Hydrogen evolution reaction (HER) in water splitting normally requires efficient and durable electrocatalysts. Herein, we demonstrate Fe-CoS2@MoS2 triangle nanowall arrays grown on carbon cloth (CC) exhibiting superior electrocatalytic performance for HER. In this strategy, CC acts as conductive substrate to generate Co-MOF and Fe is introduced through ligand exchange of [Fe(CN)6]4−, and sulfidation treatment produces the Co-Fe bimetallic disulfide (noted as Fe-CoS2) nanowall arrays, on which vertically oriented MoS2 nanosheets grow via hydrothermal reaction. The as-obtained CC@Fe-CoS2@MoS2 catalyst shows an extremely low overpotential of 68 mV to deliver 10 mA cm−2 current density (η10 = 68 mV) and high stability (24 h) in acid media (0.5 M H2SO4). The vertically growing MoS2 ultrathin nanosheets expose more catalytic active sites. Meanwhile, electron transfer from Co to Mo may result in increased electron density of MoS2 thus enhancing the conductivity. The DFT calculations reveal that the hybridization of MoS2 and Fe-CoS2 dramatically reduces the Gibbs free energy of H adsorption and speeds up HER process. All the above merits contribute to the improved HER performance. This study will provide an inspiration for the design of novel electrocatalysts via interface engineering for scalable hydrogen generation.
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