Geothermal Water Research Articles

Genesis of Geothermal Waters in Suichuan County, China: An Integrated Method Constrained by the Hydrochemical and Isotopic Characteristics

Numerous geothermal resources of medium to low temperature have been reported in southern China. Suichuan County is one of the regions where thermal manifestations are abundant. However, the study regarding the understanding of geothermal water sources, hydrochemical composition and fluid-rock interaction lacks behind. Therefore, this study has characterized the slightly acidic to slightly alkaline bicarbonate geothermal waters of medium-low temperature of the Suichuan area. Geothermal waters of the study area have been evaluated mainly as of HCO3-Ca-Na hydrochemical type with a maximum temperature of 80 °C. The results indicate the low hydrochemical concentration where HCO3− acts as a principal anion. Furthermore, the F− content in geothermal and two cold water samples have been found high with a maximum value of 13.4 (mg/L), showing high pH of 9.6 as well. Here, the compilation of deuterium and oxygen-18 isotopic data of geothermal waters showed a local precipitation origin with a recharge elevation ranging from 630–1000 m. The circulation depth and reservoir temperatures are estimated, explaining the deep thermal water behavior. Additionally, the estimation of saturation indices of various minerals shows the geothermal waters’ corrosive or scaling behavior. Subsequently, the geothermal water points in the study area represent a fracture convection formation pattern. Finally, by integrating conventional hydrochemistry along with isotopic data, and considering the geological framework, a conceptual genetic model of the Suichuan thermal ground waters has been discussed. Hydrochemistry and isotopic features along with a conceptual circulation model have been provided by the foundation towards the sustainable management of hydrothermal resources in Suichuan. Proper management policies and practices are required for further development of Suichuan hydrothermal waters.

Geothermal water in Bakreshwar-Tantoli region in West Bengal, India: Implications on water quality for irrigation and drinking purposes

Groundwater becomes more critical for drinking and irrigation purposes due to reduced surface water supplies and contamination of these sources. Knowing the quality of underground water is vital to the protection of public health and sustainable water resource development. The goal of this study is, therefore, to assess the suitability of groundwater for drinking and irrigation purposes in the Bakreshwar-Tantaloi hot springs in West Bengal, India. This study evaluates the quality of water produced from 7 different geothermal hot springs by investigating its chemical concentration. The physicochemical parameters were examined for the water samples. The suitability of groundwater for drinking purposes was measured by contrasting the chemical concentrations with the WHO standards and also computing and comparing the Water Quality Index (WQI) value with recommended norms. The concentrations of Ca2+, Mg2+, Cl−, SO42−, and NO3− are within the WHO (2011) and BIS (2012) tolerable limit. Statistical analyses are used to reveal patterns and groups from the physiochemical dataset of groundwater samples. Principal Component Analysis (PCA) and factor analysis identify the source for groundwater parameters. The correlation matrix and scatter plot matrix give the relationship among major chemical ions of water samples. Dendrogram defines the relationship between physicochemical variables and groups them into strong to weak correlations among water components.

Hydrochemical Characterization of Groundwaters’ Fluid Flow through the Upper Mesozoic Carbonate Geothermal Reservoirs in the Geneva Basin: An Evolution more than 15,000 Years Long

Groundwaters circulating in Upper Mesozoic carbonates are of great interest for geothermal heat production and storage applications in the Geneva area. This study aims at providing new insights and proposing new interpretations about the mineral-water reactions and the fluid-flow paths mechanisms across the Geneva Basin (GB). Data from previous studies are combined and improved by new ones collected from cold and hot springs and geothermal exploration wells in 2018 and 2020 in the framework of the GEothermies program and HEATSTORE project. Major ions, trace elements, and the isotopes of Oxygen, Hydrogen, Sulfur, Strontium, and Carbo have been analysed and the results show that the sampled waters have a meteoric origin, the carbonate aquifers act as preferential host rocks for geothermal waters, and partial contribution from the Cenozoic sediments can be observed in some samples. The Jura Mountains and the Saleve Ridge are the main catchment areas and an evolution from a pure Ca-HCO3 footprint for the cold springs, to a Na > Ca-HCO3 and a Na-Cl composutions, is observed at the two geothermal wells. The residence time is in the order of a few years for the cold springs and reaches up to 15–20,000 years for the deep wells.

Boron removal by using vacuum assisted air gap membrane distillation (VAGMD)

Vacuum-assisted air gap membrane distillation was used to remove boron from different waters in this study. Four different vacuum pressures (0.02 bar, 0.04 bar, 0.06 bar, and 0.08 bar) were applied and air gap membrane distillation (AGMD) configuration was also used to compare the effect of vacuum pressures on the process. Six commercial hydrophobic membranes which have the 110° contact angle value at least were used. Membranes with a 44.18 cm 2 effective area were tested with saline water, synthetic boron solution, and real geothermal water as the feed solutions which is the only study with VAGMD in the literature. Salt removal efficiencies of all experiments were higher than 98.2%. Permeate boron concentrations of synthetic boron solution and real geothermal water were lower than the 0.5 mg/L limit value for drinking water set by WHO and in terms of removal efficiency it means higher than 99% removal efficiency. Vacuum pressures enhanced the water fluxes as expected and also decreased the specific energy consumption. • The use of a supplementary vacuum pump on the AGMD system improved the flux. • Increasing pressures increase flux and GOR without any considerable rejection loss. • Higher than 99% boron removal efficiencies were achieved. • All permeate boron concentrations were obtained below 0.5 mg/L. • Specific energy consumption values did not increase although using a vacuum pump.

Application of hydrochemical and isotopic data to determine the origin and circulation conditions of karst groundwater in an alpine and gorge region in the Qinghai–Xizang Plateau: a case study of Genie Mountain

Complex structural systems, lithological differences, and extreme heterogeneity of aquifers combine to create a complex karst aquifer structure in alpine and gorge areas; however, because of the topography, direct investigation of aquifer structure is difficult. In this study, field survey, hydrochemical, and isotopic data are analyzed to reveal the development of karst groundwater and to describe the karst water cycle in Genie Mountain, Qinghai–Xizang Plateau. The results show that groundwater circulation is mainly controlled by active fracture. Atmospheric precipitation and melting ice and snow are the groundwater recharge sources, and recharge areas are mostly located in high mountains above 4500 m a.s.l. The direction of groundwater flow is mostly controlled by the Jinshajiang active Fault, with drainage areas at the intersection of multiple faults. There are two regional karst water runoff conduits. One is along the Edexi-Hongjunshan Fault, where groundwater runs from south to north; the other is along Gangtonglong Fault, where groundwater runs from north to south, and is discharged at Gangtonglong gully. The groundwater cycle can be divided into three levels: epikarst water circulation; mid to deep karst water circulation; and deep geothermal water circulation. The karst springs located in the outlet of the Huolong gully contain markedly higher levels of Na+ and SO42− than other karst springs because of the leaching effect of groundwater on mirabilite. The presence of evaporites in Huolong gully indicates that the plateau planation formed by the structural uplift will change the local climatic conditions, and then affect the groundwater circulation process and the water–rock reaction in the process.

Genetic Analysis of Geothermal Resources in Deep-Seated Fault Area in Tonghe County, Northeast China and Implications of Geothermal Exploration

Northeast China is an area with high energy consumption and high carbon emissions, and the utilization of geothermal resources can effectively overcome these problems. However, there are few geothermal manifestations in Northeast China and no systematic method for geothermal exploration at present, which hinders the utilization of geothermal resources. Here, a systematic analysis, including hydrochemistry, petrology, isotopes, controlled source audio magnetotelluric sounding, drilling, and temperature curve of two boreholes was carried out to investigate the genesis of geothermal resources in Tonghe County, Northeast China, along the Yilan-Yitong lithospheric fault (YYF). We found that the geothermal water is alkaline Na-HCO3 type water, is of local meteoric origin, and is recharged from the hilly area with an elevation of ~280 m around the study area. We established a geothermal water circulation path model: (1) cold water infiltrated along the YYF to a depth of 2–3 km, (2) cold water was heated by mantle heat, and (3) hot water was stored in sandstone/siltstone, forming a sandstone geothermal reservoir with a temperature of ~70 ℃. These results have important guiding significance for the scientific exploration of geothermal resources in Northeast China.

Hydrogeochemical processes controlling the water composition in a hyperarid environment: New insights from Li, B, and Sr isotopes in the Salar de Atacama

Northern Chile, NW Argentina, and SW Bolivia, (“the lithium triangle”), represent a world class reservoir of lithium, but this extraordinary enrichment is still controversial, and different processes have been invoked over the years, including, geothermal waters associated with active volcanism, leaching of soluble salts from volcanic rocks and leaching of lithium-rich clays. The Salar de Atacama (SDA) represents one of the richest reservoirs of Li in northern Chile and has been extensively studied during the past years. Most of the studies have been focused in the southern and southeastern portions, where the highest lithium concentrations have been reported. However, a comprehensive model of water recharge at SDA is still imprecise. We used a combination of isotopic methods, including δ7Li, δ11B and 87Sr/86Sr ratios, with their chemical composition of a set of water samples from salt lakes, geothermal manifestations, groundwaters and surficial diluted waters (rivers and streams with low salinity). This study explores the hydrogeochemical processes controlling the water composition and solute distribution of the SDA. Our data confirm that weathering of the ignimbrites constitutes one of the most important processes in relation of solute origin in the region, where deep water-rock interactions would operate at high temperature, enhancing leaching of Li and other solutes. We determine that groundwater flow entering the SDA has undergone pre-enrichment processes (e.g., leak from Altiplano salt lakes; evaporite dissolution, among others) associated with salt inputs in the Western Cordillera. Our results provide a step forward to a comprehensive understanding of the processes that govern brine formation and lithium enrichment in a hyperarid environment, contributing to a sustainable exploration and exploitation of lithium in these environments.

Thermoeconomic analysis of a geothermal and solar assisted combined organic Rankine and absorption cycle

In this paper, a geothermal and solar-assisted combined system is designed for the electricity and cooling of residences. The geothermal water from the geothermal resource and the heat transfer fluid heated in the parabolic trough collector is used as the heat source in the absorption cooling system. The organic Rankine cycle (ORC) generates power with geothermal water and heat transfer fluid from the absorption cooling cycle. The produced power is supported to the grid. Engineering Equation Solver (EES) and Aspen Plus program are used for thermodynamic and thermoeconomic analysis of the combined system. In these analyzes, the geothermal and solar energy values of Afyonkarahisar city are considered. Geothermal water at a temperature of 130 ºC and a mass flow rate of 85 kg/s and a solar source at 600 W/m2 radiation is used for the combined system. Parametric studies are performed to demonstrate the way unit electricity and cooling costs change according to the geothermal water temperature and solar radiation. The cooling capacity and the net power output of the system are 2720 kW and 2235 kW, respectively. The unit costs of cooling and electricity in the combined system are calculated 0.017 $/kWh and 0.074 $/kWh, respectively.

ВЛИЯНИЕ ТЕМПЕРАТУРНОГО ФАКТОРА НА ВЕЛИЧИНУ ГИДРОСТАТИЧЕСКОГО ДАВЛЕНИЯ ПРИ БУРЕНИИ ГЕОТЕРМАЛЬНЫХ СКВАЖИН

One of the most important tasks of modern natural science is energy saving and replacement of non-renewable energy sources with wind, solar, geothermal, wave and other energies. The main advantage of geothermal water is that it can be supplied in places where it is continuously regenerated and directly consumes heat, energy, more importantly, useful chemistry, has healing properties and abilities. The article discusses the influence of the temperature factor on the value of hydrostatic pressure while drilling of geothermal wells using chemical reagents based on water-soluble polymers in the process of drilling deep wells, which ensure the stability of drilling fluids at high temperatures.As mentioned earlier, the regulation of hydrostatic pressure by increasing the drilling mud densityat high temperatures is inappropriate. Therefore, it is necessary to take measures to improve the sedimentation stability of drilling muds.

Dynamic multi-objective optimization applied to a solar-geothermal multi-generation system for hydrogen production, desalination, and energy storage

The design of optimal energy systems is vital to achieving global environmental and economic targets. In the design of solar-geothermal multi-generation systems, most previous investigations have relied on the static multi-objective optimization approach (SMOA), which may leave considerable room for improvement under certain conditions. In this numerical study, the optimal condition at which to operate a solar-geothermal multi-generation system – which can simultaneously produce hydrogen, fresh water, electricity, and heat, along with storing energy − is determined via a dynamic multi-objective optimization approach (DMOA). Optimization is performed using a combination of NSGA-II and TOPSIS, and the results are benchmarked against those of SMOA. The decision variables include the solar area, geothermal water extraction mass flow, and hydrogen storage pressure. The objective functions include the production of electricity, heat, hydrogen, and fresh water, along with the exergy and energy efficiencies and the payback period. It is found that when compared with SMOA, DMOA can significantly improve all the objective functions. The annual production of electricity, heat, hydrogen, and fresh water increases by 14.4, 16.1, 13.5, and 14.3%, respectively, while the average annual exergy and energy efficiencies increase by 5.2 and 3.0%, respectively. The use of DMOA also reduces the payback period from 5.56 to 4.43 years, with a 4.4% reduction in hydrogen storage pressure. This shows that compared with a static approach such as SMOA, DMOA can improve the exergy and energy efficiencies, economic viability, and safety of a solar-geothermal multi-generation system.

Flow Path of the Carbonate Geothermal Water in Xiong’an New Area, North China: Constraints From 14C Dating and H-O Isotopes

Studying the flow path of geothermal water in geothermal fields is an important basis for the scientific development and management of geothermal resources. However, due to the influence of engineering volume, economic benefits and demand, it is very difficult to fully grasp the flow path of deep geothermal water in large areas. The use of hydrogeochemical tracers to determine the flow path of geothermal water is a scientific and effective research method. In order to accurately describe the flow path of carbonate geothermal water in the Xiong’an New Area and its surrounding areas, this study systematically analyzed the 14C, 18O, and 2H data of carbonate and Cenozoic sandstone geothermal water, Quaternary groundwater, as well as mountain spring water of the study area. Based on these results, we can conclude that 1) The 14C, d, and 18O values are favourable clues for indicating the circulating runoff conditions and runoff paths of geothermal water. 2) The salinity of the Xushui-Wenan and Lilan transfer zone are <3 g/l, the 14C values are lower than 25000 years, the d value is higher, and the phenomenon of “18O drift” is weak, all these indicating the dominant flow path of carbonate geothermal water, featured by relative lower temperature. 3) The salinity of karst geothermal water in the southwest of Gaoyang low uplift, Rongcheng uplift and Niutuozhen uplift is > 3 g/l, the 14C values are higher than 40,000 years, the d value is lower, and the phenomenon of “18O drift” is obvious, all these indicating that the tectonic sites are the convergence areas of regional karst geothermal water, featured by relative high temperature. 4) The hydrochemical indicators combined with previous carbonate groundwater flow field indicate that the recharge of carbonate geothermal water in the Xiong’an New Area may not only drive from the western Taihang Mountains, but also along the Xushui-Wenan transfer zone and the Lilan fault, with the recharge of carbonate groundwater from the Cangxian uplift from east to west. By further identifying and defining the dominant flow path and supply direction of carbonate geothermal water in the Xiong’an New Area and surrounding areas, it provides strong support for the scientific development of regional carbonate geothermal water.

Mechanism and Prediction of Geothermal Resources Controlled by Neotectonics in Mountainous Areas: A Case Study of Southeastern Zhangjiakou City, China

The geothermal resources in mountainous areas are usually controlled by neotectonic faults. To minimize the risk in site selection for geothermal drilling, the controlling mechanism must be identified. Based on the neotectonic control theory for geothermal resources, the occurrence of the geothermal resources in the mountainous area in southeastern Zhangjiakou city was investigated. The investigation was divided into three stages. Firstly, field investigation for neotectonics was carried out to characterize the kinematics and the stress state of the faults, including fault occurrences, tectonic stages, and paleostress analysis, and in total 19 neotectonic faults were confirmed. Based on Riedel shear model and present stress field, their conductivity for geothermal water was inferred; secondly, geophysical and geochemical surveys were applied to identify the stress state and characterize the occurrence of the potential water conductive faults. The results showed that the combined use of magnetotelluric sounding (MT), controllable source audio magnetotelluric sounding (CSAMT), and 2D seismologic survey is effective in delineating fault occurrence, strata distribution, and water conductivity within 1,000 m depth, while measurement of 222Rn activity in soil gas across the neotectonic faults is effective to investigate the groundwater conductivity of the faults, and all the neotectonic faults in the study area striking clockwise from N5°E to N25°W are considered to be water conductive; thus, the areas at the intersection zones of neotectonic faults in the basin in groundwater runoff and discharge regions are promising targets for geothermal exploration. This conceptual model was verified by the geothermal fields already discovered in the study area and proved to be reasonable, and then a potential drilling site was predicted and proved to be successful. It is suggested that this workflow for geothermal exploration is suitable for Zhangjiakou city and may also be applied to other mountainous areas.

GEOLOGICAL AND GEOPHYSICAL CONSIDERATIONS REGARDING THE MINERAL AND GEOTHERMAL WATERS FROM THE RAMNICU VALCEA - GOVORA AREA

For understanding of complex geological and geophysical phenomena, regarding the mineral and geothermal waters, we must base on the whole of knowledge and available data for the study area. The input data include: digital terrain models, geological and geophysical maps, sections, drill-holes and geological interpretation, for assemble together into the same space data from various sources, in order to ensure geometrical coherence. Also, the database includes measurements of deuterium (δD (‰)) and overall salt content (∆d (mg/l)) expressed as the difference in density between a distilled water taken as a standard and water sample. Are important to take into account the geology 'boundary' data (geology contacts, interfaces and limits), the deep geology and processing/filtering of geophysical data with properly algorithms. The type of filtering of gravimetric and magnetic data must be chosen based on the depth of the model we want to get. This is necessary because the values of the geophysical parameters recorded at the surface of the terrain contain weighted average information from both the surface and from different depths, even to the base of the Lithosphere. In this paper we made some geological and geophysical considerations regarding the mineral and geothermal waters from the Ramnicu Valcea - Govora area. The types of water sources targeted are mineral springs, boreholes and surface water in the area

Hydrothermal Features of a Sandstone Geothermal Reservoir in the North Shandong Plain, China

Abstract There are 1,000 geothermal wells with depths of 1500–2000 m drilled into the upper Tertiary sandstone geothermal reservoir in the Guantao Formation in the North Shandong Plain, which support about 61 million square meters of domestic space heating. Concerning the large-scale exploitation of the Guantao Formation geothermal reservoir and its important role in clean space heating, it is essential to fully understand the characteristics of the geotemperature, geothermal water flow, and hydrochemical features, especially the heat accumulation and geothermal water enrichment mechanism. Based on the data from pumping tests, temperature logging, water level measurements, and hydrochemistry and isotope sampling and analysis, in this study, the heat sources and accumulation, water sources, and enrichment mechanism of the sandstone geothermal reservoir in the Guantao Formation were explored. The geothermal gradient of the cap rocks and the reservoir’s temperature revealed that the geothermal temperature fields are controlled by fault structures, and the relative high temperature zones are distributed in the area where the uplifts and deep heat-controlled faults converge. The geothermal water-rich area is located in the ancient river channel zone. The closer the water-rich area is to the ancient river channel belt, the deeper and coarser the buried conglomerate aquifer is, and the better the water-rich condition is. The best water-rich areas are found in the alluvial fan of the ancient channel belt.

Geochemistry analysis of geothermal water in Tulabolo Timur, Sulawesi, Indonesia

Gorontalo has several geothermal manifestations, such as Lombongo, Pangi, Libungo, Hungayono and Tulabolo Timur. Research on geothermal areas must be carried out to obtain surface and subsurface information, then the geothermal areas can be further developed. The purpose of this study was to analyse the geochemistry water of the geothermal water in Tulabolo Timur, Bone Bolango Regency, Gorontalo Province, Sulawesi, Indonesia. The research method is divided into field observations and laboratory analysis. Data processing using Atomic Absorption Spectrophotometer (AAS) for cation and anion test. Data processing using Picaro Water Isotope Analyzer for isotope test. Subsurface temperature is determined using the geothermometer Na-K Giggenbach formula. The results of this research show that the fluid type of Tulabolo Timur geothermal area is chloride and the origin of fluid is from deep reservoir. Geothermal fluid when it approaches the surface is not affected by surrounding rocks. Tulabolo Timur geothermal fluids are categorized in the upflow zone. Geothermal fluid when it reaches the surface is diluted with meteoric water. Meteoric water is infiltrated below the surface in the recharge area, which is located in the north and south of the study area. The subsurface temperature of Tulabolo Timur is included in the high-temperature system.

Fatty acid composition of phospholipids and triacylglycerols in the flesh of the thick-lipped grey mullet (Chelon labrosus) living in Tunisian geothermal water and seawater: A comparative study

This study was conducted to elucidate the effects of rearing conditions on the composition of different phospholipid (PLs) classes and triacylglycerols (TAG) of the thick-lipped grey mullet (Chelon labrosus), a muscle originating from seawater and geothermal water. The major fatty acids in the examined lipid classes of the two fish groups were palmitic acid (C16:0), stearic acid (C18:0), oleic acid (C18:1n-9), linoleic acid (C18:2n-6), arachidonic acid (C20:4n-6), eicosapentaenoic acid (C20:5n-3), and docosahexaenoic acid (C22:6n-3). The analyses demonstrated that the fatty acid profiles of the PL classes in the seawater fish group were characterized by the predominance of n-3 polyunsaturated fatty acids (PUFA). By contrast, in geothermal fish, the distribution of PUFA series proportions differed between the phospholipid fractions. It was found PUFA n-3 was particularly abundant in PS and PI, while the n-6 series dominated the PC and PE PUFA group. Nonetheless, it was found that neutral lipid fatty acids were characterized by saturated fatty acids (SFA) followed by monounsaturated fatty acids (MUFA) in the seawater fish and by PUFA in the geothermal fish. The results presented here give useful information on the role of lipid classes in the physiological adaptation of C. labrosus which can serve for the optiminzation of these aquaculture systems.

Geochemical and Isotopic Characteristics of Two Geothermal Systems at the Nanpu Sag, Northern Bohai Bay Basin

The utilization of geothermal energy has gradually increased in northern China because of its unique advantages as a heating supply. However, the sustainable exploitation of geothermal energy usually requires a comprehensive investigation of the geothermal water circulation pattern prevailing at a proposed site. During the exploitation of geothermal energy resources at Nanpu Sag in northern China, thermal anomalies were found to exist in two adjacent regions: the Caofeidian and the Matouying. To reconcile the anomalies and to examine both the source of recharge water and the geothermal systems’ circulation dynamics, a comprehensive investigation was performed using multiple chemical and isotopic tracers (δ2H, δ18O, 87Sr/86Sr, δ13C, and 14C). The total dissolved solids (TDS) of the geothermal water are approximately 750 mg/L and 1,250 mg/L, respectively. The geothermal water isotopes at the two sites are also different, with average values of -9.3‰ and -8.2‰ for δ18O and -73.4‰ and -71‰ for δ2H, respectively. Moreover, the 87Sr/86Sr ratio of geothermal water at Matouying is 0.7185, which is much greater than that of Caofeidian, with an average value of 0.7088. All the results confirm the difference between the two geothermal systems and may explain the two circulation patterns of deep groundwater at Caofeidian and Matouying. The reservoir temperature obtained from theoretical chemical geothermometers is estimated to be 83–92°C at the Caofeidian and 107–137°C at the Matouying, respectively. The corrected 14C age implies a low circulation rate that would allow sufficient time to heat the water at Caofeidian. In addition, we propose a geothermal conceptual model in our study area. This model could provide key information regarding the geothermal sustainable exploitation and the effective management of geothermal resources.

Geochemical Characteristics of Rare Earth Elements in the Chaluo Hot Springs in Western Sichuan Province, China

High-temperature hydrothermal activity areas in western Sichuan Province, China are ideal objects for studying deep Earth science, extreme ecological environments, and comprehensive geothermal utilization. To understand the geochemical characteristics of rare Earth elements (REEs) in the Chaluo hot springs in western Sichuan Province, the authors analyzed the composition and fractionation of REEs in the hot springs through hydrochemical analysis, REE tests, and North American Shale Composite-normalized REE patterns. Moreover, the composition and complex species of REEs in the geothermal water in the Chaluo area were determined through calculation and simulation analysis using the Visual MINTEQ 3.0 software. The results are as follows. In terms of hydrochemical type, all geothermal water in the Chaluo area is of the Na-HCO3 type. The cations in the geothermal water are mainly controlled by water-rock interactions and evaporation, the anions are determined by water-rock interactions, and the hydrochemical processes are primarily controlled by the dissolution of silicate minerals. The total REE content of the geothermal water in the Chaluo hot springs is 0.306 ± 0.103 ug/L. It is low compared to the Kangding area and is primarily affected by the reductive dissolution of Fe oxides/hydroxides, followed by pH. The geothermal water in the Chaluo area is rich in light rare Earth elements (LREEs) because of the presence of Fe oxides. It shows positive Eu and Ce anomalies due to the combined effects of the dissolution of Eh and Mn oxides and surface water. Furthermore, the positive Eu anomalies are also caused by the water-rock interactions between the Qugasi Formation and deep geothermal water. Similar to alkaline water bodies, the complex species of REEs in the geothermal water mainly include Ln(CO3)2−, LnCO3+, and LnOH2+, which is caused by the stability constants of complexation reactions.

The Use of Equipment for the Study of Phase Changes to Determine the Conditions of Precipitation of Inorganic Sediments in Geothermal Waters

In Poland, there are low-temperature geothermal reservoirs that can be used for various purposes in many regions of the country. Low-temperature deposits of geothermal waters are common and occur much more frequently than high-temperature deposits. They contain water with temperatures lower than 150 °C. Their temperature normally ranges from 20 to 90 °C. Achieving a state of equilibrium depends on many factors, including the kinetics of reactions between the individual components of the system, temperature, reactivity of reservoir rock, concentration of chemical components in the water and the time the water remains in contact with the rock. Therefore, this article presents the possibility of checking the conditions of precipitation of inorganic sediments in geothermal waters with the use of PVT equipment. Tests were carried out with the use of geothermal waters under given dynamic conditions (pressure, temperature and flow). This paper confirms the suitability of using the equipment for PVT (device for the study of phase changes) testing in order to determine the conditions for the precipitation of inorganic sediments in geothermal projects. Tests on the precipitation of solid sediments in geothermal waters were carried out. A result of the research is the adaptation of the equipment for PVT testing in order to determine the conditions for the precipitation of inorganic deposits in geothermal waters. As a result, different capillary blocking times were obtained depending on the measurement conditions (e.g., for P = 40 bar, T = 120 °C and q = 1 cm3/min, the blocking start time was 10.8 min). The authors found that solid sludge inhibitors, as well as other chemicals used, including paraffin inhibitors, must be periodically adjusted to prevent precipitation in geothermal waters.

Hydrogeochemical Characteristics and Geothermometry of Hot Springs in the Tensile Tectonic Region Leizhou Peninsula and Hainan Island in South China

Hydrochemistry and isotopes are studied for characterizations of geothermal waters, groundwaters, and surface waters in Leizhou Peninsula (LZ) and the northern part of Hainan Island (HN) across the tensile-tectonic Qiongzhou Strait, southern China. Water chemistry results showed that most geothermal waters are of alkaline and HCO3-Na types, while shallow groundwater samples were significantly different with HCO3-Ca, HCO3-Mg, and HNO3-Ca types. Stable isotope data indicated that the source of LZ geothermal waters is of atmospheric precipitation, while HN geothermal water has a slight “oxygen drift”. Cation geothermometers and silica geothermometers could appropriately predict reservoir temperatures. Based on multicomponent mineral equilibria and quart geothermometer without steam loss, reservoir temperatures were estimated to be in the range of 65.0°C to 165.0°C at an average circulation depth of 2023 m, substantiated with data from a thousand-meter-depth borehole. The saturation indexes (SI) simulated by PHREEQC and Na-K-Mg triangle diagram revealed that the chemical components in the geothermal waters are possibly derived from water-rock interactions at high temperatures. Four simulation paths were established to calculate the mass flux of minerals by PHREEQC program. The hydrothermal circulation process of the volcanic rocks on both sides of the Qiongzhou Strait was similar, but the water-mineral reactions of Leizhou Peninsula were more intense. During the high-temperature hydrothermal deep circulation in the central part of Hainan Island, the molar transfer was low and the degree of mineral reaction is weak. Finally, the geothermal genetic mechanism for the study area of the extensional geostructure was proposed. The findings mark the characteristics for the tensile-tectonic region in slight “oxygen shift”, low values of 87Sr/86Sr for possible deep source from the mantle, and higher reservoir temperatures at shallower circulation depths.