An indigenous Monte Carlo neutron transport code, named PATMOC, has been designed and developed at Bhabha Atomic Research Centre (BARC) for reactor physics design applications. The code has been extensively tested for its algorithmic accuracy against numerous international numerical benchmarks, has also been validated on practical nuclear reactor systems like Advanced Heavy Water Reactor Critical Facility (AHWR-CF) and Apsara-U pool type research reactor located at BARC, and is now in regular use for day-to-day reactor physics studies. These reactor systems and most of the benchmark problems used for the verifications and validation of the code have square lattice arrangement in the core. In this paper, we present the results of verification of PATMOC code on whole-core reactor system with hexagonal lattice arrangement of fuel elements. In this exercise, we have analyzed the High Temperature engineering Test Reactor (HTTR) whole-core benchmark for integral and differential parameters at both lattice and core level. The results demonstrate the algorithmic accuracy of the code on hexagonal reactor systems also. This exercise will help make use of this code for reactor physics design studies also for the reactor systems with hexagonal arrangement.