High-temperature Materials Research Articles

Experimental determination and thermodynamic optimization of Nb-Al-Y ternary system

Niobium-aluminide-based alloys show excellent application potential as high-temperature structural materials. In the present work, the isothermal sections of the Nb-Al-Y system at 800 and 1050°C are constructed based on X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), and transmission electron microscopy (TEM). Two new ternary compounds, designated as τ-phase (Nb8Al80Y12) and ρ-phase (Nb26Al58Y16), are identified and their homogeneity ranges and crystal structures have been described. The ρ-phase can exist at temperatures within the isothermal sections of 800 and 1050°C, while the τ-phase exists at 800°C and disappears as the temperature rises to 1050°C. In addition, the primary solidification phases were also identified, and five different primary solidification phases were found. Based on the experimental data, the thermodynamic optimization of the Nb-Al-Y ternary system is carried out using the thermo-calc method. The calculated results are in good agreement with the experimental results, and a set of reasonable and self-consistent thermodynamic parameters is obtained. The results provide a basis for the design of Nb-Al-Y-based alloys and enrich the database of Nb-based alloys.

Preparation of porous β-Si3N4/Si5AlON7 composite ceramics for digital light processing and study of mechanical and dielectric properties

Porous β-Si3N4/Si5AlON7 composite ceramics are anticipated to serve as high-temperature wave-transparent materials, yet the fabrication of high-performance porous β-Si3N4/Si5AlON7 composite ceramics remains a significant challenge. Addressing this issue, this study introduces a technique for crafting high-performance porous β-Si3N4/Si5AlON7 composite ceramics. This method involves the homogeneous blending of SiO2 and Si3N4 powders, followed by digital light processing and high-temperature liquid-phase sintering at 2000 °C. The impact of SiO2 content on various properties of the ceramic slurry and the resultant ceramics was thoroughly examined, including rheology, curing depth, microstructural morphology, phase composition, flexural strength, hardness, dielectric constant, and dielectric loss. It was observed that a SiO2 content of 30 % enables the slurry to fulfill the criteria for digital light processing, leading to the production of porous β-Si3N4/Si5AlON7 composite ceramics that exhibit outstanding mechanical and dielectric properties. Specifically, these ceramics demonstrated a flexural strength of 149.2 ± 7.2 MPa and a hardness of 11.8 ± 1.1 GPa. Moreover, at a frequency of 10 GHz, the ceramics exhibited a dielectric constant of 4.02 and a dielectric loss of 0.11, highlighting their potential as high-temperature wave-transparent materials.

Utilization of doping and compositing strategy for enhancing the thermoelectric performance of CaMnO3 perovskite

The performance of high-temperature thermoelectric material CaMnO3 is primarily limited by its high electrical resistivity and thermal conductivity. In this study, we synergistically optimized its electrical and thermal transport properties by employing a combination of doping and compositing strategies. The results suggest that Yb doping promotes the transfer of electrons to the Mn d orbital and facilitates the double exchange interactions between neighbor Mn3+ and Mn4+, leading to decreased electrical resistivity and a transition of electron transport mechanism from semiconductor to metal. The further addition of CoAl2O4 nanoparticles improves the Seebeck coefficient by reducing carrier concentration and increasing electron scattering, ultimately enhancing the power factor. Meanwhile, the fluctuations in atomic mass and increased interface density strengthen the interface phonon scattering, which results in a significant reduction in lattice thermal conductivity. As a result, the Ca0.95Yb0.05MnO3 with 2 wt% CoAl2O4 nanoparticles exhibits a maximum ZT value of 0.12 at 850 K, representing a 180 % improvement compared to the pristine material. This study highlights the effectiveness of the combined doping and compositing strategy in enhancing the thermoelectric performance of CaMnO3 materials and offers a promising approach for optimizing other oxide thermoelectric materials.

PRODUCTION OF COMPOSITE CARBON ADSORBENTS BASED ON TEXTILE CORD OBTAINED FROM CAR TIRE RESIDUES

Carbon chemistry opens up very wide prospects in obtaining compositions based on carbon-containing raw materials, due to the achievements of recent years in this field. Due to their unique properties, extremely high chemical resistance, thermal resistance, heat resistance and specific strength, carbon materials have found application for the manufacture of carbon-containing refractory, high-temperature composite materials, modified electrodes as fillers for the tire and rubber industry, catalytic systems based on carbon-containing raw materials, etc. Frequently used carbon materials do not meet the requirements of the technological process, in some cases their use is economically unjustified, since they are expensive and have a small raw material base. Therefore, obtaining new efficient and cheap natural carbon materials from available types of industrial raw materials is one of the urgent tasks currently facing scientists and technologists. Textile wire, a product of processing rubber organic waste, can become a promising new raw material for the production of carbon-containing materials. Porous carbon materials were obtained in a laboratory installation, optimal parameters were determined, and the physico-chemical properties of the feedstock and the obtained adsorbents (ash content, humidity, volatility, density, sumar pore volume, elemental composition) were studied.

AlxHfTaTi (0≤x≤0.5) refractory medium entropy alloys with excellent room-temperature tensile properties

Refractory high entropy alloys are strong candidates for high-temperature structural materials, because of their high strength, excellent thermal stability and exceptional softening resistance under high-temperature. However, majority of the existing refractory high entropy alloys are seriously limited in widespread application, due to their severe brittleness at room temperature. In this study, we proposed a novel AlxHfTaTi body-centered cubic (BCC) refractory medium entropy alloy with remarkable strength-ductility combination at room temperature. Adjusting the atomic ratio of Al (from 0 to 0.5 at.%), we investigated the effect of Al on the structure-property characteristics of the alloy under as-cast as well as cold-rolled and annealed conditions. Compared with the as-cast samples, the rolled and annealed samples exhibit more excellent tensile properties due to the remarkable reduction of grain size resulted from recrystallization. The Al0.3HfTaTi sample annealed for 5 min exhibits outstanding comprehensive properties at room temperature, with a yield strength higher than 1000 MPa and a fracture elongation of up to 24 ± 1 %, respectively. Quasi in-situ EBSD analysis results reveal that, during tensile deformation, the grain size has a significant effect on the grain rotation and dislocation gliding. Small grains are more likely to initiate multiple slip bands, promoting the synergistic effect of grain rotation and dislocation gliding, thereby improving the ductility of the alloy. Our findings can provide new ideas for the development of refractory high entropy alloys with outstanding room-temperature tensile properties.

High-temperature material properties of type 316L stainless steel for the design of pressure boundary components subjected to 700°C coolant

The high-temperature material properties of Type 316L stainless steel (hereafter referred to as “316L SS”) were determined through a series of material tests to enable the design of pressure vessels and piping operating up to 700 °C. Currently, the only applicable design rule for 316L SS components in the high-temperature creep range is French high-temperature design standard, RCC-MRx. However, the material properties provided by RCC-MRx are limited to approximately 600 °C. In this study, new material properties and relevant design coefficients for Type 316L components subjected to 700 °C coolant were determined based on material tests including tension, fatigue and creep tests conducted on 316L SS specimens. Utilizing these supplemented properties and design coefficients, the design of pressure boundary components and piping made of 316L SS in a large-scale test facility known as TESET, subjected to 700 °C coolant, was carried out. Several large-scale sodium tests at high temperatures up to 700 °C were successfully conducted at the TESET facility, with the main components and piping designed and constructed using 316L SS.

A simple and feasible method for preparing chromium carbide coating on graphite through binary NaCl-KCl molten salt

Due to excellent high temperatures resistance and wear resistance, graphite showed great potential apply in refractory materials. However, the porosity defects caused by the layered stacked structure of graphite would lead to easy permeability, which would result in reducing material’s lifetime. Surface coating technology was considered to be an ideal method to solve the problems through a stable coating on the surface of graphite. But existing methods have some disadvantages, such as high-cost and complex processes. In this work, a simple, low-cost and green molten salt method was designed. This method successfully prepared a Cr7C3 coating on the graphite surface. The effect of reaction time and temperatures on the chromium carbide coating was investigated by SEM and EDS. The results showed that the thickness of the coating layer increased gradually with the increase in reaction time or reaction temperature, and finally stabilized at about 8 μm. In addition, the reasons behind the formation of Cr7C3 coatings were discussed in terms of both the molten salt reaction and Gibbs free energy, as well as the effect of the coating structure on adhesion. Based on this method, it could not only effectively address the structure defects of graphite, but also showed simple preparation processes and low cost, which would promote the development of graphite materials in high-temperature resistant materials.

Electromechanical properties of BS-PT ceramics under uniaxial pressure and hydrostatic pressure

The increasing demands of device applications in harsh environments have led to higher expectations for temperature and pressure resistance in high-temperature piezoelectric materials. In order to understand the performance characteristics of BiScO3-PbTiO3 (BS-PT) high-temperature piezoelectric materials in practical device applications, this study focuses on analyzing the dielectric, piezoelectric, and ferroelectric properties of BS-64PT ceramics under uniaxial stress up to 150 MPa, as well as its electromechanical performance under a hydrostatic pressure of up to 400 MPa. As the uniaxial pressure increases, both the bias-field and large-signal piezoelectric coefficients exhibit a pattern of initially increasing and subsequently decreasing. Furthermore, the bias-field piezoelectric coefficient exceeds 450 pC/N and the large-signal piezoelectric coefficient surpasses 630 pC/N under uniaxial pressures below 100 MPa. This highlights their exceptional resistance to depolarization caused by uniaxial stress. To obtain more precise piezoelectric properties for BS-64PT ceramics in the 31 and 33 modes under hydrostatic pressure, the admittance fitting method was utilized. This method takes into account the significant losses at higher pressures. Within the pressure range of 0–400 MPa, the values of d33 and d31 for BS-64PT ceramics exhibited a minor change of 7.6% and 8%, respectively. These findings indicate that BS-64PT ceramics exhibit more stable piezoelectric properties under both uniaxial and hydrostatic pressures when compared to the majority of Pb-based perovskite-structured materials. The exceptional stability of piezoelectric properties in BS-PT ceramics can be primarily attributed to their elevated anisotropy energy or coercivity field compared to other perovskite-structured Pb(Mg1/3Nb2/3)O3 (PMN) / Pb(Zr,Ti)O3 (PZT)-based ceramics reported.

Molecular dynamics simulation of the effect of tool parameters on nano-cutting of polycrystalline γ-TiAl alloys

As one of the most promising lightweight high-temperature structural materials in the future, the surface quality of γ-TiAl alloys has a great influence on the performance of the workpieces, and the tool parameters are an important factor affecting the machining results. In this study, molecular dynamics simulations of the nano-cutting process of polycrystalline γ-TiAl alloys with different tool parameters were carried out. The results show that increasing the tool rake angle and decreasing the tool edge radius within a certain range helps to reduce the average cutting force, cutting force fluctuation, cutting temperature, and stabilize the cutting process, while the change of the tool clearance angle has less influence on the cutting process. In contrast, negative rake angle cutting is more likely to produce grain rotation and grain boundary steps in the processed substrate and increase the processed surface roughness than positive rake angle cutting; increasing the tool rake angle within a certain range will weaken the elastic recovery effect of the substrate. During cutting at a positive rake angle, whether a portion of the substrate is prone to slip toward the surface of the substrate, thereby reducing the surface quality, depends on the relative state of grain orientation and force applied in the substrate.

An assessment of the performance of heat transfer enhancement for optimizing high-temperature thermal energy storage

Background: High-temperature phase change materials (PCMs) are increasingly recognized for their potential in applications such as solar energy utilization, industrial waste heat recovery, and power load regulation. These materials can store and release significant amounts of latent heat, making them highly efficient for thermal energy storage. Purpose: This study aims to propose and analyze a novel structure to enhance latent heat energy storage using a graphite sheet combined with a PCM (KNO3-NaNO3) with a melting point of 220 K. The focus is on improving heat transfer efficiency and understanding the parameters affecting the exothermic process. Research Design: A numerical simulation approach was employed, using Fluent 7.1 software to analyze the exothermic process. The simulation method was validated with two examples before being applied to study the energy storage system incorporating graphite sheets. Study Sample: The study analyzed the performance of a high-temperature thermtotal energy storage (HTTES) system using graphite sheets of varying thicknesses, tube spacing, tube temperatures, and PCM thermal conductivities. Data Collection and/or Analysis: The study utilized numerical simulations to examine how different parameters i.e. thickness of graphite sheets, spacing between tubes, tube temperatures, and the thermal conductivity of PCM—affect heat transfer efficiency and exothermic time. Results: The integration of graphite sheets with a thickness of 2 mm was found to significantly improve heat transfer efficiency. The results indicated that increasing the spacing between graphite sheets and tube diameter influenced the total exothermic time. A logarithmic relationship was observed between the thermal conductivity coefficient and exothermic time, suggesting diminishing returns beyond 3.5 W/(m·K). Additionally, increasing the quantity of graphite sheets enhanced heat transmission and overall system efficiency. Conclusions: The study provides valuable insights into the performance of HTTES systems, demonstrating that incorporating graphite sheets can significantly enhance heat transfer and system efficiency. These findings guide the design of more effective thermal energy storage systems, supporting the broader adoption of HTTES technologies and contributing to the transition toward sustainable energy solutions. Further research and development in this field are essential to drive advancements and promote the widespread implementation of high-temperature thermal energy storage systems. Practical applications The enhanced heat transfer techniques developed in this research offer practical applications across various sectors. These techniques, utilizing PCMs and innovative graphite structures, enhance the efficiency and reliability of high-temperature thermal energy storage systems. This advancement enables continuous power generation in concentrated solar power (CSP) plants, optimizes energy utilization in district heating and cooling systems, and improves industrial waste heat recovery. By implementing these techniques, energy costs can be reduced, system performance can be optimized, and greenhouse gas emissions can be lowered, contributing to a more sustainable energy future.

Transient thermal 2D FEM analysis of SiC MOSFET in short-circuit operation including high-temperature material laws and phase transition of aluminum source electrode

Understanding the electrothermal behavior of SiC MOSFET power devices under extreme operation conditions, such as short circuits, is crucial for their application certification. However, simulating short circuits in electronic components is challenging due to the necessity of a comprehensive thermal and electrical Multiphysics model that incorporates material laws and respects elevated temperatures with broad ranges. It is also needed to model the melting of the topside Al electrode. The paper presents for the first time a 2D electrothermal FEM that simulates the thermodynamic behavior of SiC MOSFET at high temperatures transistors under short-circuit conditions, including wide-range temperature-dependent material property laws. This work models the Al phase transition by considering the apparent heat capacity method and including the latent heat absorbed during the Al solid-liquid phase change (PC). The geometric accuracy of this study provides significant added values compared to existing 1D models. It was deduced that including the temperature-dependent material laws highly impacted the results. The rise in SiC junction temperature led to a delay in the onset of Al melting. It also impacted the progression manner of the Al melting process after the formation of new melting fronts.

Structure and mechanical properties of a refractory Al7.5(NbTiZr)92.5 medium-entropy alloy subjected to long-term annealing and oxidation

Recently, Al-containing refractory high/medium-entropy alloys (RH/MEAs) have attracted special attention from materials scientists worldwide. Some of these alloys demonstrated an excellent combination of high-temperature strength and room-temperature tensile ductility provided by the formation of a structure consisting of body-centred cubic (bcc) matrix and B2 nanodomains/particles. However, oxidation resistance and phase stability, and, more importantly, the resulting mechanical properties of the Al-containing RH/MEAs, which are critical characteristics for high-temperature structural materials, remain unexplored. Herein, these aspects were extensively investigated for the Al7.5(NbTiZr)92.5 (in at%) alloy having an initial bcc + B2 structure. The alloy was subjected to long-term (500 h) annealing or oxidation tests at 600, 700, and 800 °C followed by the evaluation of mechanical properties during uniaxial tension at 22 and 600 °C. Microstructural studies of the specimens exposed to long-term annealing showed the formation of Zr5Al3 particles that precipitated along the grain boundaries and within grain interiors. The volume fraction of these particles was the highest (∼16 %) after annealing at 600 °C and the lowest (∼0.5 %) after annealing at 800 °C. Oxidation tests revealed that the alloy was prone to pesting phenomena, which intensified with the temperature. The alloy could sustain pesting only up to 10 h at 600 °C, while it experienced a complete disintegration into powder after 5 h at 800 °C. The poor oxidation resistance originated from the formation of volumetric, non-protective (Al,Nb,Ti,Zr)O4 oxide. While insignificantly affecting the strength, long-term annealing or oxidation deteriorated the ductility of the Al7.5(NbTiZr)92.5 alloy both at 22 and 600 °C. The Zr5Al3 phase embrittled the alloy after long-term annealing at 600 or 700 °C, but marginally reduced the ductility in the 800°C-annealed specimens due to the low volume fraction and relatively homogeneous distribution of this phase. The oxidation for 1 h decreased the room-temperature ductility owing to the premature macroscopic localisation of plastic deformation induced by synergistic effects from the volumetric (Al,Nb,Ti,Zr)O4 oxide. This study highlights the necessity for the examination of a set of properties of promising RH/MEAs to critically assess perspectives of these alloys to find applications as new high-temperature materials in aircraft and aerospace sectors.

Uncovering dominant mechanisms of nano-mechanical properties of AlTaO4 ceramics from structural characteristics

This investigation comprehensively examines the nano-mechanical properties of AlTaO4 for the first time, including Young's modulus (E), hardness (H), and fracture toughness (KIC). Variability in the regional distribution of E and H within AlTaO4 is elucidated through an examination spanning both the grain and bulk material scales, and offers a correlational equation of E and H from fit statistical outcomes. Additionally, the H/E ratio and micro-hardness dissipation parameter of AlTaO4 reach 0.063 and 0.61, respectively, which demonstrate its exceptional wear resistance. Further investigation emphasizes that the distinctive crystalline structure, short bond lengths, high bond strength, and elevated charge density around aluminum ions significantly contribute to the high E (208 GPa) and H (13.1 GPa) of AlTaO4. The capacity for energy absorption during elastic deformation enhances crack formation energy and contributes to the relatively high fracture toughness (2.6 MPa m1/2) of AlTaO4. This work elucidates the excellent mechanical properties of AlTaO4 by applying nanoindentation and first-principle calculation, which will advance the applications of AlTaO4 as high-temperature materials.

Preparation and heat storage characteristics of high-temperature phase change macrocapsules of chloride eutectic salt

Chloride salts, as high-temperature phase change materials (PCMs), have advantages in terms of high application temperature and high latent heat, but the intrinsic disadvantages such as high corrosiveness and easy leakage have seriously limited their development. Employing the NaCl–KCl binary salt as PCM, a double-shell cladding strategy with an inner layer of expanded graphite and an outer layer of ceramic was proposed, thereby, the chloride phase change macrocapsule with good thermal storage performance was successfully prepared. The double-shell capsules exhibited better leakage resistance and cycling stability. On this basis, the preparation process of double-shell eutectic salt macrocapsules was simplified by using an in-situ melting method, employing the mixed NaCl and KCl as raw materials directly that were transferred to eutectic binary salt inside the capsules during sintering. It is also proposed to improve the heat storage density of the capsules by increasing the capsule size and isostatically pressing the capsule. The NaK-20-200MPa sample indicated the largest heat storage density in the temperature range from 600 °C to 700 °C, with a mass heat storage density of 190.38 J/g, which was 2.85 % higher than that of the NaK-20-0MPa capsules and 36.99 % higher than that of the NaK-5-0MPa capsules. Additionally, the volume heat storage density of the NaK-20-200MPa capsules was 339.19 J/cm3, which was 14.69 % higher than that of the NaK-20-0MPa capsules and 21.52 % higher than that of the NaK-5-0MPa capsules. The good thermal performance and low cost of chloride PCM could ensure the encapsulated salt for use in high-temperature heat storage.

Preparation of high-performance anode materials for sodium-ion batteries using bamboo waste: Achieving resource recycling

Bamboo exhibits various excellent properties and is widely used in construction. However, appropriate disposal of the bamboo waste generated in a green manner is difficult. To realize resource recycling, we used a simple treatment method to prepare waste bamboo as a negative electrode material exhibiting considerable electrochemical properties for sodium-ion batteries. The electrochemical properties of high-temperature calcination materials considerably improved after impurity removal treatment using an acid solution, which was performed to eliminate the influence of impurities on electrochemical properties. However, the materials still could not meet commercial requirements. A simple pre-oxidation modification treatment enabled the introduction of O atoms into the carbon skeleton to expand the layer spacing, improved the transport kinetics of Na+ in the carbon skeleton, and further increased the platform capacity of the pre-oxidation material. The preoxidative high-temperature co-treated materials exhibited a specific charge capacity close to 280 mAh g−1 at a 0.1 C rate and a capacity attenuation of almost zero after 100 cycles, and showing a specific charge capacity of more than 150 mAh g−1 at a 2 C rate test. In the context of sustainable development, this study makes waste bamboo become a candidate of low-cost negative electrode material for sodium-ion batteries.

Component regulation and high-entropy engineering for enhanced antioxidant and high-temperature mechanical properties of protective films

Transition metal nitrides (TMNs) have gained widespread application in protecting structural components due to their high strength and hardness. However, TMNs still have the challenge of structural instability and mechanical deterioration caused by oxidation under harsh high temperature conditions. Herein, we present a strategy combining component regulation with high-entropy engineering to develop an advanced high-temperature Al-containing high-entropy nitrides (HENs) material. To prevent the phase decomposition of AlN within the (NbMoTaWAl)N, theoretical simulations were employed to determine a critical atomic percent of 25.0% Al for maintaining the stability of the high-entropy structure. Ensuing experimental synthesis creates three NbMoTaWAlN films with varying Al content: a high-entropy film with 0.0% Al (HEN), a high-entropy film with 21.2% Al (HEN-Al), and an amorphous transition metal nitride film with 30.2% Al (a-TMN-Al), validating key high-entropy engineering benchmarks. It is found that the unique HEN-Al film exhibits excellent oxidation resistance and high-temperature hardness, attributed to the uniform distribution of Al atoms in the robust high-entropy structure, which creates conditions for forming a dense and continuous Al2O3 barrier layer, effectively hindering the diffusion of oxygen into the film interior. This study provides new insights to develop a new generation of high-temperature protective materials.

Mechanical and dielectric properties of RE2SiO5 (RE=Ho, Er, Tm, Yb, and Lu) as high-temperature wave-transparent materials

As the flight speed of aircraft continues to increase, high-temperature wave-transparent materials for radomes or antenna windows face great challenges. The shortage of new high-performance wave-transparent materials is limiting the improvement of aircraft performance. In this work, dielectric and mechanical properties of RE2SiO5 (RE = Ho, Er, Tm, Yb, and Lu) were investigated to explore their application as high-temperature wave-transparent materials. RE2SiO5 (RE = Ho, Er, Tm, Yb, and Lu) ceramics possess relatively low dielectric constant and it is insensitive to the RE species. For the dielectric loss, they gradually decrease as the radius of rare earth ions decreases. In addition, RE2SiO5 (RE = Ho, Er, Tm, Yb, and Lu) possesses good mechanical properties with high hardness and relatively low reduced modulus, and hardness is insensitive to the rare earth ion radii while the reduced modulus increases with the RE3+ ions radius decreases. They are larger than those of fused silica, the most used traditional high-temperature wave-transparent material. The results provide important material selection and optimization guidelines for RE2SiO5 as the candidate for next-generation high-temperature wave-transparent materials.

Suppressing the phase transition of ZrP 2O 7 by defect and entropy regulation for high-temperature wave-transparent material application

Suppressing the phase transition of ZrP ₂O ₇ by defect and entropy regulation for high-temperature wave-transparent material application

Unveiling high resistivity mechanism in (0.8-x)BaTiO3-0.2BiScO3-x(Bi0.5Li0.5)TiO3 ceramics with good dielectric temperature-stability

Focusing on the high resistivity together with low intrinsic conduction in BaTiO3–BiMeO3 materials, it can contribute to the development of reliable high-temperature capacitor materials. In this work, x(Bi0·5Li0.5)TiO3-(0.8-x)BaTiO3-0.2BiScO3 (where x ranges from 0 to 0.2) ceramics were fabricated by a solid reaction method. The temperature stability of dielectric permittivity and resistance are improved significantly by the introduce of (Bi0·5Li0.5)TiO3 (referred to as BL) compared to BaTiO3–BiMeO3. The composition discrepancy due to chemical inhomogeneity can be determined by SEM and EDS mapping although XRD exhibit a single perovskite phase. The characteristics of distinct conductivity behaviors in micro-regions was measured by kelvin probe force microscopy (KPFM). The non-stoichiometry gives rise to two kinds of defects for charge compensation: an ionic compensation and oxygen-vacancy compensation in different grains. The increase of the hopping activation energy of charged carries enhances the high-temperature resistance of the system. The sample of x = 0.15 shows very good temperature stability of dielectric permittivity in the temperature range from 200 °C to 400 °C, and that of x = 0.1 exhibits the highest resistivity of 3.6 MΩ cm at 570 °C. The proposed method gives an efficient strategy for improving the dielectric temperature stability and insulation by the special defect compensation in the perovskite oxides.

Development of Macro-Encapsulated Phase-Change Material Using Composite of NaCl-Al2O3 with Characteristics of Self-Standing

Developing thermal storage materials is crucial for the efficient recovery of thermal energy. Salt-based phase-change materials have been widely studied. Despite their high thermal storage density and low cost, they still face issues such as low thermal conductivity and easy leaks. Therefore, a new type of NaCl-Al2O3@SiC@Al2O3 macrocapsule was developed to address these drawbacks, and it exhibited excellent rapid heat storage and release capabilities and was extremely stable, significantly reducing the risk of leakage at high temperatures for industrial waste heat recovery and in concentrated solar power systems above 800 °C. Thermal storage macrocapsules consisted of a double-layer encapsulation of silicon carbide and alumina and a self-standing core of NaCl-Al2O3. After enduring over 1000 h at a high temperature of 850 °C, the encapsulated phase-change material exhibited an extremely low weight loss rate of less than 5% compared with NaCl@Al2O3 and NaCl-Al2O3@Al2O3 macrocapsules, for which the weight loss rate was reduced by 25% and 10%, respectively, proving their excellent leakage prevention. The SiC powder layer, serving as an intermediate coating, further prevented leakage, while the use of Al2O3 ceramics for encapsulation enhanced the overall mechanical strength. It was innovatively discovered that the Al2O3 particles formed a network structure around the molten NaCl, playing an important role in maintaining the shape and preventing leakage of the composite thermal storage phase-change material. Furthermore, the addition of Al2O3 significantly enhanced the rapid heat storage and release rate of NaCl-Al2O3 compared to pure NaCl. This encapsulated phase-change material demonstrated outstanding durability and rapid heat storage and release performance, offering an innovative approach to the application of salt phase-change materials in the field of high temperature rapid heat storage and release and encapsulating NaCl as a high-temperature thermal storage material in a packed bed system. Compared with conventional salt-based phase-change materials, the developed product is expected to significantly improve the reliability and thermal efficiency of thermal storage systems.