High-voltage Electrode Research Articles

Time-resolved characteristics of a nanosecond pulsed multi-hollow needle plate packed bed dielectric barrier discharge

In this paper, self-designed multi-hollow needle electrodes are used as a high-voltage electrode in a packed bed dielectric barrier discharge reactor to facilitate fast gas flow through the active discharge area and achieve large-volume stable discharge. The dynamic characteristics of the plasma, the generated active species, and the energy transfer mechanisms in both positive discharge (PD) and negative discharge (ND) are investigated by using fast-exposure intensified charge coupled device (ICCD) images and time-resolved optical emission spectra. The experimental results show that the discharge intensity, number of discharge channels, and discharge volume are obviously enhanced when the multi-needle electrode is replaced by a multi-hollow needle electrode. During a single voltage pulse period, PD mainly develops in a streamer mode, which results in a stronger discharge current, luminous intensity, and E/N compared with the diffuse mode observed in ND. In PD, as the gap between dielectric beads changes from 0 to 250 μm, the discharge between the dielectric bead gap changes from a partial discharge to a standing filamentary micro-discharge, which allows the plasma to leave the local area and is conducive to the propagation of surface streamers. In ND, the discharge only appears as a diffusion-like mode between the gap of dielectric beads, regardless of whether there is a discharge gap. Moreover, the generation of excited states and is mainly observed in PD, which is attributed to the higher E/N in PD than that in ND. However, the generation of the radical in ND is higher than in PD. It is not directly dominated by E/N, but mainly by the resonant energy transfer process between metastable and . Furthermore, both PD and ND demonstrate obvious energy relaxation processes of electron-to-vibration and vibration-to-vibration, and no vibration-to-rotation energy relaxation process is observed.

Mechanism of lightning damage to glass fiber composite wind turbine blades

Wind turbine blades (WTBs) are susceptible to lightning damage, resulting in significant costs for repair and replacement, which poses a considerable economic burden on wind farms. Therefore, this study investigates the mechanism of lightning damage of glass fiber composite (GFC)-WTBs to reduce the risk of such damage. The damage of GFC-WTBs caused by lightning strikes was analyzed using a numerical simulation method. The lightning pilot was simulated using high-voltage rod electrodes, and subsequently, the electric field strength and damage area on the blade surface under different conditions were measured. Additionally, a simulation model based on finite element analysis was developed to further predict and validate the experimental findings. The results reveal that the maximum electric field intensity was observed in the blade tip. Notably, the electric field intensity was found to be over 798,000 V/m when the rod electrode was positioned at a 0-degree angle with the blade tip. Further investigation revealed a non-linear and positive correlation between the damage area of GFC and lightning current amplitude, charge, and specific energy. In conclusion, the study provides a comprehensive examination of the relationship between lightning current and the damage to GFC-WTBs, as well as elucidates the mechanism of lightning damage to GFC-WTBs.

Ammonia nitrogen removal from coal gasification wastewater using a falling-film dielectric barrier discharge reactor: Process optimization and toxicity analysis

The continuous use of coal gasification technology for green energy generation to supplement the dwindling energy reserves generates significant amounts of wastewater containing ammonia nitrogen, posing a significant risk to the finite drinking water sources and aquatic lives. Herein, two falling-film dielectric barrier discharge (DBD) reactors with copper and titanium high-voltage electrodes, respectively, were designed to remove ammonia nitrogen (NH3−N) and chemical oxygen demand (COD) simultaneously from coal gasification wastewater. The operational parameters were screened using the Plackett-Burman design, and the significant parameters were further optimized via the response surface methodology. The results showed that the power parameter significantly influenced NH3-N removal, and COD removal was influenced considerably by power and treatment time. Under the optimum conditions (treatment time = 20.32 min, pH = 3, airflow rate = 1 L/min, power = 116 W, and recirculating flow rate = 50.02 mL/min), a removal ratio of 62.33 % and 37.35 % was achieved for NH3-N and COD for the reactor with the copper electrode, and 67.66 % and 44.90 % for NH3-N, and COD for the reactor with the titanium electrode. Additionally, the concentrations of O3, ·OH, and H2O2 produced by the reactors were quantified, and their crucial roles in the removal process of NH3-N were evaluated. Although smaller concentrations of NO2− and NO3− were detected in the treated wastewater, over 97 % of N2 selectivity encompassed NH3-N removal. Finally, acute phytotoxicity tests were performed, and the results indicated that at 100 mL/L dosage, the treated wastewater from both reactors did not restrict Barbarea verna growth.

Three-Dimensional Transient Electric Field Characteristics of High Pressure Electrode Boilers

An uneven electric field during the operation of an electrode boiler will lead to the emergence of a high field strength area and low field strength area in the furnace, which will endanger the safe and reliable operation and heating efficiency of the electrode boiler. A numerical study of three-dimensional transient electric field distribution characteristics in a 10 kV high-voltage electrode boiler was carried out. The distribution characteristics of the global electric field of the electrode boiler under the nominal voltage of 10 kV were studied, and the distribution law of the electric field of the electrode boiler under poor power quality, such as different bus voltage and three-phase voltage imbalance, was explored. The results show that the electric field distribution characteristics of the three-phase transient are more obvious in the section closer to the electrode disc, and the electric field distribution is the most uniform in the section that is 1.4 m away from the furnace water. In the case of poor power quality, such as different bus voltage and three-phase voltage imbalance, the points of the maximum electric field intensity of the four surfaces change periodically with time, and the greater the bus voltage fluctuation, the more severe the impact on the transient electric field. The three-phase voltage imbalance will shift the peak value of the electric field intensity. The decrease or offset of electric field intensity in the electrode boiler caused by poor power quality will directly affect its heating efficiency. The electric field simulation results have a specific reference value for improving the internal electric field distribution and on-site operation and maintenance of the electrode boiler.

Attachment of Fibrinogen on Ion Beam Treated Polyurethane.

Protein-stable coverage of the artificial implant is a key problem for biocompatibility. In the present study, a protein layer was attached covalently to a polyurethane surface treated by an ion beam. A plasma system consisting of a vacuum chamber (0.8 Pa pressure) with a high voltage electrode powered by a short pulse (20 μS pulse duration and 200 Hz pulse repetition) generator was designed. Polyurethane with a formulation certified as a material for medical implants was treated by nitrogen ions with an energy of 20 keV and 5 × 1014-1016 ions/cm2 fluence range. Wettability measurements, X-ray photoelectron, Raman, Fourier transform infrared attenuated total reflection, and ellipsometry spectra showed a significant change in the structure of the surface layer of the treated polyurethane. The surface of the treated polyurethane contained a carbonised layer containing condensed aromatic clusters with terminal free radicals. The surface energy of polyurethane surface increased from 33 to 65 mJ/m2. The treated polyurethane surface became capable of adsorbing and chemically binding protein (fibrinogen). The designed system for ion beam treatment can be used for surface activation of biomedical polymer devices, where a total protein coverage is required.

Scaled experiment and observation of the lightning discharge process of rotating wind turbines under different shapes of high-voltage electrodes in the laboratory

In this study, a discharge test for scaled wind turbine is performed to examine the lightning discharge characteristics of rotating wind turbines, and an observation platform is designed. Moreover, the wind turbines are subjected to discharge simulation with rod and arc electrodes, and high-speed and single-lens reflex cameras are used to observe the physical discharge process. Under the rod electrode, the downward leader is initiated first, and its length occupies a larger proportion of the discharge gap. The discharge contains multiple stepped leaders. When the gap distance is less than 4 m, the probability of occurrence of negative stepped leaders may be smaller. As the gap distance increases, the number of stepped leaders increases significantly. Under the arc electrode, the upward leader is initiated first, and its length accounts for a larger proportion of the discharge gap. With the rotation of the wind turbine, the upward leader is initiated earlier and the length is longer. Furthermore, the speed of its development does not differ significantly. The discharge simulation process under the arc electrode is similar to natural lightning strikes on wind turbines.

Examining Performance Loss Mechanisms in Lithium-Ion Batteries with the High-Voltage Mn-Rich Spinel Positive Electrodes

The high-voltage spinel, with the nominal composition of LiNi0.5-xMn1.5+xO4 (LNMO), could be a sustainable alternative to the layered-oxide positive electrodes used in lithium-ion batteries. However, commercial acceptance has been limited as LNMO cells display rapid performance loss during cycling. To examine reasons for this loss we prepared cells with LNMO-based positive and either graphite or lithium titanate (LTO) based negative electrodes. Our initial cells displayed high impedance and rapid impedance rise during cycling. Adding single walled carbon nanotubes in the positive lowered initial cell impedance but impedance increased during cycling because of coating delamination from the Al foil. Using a primed Al current collector solved the delamination problem: cells with this current collector showed only a small impedance rise. Regarding capacity, cells with the LTO negative showed higher initial capacities and smaller fade. Our data indicate that cell capacity retention is determined by reduction reactions at the negative electrode that lower capacity and oxidation reactions at the positive electrode that increase capacity: both types of reactions deplete the cell electrolyte during extended cycling. All things considered, species generated at high voltages, either in the electrolyte or at the LNMO electrode, drive cell capacity fade.

Plasma characteristics and de-icing of three-electrode double-sided pulsed surface dielectric barrier discharge

Ice accumulation on aircraft can lead to aerodynamic performance degradation and even trigger security incidents. However, traditional surface dielectric barrier discharge (SDBD) reactors cannot work while covered by glaze ice. In the present work, a novel three-electrode double-sided SDBD is proposed and employed for glaze ice deicing. Compared with traditional SDBD reactor, three-electrode double-sided SDBD introduces an additional discharge area and grounding electrode. On one hand, the heat generated in the additional discharge area can melt the glaze ice covered on the high-voltage electrode, providing a discharge gap for the subsequent discharge. On the other hand, the introduction of the additional grounding electrode can also dramatically enhance the upper discharge and thermal effect. As a result, compared with the three-electrode single-sided SDBD and two-electrode double-sided SDBD, the three-electrode double-sided SDBD has the highest deposited energy, maximal temperature, and deicing rate. To further optimize the structural design, the effect of air gap length below the dielectric on three-electrode double-sided SDBD is investigated. And it is found that the best deicing performance can be obtained at the air gap length of 1 mm.

Miniaturized flexible micro-tube plasma ionization source for the effective ionization of non-easily ionizable pesticides in food with liquid chromatography/mass spectrometry

In this article, we have studied the potential of flexible microtube plasma (FμTP) as ionization source for the liquid chromatography high-resolution mass spectrometry detection of non-easily ionizable pesticides (viz. nonpolar and non-ionizable by acid/basic moieties). Phthalimide-related compounds such as dicofol, dinocap, o-phenylphenol, captan, captafol, folpet and their metabolites were studied. Dielectric barrier discharge ionization (DBDI) was examined using two electrode configurations, including the miniaturized one based on a single high-voltage (HV) electrode and a virtual ground electrode configuration (FμTP), and also the two-ring electrode DBDI configuration. Different ionization pathways were observed to ionize these challenging, non-easily ionizable nonpolar compounds, involving nucleophilic substitutions and proton abstraction, with subtle differences in the spectra obtained compared with APCI. An average sensitivity increase of 5-fold was attained compared with the standard APCI source. In addition, more tolerance with matrix effects was observed in both DBDI sources. The importance of the data reported is not just limited to the sensitivity enhancement compared to APCI, but, more notably, to the ability to effectively ionize nonpolar, late-eluting (in reverse-phase chromatography) non-ionizable compounds. Besides o-phenylphenol ([M − H]-), all the parent species were efficiently ionized through different mechanisms involving bond cleavages through the effect of plasma reagent species or its combination with thermal degradation and subsequent ionization. This tool can be used to figure out overlooked nonpolar compounds in different environmental samples of societal interest through non-target screening (NTS) strategies.

Development of High-Voltage Electrodes for Neutron Scattering Sample Environment Devices

The sample environment is essential to neutron scattering experiments as it induces the sample under study into a phase or state of particular interest. Various sample environments have been developed, yet the high-voltage electric field has rarely been documented. In this study, Bruce electrodes with various sectional geometries and chamber sizes were examined by using simulation modeling based on ANSYS Maxwell. A large uniform field region where samples would sit could be achieved in the planar region for all specifications, but the size of the region and the field strength varied with the gap distance between electrodes. The edging effect was inherently observed even for bare electrodes, about 1.7% higher in the sinusoidal region than the planar region, and was significantly deteriorated when a chamber was applied. This effect, however, presented an exponential decrease as the minimum distance between the electrode edge and the chamber shell increased. A compromise between the spatial confinement and the achievable field (strength and uniform region) could be reached according to the unique applicability of neutron instruments. This research provides a theoretical basis for the subsequent design and manufacturing of high-voltage sample environment devices.

Research on the Effects of an Electrode Drill Bit during the Rock Drilling Process by High-Voltage Electric Pulse

Summary High-voltage electric pulse rock-breaking (HVEPB) has proved to be a novel and inexpensive method of breaking rock regardless of rock composition, but the design of the electrode drill bit lacks a theoretical basis. In this paper, we first establish a plasma channel model for electric breakdown and a numerical rock-breaking model for HVEPB, which can simulate the rock electrical breakdown plasma channel and the effect of different electrode drill bits on HVEPB. Second, we analyze the effects of different electrode arrangement structures and high-voltage electrode angles on plasma channels and the effects of internal cracks and rock-breaking processes through numerical simulation. Finally, we describe HVEPB experiments conducted using electrode drill bits with different electrode arrangement structures and high-voltage electrode angles, and with the boreholes reconstructed in three dimensions to analyze the effects of different electrode arrangement structures and high-voltage electrode angles on HVEPB drilling. The results show that the effects of the electrode drill bits on HVEPB are reflected mainly in the difference between the plasma channel and shock wave. Different electrode arrangement structures and high-voltage electrode angles result in different electric fields and energy utilization efficiencies within the rock, resulting in different shock waves and differences in the depth, shapes, and penetration of the plasma channels. The simulations and experimental studies in this paper can guide and optimize the design of the discharge tool to upgrade the drilling efficiency of HVEPB.

Customizing polymeric binders for advanced lithium batteries: Design principles and beyond

As society strides toward a sustainable future powered by lithium-ion batteries, the integral role of polymeric binders becomes increasingly evident. Historically serving as a film former and chemical adhesive that amalgamates the active host materials and conductive carbon in battery electrodes, their role has been redefined with the advent of innovative battery systems and host materials. These emerging technologies pose unique challenges, propelling the shift toward “customizable” binder designs. Polymeric binders should now ensure structural robustness, especially for high-capacity host materials, by leveraging varied intermolecular interactions to counteract internal stresses. Additionally, incorporating high-voltage electrode materials or electrolytes demands binders with an expansive electrochemical stability window. The interface energy control of binders is also critical, especially when incorporating dissolving cathodes or transitioning to solid-state electrolytes. This review provides a comprehensive understanding, breaking down the design principles of polymeric binders into three distinct paradigms: (1) structural design for high-capacity anodes, (2) electrochemical design for high-voltage cathodes or electrolytes, and (3) interfacial design for dissolving cathodes and solid-state batteries. Our discourse offers both a reflection on the evolving multifunctional nature of binders and a roadmap for future endeavors in the binder design for advanced lithium battery chemistries.

Impact of synergistic interfacial modification on the electrochemical performance of LiNi0.5Mn1.5O4 cathode materials

Developing sophisticated lithium-ion batteries with high energy and power density requires using high-voltage positive electrodes. Due to its three-dimensional lithium-ion diffusion and greater nominal operating voltage, spinel LiNi0.5Mn1.5O4 has emerged as one of lithium-ion batteries' most viable cathode materials. Electrolyte breakdown, Mn dissolution, and rapid cathode-electrolyte interface (CEI) degradation in lithium-ion cells are exacerbated by the high operating voltage of LNMO. Consequently, the long-term cycling of LNMO is hampered by such adverse side effects, making the commercialization of such a battery impractical. Here, we document the enhancement in the electrochemical performance of LNMO by surface modification utilizing a combination of Al2O3 coating and Graphene enveloping employing a facile wet synthesis technique. The presence of highly crystalline spherical secondary microspheres consisting of primary nanoparticles of disordered LiNi0.5Mn1.5O4, the surface modification with Al2O3, and the subsequent graphene wrapping were all confirmed by structural and surface analysis techniques. The fabricated cells containing the enhanced cathode material (LNMO-Al-GO) were cycled at a C/10 rate for 100 cycles in a voltage window of 3.5–4.9 V, providing a specific discharge capacity of 134.7 ± 3.8 mAhg−1. Delivering a capacity retention of 97.7 ± 3.9% compared to the unmodified LNMO sample (84.7 ± 5.3%). Ex-situ XRD, Electrochemical Impedance Spectroscopy (EIS), and Differential Scanning Calorimetry (DSC) investigations reveal that the alumina coating protects the cathode by acting as a hydrogen fluoride (H.F.) scavenger and minimizes unfavorable phase formations at the CEI, inhibiting Mn3+ dissolution and enhancing cyclability.

Atmospheric pressure argon plasma jets I – Measurements of spatial distribution for visible emission spectrum and vacuum ultraviolet

AbstractThis paper describes the observed position dependent emission spectrum and vacuum ultraviolet (VUV) to clarify the optical structure of argon atmospheric pressure plasma jets (APJs). Visible emission spectra of argon, nitrogen, and OH molecules were measured as a function of position from the nozzle of plasma jet generator to gas flow direction. From the results, we realized that a certain electric field is required for producing high energy excited atoms of argon in the jet from the high voltage electrode in the device to the ground positioned at downstream side. Moreover, VUV was detected along the plasma jet through the downstream direction. Thus, we could picture that the light pattern of plasma jet of which intensity weaken depend to the distance from the nozzle is sustained by the above two factors with the present steady state experiments.

Particle removal performance of a novel ESP type air cleaning system for indoor air quality in a subway station

A novel electrostatic precipitation type air cleaning technology with near zero ozone emission for indoor air quality of a subway station was developed. To minimize ozone emission and achieve high particle removal performance against ultrafine particulate matters (PMs), a multi-channel charging method using soft ionization by micrometre carbon fibers and a narrow gap collection method using high electric field by thin conductive plastic sheets as a high voltage electrode were used. In this study, the novel electrostatic charging and collection technologies were applied to a real scale air cleaning system in an Air Handling Unit (AHU) with air flow rate of 950 m3/min in Yuseong Oncheon subway station with an area of 3000 m2 in Daejeon, South Korea. The particle removal performance of the demonstration system was evaluated with real suspended particles in the subway station during test period with high PM concentrations in Korea over 40 μg/m3. Particle collection efficiency, pressure drop and ozone emission were evaluated, and compared to those of the a minimum efficiency reporting value (MERV) 10 and 14 filters used in the typical subway stations in Korea. In the field researches, the developed ESP achieved over 80% of the PM collection efficiency higher than those of the filters with MERV-10 and -14, and even 10% higher efficiency against PM1.0, while generating only 10% of pressure drop and also emitting nearly zero ozone. It is concluded that a novel ESP type air cleaning system with near zero ozone emission could be a promising air cleaning method for a large indoor environment such as a subway station where polluted air with ultrafine particles flowed in with a very high flow rate.

A dielectric barrier discharge based low pressure narrow band far UV-C 222 nm excimer lamp and its efficiency analysis

Far UV-C light at wavelength 222 nm is gaining popularity nowadays due to its properties that it cannot penetrate even the outer dead skin of humans and the tear layer of the eyes. This wavelength has been proven to be much safer for human health. In this paper, a dielectric barrier discharge (DBD) based Far UV-C excimer lamp with a very narrow and intense spectrum peaking at a wavelength of 222 nm has been reported. Optimization of high voltage electrodes has been carried out to minimize the lamp heating without using any external cooling. The discharge produced in this configuration is diffused discharge at a low pressure of 140 mbar. Generally, at low pressure, a very wide band of spectra having full-width half maxima (FWHM) of 8–15 nm is obtained. In this case, due to the confined gas gap and bi-polar pulse power arrangements, the spectra obtained are very narrow, having an FWHM of 1.7 nm. Applied voltage, frequency and gas pressure are optimized to get high electrical-to-optical conversion efficiency of the lamp. The measured radiated intensity at the applied input electrical power of 31 W from the optimized lamp is ∼2.5 mW cm−2, which results in the electrical to optical conversion efficiency as high as 12.5%. The bacterial efficiency of the developed lamp is also examined on pathogenic gram-positive (S. aureus) and gram-negative (E. coli) bacteria. Complete inactivation of S. aureus and E. coli has been achieved at a UV dose of 3 mJ/cm2 and 12 mJ cm–2, respectively. Morphological studies of treated bacteria have also been performed to correlate the results.

Characteristics of annular surface dielectric barrier discharge with microsecond pulse under water-covered condition.

Surface dielectric barrier discharge (SDBD) has wide applications in flow control, wastewater treatment, and biomedicine. The dielectric surface of an SDBD actuator is generally attached to the water droplets during applications. Thus far, only a few studies have been conducted on the effects of water covering the dielectric surface on the discharge characteristics of SDBD. Therefore, the effects of water droplets on the discharge of an SDBD actuator based on a repetitive microsecond pulse power supply were investigated in this study. The results show that a filament micro-discharge channel forms between the light and dark regions at the internal edge of the SDBD high-voltage electrode and develops toward the center of the dielectric surface in the region without water droplet coverage. SDBD in the water-covered region was divided into two stages. This paper compares the electrical characteristics of SDBD with and without water droplet, and explores the electric field distortion effect of water droplet endpoints through 3D simulation.Based on the theories of water droplet polarization and gas discharge, the effects of water droplets on plasma development and surface charge accumulation under water-covered condition were analyzed. The water droplet plays a similar role as a "secondary electrode" during the discharge process.

Gradient pulsed transient plasma for initiation of detonation

The formation of a gradient of atomic oxygen is demonstrated by means of a nanosecond non-equilibrium plasma for a varying gap size plane-to-plane electrode. Using a flat high-voltage electrode in front of a rounded triangle a 2.9 to 5 cm gap is formed over a 9.8 cm span. ICCD imaging determined an adequate ground electrode shape and slope to create a gradient. The plasma is formed by three consecutive high voltage pulses of -30, -40 and -50 kV in 100 mbar of air. O-TALIF measurements confirm that atomic oxygen production changed with gap size within the same plasma. This setup will be used to test detonation initiation by Zel’dovich gradient mechanisms in stoichiometric H2:O2 mixtures.Novelty and Significance: A novel configuration of a nanosecond non-equilibrium discharge was developed to create a controllable gradient of atomic oxygen. This was achieved by using varying gap plane-to-plane electrodes to generate an electric field of varying strength along the length of the gap. This setup will be tested in combustible mixtures to initiate a detonation wave using a gradient mechanism of Zel’dovich.

Towards the 4 V-class n-type organic lithium-ion positive electrode materials: the case of conjugated triflimides and cyanamides.

Organic electrode materials have garnered a great deal of interest owing to their sustainability, cost-efficiency, and design flexibility metrics. Despite numerous endeavors to fine-tune their redox potential, the pool of organic positive electrode materials with a redox potential above 3 V versus Li+/Li0, and maintaining air stability in the Li-reservoir configuration remains limited. This study expands the chemical landscape of organic Li-ion positive electrode chemistries towards the 4 V-class through molecular design based on electron density depletion within the redox center via the mesomeric effect of electron-withdrawing groups (EWGs). This results in the development of novel families of conjugated triflimides and cyanamides as high-voltage electrode materials for organic lithium-ion batteries. These are found to exhibit ambient air stability and demonstrate reversible electrochemistry with redox potentials spanning the range of 3.1 V to 3.8 V (versus Li+/Li0), marking the highest reported values so far within the realm of n-type organic chemistries. Through comprehensive structural analysis and extensive electrochemical studies, we elucidate the relationship between the molecular structure and the ability to fine-tune the redox potential. These findings offer promising opportunities to customize the redox properties of organic electrodes, bridging the gap with their inorganic counterparts for application in sustainable and eco-friendly electrochemical energy storage devices.

An Overview on Polymer-Based Electrolytes with High Ionic Mobility for Safe Operation of Solid-State Batteries

Liquid electrolytes used in commercial Li-ion batteries are generally based on toxic volatile and flammable organic carbonate solvents, thus raising safety concerns in case of thermal runaway. The most striking solution at present is to switch on all solid-state designs exploiting polymer materials, films, ceramics, low-volatile, green additives, etc. The replacement of liquids component with low-flammable solids is expected to improve the safety level of the device intrinsically. Moreover, a solid-state configuration is expected to guarantee improved energy density systems. However, low ionic conductivity, low cation transport properties and issues in cell manufacturing processes must be overcome [1].Electrochemical performance in lab-scale devices can be readily improved using different RTILs or specific low-volatile additives. Here, an overview is offered of the recent developments in our labs on innovative polymer-based electrolytes allowing high ionic mobility, particularly attractive for safe, high-performing, solid-state Li-metal batteries, and obtained by different techniques, including solvent-free UV-induced photopolymerization. Cyclic voltammetry and galvanostatic charge/discharge cycling coupled with electrochemical impedance spectroscopy exploiting different electrode materials (e.g., LFP, Li-rich NMC, LNMO, Si/C) demonstrate specific capacities approaching theoretical values even at high C-rates and stable operation for hundreds of cycles at ambient temperature [2,3]. Direct polymerization procedures on top of the electrode films are also used to obtain an intimate electrode/electrolyte interface and full active material utilization in both half and full-cell architectures. In addition, results of composite hybrid polymer electrolytes [4] and new single-ion conducting polymers [5] are shown, specifically developed to attain improved ion transport and high oxidation stability for safe operation with high voltage electrodes even at ambient conditions.