This manuscript proposes the concept of Schweizer–Sklar operational laws under the consideration of the complex interval-valued intuitionistic fuzzy (CIVIF) set theory, where the Schweizer–Sklar norms are the essential and valuable modification of many norms, such as algebraic, Hamacher, and Lukasiewicz norms. Moreover, keeping the dominancy of the presented laws, we derive the concept of CIVIF Schweizer–Sklar power averaging (CIVIFSSPA), CIVIF Schweizer–Sklar power ordered averaging (CIVIFSSPOA), CIVIF Schweizer–Sklar power geometric (CIVIFSSPG), and CIVIF Schweizer–Sklar power ordered geometric (CIVIFSSPOG) operators, which are the combination of the three different structures for evaluating three different problems. Further, some reliable and feasible properties and results for derived work are also invented. Additionally, we also illustrate an application, called multi-attribute decision-making (MADM) scenario for evaluating some real-world problems with the help of discovered operators for showing the reliability and stability of the evaluated operators. Finally, we compare our mentioned operators with various prevailing operators for enhancing the worth and stability of the evaluated approaches.