of the Noachian, the earliest period of Mars history, is less certain, but abundant evidence for fluvial channels (valley networks) and lacustrine environments (open-basin lakes) has been interpreted to represent warm and wet conditions, including rainfall and runoff. Alternatively, recent atmospheric modeling results predict a “cold and icy” Late Noachian Mars in which moderate atmospheric pressure accompanied by a full water cycle produce an atmosphere where temperature declines with elevation following an adiabatic lapse rate, in contrast to the current situation on Mars, where temperature is almost completely determined by latitude. These results are formulated in the Late Noachian Icy Highlands (LNIH) model, in which these cold and icy conditions lead to the preferential deposition of snow and ice at high elevations, such as the southern uplands. What is the fate of this snow and ice and the nature of glaciation in such an environment? What are the prospects of melting of these deposits contributing to the observed fluvial and lacustrine deposits?To address these questions, we report on a glacial flow-modeling analysis using a Mars-adapted ice sheet model with LNIH climate conditions. The total surface/near-surface water inventory is poorly known for the Late Noachian, so we explore the LNIH model in a “supply-limited” scenario for a range of available water abundances and a range of Late Noachian geothermal fluxes. Our results predict that the Late Noachian icy highlands (above an equilibrium line altitude of approximately +1km) were characterized by extensive ice sheets of the order of hundreds of meters thick. Due to extremely cold conditions, the ice-flow velocities in general were very low, less than a fewmm/yr, and the regional ice-flow pattern was disorganized and followed topography, with no radial flow pattern typical of an equilibrium ice sheet. Virtually the entire ice sheet is predicted to be cold-based, and thus the range of wet-based features typically associated with temperate glaciers (e.g., drumlins, eskers, etc.) is not predicted to occur. Wet-based conditions are predicted only locally in the thickest ice (on the floors of the deepest craters), where limited subglacial lakes may have formed.These LNIH regional ice-sheets provide a huge reservoir of potential meltwater as a source for forming the observed fluvial and lacustrine features and deposits. Top-down melting scenarios applied to our LNIH ice sheet model predict that periods of punctuated warming could lead to elevated temperatures sufficient to melt enough snow and ice to readily account for the observed fluvial and lacustrine features and deposits. Our model indicates that such melting should take place preferentially at the margins of the ice sheets, a prediction that can be tested with further analyses.

Late Noachian and early Hesperian ridge systems in the south circumpolar Dorsa Argentea Formation, Mars: Evidence for two stages of melting of an extensive late Noachian ice sheet

The Dorsa Argentea Formation (DAF), extending from 270°–100° E and 70°–90° S, is a huge circumpolar deposit surrounding and underlying the Late Amazonian South Polar Layered Deposits (SPLD) of Mars. Currently mapped as Early-Late Hesperian in age, the Dorsa Argentea Formation has been interpreted as volatile-rich, possibly representing the remnants of an ancient polar ice cap. Uncertain are its age (due to the possibility of poor crater retention in ice-related deposits), its mode of origin, the origin of the distinctive sinuous ridges and cavi that characterize the unit, and its significance in the climate history of Mars. In order to assess the age of activity associated with the DAF, we examined the ridge populations within the Dorsa Argentea Formation, mapping and characterizing seven different ridge systems (composed of nearly 4,000 ridges covering a total area of ~300,000km2, with a cumulative length of ridges of ~51,000km) and performing crater counts on them using the method of buffered crater counting to determine crater retention ages of the ridge populations. We examined the major characteristics of the ridge systems and found that the majority of them were consistent with an origin as eskers, sediment-filled subglacial drainage channels. Ridge morphologies reflect both distributed and channelized esker systems, and evidence is also seen that some ridges form looping moraine-like termini distal to some distributed systems. The ridge populations fall into two age groups: ridge systems between 270° and 0° E date to the Early Hesperian, but to the east, the Promethei Planum and the Chasmata ridge systems date to the Late Noachian. Thus, these ages, and esker and moraine-like morphologies, support the interpretation that the DAF is a remnant ice sheet deposit, and that the esker systems represent evidence of significant melting and drainage of meltwater from portions of this ice sheet, thus indicating at least some regions and/or periods of wet-based glaciation. The Late Noachian and Early Hesperian ages of the ridge systems closely correspond to the ages of valley network/open basin lake systems, representing runoff, drainage and storage of liquid water in non-polar regions of the surface of Mars. Potential causes of such wet-based conditions in the DAF include: 1) top-down melting due to atmospheric warming, 2) enhanced snow and ice accumulation and raising of the melting isotherm to the base of the ice sheet, or 3) basal melting associated with intrusive volcanism (volcano-ice interactions). The early phase of melting is closely correlated in time with valley network formation and thus may be due to global atmospheric warming, while the later phase of melting may be linked to Early Hesperian global volcanism and specific volcano-ice interactions (table mountains) in the DAF. Crater ages indicate that these wet-based conditions ceased by the Late Hesperian, and that further retreat of the DAF to its present configuration occurred largely through sublimation, not melting, thus preserving the extensive ridge systems. MARSIS radar data suggest that significant areas of layered, potentially ice-rich parts of the Dorsa Argentea Formation remain today.

The climate history of early Mars: insights from the Antarctic McMurdo Dry Valleys hydrologic system

AbstractThe early climate of Mars (Noachian Period, the first ~20% of its history) is thought to differ significantly from that of its more recent history (Amazonian Period, the last ~66%) which is characterized by hyperarid, hypothermal conditions that result in mean annual air temperatures (MAAT) well below 0°C, a global cryosphere, minimal melting on the ground surface, and a horizontally stratified hydrologic system. We explore the nature of the fluvial and lacustrine environments in the Mars-like hyperarid, hypothermal McMurdo Dry Valleys (MDV), where the MAAT is well below 0°C (~ -14 to -30°C) in order to assess whether the Late Noachian geologic record can be explained by a climate characterized by “cold and icy” conditions. We find that the MDV hydrological system and cycle provide important insights into the potential configuration of a “cold and icy” early Mars climate in which MDV-like ephemeral streams and rivers, and both closed-basin and open-basin lakes could form. We review a series of MDV fluvial and lacustrine features to guide investigators in the analysis of the geomorphology of early Mars and we outline a new model for the nature and evolution of a “cold and icy” Late Noachian climate based on these observations. We conclude that a cold and icy Late Noachian Mars with MAAT below freezing, but peak seasonal and peak daily temperatures above 0°C, could plausibly account for the array of Noachian-aged fluvial and lacustrine features observed on Mars. Our assessment also provides insight into the potential effects of punctuated warming on a cold and icy early Mars, in which impact crater formation or massive volcanic eruptions cause temperatures in the melting range for decadal to centennial timescales. We outline a set of outstanding questions and tests concerning the nature and evolution of these features on Mars.

A progressive black top hat transformation algorithm for estimating valley volumes on Mars

The depth of valley incision and valley volume are important parameters in understanding the geologic history of early Mars, because they are related to the amount sediments eroded and the quantity of water needed to create the valley networks (VNs). With readily available digital elevation model (DEM) data, the Black Top Hat (BTH) transformation, an image processing technique for extracting dark features on a variable background, has been applied to DEM data to extract valley depth and estimate valley volume. Previous studies typically use a single window size for extracting the valley features and a single threshold value for removing noise, resulting in finer features such as tributaries not being extracted and underestimation of valley volume. Inspired by similar algorithms used in LiDAR data analysis to remove above-ground features to obtain bare-earth topography, here we propose a progressive BTH (PBTH) transformation algorithm, where the window size is progressively increased to extract valleys of different orders. In addition, a slope factor is introduced so that the noise threshold can be automatically adjusted for windows with different sizes. Independently derived VN lines were used to select mask polygons that spatially overlap the VN lines. Volume is calculated as the sum of valley depth within the selected mask multiplied by cell area. Application of the PBTH to a simulated landform (for which the amount of erosion is known) achieved an overall relative accuracy of 96%, in comparison with only 78% for BTH. Application of PBTH to Ma’adim Vallies on Mars not only produced total volume estimates consistent with previous studies, but also revealed the detailed spatial distribution of valley depth. The highly automated PBTH algorithm shows great promise for estimating the volume of VN on Mars on global scale, which is important for understanding its early hydrologic cycle.

Knobby terrain on ancient volcanoes as an indication of dominant early explosive volcanism on Mars

AbstractDetermining if the mechanically weak materials of the upper crust are products of early explosive volcanism or generated by modification of extensive effusive lava flows is important for understanding the geologic and thermal history of Mars. We examined 75 recently identified preserved ancient volcanoes, whose eruption styles are representative of early volcanism. We describe a unique knobby terrain that is associated with 17 of these volcanoes. This newly identified terrain is characterized by a combination of high‐resolution images and thermophysical and thermal infrared hyperspectral data. The morphology characteristics of these knobby terrains are similar to terrestrial eroded ignimbrites, and the thermophysical properties indicate that they are composed of unconsolidated fine‐grained materials. The spectral analysis indicates that they experienced some aqueous alteration. We explain the knobby terrain associated with these ancient volcanoes as the products of an early explosive volcanic phase in Martian history, followed by subsequent modification of these deposits.

Erosion rate and previous extent of interior layered deposits on Mars revealed by obstructed landslides

We describe interior layered deposits on Mars that have obstructed landslides before undergoing retreat by as much as 2 km. These landslides differ from typical Martian examples in that their toe height increases by as much as 500 m in a distinctive frontal scarp that mimics the shape of the layered deposits. By using crater statistics to constrain the formation ages of the individual landslides to between ca. 200 and 400 Ma, we conclude that the retreat of the interior layered deposits was rapid, requiring erosion rates of between 1200 and 2300 nm yr–1. We suggest that the interior layered deposits are either extremely friable, if eroded strictly by wind, or composed of a material whose degradation has been enhanced by ice sublimation. These erosion rates also confirm that the interior layered deposits have been in a state of net degradation over the past 400 m.y., suggesting that the process that caused net deposition in the past has ceased or slowed substantially on Mars relative to erosion. Our results imply that interior layered deposits with a similar morphology across Mars, including the mound in Gale Crater, have probably undergone similar rapid erosion and retreat, suggesting that their total modern volume underrepresents the depositional record and thus sedimentary history of Mars.

The Aeronomy of Mars: Characterization by MAVEN of the Upper Atmosphere Reservoir That Regulates Volatile Escape

The Mars thermosphere-ionosphere-exosphere (TIE) system constitutes the atmospheric reservoir (i.e. available cold and hot planetary neutral and thermal ion species) that regulates present day escape processes from the planet. The characterization of this TIE system, including its spatial and temporal (e.g., solar cycle, seasonal, diurnal, episodic) variability is needed to determine present day escape rates. Without knowledge of the physics and chemistry creating this TIE region and driving its variations, it is not possible to constrain either the short term or long term histories of atmosphere escape from Mars. MAVEN (Mars Atmosphere and Volatile Evolution Mission) will make both in-situ and remote measurements of the state variables of the Martian TIE system. A full characterization of the thermosphere (∼100–250 km) and ionosphere (∼100–400 km) structure (and its variability) will be conducted with the collection of spacecraft in-situ measurements that systematically span most local times and latitudes, over a regular sampling of Mars seasons, and throughout the bottom half of the solar cycle. Such sampling will far surpass that available from existing spacecraft and ground-based datasets. In addition, remote measurements will provide a systematic mapping of the composition and structure of Mars neutral upper atmosphere and coronae (e.g. H, C, N, O), as well as probe lower altitudes. Such a detailed characterization is a necessary first step toward answering MAVEN’s three main science questions (see Jakosky et al. 2014, this issue). This information will be used to determine present day escape rates from Mars, and provide an estimate of integrated loss to space throughout Mars history.

Thermal expansion of monoclinic natrojarosite

Jarosites and related minerals are of great interest to a range of mineral processing and research applications. In some industrial settings jarosite formation is encouraged; for example to aid the removal of iron species from solutions in hydrometallurgical processes. In other environments such as bioleaching, jarosite formation can hinder the process by creating a kinetic barrier, in the form of a passivation layer, to the desired reaction. Jarosites are a major component of acidic soils and are present in significant amounts in acid mine drainage environments. There has been a recent resurgence in interest in jarosite minerals since their detection on Mars by the MER rover Opportunity. In this context, the presence of jarosite has been recognised as a likely indicator of the presence of water on Mars in the past. It is hoped that study of their formation mechanisms, stability and thermoelastic properties will provide insight into the environmental history of Mars as well as informing terrestrial industrial concerns. To this end we are engaged in a program to study jarosites and their formation and stability behaviour over a range of conditions. This contribution describes in situ powder diffraction experiments to determine the thermal expansion of a deuterated natrojarosite. Data were collected on the HRPD beamline at the ISIS spallation source where the natrojarosite sample was heated from 10–700K, and at the powder diffraction beamline at the Australian synchrotron where the sample was heated from 80-700K. Isothermal neutron and synchrotron datasets were refined simultaneously. Analysis of the lattice parameter variation with temperature shows that all cell edges increase smoothly to ~500 K where there is a discontinuity. This discontinuity represents the initially non-stoichiometric monoclinic jarosite converting to a stoichiometric, rhombohedral phase, shortly after which FeOHSO4 peaks become visible. Thermal expansion coefficients have been fitted from 10-470K and show that there is most variation in the monoclinic c-axis. This direction is normal to the layers of sulphate tetrahedra and iron octahedra within the jarosite structure and contains more flexible hydrogen bond linkages which more easily accommodate expansion than the more rigid polyhedra. Details of the combined neutron-synchrotron diffraction approach will also be discussed.

Timescales of fluvial activity and intermittency in Milna Crater, Mars

Milna Crater, Mars (23.4S, 12.3W) exhibits signs of fluvial modification early in Mars history, including a large multi-lobed fan deposit cut by several sinuous valleys. We describe the past hydrologic conditions in Milna and the surrounding area, including a potential lake with a volume of 50km3. We also introduce new methods (i) to calculate the timescale of sediment deposition by considering fluvial sediment input into the entire crater while accounting for non-fluvial input, and (ii) to place improved constraints on the channel dimensions through which sediment was delivered to Milna by comparing to the dimensions of inner channels found in valleys in the region surrounding Milna. By calculating the flux of fluid and sediment into the crater, we find that the crater cavity was flooded for at least months and that the time of active fluvial sediment transport without hiatus is on the order of decades to centuries, with a preferred timescale of centuries. We also calculate the total amount of water required to transport the volume of sediment we measure in Milna and conclude that impacts alone are likely insufficient to deliver enough water to Milna to allow the sedimentary fill we see.Combining the timescales of fluvial activity in the adjacent Paraná Valles with estimates for global Noachian erosion rates, we calculate an intermittency factor for fluvial activity of ∼0.01–0.1% during 105–106yr near the Noachian–Hesperian boundary in the Paraná Valles region. These values are comparable to arid climates on Earth where the majority of fluvial sedimentary transport takes place during floods with multi-year to decadal recurrence intervals. Our calculations of intermittency help to quantitatively reconcile the divergent estimates of the short and long timescales of fluvial activity on Mars reported in the literature.

Mineralogy of the Martian Surface

The past fifteen years of orbital infrared spectroscopy and in situ exploration have led to a new understanding of the composition and history of Mars. Globally, Mars has a basaltic upper crust with regionally variable quantities of plagioclase, pyroxene, and olivine associated with distinctive terrains. Enrichments in olivine (&gt;20%) are found around the largest basins and within late Noachian–early Hesperian lavas. Alkali volcanics are also locally present, pointing to regional differences in igneous processes. Many materials from ancient Mars bear the mineralogic fingerprints of interaction with water. Clay minerals, found in exposures of Noachian crust across the globe, preserve widespread evidence for early weathering, hydrothermal, and diagenetic aqueous environments. Noachian and Hesperian sediments include paleolake deposits with clays, carbonates, sulfates, and chlorides that are more localized in extent. The late Hesperian to Amazonian mineralogic record of water is sparser, though sulfates and silica in some locations indicate local availability of ground and surface waters even in the most recent geologic epoch.

Long-term monitoring of martian gully formation and evolution with MRO/HiRISE

Gully landforms are commonly taken as evidence for surface liquid water in the recent geological history of Mars. Repeat observations with the High Resolution Imaging Science Experiment (HiRISE) instrument on the Mars Reconnaissance Orbiter demonstrate widespread activity in gullies in the southern hemisphere, particularly in those with the freshest morphologies. This activity includes substantial channel incision and large-scale mass movements, and constitutes ongoing gully formation rather than degradation of older landforms. New apron deposits that are bright, dark and neutrally toned have all been observed. The timing of gully activity is seasonally controlled and occurs during the period when seasonal frost is present and defrosting. These observations support a model in which currently active gully formation is driven mainly by seasonal CO2 frost. Gullies in the northern hemisphere are far less active than those in the south. This may be due to the current timing of perihelion near the northern winter solstice. Integrated over time, activity like that observed within the past few years appears capable of forming all of the martian gully landforms on timescales of millions of years. Additionally, the current style and rate of activity is able to erase meter- to decameter-scale surface features that might have been uniquely produced by other processes during the last obliquity high ∼0.4Ma. Although it is impossible to rule out a past role for water in the formation of martian gullies, a model in which gullies form only through currently active processes with little or no liquid water is consistent with our observations.