To meet the thermal protection and load-bearing requirements of ultra-high-speed vehicles, it is urgent to improve the ablation resistance, high-temperature oxidation resistance and mechanical properties of carbon fiber/ boron phenolic resin (CF/BPR) composites simultaneously. Herein, polyhedral oligomeric silsesquioxane-modified attapulgite (ASP) with abundant porous structure was successfully introduced into the CF/BPR (CF/ASPBPR). The co-effect of ceramization, high infrared emissivity, and low thermal conductivity endowed the CF/ASPBPR with desirable ablation resistance, where the linear ablation rate and mass ablation rate reduced to 0.038 mm/s and 0.035 g/s, respectively. Meanwhile, due to the high thermal stability and energy dissipation of ASP, the CF/ASPBPR also presented the interlaminar shear strength of 35.40 and 9.79 MPa before and after high-temperature treatment, which were 24 % and 63 % higher than that of CF/BPR, respectively. This study provides a promising pathway for preparing advanced thermal protection materials that can adapt to severe mechanical spalling and thermochemical erosion environments.
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